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By Y. Huang

Corrosion of GaAs in aqueous electrolytes is a major limitation in implementing GaAs-based photoelectrochemical solar energy conversion systems, In this work, the corrosion behavior was investigated by electrochemical methods and surface analysis approaches, in both H2SO4 and NH3?H2O solutions, Open-circuit measurements showed that the cleaned GaAs surface was very sensitive to water/air, Impedance measurements for n-GaAs showed that an inductive loop only appeared at a high corrosion rate because a reaction intermediate is the oxidant for a further decomposition step in combination with chemical reaction with water, The results suggest that the same corrosion/decomposition mechanism occurred on n-GaAs in the two solutions, When the surface-hole concentration was low, the hole injection or generation process was the rate-determining step, At large reverse bias on n-GaAs, with high-hole concentration, the corrosion rate was limited by a Faradaic adsorption process, involving an adsorbed intermediate, The different surface compositions after corrosion in the two solutions can be explained by the dissolution of As(0), Further oxidation of As(0) to As(III) in NH3?H2O solution is still slow, as suggested from X-ray photoelectron spectroscopy (XPS) analysis,

Jan 1, 2005

By E. Burdukova

Rheological measurements have found a wide array of applications in mineral processing research. Rheological properties of mineral suspensions are highly dependent on the mineral surface properties as described by DLVO theory, and the relationship between these properties and inter-particle interactions is well established. In this paper, rheological properties of mineral suspensions are used to study the differences in behaviour of isotropic talc and anisotropic zirconia minerals as a function of varying properties of the suspension medium, such as pH and polymer dosage, specifically carboxymethyl cellulose (CMC). It was found that the rheological tests when carried out in parallel with electrophoretic or point of zero charge measurements, clearly reveal differences between behaviour of the suspensions of isotropic and anisotropic minerals. These differences are further accentuated with the addition of carboxymethyl cellulose (CMC).

Jan 1, 2006

By V. L. Gravitis

Radioisotope X -ray techniques of analysis for nickel have been tested in laboratory and plant trials. In the laboratory tests. a comparison was made of radioisotope and conventional analyses for nickel in solid s samples taken from streams of a nickel concentrator. Coefficients of variation of 1.7% for feed and concentrate samples , and equal to 10% for final tailing samples, were obtained. Continuous determination of nickel in final tailing slurries was demonstrated in a trial lasting 20 days at a nickel concentrator (Western Mining Corporation), nickel being determined with a standard error of 0.036% Ni in the slurry solids within the range of 0.24 to 0.68% Ni. This error, obtained by comparison of on-stream probe analyses with assays of samples taken from the stream, includes errors in sampling and assay by conventional techniques.

Jan 1, 1977

By D. Yuan, M. Sitter, S. St. Jean, M. Collins

The Ambatovy Joint Venture comprises an operating lateritic nickel mine, ore slurry pipeline, pressure acid leach plant and nickel refinery in Madagascar. The hydrometallurgical process selected by Sherritt for treatment of the Ambatovy ore is a long-term, sustainable approach to producing nickel. Sulphur, used to prepare hydrogen sulphide, which is used to produce mixed sulphide intermediate, is recovered in the refinery as ammonium sulphate fertilizer. Additional sulphur is used to generate sulphuric acid for treatment of the ore in the high pressure acid leach (HPAL) step; fossil fuel consumption is minimized by using the heat generated from the exothermic reaction between sulphur and oxygen in the acid plant to produce power and steam. Steam consumption is minimized by design of efficient flashing and preheat systems for HPAL, while the high temperature of the HPAL step serves to minimize acid consumption. Fossil fuel consumption by the operation as a whole is further minimized by locating the leach plant and refinery near the port of Toamasina and utilizing a 220 km slurry pipeline to transport ore from the mine to the leach plant. In addition, Ambatovy has demonstrated a strong commitment to sustainability programs such as the biodiversity management program at the mine and local procurement in Madagascar. In this paper, the hydrometallurgical process for nickel and cobalt recovery from Ambatovy ore is described, along with highlights of Ambatovy’s approach to sustainability in Madagascar.

