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By L. Tafaghodi, S. Sarbishei

"Following the depletion of nickel sulfide ores, laterites are considered as one of the main sources for producing nickel and cobalt. One of the primary steps in pyrometallurgical extraction of nickel from laterites involves partial reduction of the ore at temperatures below 1000°C. Studying the kinetics of laterite reduction provides valuable information on reducibility of nickel laterites using coal as a reductant. The present study investigates the reduction behavior of a nickel laterite by thermal gravimetric analysis and differential scanning calorimetry. Non-isothermal reduction tests and X-ray diffraction analysis were performed to find the main reactions that occur during the process. The kinetic parameters were calculated by Coats-Redfern method. The general model of simple reaction f(a)=(1-a)n was used for calculating kinetic parameters.INTRODUCTION Nickel (Ni) naturally occurs in the form of sulfide and laterite ores. Laterite ores are mainly available in tropical regions. Weathering phenomena during millions of years has led to the formation of several layers with specific mineralogy (Butt & Cluzel, 2013). The three main layers downward are limonite, smectite, and saprolite (Crundwell et al., 2011). Although laterites are the most available nickel ore resource (70%), their share in the overall Ni production is limited to 40% (Crundwell et al., 2011). The main reasons for not materializing the full potential of laterites are as follows (Ray et al., 1985): •,Laterite ores contain high water content (free and combined) which in turn results in high energy consumption of the extraction process. •,As Ni is present in the form of solid solution in laterites, physical upgrading methods such as flotation are not effective in increasing the Ni content before the extraction process. •,Extracting Ni from sulfide ores involve exothermic reactions which are beneficial due to decreasing the overall energy requirement of the process, however there is not efficient release of energy in the process of extracting Ni from laterite ores."

Jan 1, 2017

By V. G. Papangelakis, M. Cheung, M. Dry

The high pressure acid leaching of laterite was modelled and simulated using a combination of two commercially available software packages, namely Aspen Plus 11.1 and the OLI Stream Analyzer. New kinetic parameters for the acid-controlled metal dissolution and precipitation reactions at temperature were first determined from previous experimental data on the leaching of limonite. A grain model with cylindrical pellets was used to model the solid-liquid dissolution reactions. Precipitation reactions were modeled via aqueous equilibrium chemistry. A dedicated thermodynamic database previously developed at the University of Toronto was used in conjunction with the OLI software to model the solution chemistry and calculate the concentration of hydrogen ions in solution at the leaching temperature. Mass balances were handled by Aspen Plus. The simulation gave good predictions of nickel dissolution under industrial and laboratory conditions, for the dissolution of limonite and limonite/saprolite blends. Computational

Jan 1, 2005

By S. A. Willis

For over 150 years gypsum from Nova Scotia has been shipped via water to the United States east coast. The history of the movement has been one of continual improvements in quarrying, loading, and shipping. At the start, man-size rock quarried by hand auger and black powder was loaded into horse-drawn carts, hauled to the waterfront, and dumped into 100-ton sailing schooners. Last year the Canadian Gypsum Company completed the latest and most modern of these successive installations for the movement of this Nova Scotia product. The new system loads crushed gypsum into 11,600-ton vessels at Hantsport in two hours' time at high tide. At the head of the bay of Fundy are located vast deposits of gypsum. The tidal rise and fall of 45 feet twice a day, with its attendant swift currents, has always presented major navigation and shipping problems. When the tide is low, the Hantsport ship-loading pier is high and dry, with no water within 400 feet. Three hours later a large river has flooded in (running up hill) and large steamers can dock at the wharf. Before high water, the ship has been loaded and -there is a depth of 30 feet or more of water around the wharf. At high water, the ship sails away on the ebbing tide as the river runs in the other direction. Tides are caused by the gravitational attraction of the moon and sun on the ocean. When both celestial bodies are pulling together the 'spring tide' results, which means a 50-foot variation from high to low. This occurs at new and full moon. A week later, when the sun and moon work in opposition, the difference is only 32 feet between high and low water. The bay of Fundy, having a funnel shape (150 miles wide at mouth from Yarmouth to Portland, while the upper estuary at Hantsport is only one mile wide), builds up a tidal influence from 10 feet at the mouth to an average of 45 feet at Hantsport.

