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By J. Martinovic

The large proportion of gangue minerals present in platinum bearing ores in South Africa provides challenges to the flotation and down stream processes. In order to take effective measures to reduce their recovery in flotation an understanding of the mechanisms and factors influencing their behaviour is needed. Typical gangue minerals are pyroxene, feldspar, quartz, chromite and talc. Of these, talc is a naturally hydrophobic mineral and although it is present in relatively small quantities, it has a disproportionate effect as it has a strong froth stabilizing effect, increasing the recovery of other gangue minerals by entrainment. Talc recovery is effectively reduced with the addition of polymeric depressants. Although the other gangue minerals are assumed to be hydrophilic and their recovery by entrainment is expected to follow the water recovery, there is some evidence that they may be activated by the typical reagent suites used. Reagents such as copper sulphate, added as an activator, and collectors are used to selectively induce hydrophobicity on the sulphides. It has been shown that some of these gangue minerals can be activated. This research work investigates whether inadvertent copper activation is mineral specific and evaluates the mechanisms and factors affecting the reversal of activation with the addition of the depressants using electrokinetic measurements, adsorption and microflotation tests. Results are presented that show that the selected minerals do respond differently and that the reversal of activation is dependent on mineral type, depressant type, dosage and ionic strength of the electrolyte.

Jan 1, 2004

By C. A. Young, J. L. Bowden

"Cyclic voltammetry experiments were conducted on copper and chalcopyrite (CuFeS2) in the absence and presence of ethyl xanthate, and compared to mass-balanced EH–pH diagrams. The results for copper duplicate those found in the literature and confirm xanthate chemisorption. However, the, results indicate that chalcopyrite oxidizes to chalcocite (Cu2S) and only afterwards is chemisorption observed due to small currents appearing with xanthate. This phenomenon suggests that the mineral's hydrophobicity is induced by more than dixanthogen and copper xanthate. Hydrophobicity was found to be pH-dependent over a range of alkaline conditions (pH 7–11) at narrow potentials (0 to –200 mV). An EH–pH diagram for chalcopyrite with xanthate is presented to illustrate the conditions under which chalcopyrite would be hydrophobic and thereby more thoroughly explain the results in the literature. IntroductionSulphide minerals are generally concentrated from ores by froth flotation, a physiochemical process that induces separation based on differences in hydrophobicity. In this process, a gas is bubbled into a slurry and the minerals that are hydrophobic (water-repelling) adhere to the bubbles and float to the surface while the hydrophilic (water-loving) minerals remain in the slurry. With sulphide minerals, the hydrophobicity is generally established in two ways. The first is by the addition of a collector, which is a heteropolar molecule with a reactive inorganic head group and an inert organic tail. Typically, the head group bonds with the sulphide mineral surface by adsorbtion either chemically (chemisorption) or physically (physisorption) or by complexing with atoms that solubilize somewhat at the surface (surface precipitation). These interactions leave the organic tail protruding from the mineral surface, thereby inducing hydrophobicity. The second method is by oxidation of the mineral surface to form a layer that is metal-deficient/sulphide-rich or comprised of elemental sulphur. Because the layer mimics naturally hydrophobic sulphur, this enables ‘collectorless’ flotation. Furthermore, this oxidation phenomenon adds an electrochemical dimension to the understanding of sulphide mineral flotation."

Jan 1, 2016

By R. G. B. Pickering

The South African narrow reef hard rock mining industry has been stuck in a time warp with relatively little change in the mining process in the last century. This paper presents a methodology on how to implement change in narrow reef hard rock mining. It then explores a number of technologies that have been introduced into this mining industry and the impact that they have had on the mining process. The author then presents his view on whether the defined change process has been followed and sets out to identify the most critical aspect of ensuring that change is successfully implemented. Future demand will also be speculated on.