Jan 1, 2015

By S. M. Bradshaw, E. Charikinya

"Microwave induced cracks have the potential to enhance metal recovery from coarse sphalerite particles in heap leaching operations by creating new crack surface areas for lixiviant and enhancing value mineral exposure. The mode of fracture and the extent of mineral exposure due to microwave induced cracks have not yet been investigated. The objective of this study was to determine the extent of particle damage and mineral exposure in microwave treated particles. This was done using X-ray computed tomography (XCT) and image analysis techniques. XCT analysis was conducted on small (–5+4.75 mm), medium (–16+9.5 mm), and large (–25+19 mm) sphalerite ore particles before and after microwave treatment (MT). Geometrical properties, such as volume and surface area of each mineral phase in each particle was determined from the XCT reconstructed images using VGStudioMax image analysis software. These geometrical properties were used to calculate the interfacial areas of sulphide mineral grains in microwave treated particles before and after MT. The ratio of specific interfacial area after MT to specific interfacial area before treatment was used as an indicator of the degree of preferential grain boundary fracture. The results showed significant grain boundary fracture after MT at all sizes. For small sized particles, about 31% of the interfacial area was lost compared to 23 and 16% for medium and large particles, respectively. The results also showed an increase in the degree of mineral grain exposure of 28, 26, and 15% for small, medium, and large particles, respectively, after MT. These results provide experimental evidence supporting improved mineral exposure due to MT. INTRODUCTIONFor some years it has been suggested that microwave treatment (MT) of ores might result in preferential grain boundary fracture that would have benefits such as improved grain exposure and particle weakening. (Kingman, 2006). Most of the experimental work investigating the application of microwaves to mineral processing flow sheets has focused on assessing the benefits of applying microwave technology to flow sheets consisting of size reduction and mechanical flotation cells (Kingman et al., 2004). Experimental studies have shown that coarse crushing during tertiary grinding of microwave treated ore resulted in a better liberated coarser flotation feed (Scott, Bradshaw, & Eksteen, 2008). It has been suggested that improved liberation in milled flotation feed, was due to the presence of grain boundary fracture in microwave treated particles. However, this improvement in coarse particle liberation does not necessarily translate to a significant improvement in downstream flotation recovery (Kobusheshe, 2010). This is as a result of the size limit to the flotation of coarse material, due to detachment forces acting on particle-bubble aggregates, which increase as the particle size increases (Jameson, 2012). Current conventional, mechanically agitated flotation cells are not designed to float coarse material (Jameson, 2012). Hence it has been difficult to show the downstream processing benefits of applying microwaves to ores processed by comminution followed by flotation (Kobusheshe, 2010). It is clear from investigations carried out so far that inappropriate downstream exploitation of microwave treated ore would fail to realise a meaningful process benefit (Kobusheshe, 2010; Ali & Bradshaw, 2011)."