Jan 1, 1948

By J. J. Denny

IN November, 1932, an investigation of silicosis was undertaken at the Mcintyre Porcupine mine, Schumacher, Ont., after a discussion of the p"roblem with Sir Frederick Banting and his staff. As a result, it was decided to carry on dusting experiments with animals at the mine in a manner that would duplicate as far as possible actual industrial conditions. At that time 50 guinea pigs were placed in the crusher house tunnel of the mill where a considerable quantity of fine dust, containing approximately 35 per cent of free silica, was being constantly produced. These animals lived in this atmosphere for periods up to one year, and, while on autopsy large amounts of dust were found in the lungs, not a single case of silicosis had developed. These negative results suggested, among other things, that the mine gases might be a predisposing factor in the production of silicosis, and the results of this investigation (1) led us to undertake the study of the hydrogen-ion concentration of the condensate of the atmosphere, both in the mine and in various sections of the mill. The CO, combining power of blood serum on a series of 400 miners was also studied at this time. While these results were inconclusive, the variation in the hydrogen-ion concentration of the condensate between the surface and underground atmospheres encouraged us to investigate the effect of neutral, weak acid, and alkaline solutions on the solubility of siliceous materials. Gye and Purdy (2) were the first to point out that the chemical reaction, and not the physical presence of siliceous material, was responsible for the production of the fibrosis in silicosis. This work was investigated by Gardner and Cummings (3), who showed that the tissue reaction to quartz was definitely proportional to the size of the particle. They found that 1-3 micron particles of quartz produced an acute proliferative fibrotic response, while the 10-12 micron particles produced only a foreign-body reaction up to a period of three years. It is accepted that the dangerous silica particles retained by the lung are under 5 microns in diameter.

Jan 1, 1937

By H. Arima, Y. Kudo

In general, the iron content of zinc leach residue produced by sulphuric acid leaching from calcine is disposed as jarosite or goethite into a tailing dam. More recently, these iron residues have been treated pyrometallurgically to avoid waste disposal. The Iijima refinery selected a different zinc leach residue treatment process for iron control when it was established in 1971. The Iijima refinery is the only plant in the world that has processed a zinc leach residue by the combination of SO2 pressure leaching and O2 pressure hematite precipitation. The process enhances zinc recovery and recovers gold, silver, copper, lead and rare metals in saleable by-products. This paper focuses on the two stages of autoclave application in the zinc leach residue treatment process. The detailed flowsheet and recent advancements to improve the quality of by-products are discussed.

Jan 1, 2004

By A. W. Jolliffee

ANY attempt to forecast the mineral resources of a largely unknown region is hazardous and, in the case of the Northwest Territories, such a task is even more hazardous than usual. This is not merely because of the immense territory involved (over a million and a quarter square miles), only a small fraction of which has ever been explored or prospected, but also be-cause both the geology and mineral deposits thus far examined show many unique features, and, finally, because the region is being actively prospected at the present time. However, in view of the present widespread interest in Canada's mineral resources, a brief compilation of what is known regarding mineral occurrences and geology in the explored parts of the far north seems timely. From these assembled data, a few inferences are warranted as to future mineral production from this region. HISTORY The story of mineral discovery in the Canadian northwest is a fascinating one. As well, it abundantly illustrates the importance of mineral occurrences in indicating future mining possibilities. The same sequence of events has repeated itself too often to be merely fortuitous.? In most cases, the dis-covery of a mineral deposit of possible economic value has been foreshadowed by the finding of the valuable mineral or an associated mineral in the same district, generally in small quantity, by an early explorer or traveller. Thus, John Franklin reported oil seepages from the base of Bear Rock, near Nor-man, at almost the very spot where oil was struck nearly one hundred years later. Again, some would-be Klondikers, deterred by the hardships of the route, remained to prospect around Great Slave lake, and were the first to report the Pine Point lead-zinc occurrences there and the gold-bearing veins on Yellowknife bay. Sporadic prospecting followed at the latter locality for over thirty years before the recent rich strikes were made. Similarly, in 1847, Dr. John Rae picked up a boulder of copper ore south of Rankin inlet, on Hudson bay. More than eighty years later, a body of copper-nickel sulphides carrying values in platinum metals was found at this locality. Also, the report of cobalt bloom on the east coast of Great Bear lake brought back by a Geological Survey of Canada party in 1900 was a factor in the events leading to the discovery of silver and radium there in 1930.

