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By Samuel G. Lasky

The writer has been interested in determining the mineralogic dis-t,ribut.ion of silver in the base-metal ore of thc Ground Hog mine of the Asarco Mining Co. in the Central mining district of New Mexico.' This ore consists of a varitextured mixture of sphalerite, chalcopyrite, galena and pyrite in a quartz gangue. The average ore contains 14 per cent of zinc, 9.5 per cent of lead, 5 per cent of copper, and 10 oz. of silver per ton. Generally it is accepted that the silver in ores of this type, in which no definite silver minerals can be recognized, is contained in the base-metal minerals. Published assays of pure mineral specimens from many districts show that each of the base-metal minerals contributes in some degree to the total silver content of the ores, and to determine the proportionate amount contributed by each mineral in any specific ore it has been the practice to assay selected specimens of each mineral, the purity of which has been determined microscopically. There being no such assays available for the Ground Hog ore, and it being impracticable to have enough of them made to give average results, the writer resorted to a mathematical attack upon composite assays of large quantities of ore and concentrates. Surprising results were obtained, and it is the threefold purpose of this paper to present these results, to describe the mathematical method used, and to point out the value of using this method even when assays of pure specimens are available. Value of the Mathematical Method The obvious way of attacking the problem would be to separate cleanly large quantities of ore into its component minerals and then to determine the average silver content of each mineral by assay of representative samples. Since an absolutely clean separation is not feasible, it has been the practice, as mentioned above, to assay pure specimens of the different minerals. No one will contend seriously that the silver content of a base-metal mineral is constant throughout any particular deposit, and it will

Jan 1, 1935

By Samuel G. Lasky

The writer has been interested in determining the mineralogic dis-t,ribut.ion of silver in the base-metal ore of thc Ground Hog mine of the Asarco Mining Co. in the Central mining district of New Mexico.' This ore consists of a varitextured mixture of sphalerite, chalcopyrite, galena and pyrite in a quartz gangue. The average ore contains 14 per cent of zinc, 9.5 per cent of lead, 5 per cent of copper, and 10 oz. of silver per ton. Generally it is accepted that the silver in ores of this type, in which no definite silver minerals can be recognized, is contained in the base-metal minerals. Published assays of pure mineral specimens from many districts show that each of the base-metal minerals contributes in some degree to the total silver content of the ores, and to determine the proportionate amount contributed by each mineral in any specific ore it has been the practice to assay selected specimens of each mineral, the purity of which has been determined microscopically. There being no such assays available for the Ground Hog ore, and it being impracticable to have enough of them made to give average results, the writer resorted to a mathematical attack upon composite assays of large quantities of ore and concentrates. Surprising results were obtained, and it is the threefold purpose of this paper to present these results, to describe the mathematical method used, and to point out the value of using this method even when assays of pure specimens are available. Value of the Mathematical Method The obvious way of attacking the problem would be to separate cleanly large quantities of ore into its component minerals and then to determine the average silver content of each mineral by assay of representative samples. Since an absolutely clean separation is not feasible, it has been the practice, as mentioned above, to assay pure specimens of the different minerals. No one will contend seriously that the silver content of a base-metal mineral is constant throughout any particular deposit, and it will

Jan 1, 1935

The writer has been interested in determining the mineralogic dis-t,ribut.ion of silver in the base-metal ore of thc Ground Hog mine of the Asarco Mining Co. in the Central mining district of New Mexico.' This ore consists of a varitextured mixture of sphalerite, chalcopyrite, galena and pyrite in a quartz gangue. The average ore contains 14 per cent of zinc, 9.5 per cent of lead, 5 per cent of copper, and 10 oz. of silver per ton. Generally it is accepted that the silver in ores of this type, in which no definite silver minerals can be recognized, is contained in the base-metal minerals. Published assays of pure mineral specimens from many districts show that each of the base-metal minerals contributes in some degree to the total silver content of the ores, and to determine the proportionate amount contributed by each mineral in any specific ore it has been the practice to assay selected specimens of each mineral, the purity of which has been determined microscopically. There being no such assays available for the Ground Hog ore, and it being impracticable to have enough of them made to give average results, the writer resorted to a mathematical attack upon composite assays of large quantities of ore and concentrates. Surprising results were obtained, and it is the threefold purpose of this paper to present these results, to describe the mathematical method used, and to point out the value of using this method even when assays of pure specimens are available. Value of the Mathematical Method The obvious way of attacking the problem would be to separate cleanly large quantities of ore into its component minerals and then to determine the average silver content of each mineral by assay of representative samples. Since an absolutely clean separation is not feasible, it has been the practice, as mentioned above, to assay pure specimens of the different minerals. No one will contend seriously that the silver content of a base-metal mineral is constant throughout any particular deposit, and it will