Jan 1, 2016

By G. Shaw

IN recent years, most of the reconnaissance work of the Geological Survey of Canada has been mapped on a scale of 1 inch to 4 miles. Topographic base maps, commonly made from aerial photographs, were available to the geologist for such work. The advent of war curtailed aerial photography for civilian purposes, and by 1941 all areas already photographed had been geologically mapped. Nevertheless, the need for geological maps to assist post-war prospecting was so apparent, and the country to be covered is so vast, that some new method of rapid mapping had to be devised. It was felt that the need would be met if geological maps could be produced at a scale of 1 inch to 8 miles, provided they were sufficiently accurate in topographic detail to serve as guides to travel. Though in such maps there would be considerable sacrifice of geological detail, they would serve to outline, at least approximately, the major geological units, some of which might prove of sufficient interest to warrant later detailed study. It seemed that such mapping would be particularly useful in the northern regions of Canada which the work of early explorers has indicated are underlain largely by granitic rocks. These, so far as is known, are barren of mineral deposits, but within them are known to be areas or bands of 'greenstones' of the type that, in some localities, have been found to contain valuable orebodies. The problem, then, was to devise a method of mapping, particularly of such greenstone bands, that would make it possible to cover a relatively large area-say 30,000 square miles-in one season and at a cost below that of 4-mile mapping, with, of course, some sacrifice of accuracy. The problem seemed to be threefold: (a) to observe as much of the bed-rock as possible; (b) to produce a topographical map of as much of the area as possible, with particular reference to portions of geological interest; and (c) to cover as large an area as possible in a limited time, which meant faster modes of travel than have hitherto been used. The obvious answer to all three phases of the problem was the use of aircraft. If rock types could be broadly differentiated from the air, reconnaissance traverses by air would supply the answer to the first part of the problem. For topography, air photographs taken on reconnaissance flights appeared to be the answer. For the third phase of the problem, the use of aircraft was ideal.

Jan 1, 1943

By A. E. Flynn

Introduction The purpose of this paper is to record the results of researches on anhydrite that have been undertaken at the Nova Scotia Technical College during the last two or three years. The work was carried out in the Mining Department of the College, and several investigators were engaged on the work from time to time. Messrs. R. E. Hanson and K. M. Ed devoted their mining theses to the investigation, and Messrs. J. C. Hall and G. W. Baker were engaged on the work during the summers of 1928 and 1929, respectively. The writer was responsible for the initiation and direction of these researches, which were made possible by the financial assistance of the Department of Mines of the Province of Nova Scotia. Nova Scotia is the leading Province in Canada for gypsum production, its output being about a million tons per year, or over 80 percent of the production for the whole of Canada. The commanding position of Nova Scotia in this regard is due to the abundant supply of gypsum and its proximity to areas of intense utilization in the eastern United States. The resources of gypsum are contained in a total area of 627 square miles of gypsiferous rocks, so that an enormous reserve of this mineral is available. Present operations are confined to the highest grade and most easily worked deposits close to water transportation.

Jan 1, 1930

By Warwick Bullen

A hypothetical economic model has been developed for diamond projects in the Canadian Arctic using data from recent exploration and mining projects. The model reflects economic conditions as it applies to the diamond mining industry in the Canadian Arctic at the present time. The economic model captures pre-production expenditures, production data, and post-production costs. Before- and after-tax cash flows are derived from the data along with the relevant economic criteria. From the corporate perspective, the model provides guidance as to the minimum size and/or in-situ value per tonne requirements of targets being sought in order to ensure economic success and probable exploration and development expenditures. From the government perspective, the model provides an indication of income and mining tax revenues that can be expected from a particular diamond project. The model shows, on average, diamond projects in the Canadian Arctic are expensive to explore for and develop, but are economically robust. They generate great economic return for mining companies and significant amounts of tax revenue for governments. The fact that diamonds can be transported directly from the mine site by air makes them particularly attractive targets for mining companies that operate in the Canadian Arctic.