Jan 1, 2007

By S. Potgieter-Vermaak

The main mineral components of the so-called heavy sands (or black sand) are the titanium, zirconium and iron-bearing minerals, rutile, zircon and illmenite, accompanied by various minor and trace amounts of silicates or phosphates, often present together with the rare earth elements. The investigated samples originated from Richards Bay Minerals (RBM) in South Africa, which is jointly owned by BHP Billiton and Rio Tinto, the largest titanium slag producer in the world. The present study focused on the characteristics of samples originating from various points in the separation plant. The heavy-mineral fractions and concentrates of a representative suite of samples were investigated using various analytical techniques to establish the differences in morphological and elemental compositions at the different points in the plant. These techniques included: reflected light microscopy, micro-raman spectrometry (MRS), scanning electron microscopy coupled with energy dispersive X-ray analysis (SEM/EDX) and structural and chemical analyser (SCA). All samples comprised a heterogeneous population of zircon and rutile grains with diverse physico-chemical properties, expressed by large differences in colour and trace element chemistry of single grains. The elemental composition proved the presence of the rare earth elements that appeared to coexist with both Ti and Zr minerals. The percentage of grains hosting inclusions, such as anatase, monazite, quartz, spessartine, augite, epidote and actinolite, varied for each sample and could be uniquely characterized by Raman investigations. Keywords: heavy mineral sands, micro-ram an spectrometry, elemental analysis

Currently the most widely used formula in pillar design is the power formula, which implicitly assumes a volume effect. This assumption is critically examined, and it is proposed .that a limiting strength value, the critical rock mass strength, be used for pillar design instead. A methodology is provided to determine this value. It is suggested that the effects of geometry on pillar strength are well described by a linear function and the power formula, for w/h ratios less than or equal to about 5. This approach together with the use of the critical rock mass strength, removes the volume effect. Various factors that affect pillar strength are examined. The concept of explicitly determining the stability of each component in the pillar system is briefly discussed. It is proposed that pillar design be expanded to a pillar system design procedure that incorporates the interaction of the pillar, roof and floor strata, and the loading system.

Jan 1, 1998

The relationship between the aspect ratio and physical fields in aluminium reduction cells wase studied numerically. The aspect ratio was firstly defined and 7 kinds of 320 kA cells with different aspect ratios were put forward. By using numerical simulation, the relationship between the aspect ratio and the electric-magnetic flow fields, magnetohydrodynamic stabilities, and thermal stability was discussed. It is concluded that the electric-magnetic flow field distributions are greatly affected by the aspect ratio. From the perspective of magnetohydrodynamics stability, the larger the aspect ratio is, the more stable the cell will be. A larger aspect ratio is more beneficial for the thermal stability under the same current density.

Jan 1, 2011

By B. Yu, M-H. Cao, C. Zhou, X-Z. Zhang

The transient infiltration and lubrication behaviour of slag during continuous casting of steel is important for billet quality. A two-dimensional coupled mathematical mould model was developed to investigate these phenomena. The accuracy of the model was verified by comparing the calculated slag consumption with measurements by the plant. The results show that the liquid slag is consumed from the middle and late period of positive strip time to the next early period of positive strip time, including the entire negative strip time. The maximum downward infiltration velocity and positive pressure in the slag channel is at the middle of the negative strip time. Increasing the positive pressure of the slag channel is conducive to lubrication. The shear stresses acting on the shell surface and at the mould side were determined by the lubrication slag consumption and total slag consumption, respectively, and gradually decreased with increasing slag consumption. The negative strip time was lengthened to increase the slag consumption and prolong the time near the maximum downward shear stress, so as to be conducive to the demould.

Apr 16, 2024

By G. R. Sawyer

Although backfilling has been in operation for many years, the methods for selecting appropriate slurry dewatering aids have, in some cases, been rather unsophisticated. This has led to many misconceptions regarding the role of the dewatering aid and its various means of application. Testing procedures employed in the correct selection of any practically applied dewatering aid must mirror the actual working processes in which they are to be used. This constraint necessitates the development of complex testing methods when applied to backfilling. The current testing procedures were scrutinized and their various merits noted. From this study a series of testing methods was evolved which incorporate the best aspects of these testing procedures with novel ideas which would eventually result in the correct selection of the dewatering aid. A major consideration in the application of any of these methods is the modus operandi of the backfilling process, and the relevance of the tests to the process. This work attempts to consolidate the testwork performed in the past and suggest new approaches in the correct selection of acceptable dewatering aids for backfilling.