Jan 1, 1935

By Samuel G. Lasky

The writer has been interested in determining the mineralogic dis-t,ribut.ion of silver in the base-metal ore of thc Ground Hog mine of the Asarco Mining Co. in the Central mining district of New Mexico.' This ore consists of a varitextured mixture of sphalerite, chalcopyrite, galena and pyrite in a quartz gangue. The average ore contains 14 per cent of zinc, 9.5 per cent of lead, 5 per cent of copper, and 10 oz. of silver per ton. Generally it is accepted that the silver in ores of this type, in which no definite silver minerals can be recognized, is contained in the base-metal minerals. Published assays of pure mineral specimens from many districts show that each of the base-metal minerals contributes in some degree to the total silver content of the ores, and to determine the proportionate amount contributed by each mineral in any specific ore it has been the practice to assay selected specimens of each mineral, the purity of which has been determined microscopically. There being no such assays available for the Ground Hog ore, and it being impracticable to have enough of them made to give average results, the writer resorted to a mathematical attack upon composite assays of large quantities of ore and concentrates. Surprising results were obtained, and it is the threefold purpose of this paper to present these results, to describe the mathematical method used, and to point out the value of using this method even when assays of pure specimens are available. Value of the Mathematical Method The obvious way of attacking the problem would be to separate cleanly large quantities of ore into its component minerals and then to determine the average silver content of each mineral by assay of representative samples. Since an absolutely clean separation is not feasible, it has been the practice, as mentioned above, to assay pure specimens of the different minerals. No one will contend seriously that the silver content of a base-metal mineral is constant throughout any particular deposit, and it will

Jan 1, 1935

Established as a Division March 24, 1922 John R McMillan, '56, Chairman Claude R Hocott, '55, Past Chairman Thomas C Frick, '56, Vice-Chairman D W Akins, '57, Vice-Chairman Joe B Alford, Executive Secretary 800 Fidelity Union Building Dallas 1, Texas T A Pollard, Treasurer

Jan 1, 1954

By J. J. Jonas, J. L. Uvira

Equipment was constructed which permitted the hot compression of 99.8 pct Armco iron and 2.8 pct Si steel at constant true strain rates of 0.05 to 1 per sec over the temperature range 600" to 1000°C. A maximum true strain of 1.9 could be attained, followed by immediate quenching or by isothermal annealing. True stress-true strain curves were obtained, and the steady-state flout stress, a, strain rate, i, and temperature, T, were found to fit the following expression: The constants A, a, n', and AH were determined for the two ,materials. The activation energies obtained for Arrnco iron and silicon steel are 66 and 80 kcal per mole, respectively, and approximate those for seu- diffusion and for creep. This indicates that hot compression is a diffusion-controlled thermally activated process. THE hot compression of iron and steel is usually carried out in the austenite temperature range,1"7 as this is the one of greatest interest with respect to industrial hot working. However, a disadvantage of testing in the austenite range is that the hot-worked structure is destroyed by the phase transformations taking place during cooling. The present study was therefore carried out in the ferritic temperature range, and the hot-worked substructures were preserved by rapid quenching after deformation. The substructural results will be described in a separate paper, and the present communication is restricted to the strain rate/stress/temperature relationship observed during hot working. The results of hot-compression testing are usually given in the form of true stress/true strain curves, with a different curve for each temperature/strain rate ~ornbination.',~,~ Sometimes simple algebraic equations are fitted to the curves, so that certain extrapolations or interpolations can be performed.1'2'5 These equations are, however, devoid of mechanistic interpretations. The present study was undertaken to show that hot compression can be described by an equation of the type used in creep studies. That is, it will be shown that the temperature dependence of the strain rate in hot working is well-represented by an Arrhenius term, with an activation energy similar to that for creep. Also it will be seen that the stress dependence of the strain rate is similar to that for creep EXPERIMENTAL METHOD AND MATERIALS The investigation was carried out with the following three ferrous materials: 1) Armco iron; 2) Armco iron with 0.26 pct Mn; 3) 2.8 pct Si steel. The first two materials were utilized for investigations performed in the temperature range 600" to 800°C; the last one was used for tests at temperatures from 600" to 1000°C. The materials were of commercial purity,* as shown in Table I. Cylinders of five different sizes were prepared by strain annealing. The resulting mean grain diameter was 3 mm in the 1-in. Armco iron and 2 mm in the other sizes and grades. Different ratios of diameter/height were used to enable the determination of the coefficient of friction. The specimen faces were provided with concentric grooves, which acted as lubricant holders during compression, as recommended by English and ~ackofen' and others.2'9 Powdered glass lubricants were applied to the samples before hot compression to decrease friction and barreling, following the practice of previous investigator~.~~~~~~~~ Different mixtures of glass powder were used for each temperature, after the determination of suitable compositions by experiment.'' Equipment for Hot Compression. Hot-compression tests were carried out on an adapted 150-ton vertical hydraulic extrusion press and also on a modified high-temperature creep machine. The modified extrusion press was used for temperatures up to 800°C. The following items were added to the press: a) a high-temperature furnace with built-in upper and lower platens; and b) a transmission assembly, which permitted the attainment of logarithmically decreasing crosshead speeds. These accessories are described in detail in Ref. 11.