Jan 1, 1937

By M. W. Bates, A. L. Mular

This paper, based on work carried out at Queen's University, describes the development and use of mathematical models of the parallel cyclone classifiers being used in the Strathcona mill of Falconbridge Nickel Min.es Ltd.

Jan 1, 1971

By J. C. Farge, G. G. Jacox

"The effect of composition and process variables on the properties of Marmet and modified Ni-Hard slugs will be discussed. The effect of shape on the over-all performance of grinding media and its relationship to the end product has been investigated and these results will be reviewed. The cost effectiveness of slugs versus balls has been well documented under various operating conditions and this will be presented in detail. IntroductionThe selection of grinding media is based on the cost-to-wear ratio combined with the consideration that it must stand repeated impacts without breaking. The specific consumption of grinding balls and slugs depend s primarily on their microstructure, which, in turn, is controlled by chemical composition and by the processing condition s to which they are subjected during manufacture.The first part of the paper deals with the optimization of alloy content to produce cast iron slugs with microstructures consisting essentially of marten site and carbide and with hardnesses of 650 B.H.N. and higher. The second part deals with the use of cast iron slugs to replace forged steel balls in milling operations. Tests indicate that the shape of the media has little if any effect on results and that the hardness and microstructure of grinding media will determine its relative performance. Where price is equal under similar milling conditions, the cost effectiveness of cast iron slugs is superior to that of forged steel balls.In order to understand the role of alloying elements in cast irons, it is judicious to consider the microstructural changes which occur during solidification and subsequent cooling, particularly from above the eutectoid temperature. Solidification starts with the formation and growth of dendrites of austenite. As temperature decreases, an eutectic nucleates and grows between the primary austenite dendrites. Immediately after solidification, the structure consists of proeutectic austenite and of the eutectic of primary carbides and austenite. On cooling to room temperature, austenite can be retained or transformed to pearlite, bainite, martensite or mixtures thereof. It is necessary to prevent decomposition of austenite into pearlite by adjusting the alloy content. For best abrasion resistance, the microstructure at room temperature should consist essentially of martensite and carbide. These types of irons are known as ""martensitic irons "". Depending on the carbon content of the austenite and cooling rate, "" as-cast"" martensitic irons will contain different proportions of martensite and retained austenite. The more carbon in solution in the austenite, the lower is the temperature at which the martensitic transfoemation takes place. By the time room temperature is reached ., the transformation is seldom complete, and the end product is generally a mixture of martensite and retained austenite."

Jan 1, 1980

By P. C. Lighthall, D. W. Zandee, W. Shukin

"IntroductionThis chapter deals with the on land disposal and storage of fine tailing in slurry form behind dams. Other types of tailing, such as coarse dry cobbs from magnetic separation of iron ores and other dry materials, have special problems and are not addressed in this paper. The disposal of mine waste is not included, except as such materials may be of value in the construction activities related to tailing disposal.In earlier North American mining, mines were smaller and frequently disposed of their tailing by direct discharge into neighbouring streams or bodies of water. Where that was not practical or not permitted, the solids were collected in tailing ponds and only the effluent liquids were released or decanted. The dams used for these early impoundments were fragile structures and failures were common. With the advent of large, low-grade open pit mines, and increasing awareness of environmental and safety considerations, recently established mines have carefully-designed tailing disposal systems, with wellconstructed dams and attention given to protection of the environment. Older mines are being improved or at least being examined critically with a view to upgrading as necessary to meet the new standards.Modern tailing disposal systems are highly variable and unique to each mine. Tailing pond selection and design is dependent on available topography as also is the design of transport and water reclaim systems. Suitable sites that are at higher elevations than the mills or distant from them may require that the tailings be pumped. Dams, either earth or rock structures built of the most convenient and economic material, are usually a suitable mix of local borrow, mine waste and coarse tailings. The most economic structures are those built mostly of coarse tailing."