Apr 1, 2005

By B. Lafrance, C. J. Beaumont-Smith, L. R. Jones

"Abstract - The Burnt Timber gold deposit is located in the Paleoproterozoic Lynn Lake greenstone belt of the Trans-Hudson Orogen, Manitoba. The deposit occurs along the Johnson shear zone, and is hosted by enriched and depleted tholeiitic volcanic arc basalts cut by feldspar porphyry dikes. The Johnson shear zone is a regional, belt-parallel structure characterized by the intensification of the regional S2 foliation. At the Burnt Timber deposit, S2 is folded by centimeter- to meter-scale, Z-shaped, F3 chevron folds that have an axial planar S3 crenulation cleavage. Within the 20 to 30 m-wide core zone of the shear zone, S2 and F3 are transposed parallel to S3 and the volcanic rocks are strongly sheared parallel to S3. The presence of a steeply plunging stretching lineation, together with dextral shear sense indicators along both S2 and S3 on horizontal surfaces, suggest that the Johnson shear zone is a dextral transpression zone. Gold was introduced in pyritic, biotitic, and carbonatized mafic volcanic rocks along the core of the shear zone. Mylonitic mafic volcanic rocks contain localized high-grade zones (=10 g/t Au) that differ from wider carbonatized, low-grade zones (<3 g/t Au) by the presence of deformed gold-bearing quartz-pyrite veins. High-grade zones are also associated with swarms of quartz-pyrite veins that cut across sericitized and carbonatized feldspar porphyry dikes, which acted as brittle, competent bodies during shearing. Gold deposition in the high-grade zones was controlled by the channeling of hydrothermal fluid along the core of the shear zone during shearing of the volcanic rocks, and brittle fracturing of the porphyry dikes. Sommaire - Le gîte aurifère de Burnt Timber est situé dans la ceinture de roches vertes Paléoprotérozoïque de Lynn Lake dans l’orogène Trans-Hudsonien, au Manitoba. Ce gîte est situé le long de la zone de cisaillement de Johnson et est encaissé dans des basaltes tholéiitiques d’arc enrichis et appauvris recoupés par des dykes porphyriques. La zone de cisaillement de Johnson est une structure régionale parallèle à la ceinture de Lynn Lake caractérisée par une intensité accrue de la foliation régionale S2. Au gîte de Burnt Timber, S2 est affectée par un plissement F3 en chevrons en Z d’échelle centimétrique à métrique associé à un clivage de crénulation de plan axial S3. Dans la zone centrale de 20 à 30 m de largeur au sein de la zone de cisaillement, S2 et F3 sont transposés parallèlement à S3 et les roches volcaniques sont fortement cisaillées le long de S3. La présence conjointe d’une linéation d’étirement à forte plongée et d’indicateurs cinématiques dextres sur les surfaces horizontales S2 et S3 suggère que la zone de cisaillement de Johnson est une zone transpressive dextre. L’or a été mis en place dans des volcanites mafiques altérées en pyrite, en biotite, et en carbonate au coeur de la zone de cisaillement. Les roches volcaniques mylonitiques présentent des zones aurifères locales à haute teneur (=10 g/t Au) qui diffèrent des zones à basse teneur (<3 g/t Au) par la présence de veines de quartz et de pyrite aurifère. Des zones à haute teneur associées à des essaims de veinules de quartz et de pyrite sont aussi notées dans des dykes porphyriques à plagioclase altérés en séricite et en carbonates; ces dykes se sont comportés comme des corps compétents durant le cisaillement. La déposition de l’or dans le zones à haute teneur a été contrôlée par la circulation du fluide hydrothermal au coeur de la zone de cisaillement durant la déformation des roches volcaniques et la fracturation des dykes porphyriques."