Jan 1, 1969

By R. G. Ward

The temperature gradient in the subhearth metal or "salamandern of the iron bhst furnace results in the establishment of gradients in the concentrations of silicon, manganese, carbon, and sulfur. The temperature and compositional variations observed in three blast furnaces are analyzed according to irreversible thermodynamics and the systems appear to be close to the steady state condition. Apparent heats of transport, Q, for silicon, manganese, carbon, and sulfur are found to be respectively -17.5, -5, -2.1, and+22k cal per g mol. In conclusion the significance of thermal diffusion in extraction metallurgy is briefly discussed. INCREASING interest has been shown in recent years in the application of irreversible thermodynamics to metallurgical problems. In particular studies have been made of the transport of matter in thermal gradients1-' and under chemical gradients imposed by a binary solvent However, no detailed example in extraction metallurgy has been reported although gradients are the essence of many extractive processes. The case of the distribution of elements in molten blast furnace iron under a thermal gradient is discussed here. DATA In blast furnace operation the hearth bottom is often extensively destroyed by molten metal, and the metal may penetrate perhaps 10 ft into the furnace foundations forming a "bear" or "salamander". Several hundred tons of molten metal may thus exist beneath the level of the conventional tap hole and remain relatively undisturbed for several years under a thermal gradient. This system is subject to little convective stirring because the temperature decreases from top to bottom, and mechanical stirring due to movements in the stack and to tapping operations is unlikely to penetrate far into the metal. The system may thus be regarded as static

Jan 1, 1963

By Paul J. Fopiano

SOME relationships between the flow characteristics of iron single crystals of 99.9 pct purity and the behavior of imperfections have been investigated. X-ray rocking-curve measurements and etch-pit counts were made as a function of plastic strain, and compared to the stress-strain curve obtained on a modified Polyani tensile machine. Crystals grown from rolled strips of vacuum-melted iron by the strain-anneal method1 had a high preference for a (110) longitudinal direction and a (211) face normal. The tensile specimens were prepared from 2 by i by 0.040 in. single crystals having a gage area of 3 by \ in. Rocking-curve measurements were carried out with a highly perfect germanium monochromating crystal in which the dazz spacing was matched to that of the dZl1 in the ir0n.l Well-collimated CuKal radiation was used throughout. These procedures practically eliminated errors due to geometrical and wavelength resolution. Inasmuch as the rocking-curve half breadth may vary markedly from point to point in the specimen being irradiated, the crystals were strained in place by mounting a hydraulic loading device on the double-crystal spectrometer. The rocking curves were taken after each increment of strain in the unloaded condition, since no observable difference was found in the rocking-curves between the loaded and unloaded states. The rocking-curve half breadths of the as-grown specimens were in the range 90 to 120 sec of arc when the beam irradiated an area of about -£ by -& in. on the specimen. DeMarco and weiss3 have shown that, for a well-colli- mated X-ray beam, irradiating about 10"! sq in. of the very same material, half breadths within 10 pct of the Darwin natural half breadth were observed. Since the rocking-curve specimens were stressed by the load-unload technique, the strain achieved at any given stress depended on the time of holding because of low-temperature creep. Fig. 1 shows the rocking-curve half breadth (also area/peak height) as a function of plastic strain for a relatively short holding time (2 to 5 min) at each stress level. For strains less than 0.1 pct the rocking-curve breadth is essentially constant; it is only for larger strains that there occurs a significant increase in this breadth. Where the holding times at each stress level were longer (by well over an order of magnitude) there occurs a significant increase in the rocking-curve breadth only after plastic strains of the order of 0.6 pct had been introduced into the specimen. This observation is related to the time dependence of creep phenomena and emphasizes the difficulty in comparing data obtained by two such different straining methods. Etch-pit results were obtained using a 2 pct nital etch on specimens strained in the range of 0 to 1 pct. Prior to etching, all specimens were annealed for 3 hr at 150°C, the carbon content being sufficient to decorate the dislocations for strains of at least 1 p~t.~ The data points were all taken from parts of the same single crystal which had been strained with short holding times at stress in increments of strain of the order of tenths of 1 pct. The (211) plane is particularly difficult to etch-pit in vacuum-melted iron and therefore it is felt that these values are as much as an order of magnitude low. Fig. 2 shows the etch-pit density as a function of plastic strain. The smooth curve passing through the data points is not meant to infer a quantitative correlation with the rocking-curve data. What is of interest, however, is the change in etch-pit density in the region of 0.2 pct plastic strain. The first three increments in strain (points 2,3, and 4) did not produce a measurable change in the etch-pit density while subsequent increments did produce a measurable change. While the absolute values of these results do not appear to be cor-