Jan 1, 1989

By A. A. Brant

BECAUSE of its simplicity, the dip needle is widely used for locating magnetic rock formations in drift-covered areas. Although it responds only to strong magnetic disturbances, it has the advantage that surveys with it can be carried out rapidly, at relatively low cost, by untrained operators. More accurate surveys can be made with a much more sensitive instrument known as the magnetometer, but this must be operated by a specialist and the resulting survey costs are much higher. Mining men use the dip needle for the location of magnetic ores or mineral deposits associated with magnetic rocks. In certain districts, a survey with the dip needle may aid in solving geological structure. In the Little Long Lac and Crow River gold camps of Ontario, it has recently been used for these purposes. In interpreting the results of a dip needle survey, an understanding of the chief magnetic and mechanical factors determining the dip recorded by the needle is definitely necessary. For example, many observers locate a magnetic body by the highest dip values, apparently unaware that these frequently may not lie directly above the body. It should also be realized that a careful dip needle survey may yield information regarding the dip, breadth, and perhaps depth, of the magnetic body. Moreover, the observer should know when numerous closely-spaced dip readings are necessary, and when the dip may be measured at more widely separated intervals. The purpose of the following article is primarily to describe the factors affecting the registration of the dip needle, with a view to aiding investigators in a more accurate and complete interpretation of their results. To explain the cause of magnetic disturbances (anomalies) and the action of the dip needle, a knowledge of certain fundamental magnetic terms is necessary.

Jan 1, 1938

By M. R. Khalesi, S. Bellec, C. Bazin, D. Hodouin

Batch grinding tests conducted on a gold ore indicated that gold is not randomly distributed within the size fractions of the ground ore. Since gold leaching performances were found to be dependent of the size of the gold carrying particles an integrated gold ore grinding-leaching simulator should incorporate a method to predict the gold size distribution of a ground ore. The paper describes the results obtained from batch grinding tests showing the non random distribution of gold within the size intervals of a ground ore and the initial developments of a grinding model to predict the gold size distribution in a batch grinding product.

Jan 1, 2011

By Karl J. C. Harries

This paper looks briefly at some of the agreements and types of royalties that may be met during exploration activities, but does not go into details relating to them. Agreements can either make or break a deal or relationship. A well drafted, comprehensive and fair agreement can create good relations and trust among the parties and will go a long way towards making a deal work. In the best of all worlds the agreement will be put away and not need to be referred to after it has been signed (but it will be there if needed to sort out potential problems). On the other hand, a poorly drafted agreement or one that is inappropriate to the circumstances or unfair to one of the parties can break a deal and end up with the parties facing each other in that expensive, unproductive and time-consuming occupation ? a lawsuit. Accordingly, it is advisable to involve professional advisers with any agreement. The straightforward one may involve no more that a read through whereas the more complex agreement will require considerable involvement. There is, however, one rule for every explorationist to remember: a professional adviser is only an adviser. His responsibility is to make sure that you have the necessary information to make a reasoned decision but the decision is yours, not the adviser?s. It is your deal, you are going to have to live with it, and it is inappropriate for an adviser to introduce new concepts or amend negotiated ones without your specific instructions. Mineral exploration agreements, although basically option, acquisition and joint participation agreements, come in all the shapes and forms, appropriate to give effect to the endless variety of deals negotiated by the ever-active minds of explorationists. You will note the reference to "joint participation agreements" rather than "joint venture agreements". The latter term was purposely avoided because, with the current activity of explorationists from common law jurisdictions in civil law jurisdictions, it has become necessary for the explorationist to become familiar with corporations and shareholders agreements. As most of you are no doubt aware, under the civil law system a joint venture is normally not recognized as a legal entity and, therefore, joint participation in projects is usually by way of corporations.

May 1, 2003

By R. D. Brown

Higher employer costs and increased employee benefits will result from the current sweeping revisions of the un-employment insurance system now receiving consideration before Parliament. The new legislation, the Un-employment Insurance Act, 1971, will substantially increase the unemployment insurance costs of many employers through an increase in the level of employer contributions -generally, employer contributions will go to 1.4 times employee costs -as well as by extending coverage to many classes of employees now exempt. Under the new legislation, executives, technicians, teachers, institutional workers and others will be covered, and eligible for the higher benefits which it provides. For the first time, absence from work because of illness or accident may qualify individuals for unemployment insurance benefits.