Jan 1, 2006

By Xiqing Wu, Liang Dai, Tao Yue, Longsheng Yi, Ruifang Wang

Magnetic seeding flotation (MSF), i.e. adding magnetic seeds and pre-magnetization-flotation, is a new flotation technology especially for fine particles, which improves the flotation performance by enlarging the apparent size of the particles in a way of magnetic agglomeration. Both the fine coal slimes with a size of 66.68% –38µm and the pyrite slimes with a size of 73.95% –23 µm were investigated by the MSF, respectively. Flotation tests with variable of dosages of magnetic seeds and polyacrylamide were conducted, and some measurements, such as laser diffraction size analysis, magnetic susceptibility by vibrating sample magnetometer (VSM) and infrared spectroscopy (IRS), were also applied in order to probe the mechanism of the MSF. Based on the tests, measurements and calculations it was found that both the recovery of coal and the flotation kinetics of pyrite slimes increased with the additions of the magnetic seeds, and in the presence of polyacrylamide the coal flotation was further strengthened due to a synergetic effect of magnetic seeds and polyacrylamide on the flotation and a relatively larger apparent size of slimes after additions of magnetic seeds and polyacrylamide. The reason for the MSF lies in fact that the presence of the polyacrylamide intensified the adsorption of magnetic seeds on the coal particles and increased the coverage of the magnetic seeds on the coal surface from 0.2 to 1.3 wt%, resulting in increased magnetic susceptibility of coal particles from 9.13×10-9 to 22.17×10-9 m3/kg and thus a low magnetic field strength of pre-magnetization needed for the magnetic agglomeration among the coal particles from 602 to 24 mT prior to proper flotation. IRS shows that polyacrylamide chemisorbed on the surfaces of both coal particles and magnetic seeds, thus acting as the bridging media between particles and seeds.

Jan 1, 2016

By David S. Robertson

"IntroductionCanada has been one of the world's leading producers of uranium since atomic energy first became of practical importance in 1942. Indeed, prior to this time, between 1933 and 1940, Canada produced significant amounts of pitchblende, as a source of radium, from the Eldorado Mine at Great Bear Lake*.Uranium was first reported in Canada, however, in the middle of the 19th Century in the vicinity of Theano Point on Lake Superior north of Sault Ste. Marie. In the early 1900s, uranium-bearing minerals were reported in Quebec north of the St. Lawrence River and in pegmatites in Quebec and eastern Ontario. In 1930, G.A. LaBine and E.C. St. Paul visited an occurrence of cobalt reported by the Geological Survey of Canada in 1900, and brought the Eldorado Mine into production in 1933, as noted above, producing, in the main, silver and pitchblende.In 1942, developments in atomic energy were such that the Government of Canada, at the behest of Great Britain and the United States, requested that Eldorado, which had been closed in 1940, be re-opened to produce uranium for the Manhattan Project. In September, 1943, all discoveries of radioactive minerals were reserved to the Crown and their staking by private interests was banned. In January, 1944, the government nationalized Eldorado and formed a Crown corporation, the present Eldorado Nuclear Limited, to take over the assets. That year marked the formal beginning of uranium exploration in Canada.The Period 1944 to 1948In 1944, the Crown Corporation and the Geological Survey of Canada began exploring for uranium deposits, largely in the areas of Great Bear Lake and Lake Athabasca. In that year, A. W. Joliffe of the Survey visited properties on the north shore of Lake Athabasca near Beaverlodge Lake and recommended that Eldorado acquire claims in the area. In 1946, P. St. Louis and E. Laurum, prospectors working for Eldorado, found the pitchblende veinlets that led to the Ace Mine. Shaft sinking began in 1951, and production, through a carbonate leach plant, began in 1953.Continuing drilling on the Eldorado claims led to the Verna ore bodies, some 6,000 feet northeast of Ace, on which shaft sinking started in 1954."

Jan 1, 1986

By J. Paraszczak

High productivity of the equipment employed is one of the key factors in reducing production cost in mining. One of the best ways to achieve it is an increase in availability. In order to identify the most adverse factors affecting it, reliability and maintainability analysis ought to be done. If its results are to be conclusive, a sufficient amount of credible and consistent data is indispensable. Following the experience from field studies done in underground mines, this paper discusses the current status of failure and maintenance reporting, as well as problems encountered. It exposes the importance of adequate data collection on failures and downtime as well as it reviews the benefits of analysis based on such material. The question of benchmarking with regards to mining equipment performance is also addressed. The paper concludes with some recommendations on data collection and processing, as well as stresses the need to standardize the most important reliability/ maintenance notions throughout the mining industry and to conceive appropriate performance measures.