Jan 1, 1988

By M. David

This paper addresses the problem of technological transfer in geostatistics. Expert systems have become popular in certain fields because the needs of the industry are not provided for by traditional concepts and systems of education. The explicit knowledge approach in developing expert systems is presented through two experiments. The first describes a dedicated system written in GOLDEN LISP and the second a shell, using INSIGHT2, which has more general applications. Using expert systems forces on the user a new approach to parameter definition, and as an example an original method for the research of any anisotropy axes is developed which might well be useful in traditional programming. Two examples of application to a coal and a gold deposit are given.

Jan 1, 1987

By K. Eckert, A. E. Sommer, S. Heitkam

One highly relevant challenge in flotation is the recovery of fine particles. Due to their low inertia, these particles are mostly pushed aside by rising bubbles. Consequently, they typically exhibit low probability for bubble-particle collision and thus, a poor recovery rate. In this work, the trajectories of fine particles in the vicinity of rising bubbles were investigated. The measurements considered a chain of millimetric bubbles in a rectangular container filled with deionized water. The flow field near the bubbles was measured by tomographic particle image velocimetry (TPIV), employing fluorescent tracer particles of 33μm diameter. Subsequently, trajectories of larger particles and bubble-particle collision events are recorded with 4D particle tracking velocimetry using a high temporal and spatial resolution. The results reproduce the well-known collision of particles on the leading edge of a rising bubble. Additionally, collisions on the tailing edge were observed in cases with a low Stokes number. The TPIV results demonstrate, that the high turbulent kinetic energy in the bubble wake allows particles to divert from the fluid streamlines and collide with the tailing edge of the bubble. The tailing edge collision probability increases with the bubble Reynolds number and decreased particle inertia. Overall, the investigation shows that the collision of fine particles in the bubble wake should be considered for the development of further collision probability models. Furthermore, the importance of turbulence on the fine particle flotation was demonstrated. Keywords: 4D Particle tracking velocimetry (PTV), tomographic particle image velocimetry (TPIV), fine particle flotation, collision probability, bubble-particle interaction, wake induced collision

Jan 1, 2020

By C. -I. Lee

Since the early 1970s, Korea has constructed many large-scale tunnels and underground storage caverns in response to the rapid industrial development. The rock mechanics engineers have accumulated valuable experiences in the area of underground space technologies. But they still face technical challenges in environmental and safety aspects. To discuss those challenges in Korea, a brief engineering description of underground space projects including oil and gas storage, food storage, pumped storage power plant, transportation tunnels, waterway tunnels, and radioactive waste disposal is presented. Mechanical and hydrological stability analyses of the storage caverns in Korea are also introduced. Depuis le début des années soixante-dix, le développement industriel rapide en Corée a entraîné la construction de nombreuses galeries et cavernes de stockage souterraines. Les ingénieurs de mécanique minière ont donc accumulé des expériences précieuses dans le domaine de la technologie de l’espace souterrain. Cependant, ils font toujours face à de nombreux défis techniques en ce qui concerne les aspects de l’environnement et de la sécurité. Pour présenter ces défis en Corée, l’étude présente décrit les projets d’espace souterrain, y compris le stockage de pétrole et de gaz, de nourriture, centrales de stockage pompé, tunnels de transport, tunnels navigables, et évacuation des déchets radioactifs. Des analyses de stabilité mécanique et hydrologique des cavernes de stockage en Corée sont aussi présentées. Seit Anfang der 70er-Jahre, baute Korea in Folge raschen Industriewachstums viele lange Tunnelsund unterirdische Lagerungsräume. Fachkräfte im Bereich Gesteinsmechanik sammeltenwertvolle Erfahrungen über unterirdische Raumtechnologien. Dennoch stehen sie auch heute nochvor technischen Herausforderungen im Bereich Umweltschutz und Sicherheit. Zur Erläuterungdieser Herausforderungen in Korea folgt eine kurze technische Beschreibung der Projekte zurSchaffung unterirdischen Raumes für beispielsweise Öl- und Gaslagerung,Nahrungsmittellagerung, Pumpspeicherwerke, Straßen- und Wasserstraßentunnels, als auchLagerung radioaktiven Mülls. Mechanische und hydrologische Stabilitätsanalysen derLagerungsräume in Korea werden ebenfalls dargestellt.