Jan 1, 1971

By H. Vermette, J. Demers, R. Leclerc, P. Bergeron, P. Hudon, A. Lessard

The Arvida Smelter marked its 80th anniversary in 2006. Arvida currently operates 6 potrooms equipped with prebaked side-feeding pots producing 160 000t of aluminum per year, requiring the supply of 300 000t of alumina per year. In the past, to ensure reliable alumina supplies to the pots, especially in winter, a safety stock of alumina was kept inside the plant. The improved reliability of shipping on the Saguenay River has cut the need for such a stock. However, the stoppage of 8 Soderbergtechnology potrooms, starting in the 1980s up to 2003, generated alumina from the cleaning of pot pits, totaling 18000t and leading to the building-up of a significant alumina stock again. Concerns over working conditions, effect on potroom operations, and dust emissions prevented Arvida from tackling effectively this impressive alumina stock. Yet the increasing cost of alumina has created a strong motivation to use the stored alumina. In 2004 Arvida launched a project to recycle the stored alumina. This 4-year project aimed at clearing the alumina stock without affecting the operation of the smelter. It involved changing work organization, improving equipment and controlling the effect of the recycled alumina on the smelting process and working conditions.

Jan 1, 2006

By Niraj Bala

Boiler tubes of coal-fired boilers suffer severe erosion-corrosion (E-C). One method to counteract this problem is by the use of therma, spray protective coatings. Cold spray coating process was used to deposit Ni-20Cr powder on SA 516 (Grade 70) boiler steel. The bare as wel, as the coated steels were subjected to cyclic experimenta, studies, in the superheater zone of a coa, fired boiler. The weight change technique was used to establish kinetics of the erosion-corrosion. XRD, FE-SEM/EDS and X-ray mapping techniques were used to analyse the as-sprayed and corroded specimens.

Jan 1, 2010

By Z. Z. Öztürk, N. Sarica, A. H. Üçisik, C. Bindal

"Titanium oxide films were fabricated on commercially pure titanium surfaces via anodization procedure. Anodization parameters, anodization time and voltage were altered, whereas temperature and chemical composition of anodization bath were kept constant. The main idea in this study is to obtain rough titanium-oxide surfaces. The type and feature of titanium oxide formed were observed via SEM and EDX analyses. What was revealed from SEM and EDX analyses were combined with Ti-O phase diagram in order to make judgment on the type of phases obtained, e.g. solid solution and/or compounds. Studies on the different regions of each sample showed that surfaces consist of different titanium oxide compounds with various O/Ti ratios in nano level and solid solutions varying in terms of chemistry on the same sample. Thus together rough surfaces and inhomogeneous distribution of "titanium oxides" were obtained. It was also found that when anodization time and voltage were increased, more granular surface with higher O/Ti atomic ratio was obtained."

Jan 1, 2015

By Iwueze Anaekperechi Rose

The International Labor Organization has declared mandatory adequate provision of safe workplace and safety for all workers in all occupations including the mining sector. Early scientists like Agricola (1559) who studied the health of Miners, found that there are peculiar health problems associated to their work and working environment. This unsafe working condition was one of the major factors that resulted to the Industrial revolution in England and eventually led to the establishment of regulations and laws guiding operations in all workplaces and workers in England and all over the world. Recent studies by Heinrich suggested chains of events of safety issues in the mining sector. Occupational injuries, accidents and ill health have huge social and economic implications on workers, their families and communities. Top mining top issues are respiratory diseases, noise, explosives, ventilation, fire, and explosion. However, one of the principal mechanisms for achieving Occupational Health and Safety (OHS) goals and mapping the future is government regulations of employers. In Nigeria, the situation is not different; mining operations are equally hazardous and have far reaching implications. In 1995 the Ministry for Solid Minerals was established to focus on the development of other categories of mineral products ranging from gold, coal, uranium, and tantalum deposited across the country. Prior to this an Act of Parliament Act Cap 121 of 1946, was in place to regulate amongst other contents mining safety. This was subsequently reviewed following the incidence of Lead poisoning resulting from small scale miners processing gold ore highly contaminated with lead in Zamfara state (northern Nigeria). Hundreds of children died as a result of exposure to lead poisoning, it was clear that the regulations were not sufficient (details to be discussed). However, advances have been achieved in mining engineering since then. A review team was constituted to provide a more stringent law to regulate mining operations in Nigeria. The strategies for mapping the future of OHS in mining engineering will employ amongst others setting and adopting ISO/ILO standards and enforcement; providing technical assistance; and establishing sustainable developmental structures as surveillance and compensation. The management systems approach was also developed as a result of cases of accidents. The accepted international standards guidelines and requirements will be proposed. Furthermore in mapping the future for Mining Engineering, it is suggested that most countries have their own management strategies and legislation to improve safety of workers through greater consistency and efficiency of OHS programs. Some American researchers came up with the Safety Engineering Model. The Australian Mining Council of mineral and petroleum resources after the Catastrophic Maura Disaster developed the National Mine and Safety Framework. In Canada, after the Hillcrest mine disaster in 1914, Allan shaft coal mine catastrophe in 1918, Westray mine explosion in 1992 and other disasters, Occupational Health and Safety Act R.R.O 1990 was sufficiently developed to provide adequate safety conditions and standards. In Nigeria after the disastrous Zamfara lead poisoning, which claimed the lives of hundreds of children due to exposure and lack of appropriate safety measures, stringent measures were developed by the federal ministry of Justice to address and regulate mining process in Nigeria.