Jan 1, 2000

By Vicki Tschirhart, Bill Morris, McMaster University

A new method for mapping faults within basement rocks underlying the Thelon Formation and glacial overburden was developed and tested in the Aberdeen Sub-basin. This method utilizes newly acquired aeromagnetic data, the Blakely algorithm for defining magnetic source edges, a calculated dip-direction map, a digital elevation model (DEM) derived from the Canadian Digital Elevation Database, and the positions of identified, inferred and newly mapped faults that are within and adjacent to this sub-basin. Combining these data revealed three age groups of faults. One group is seen only on the DEM; these faults are young brittle structures that have no effect on the sub-Thelon basement unconformity, and are not visible on the dip direction map. A second group is evident on the dip direction map but not the DEM; these faults are old basement structures that did not propagate upward through the Thelon Formation. The third group is expressed on both the DEM and dip direction map; these faults are also old structures that propagated upward during and/or after deposition of the Thelon Formation. The latter group of faults may be of greatest interest for uranium exploration, with reactivation increasing their potential to serve as conduits to transport uranium-rich fluids and focus deposition at or near the unconformity surface. This methodology has promise for comprehensive mapping of basin faults and tracking the tectonic development of the whole Thelon Basin through time.

Jan 1, 2013

By Grant Small, Jessica Kinal, Christopher J. Greet

"The conversion from an electrochemically reactive grinding media (forged steel) to a more electrochemically inert alloy (high chrome white iron) not only reduces the wear rate of the grinding media, but also has an impact on the grinding chemistry. Typically the grinding chemistry becomes more oxidising, with less reducing Eh values and more dissolved oxygen in the pulp. There is also a decrease in the EDTA extractable iron, which is an indication of the change in the media corrosion. These changes are indicative of alterations in the surface chemistry of the minerals that the operator is trying to separate. For porphyry copper ores the changes in the pulp and surface chemistry not only affect the copper sulphide minerals, but also impact the iron sulphides (i.e. pyrite and pyrrhotite). Generally, with more oxidising pulp chemical conditions during grinding there is an increase in the oxidation of the iron sulphides which renders their surfaces hydrophilic, thereby depressing flotation. This leads to improved selectivity for copper sulphides against iron sulphides.INTRODUCTIONPorphyry copper deposits are the dominant source of copper that is mined today to satisfy global demand. These style of deposits typically contain one percent copper mostly as chalcopyrite, but may contain other copper bearing minerals (for example, bornite, chalcocite, azurite, malachite), small quantities of pyrite and quartz. Porphyry copper deposits also contain economically significant quantities of gold, silver and molybdenum. Interestingly, the majority of the world’s porphyry copper deposits are concentrated along tectonic plate boundaries (Figure 1)."

Jan 1, 2016

By Kuwauchi. Y., M. Barati

Recycling of dust using a rotary hearth furnace (RHF) has gained considerable attention in the past two decades for the sustainable production of steel with less environmental impact. In order to further promote the recycling of electric arc furnace dust and carbonaceous wastes using the RHF process, a mathematical model was developed to predict the reaction behaviour of dust-reductant composites. The reduction kinetics of zinc and iron oxides as well as the volatilization behaviour of volatile matter in the reluctant were considered. The modeling approach and some preliminary results are presented in this article.

Jan 1, 2011

By C. A. Pickles

Microwaves are being applied industrially in a number of fields and possess a number of potential advantages that could be applied in extractive metallurgy. Microwave heating has a number of unique characteristics, which distinguish it from the conventional heating methods. In microwave heating, the absorption of energy occurs at the molecular or atomic level and therefore the heat is generated within the material itself. In conventional heating, the exterior temperature is usually higher than the interior, but with microwave heating, the temperature gradient is inverted and thus the interior temperature can be much higher than that of the surface. The energy densities in microwave systems can be relatively high and this in combination with the low thermal conductivities of oxide ores, can lead to very high internal heating rates. In this research, the application of microwave energy for the reduction of a nickeliferous silicate laterite ore has been investigated. The real and imaginary permittivities are the two fundamental properties which determine the microwave absorption characteristics of a material and these were measured for the ore, both with and without carbon additions using the cavity perturbation technique. The microwave heating and reduction experiments were performed in a 0 to 2 kW CTC microwave system. The effects of power input, processing time, sample mass and charcoal additions on the microwave absorption were investigated. Then reduction experiments were performed and the nickel grade of the magnetic concentrate and the nickel recovery in the concentrate were determined.