Jan 1, 1967

By D. A. Elgillani, S. Atak, D. A. Rice, M. C. Fuerstenau, R. B. Bhappu

Quartz and feldspar cannot be floated with sulfonate at any pH; spodumene floats over a narrow acid pH range, while beryl responds moderately over a broad pH range. After wet-grinding in a steel mill, beryl, quartz, and spodumene float well with sulfonate below about pH 7, whereas the improvement in the response of feldspar is not so marked. A mechanism by which iron can be adsorbed on these minerals is presented. Also, the responses of leached, natural, and wet-ground beryl to amine, sulfonate, and oleate flotation are shown and related to the measured zero-points-of-charge of these materials. Earlier work with leached beryl showed that good flotation could be obtained with alkyl aryl sulfonate over a rather wide pH range using a Fagergren flotation cell.' When a similar response was observed with leached quartz, it was decided that unintentional activation was being obtained from the metallic components of the Fagergren cell. To obviate this difficulty, a microflotation cell was designed, and an experimental technique was devised. These have been described elsewhere. Experiments conducted with the small cell showed that leached quartz could not be floated at any pH with any sulfonate addition,3 which is in agreement with the observations of Kraeber and Boppel.4 Similarly, it was also found that leached beryl responded to sulfonate flotation only over a narrow pH range rather than the broad range reported earlier.1 This early work,1 however, revealed the important effect that wet-grinding in a steel mill has on the flotation response of certain silicates. That is, it was found that quartz and especially beryl floated well over an unusually wide pH range after wet-grinding in a steel mill. Microcline, however, floated poorly below pH 4, even though wet-ground under the same conditions. The work of Eigeles6 on adsorption of oleic acid on leached quartz and iron-contaminated quartz at constant pH is in agreement with these flotation data. Other research has shown that ferric iron, added as a salt to the system, functions as an activator in the narrow pH range in which Fe +++ iron hydrolyzes to its hydroxy complexes.3,5 These phenomena indicate that iron functions differently in flotation systems depending on its method of introduction. The object of this paper is to determine the mechanism by which iron is adsorbed on certain minerals, the mechanism of collector adsorption after iron abstraction, and the role that Fe++ and Fe+++ assume in the selective separation of these minerals. EXPERIMENTAL MATERIALS AND METHODS Sodium alkyl aryl sulfonate, mol wt 450,7 pure potassium oleate, and pure dodecylamine were used as collectors. All other chemicals were reagent grade in quality, i.e., n-amyl alcohol as frother; HC1, H2SO4, and KOH for pH adjustment; and ferric chloride as activator. Conductivity water, made by passing distilled water through an ion exchange column, was used in the experimental work. All minerals used in the investigation were hand-picked specimens. Sample Preparation: Each of the minerals was crushed through 8 mesh, and the product was divided into two groups, one to be ground dry and the other wet. Dry grinding was accomplished with an alumina mortar and pestle. The product was dry-screened to 48 x 150 mesh, cleaned magnetically, deslimed in conductivity water, and dried. Preparation of the samples by wet-grinding involved grinding a 200-g charge of the mineral (-8 mesh) at 60% solids with natural water in a mild steel rod mill for four minutes. This charge was then wet-screened immediately with natural water to 48 x 150 mesh, dried, and cleaned magnetically. Some experiments were also conducted with leached beryl and quartz. These products were prepared by leaching the sized sample (48 x 150 mesh) with concentrated HC1 with a percolation technique until no iron could be detected in the leach liquor. Following this step, the sample was rinsed with conductivity