Jan 1, 2003

By S. K. Gilman, P. S. Marcos

There are basic areas of importance within a concentrator or mineral separation plant, which require focus to ensure acceptable recoveries, throughputs remain at an acceptable level and product grades meet specification. Professional and para-professionals within the mineral sands industry are in demand due to the booming resource sector. Added to this, new mineral sands operations are being commissioned straining the industry further. These factors have increased staff turnover and introduced many new people to the industry. It is essential these new entrants are armed with basic plant troubleshooting skills relevant to the minerals sands industry to minimize production lost through poor recoveries. Mineral sands processing does not involve highly technical or sophisticated unit processes. However, success is often slow to arise due to a lack of detailed understanding, as well as managing multiple interrelated unit processes within a plant. Fundamental background physical conditions (such as equipment loading and water quality) must be met for unit processes to be efficient. Technical management of these process plants should always include observation of these background conditions for they often provide the answer to underperformance. Examples are presented with an indication of the possible effects on recovery and product grade.

Jan 1, 2007

By M. J. Santofimia

Multiphase microstructures in steel have been intensively studied in the past years, but combining non-equilibrium phases still offers a great potential for further development of these steel grades. Thus, improved combinations of mechanical properties can be obtained with microstructures formed by bainite or martensite, in combination with retained austenite. In particular, microstructures on the basis of carbon-depleted martensite and retained austenite can be produced by the very promising production process named quenching and partitioning (Q&P). Originally, the Q&P process aimed to avoid the formation of bainite during the heat treatment. However, the process does provide the possibility for (carbide-free) bainite formation during the partitioning step, i.e. in the presence of martensite. This article evaluates this approach, considering thatthe formation of bainite from austenite is strongly influenced by the preceding formation of martensite. Although the accelerating effect of the presence of martensite during bainite formation has been observed, it is not yet fully understood, and experimental and theoretical studies are being performed in order to come to a more effective exploitation of these processes for the formation of multiphase microstructures.

Jan 1, 2013

By N. Steven

Published parameters from the Mufulira copper in situ leach (ISL) in Zambia are used for order-of-magnitude flow-rate calculations for an envisaged gold ISL in back-filled Witwatersrand stopes. A successful leach operation requires that the porous medium, usually a sand, has a hydraulic conductivity in excess of 5 x10-7m/second (i.e. a permeability >50 millidarcies).Empirical evidence suggests that average linear velocities would be of the order of 60 m/day if the backfill has the grain size of a fine sand. The proposed gold lixiviant would probably be an alkaline or ammonium thiosulphate, not cyanide. The resultant sulphate-rich ground and drainage waters could probably be processed using existing purification techniques to produce gypsum and magnesium/calcium carbonate. Within the next 100 years it is inevitable that solution mining will find widespread application on the Witwatersrand, if not for gold extraction, then certainly for water remediation purposes.