Aug 1, 2013

By Ray Mason

Marathon PGM Corporation?s PGM-Cu Project in Northwestern Ontario (Figure 1.0) serves as a case study to describe the process involved in advancing a deposit from grass roots exploration to the completion of several feasibility studies and the parallel commencement of environmental permitting. Through the following examination of historical exploration activities, it is clear that these activities are directly related to economic stimulus, mostly measured by downturns in the mineral industry. Other factors that influence the success of exploration advancing to feasibility and new mine development includes the ownership of the mineral claims, which also changes under these economic influences and the crucial role of interactions between the Company, the Crown and First Nations. The Marathon PGM-Cu deposit is hosted within the Eastern Gabbro Series of the Proterozoic Coldwell Complex, which intrudes and bisects the much older Archean Schreiber-Hemlo Greenstone Belt. The sub-circular complex has a diameter of 25 km and a surface area of 580 km2 and is the largest alkaline intrusive complex in North America (Walker et al., 1993). Mineralization at the Marathon PGM-Cu deposit is part of a very large magmatic system that consists of at least three cross-cutting intrusive olivine gabbro units that comprise the Eastern Gabbro Series of the Coldwell Complex (Figure 3.2.4-3). In order of intrusion, the three gabbroic units consist of (1) Layered Gabbro Series, (2) Layered Magnetite Olivine Cumulate (LMOC) and (3) Two Duck Lake (TDL) Gabbro. The relative size and abundance of the gabbroic units decrease in the order Layered Gabbro Series>TDL Gabbro>>LMOC. Late quartz syenite and augite syenite dikes cut all of the gabbros but form a minor component of the intrusive assemblage.

May 1, 2010

By B. K. Choi, S. H. Kang, G. E. Kim, K. B. Kim, S. Noh, T. K. Kim, H. J. Jin

Oxide dispersion strengthened (ODS) steel is being considered as an in-core structural material of future nuclear reactor systems because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperature in a ferritic/martensitic matrix. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. The primary activity is to develop high strength advanced ODS steel, fabrication technology for the structural components and key joining technology for the component fabrication. As a result, a Fe-10Cr-1Mo alloy with a superior creep resistance at high temperatures has been developed. An optimized fabrication process of this alloy system has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. Joining technology for the ODS steel components is also being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. These R&D activities will contribute to the realization of ODS materials for future nuclear reactor system applications.

Jan 1, 2015

By H. Hao

This paper outlines the development of a 2-D axisymmetric mathematical model to predict the evolution of temperature during the Direct Chill (DC) casting of AZ31 magnesium billets. Model predictions of temperature have been compared to measurements made on an industrial DC casting machine at Timminco Ltd, in Haley, Ontario. These measurements have been used to fine-tune the thermal boundary conditions employed in the mathematical model, The model, which is based on the commercial finite-element code ABAQUS, has been developed as part of a strategic project aimed at improving the DC casting process for light metals through a reduction in casting related defects and increased productivity.

Jan 1, 2004