Jan 1, 1967

By L. V. Pirela, S. M. Farouq Ali

Some interest has been expressed recently in the application of solvents in conjunction with a thermal drive, such as a steamflood. At least one field project of this type has been reported. This paper makes the first attempt to provide some of the basic information necessary for choosing a solvent for such an application. Results of displacements conducted at elevated temperatures are also discussed. This paper shows that, in the case of alcohol-hydrocarbon-water or brine ternary systems, the system miscibility may increase, decrease, or both increase and decrease within the same system when the temperature increases. The distribution coefficient was consistently found to increase in favor of the oleic phase with an increase in temperature, which is advantageous from the standpoint of oil recovery. Results of solvent displacements in a sandstone core showed that even a relatively small temperature effect in the favorable direction (increase in miscibility and distribution coefficient) can lead to a 50 percent increase in oil recovery. On the other hand, if the system miscibility decreases with the temperature, even though the distribution coefficient increases, the oil recovery at the higher temperature may not increase. INTRODUCTION Miscible displacement has been the subject of many investigations. Miscible-phase solvent flooding, employing solvents such as alcohols that are miscible with both oil and water, has received considerable attention. Investigations conducted by Gatlin and Slobod,l Taber, Kamath and Reed,2 Holm and Csaszar,3 and Farouq Ali and Stah14 have helped in understanding the mechanism of solvent flooding. While the use of alcohols and similar solvents as oil recovery agents is economically unattractive, these solvents nevertheless provide a means of understanding the mechanistic aspects of important miscible-phase oil recovery processes such as the Maraflood process (discussed by Gogarty5). As shown by Taber et a1.,2 the phase behavior of a solvent-oil-water system is of .utmost importance in determining the efficiency of the oil displacement. This paper makes the first attempt to obtain the ternary phase behavior data for nine alcohol-hydrocarbon-water/brine systems at elevated temperatures. Results of core tests at elevated temperatures are also presented which corroborate the effect of temperature on oil recovery, as judged on the basis of phase-behavior data. The use of solvents at elevated temperatures has been suggested earlier by Farouq Ali.6 At least one field test of this type has been reportedO7 With the widespread use of thermal recovery techniques, it is possible in some situations (especially in steamflooding) that the use of a suitable solvent in conjunction with the heat carrier may be economically feasible. This paper attempts to provide some of the basic information needed for judging such feasibility. LOCATION OF THE PLAIT POINT The phase behavior of a typical ternary system consisting of a solvent, hydrocarbon and brine (or water) can be represented by a triangular diagram such as the one shown in Fig. 1 (for temperature TI). Point Pon the binodal curve represents the plait point, being the limit of tie lines such as Y1 Y2 The compositions of the coexisting oleic and aqueous phases are given by points Y2 and Y1, respectively, for any mixture composition along Y1Y2. The characteristics of ternary diagrams have been discussed by Findlay8 and others. Taber et aL3 have shown that the position of the plait point in a particular ternary system plays the decisive role in determining whether or not theoleic phase would be displaced in a continuous manner during an alcohol displacement. The area above the binodal curve also is important, since it represents

Jan 1, 1969

By Samuel G. Lasky

What the evidence prevails upon the mind to believe, depends upon the mind as well as upon the evidence. M. L. IN a recent discussion of the mineral resource position of the United States, published in the September 1946 issue of MINING AND METALLURGY, I expressed my conviction that ore deposits of major magnitude remain to be found in this country and that they can be found without undue cost or risk. I stated with equally strong conviction, however, that if the search for such deposits is to be notably successful there must be, among other things, a reorientation of philosophy and mental habits on the part of many who would be connected with the search. I would now like to enlarge upon that statement. For such a purpose, we may consider that the search for concealed deposits involves four steps: (I) the selection of areas for further study; (2) the geologic study of those areas in order to verify their general favorableness and in order to choose specific patches worthy of being tested; (3) the decision whether exploration of the patches chosen should actually be undertaken; and (4) the exploration itself. The first two steps and the last rest upon the judgment and skill of geologists. The third step-the decision whether exploration should be undertaken-rests upon management. In my opinion, the philosophies or principles that have guided these steps in the past are now inadequate. PHILOSOPHY OF APPRAISAL If concealed deposits are to be looked for, how are the places of their possible concealment to be recognized? Every known mineralized area still in the prospect stage has already been repeatedly examined and condemned. As for those deposits concealed under later rocks, there may be not even the clue of a near-by outcrop for engineer or geologist to consider. How then, are we to know where to look? Geologic Probability In the early days of our mining industry, ore deposits were found mainly by "following the ore." Later, as such opportunities decreased, and as geologic concepts became accepted, deposits were found more and more through use of the notion of geologic probability. Many instances can be cited wherein a courageous operator ignored the implications of the unsuccessful efforts of predecessors and, solely by "following the ore," converted a discredited prospect into a good mine. Similar experience doubtless will occur in the future, but "following the ore" will no longer in itself find new deposits in the amount needed. Nor can enough new ore be expected from further use of the notion of geologic probability, for, as mentioned above, our known prospects `have already been ex-

Jan 1, 1947

Mining Methods GERALD F. SHERMAN, Chairman JOHN A. CHURCH, Vice-chaiman CHARLES W. WRIGHT, Secretary Alluvial Mining CLINTON BERNARD CHARLES JANIN H.R. NORSWORTHY Open-cut Mining Iron MAX H. BARBER J. A. MACKILLICAN Copper MICHAEL CURLEY R.B. TEMPEST Underground Mining Iron C. H. BAXTER TENNEY C. DESOLLAR