Jan 1, 2005

By B. G. Cousins, L. Racine, R. S. MacPhail

"FLEX 31 is a chemically enhanced sodium isopropyl xanthate that has shown improved collection properties over SIPX for copper-bearing and copper-activated minerals. Characteristics such as improvement of recoveries with lower dosages and high pyrite and pyrrhotite rejection capabilities have all been exhibited by FLEX 31.The most improved results have been seen insphalerite flotation. Plant trial work carried out in the zinc circuit at the Louvicourt Concentratorin northern Quebec has produced data showing superior grade and recoveries from rougher concentrates that previously had not been attain-able with other reagents effectively. The improvement over SIPX adds up to an almost$1,000,000 annual improvement on the mine’s bottom line at present zinc prices.IntroductionSodium Isopropyl Xanthate (SIPX) is one of the most popular flotation chemicals on the market today. Somewhat more specific than amyl xanthates, SIPX is used in a variety of ores like copper/zinc, lead/zinc, arsenopyrite/pyrite, and many others (Melis et al., 1991). An investigation carried out by Tennants Research Technology Applications (TRTA), a division of Charles Tennant & Co. (Canada) Ltd., produced a chemically enhanced SIPX that has shown all the advantages of normal SIPX along with improved recoveries of copper and copper activated minerals. The new product has been named FLEX 31. Currently, FLEX 31 is manufactured at the Prospec Chemicals, another division of Charles Tennant & Co. (Canada) Ltd.A large amount of laboratory testing pro-grams have been carried out with FLEX 31 todate (MacPhail and Cousins, 1995; Cousins and MacPhail, 1996). One of the minerals that has a defnite affinity to improved fotation is sphalerite (ZnS). Once activated with copper sulphate, sphalerite has produced some of the most spectacular test work when FLEX 31 is compared directly to SIPX. Plant trials of FLEX31 at Aur Louvicourt Inc. carried out in 1995show that FLEX 31 is far superior to SIPX for activated sphalerite flotation."

Jan 1, 1997

By R. Vergunst, E. A. Devuyst, G. Robbins

"INTRODUCTIONThe Inca process for continuous cyanide removal from industrial wastewaters was patented in 1984 by G.J. Borbely, et.al. (1). The process requires SO2, air, lime and a copper catalyst. Both free and complexed cyanide are oxidized to cyanate in the pH range 8 to 10. Cyanide bound to iron is removed by precipitation as a ferrocyanide insoluble salt and other base metals are removed as hydroxides.The process was piloted in 1982 on barren bleed solution at Campbell Red Lake Mines Ltd., Ontario (2). Since 1982, the Inca SO2-air cyanide removal technology has been applied in twelve commercial installations. The process has significant advantages over other commercial processes in the completeness of cyanide removal and lower reagent requirements and costs.COMMERCIAL INSTALLATIONSBy the end of 1988 Inca will have applied its patented cyanide removal technology to twelve commercial operations. Three of these, namely Scottie Gold Mines, Dupont of Canada Expl. Baker mill and Carolin, all in British Columbia, Canada, have ceased cyanidation operations but SO2-air cyanide destruction results were good for all mills, particularly so for over two years for the Scottie mill.Removal of cyanide from CIL slurry tailings is applied at Equity Silver (9,500 tpd) and Inca's new 1,200 tpd mill at Inca/Golden Knight. Detoxification of CIP tailings is carried out by Colosseum California (3,600 tpd) and Canamax's Ketza River operation (360 tpd). Repulped tailings from Merril-Crowe flowsheets are treated at Total Erickson's Mount Skukum mill (300 tpd) and Skyline's Johnny Mountain mill (200 tpd) and barren bleed at Inco/Queenston's McBean mill (500 tpd). Lynngold's MacLellan mill (1,800 tpd) treats pond supernatant water. Plating shop cyanide effluents are decyanized at Kuntz Electroplating in Kitchener, Ontario. Many of the above commercial operations were described in some detail in previous publications (3,4). Typical installations are described in this paper. A summary of operating results is given in Table 1."