Jan 1, 1934

By Dr. O’Neil Thomas J., Donald W. Gentry

"There are two characters to the value of mining properties-one mine may have a value, owing to its real intrinsic worth; an- other (having no intrinsic value) may have a value by being so situated as to harass the working of the really valuable mine-in mining camps one is looked upon as much of ligitimate enterprise as the other.'' -Victor Clement to Simeon Reed, Wardner, Jan. 11, 1890, Reed Mss. APPROACHES TO VALUATION Value and costs are two terms basic to financial analysis which cause, perhaps, the greatest amount of misunderstanding in mine valuation studies. When discussing the value of an asset or the costs of producing a product, it is absolutely essential that the speaker define the terms being used. There are many types of value and many categories of costs. Without specific accompanying definitions, value and cost data are not very meaningful. Value refers to a measure of the desirability of ownership of property. Some of the types of value which might be encountered in a mine valuation study are: 1) Market value 2) Full cash value 3) Salvage value 4) Replacement value 5) Capitalized value 6) Book value 7) Assessed value 8) Insured value Each of these has a specific meaning which can be applied to determine a monetary amount in a specific situation. The major item of interest here is the broader question of "what is the value of the mine?" or "what is the mine worth?" In this case, we are speaking of market value. Market value is the value (price) established in a public market by ex- changes between a willing buyer and a willing seller when neither is under duress to complete the transaction. Market value fluctuates with the degree of willingness of the buyer and seller and with the conditions of the sale. The use of the term market suggests the idea of barter. When numerous sales occur on a market, the

Jan 1, 1984

By D. A. Dahlstrom

Although the liquid-solid cyclone is a relatively recent innovation in the field of coal preparation, various authors have already indicated three distinct applications to operations encountered in the modern tipple. Driessen's articles and work at the Dutch State Mines exhibited its possibilities in the bene-ficiation of fine coal with apparently high efficiencies down to the 200-mesh fraction. l,2,3,4 Other publications point out its use as a recoverer, thickener, and preliminary dewatering agent of fine coal which in too many cases is being wasted due largely to former high operating cost limitations.M Finally, certain authors have emphasized the practicability of applying the cyclone to the elimination of coarse and fine solids from water slurries in the tipple in order to produce a water suitable for recycle purposes containing only minute particles far below the 200-mesh size.6 This would result in a closed water system for many cases, with its accompanying economic and operating advantages to locations where water quantity and quality problems are severe; better operation of washing equipment using a consistent water devoid of injurious fine particles; lowered maintenance costs due to the lesser abrasion resulting when the fine abraiding particles are removed; and the greater ease of disposing of refuse streams of reduced volume containing greater percentages of solids. While the three applications have been indicated to be feasible, only a meager amount of data is available on capacities and solid elimination eficiency as a function of design variables and cyclone friction loss. This information is essential for the optimum use and construction of the solid-liquid cyclone, and accordingly, work on the problem was initiated at Northwestern University. For the unfamiliar reader, briefly the cyclone consists of a cylindrical section mounted above a truncated cone. The feed nozzle enters the cylindrical ring tangentially with the underflow nozzle permitting discharge of the concentrated solids located at the apex of the cone. The overflow nozzle through which the clarified water exits is centered in the cylindrical section at the top of the cyclone. Half sections of experimental cyclones will be found in Fig la and 6. The feed slurry enters with a tangential velocity, thus creating a spiral pattern of high centrifugal force. The solid particles of sufficient size and gravity are ejected outward to the walls and spirally discharge to the underflow. Most of the water with uneliminated fine solids moves radially inward along the path of the outer

Jan 1, 1950

By A. H. Jones

(San Francisco Meeting, September, 1915). THE Belmont mill at Tonopah, Nev., was designed and constructed by the Belmont staff. Ground was broken in August, 1911, and milling operation started July 25, 1912. The metallurgical flow sheet, and the machinery adapted to carrying out operations in accordance with this plan, were decided upon from experience gained in the treatment of Belmont mine ores at the old Belmont mill at Millers, Nev. The detail drawings were made by the-engineering staff of the Tonopah-Belmont Development Co., under the supervision of Otto Wartenweiler, who also .had direct charge of the construction, consulting with the General Superintendent of the company, Frederick Bradshaw, and the writer.