Jan 1, 1989

By Henk Dijkman, Wageningen University, Paula Gonzalez Contreras, Irene Sánchez-Andrea, Jan Weijma, Silvia Vega

"More than 20 years ago, Paques B.V. introduced innovative biotechnologies to recover metals and to remove sulfate from aqueous streams. These technologies find their origin in the exploration of microorganisms involved in the global sulfur cycle. Currently, several sulfur cycle biotechnologies are applied successfully at full-scale. The sulfur cycle is closely linked with the iron cycle, and also the latter offers opportunities for application of innovative biotechnology for the mining industry. Microorganisms of the natural iron cycle carry out reactions that are not feasible by chemical methods such as ferrous iron oxidation with oxygen at pH below 4. Iron oxidation with oxygen can be conducted using microorganisms living at pH between 0.5 and 7 and at temperatures between 0 and 95ºC. Remarkably these microorganisms can also carry out arsenite oxidation at similar acidic conditions and high temperatures. Making use of the extreme features of these microorganisms, Paques and Wageningen University have developed a biological process to precipitate arsenic as scorodite. This biological formation of scorodite is a novel combination of biological oxidation and biocrystallization. Depending on the level of saturation, biological oxidation rates and operational conditions, we could control the formation of the iron precipitates such as jarosite and scorodite. Currently new microorganisms have been harvested from hot springs and rock acid mine drainage to foster the growth of specialized microbial communities with potential high iron and arsenic oxidation capacities and higher resistance to other metals. In our paper we address the ongoing research and development of the bioscorodite process.THE USE OF IRON TO REMOVE ARSENIC In 2015 several environmental disasters related to the release of mine wastewater and tailings occurred. On August 5th, a waste water spill occurred from the Gold King Mine near Silverton, Colorado. A dam holding the tailing pond was damaged and spilled three million US gallons (11 ML) of mine wastewater and tailings, including elements such as cadmium, lead and arsenic, into Cement Creek, a tributary of the Animas River in Colorado. “At their peak, arsenic levels were 300 times the normal level and lead was 3,500 times the normal level” (The Guardian, 2015). In early November, another collapse of a mining dam in the Brazilian state of Minas Gerais spilled between ten and sixteen thousand US gallons of water and sediment after a dam failed from an iron ore mine. Arsenic and mercury polluted the Doce River, arsenic levels were found more than ten times above the legal limit in some places of the river (The Guardian, 2015). Waste production is inevitable during Mining. However, a preventive waste management strategy could have minimised waste production, maximised waste reuse and classified waste by their hazardous degree."

Jan 1, 2016

By M. W. Grabinsky, B. D. Thompson

ABSTRACT: Use of cemented paste backfill (CPB) offers economic and environmental advantages over other backfill methods. However, many operations have limited knowledge of how their CPB behaves in situ. Therefore, to avoid over-pressuring containment barricades, backfilling strategies necessarily tend to be conservative. In situ monitoring at Barrick Gold Corporation’s Williams Mine and Inmet Mining Corporation’s Cayeli Mine has been conducted and factors controlling barricade pressures are demonstrated, including rise rates, binder content, stope geometry, and tailings properties. The application of barricade pressure monitoring on a stope-by-stope basis can increase backfilling efficiency and, thus, reduce stope cycle times, while maintaining optimal safety.

Jan 1, 2011