Jan 8, 1915

By A. H. Lee

Discussion of the paper of H. P. HOWLAND, printed in Bulletin No. 111, March, 1916, pp. 627 to 650. A. H. LEE, Buffalo, N. Y. (communication to the Secretary*). The statements and results recorded in Mr. Howland's paper can be accounted for by the use of coke with a low sulphur content (0.60 and under). This allows the furnaces to be run on a small volume of acid slag, which it is presumed was done in Mr. Howland's practice. H. A. Brassert has admitted that this was the largest factor in low fuel consumption in his practice. Where the coke contains from 1.00 to 1.25 per cent. of sulphur the situation is quite different and I doubt whether the results mentioned by Mr. Howland could be obtained under such circumstances. ` N. M. LANGDON, Mancelona, Mich. (communication to the Secretary + ).-Gruner's ideal working (which is but a statement of the law first enunciated by Bell) as given in Gordon's Translation of Studies of Blast Furnace Phenomena, "supposes that the reduction of the oxide of iron is effected by the CO only, without intervention of solid carbon." This ideal, if reached, would mean theoretically perfect or 100 per cent. efficiency of reduction. The workings of the large number of furnaces as given in Bell's and Gruner's great works do not show that this standard of perfection ever was reached. This problem has been worked out by the writer for a number of furnaces, and his results, as well as those given by others, all show a failure to reach perfection. Some furnaces, however, approach nearer to perfection than others. The "ideal" as given by Gruner was not stated as a solved problem in blast-furnace practice, but as an ideal to the attainment of which furnace managers should strive. A study of the factors involved from every angle is interesting and instructive and the paper on this subject contributed by H. P. Howland is no exception to the rule. This article is fairly open to criticism, not because of the unique method of presenting the subject, but for the reason that, as the writer conceives, erroneous assumptions are taken which lead naturally to incorrect conclusions.

Jan 7, 1916

By G. R. Speich

The age-hardening of Fe-18 to 21 pct Ni marten-sites containing small amounts of titanium, aluminum, copper, or molybdenum has been studied by hardness measurements, transmission electron microscopy, extraction replicas, and X-ray and electron diffraction. Electyon-probe microanaly-sis of the extracted precipitates was also performed. The effects of temperature and composition on the aging kinetics have been studied in detail for Fe-20 pctNi-Ti martensites. All the martensites hardened on aging at 400" to 500 "C with a single aging peak. In the Fe-20 pct Ni-Ti martensites hardening was associated with the formation of a fine dispersion of NisTi. No precipitation was observed in an Fe-21 pct Ni-2.6 pct A1 alloy, although the hardness increased from 327 to 545 Dph during aging at 500°C. Copper was precgitated from an Fe-20 pct Ni-10.7pct Cu alloy, at least during the later stages of age-hardening. Hardening in an Fe-18 pctNi-5pct Mo alloy was associated with the precipitation of an intemzetallic compound tentatively identified as NisMo. The formation of austenite and the recovery of the defect structure of the martensite occur simultaneously with the normal precipitation processes &ring aging of these alloys. THE age-hardening of substitutional iron-base martensites is an important subject for study since age-hardening is one of the principal means of strengthening the substitutional iron-base martensites in precipitation-hardening stainless steels1 and maraging steels.a~4 In contrast to Fe-C martensites, these martensites are relatively soft and ductile in the as-quenched condition, due to the low solid-solution hardening effect of the substitutional elements as compared to carbon. Also, these martensites are hardened by aging at low temperatures in contrast to Fe-C martensites which generally soften on tempering. Titanium and aluminum, singly or in combination, as well as copper and molybdenum, have been the principal alloying additions to stainless steels to obtain an age-hardening reaction.' Ti-A1 or Co-Mo-Ti combinations have been used in the case of maraging steels.3"4 The present work has been confined to a study of the age-hardening characteristics of an Fe-18 to 21 pct Ni martensite to which small amounts of titanium, aluminum, copper, and molybdenum were added in order to study the effects of each alloying element separately. The age-hardening characteristics of these alloys were studied by hardness measurements, transmission electron microscopy, extraction replicas, and X-ray and electron diffraction. Electron-probe micro-analysis of the extracted precipitates was also performed. The types and dispersion of precipitates, the formation of austenite, and the recovery of the defect structure of the martensite all were studied. EXPERIMENTAL PROCEDURE Alloys. The compositions of the alloys studied are listed in Table I. The level of 18 to 21 pct Ni was chosen to assure complete transformation to martensite on quenching and is the same nickel level used in maraging steels. The concentrations of titanium, aluminum, copper, and molybdenum were chosen after a study of the and Fe-Ni-MO' ternary diagrams indicated how much of each alloying element could be dissolved in austenite. Alloys with 2 and 4 pct Cu were also studied, but these did not show precipitation hardening at the nickel levels studied and will not be discussed further. The alloys were prepared from electrolytic iron and high-purity* nickel, titanium, aluminum, copper, and molybdenum by vacuum melting of 20-lb heats. These were vacuum-cast into two 8-lb ingots. The ingots were hot-rolled at 1100°C to 1/2-in. plate and subsequently cut into 3/8-in. cubes. The cubes were sealed in evacuated quartz capsules and solution-treated for 16 hr at 1100°C, except for the Fe-20 pct Ni-10.7 pct Cu alloy and Fe-21 pct Ni-2.6 pct A1 alloys which were solution-treated for 16 hr at 1300" and at 1250"C, respectively. Metallographic examina-

Jan 1, 1963

By John A. Prof. Church

ONE of the most striking phenomena connected with the mines on the Comstock lode is the extreme heat encountered in the lower levels. This heat is not due to the burning of candles, heat of the men, and decomposition of timbers, all intensified by bad ventilation, as was the case nearer the surface. It proceeds from the rock, which maintains constantly a temperature very much higher than the average of the atmosphere in Nevada. The heat of these mines is a matter of more than usual interest, for they are the only hot ones now worked in the United States, and both in the present temperature encountered and in the increase which is to be expected as greater depths are reached, they appear to surpass any foreign mines of which we have a record. Hot mines are known also in other countries, as in the tin and copper lodes of Wales, where one of the veins worked by the United Mines is known as the hot lode. It has springs which discharge water at a temperature of 116° Fahrenheit, the depth being 220 fathoms, or 1320 feet. The heat of the air in these workings is given at 100° to 113° Fahrenheit. The air is bad, and the heat in the drifts seems to be traceable to defective ventilation rather than to the real necessities of the case. Air is supplied through a small pipe, and is drawn from a place where the temperature is 95° Fahrenheit. Under such circumstances it is not surprising to read that in this hot mine the air is hotter than the rock, a state of things which I have never observed in the Comstock. Other mines have been reported to the British Coal Committee as having temperatures of 106° Fahrenheit and thereabouts, but the only positive comparisons that are available at this writing are the following, all from Cornish mines * Read by permission of Lieut. Geo. M. Wheeler, Corps of Enginerrs, U. S. Arm J, in charge of U. S. Geographical and Geological Surveys, west of the 100th meridian.

Jan 1, 1879

By W. F. Hosford

W. F. Hosford, (Massachusetts Institute of Technology) —evelopment of methods for predicting the plastic anisotropy of textured metals is an important step toward the improvement of properties by texture control. The engineering value of the present analysis is indicated by the good agreement between prediction and experimental findings. The purpose of this discussion, however, is to point out the weakness of the assumptions on which the analysis is based. The authors state that "the relative width and thickness strains are believed to depend only on the slip direction" and accordingly they disregard the orientation of the active slip plane. where E,, cW, and et are the tensile, width, and thickness strains, A,, A,, and At are the angles between the tensile axis x, the width direction w, and the thickness direction t, respectively; and G,, GW, and 4 are the angles between the slip-plane normal and x, w, and t, respectively. Therefore, the ratio of width to thickness strains resulting from slip on a single system would be These relations hold regardless of whether the slip plane is a crystallographic plane of the {110}, (1121, or (123) type or whether noncrystallographic slip occurs. If noncrystallographic slip occurs, it might be reasonable to assume that the effective slip plane is the most highly stressed plane containing the slip direction. In this case the slip direction, S.D., the slip plane normal, S.P.N., and the tensile axis, x, are coplanar (Fig. 19) and the angles are related by following expressions: where 9 is the angle between t and the projection of the slip direction in the w-t plane (igs. 1 and 2). The normal strains, Eq. [9], become

Jan 1, 1963

By T. H. Troller

FOR a long time propeller-type fans have been considered a very adequate means to move great quantities of air against small static pres-sures. They have been in use for this purpose in mines, as well as in other installations. For static pressures of over 2 or 3 in. of water, the centrifugal blower almost ruled the field until very recently. Some attempts were made to use a number of propellers in line. Such arrange-ments made it possible to obtain pressures higher than 2 in. of water, but they complicated the construction and increased its expense, and the efficiencies were not improved. The more recent development of propeller-type fans has been decidedly influenced by the intensive aerodynamic research in connection with aeronautical development, which has taught us, in particular, how to use airfoils properly. The characteristic that makes an airfoil so valuable is the fact that when it moves through the air a high force component, the "lift," acts on it vertical to the motion, while the "drag" in the direction of the flow is small. The ratio of lift to drag is approximately 20 to 1 at the angles at which the profile is used in practice. An element of the turning blade, the movement of which, relative to the air, is mainly in the direction of the plane of rotation, thus experiences only a small "drag" FIG. 1.-DIAGRAM OF FORCES ON WING SECTION. opposing its rotation, and for this reason a relatively small torque is required at the driving shaft. At the same time there is a strong force component at 90° to the plane of rotation. This force is parallel to the propeller axis in the direction opposite to that of the flow of air, with a correspondingly high pressure increase.

Jan 1, 1936