Jan 1, 2009

Acid heap leaching has been extensively applied to the processing of copper oxide ores, with recovery of copper by solvent extraction and electrowinning. Heap leaching has also been extended to the treatment of secondary sulphide copper ores, where oxidative conditions are generated in aerated heaps by the bacterially-assisted oxidation of ferrous iron to ferric iron. The treatment of low-grade chalcopyrite ores has recently been the focus of research, with Mintek playing a prominent role. When processing chalcopyrite ores, more complex column test work is performed, which incorporates the prediction and simulation of temperature behaviour in pyrite-containing heaps. Mintek has devised a trade-marked column leaching apparatus (SmartColumn?) for the simulation of the natural temperature profile development in pyrite-containing heaps. As heap leach applications are becoming more complex, the parameters that need to be built into the design and operation of heap leach plants are growing in number, and the amount of data to be collected and processed, and the number of decisions to be taken daily, are also increasing. Mintek has therefore developed the HeapStar® administrative advisory software, as a guidance system to ensure that the correct protocols are implemented at various stages of the leach cycle.

Jan 1, 2012

By R Linares

For centuries, diamond's superlative properties have earned it a reputation as the 'dream' material for mankind in its search to create advanced applications. Until recently, this dream has been realized only in the use of diamond for gemstones and abrasive applications where several tons of diamonds are now used on an annual basis. The vision of having large, high quality diamond as part of a broad engineering tool-kit for many diverse high tech industries is now becoming a reality however, with the advent of early stage commercial availability of single crystal and poly crystalline CVD diamond.

Jan 1, 2010

By L. Bloch

Most mine safety initiatives in South Africa are doomed to limited success because of one simple fact: they are a-historical and un-cultural and do not deal with the serious ?legacy issues? that still negatively impact on safety, production, and relationships. We in the SA mining industry continually use imported, foreign safety concepts and systems that will not work fully in a South African context. ?The 4th Wave: Culture-Based Behavioural Safety?, as developed by Lance Bloch, an international award-winning clinical psychologist with 12 years? experience in the mining industry - focused mostly on Platinum - is making waves. He has been very successful in creating people-centred, empowered, high-performance safety cultures wherever he has worked. Not only does the 4th Wave transform the corporate culture of a mine, improving safety and production and building an environment of Ubuntu, but it also uses people?s cultures as a means of winning hearts and minds in the battle for safe production. Powerful relationships are built through engagement at all levels, leading to all being focused on the best needs of the company and its constituents as a whole. The programmes are no less than nation-building - something most necessary in the industry, with the pressures from community, unions, the DMR, and politicians. This presentation will describe and discuss the 4th Wave as an advance on previous safety technology and programmes, as particularly relevant to platinum mining in South Africa today.

Jan 1, 2012

By J. A. L. Napier

An analytical solution to the best choice of cutoff grade for a mine is deduced for an assumed model of selective mining. It is found that this choice is determined by the constancy of a special function, the Hamiltonian, over the life of the mine. It is suggested that the appropriate constant value for this function should be determined by the expected long-term average of the paylimit. In that case, the optimum profile can be calculated at each point in time according to the prevailing working cost and product price. In particular, a decision can be made between operation at the true paylimit or at the subsidized paylimit implied by either the lease and tax formulas or the assistance formula for gold mines. It is also shown how the basic formulation can be extended for 'use in the determination of the optimum joint paylimit for two products over the life of the mine.

Jan 1, 1983

By F. Lombard

We consider in this paper the use of a modified version of Hotelling?s statistic in the analysis of particle size distributions. The statistic can be adversely affected by the presence of outliers among the data. We propose a competitor to the statistic that is based on ranks, and hence is less sensitive to outlier effects. The results of a Monte Carlo study suggest that the rank test is highly competitive with the Hotelling test in its ability to detect differences between two mass size distributions. The calculation of the rank statistic is explained in detail and its application is illustrated on two sets of data.

Jan 1, 2012

By B. Rezai, Z. Pourkarimi, M. Noaparast, S. Chehreh Chelgani

Nanobubbles (NBs) flotation separation can be an indicator for improving the efficiency of fine particles through the conventional process. Since flotation reagents such as frothers can reduce bubble size, they can potentially be used for the generation of NBs and develop a selective NB flotation separation. This study explored the flotation separation of fine phosphate particles from their associated minerals in the presence of NBs, which were generated by using a phosphate flotation reagent (Flo-YS: collector-frother). The results of flotation tests showed that in the presence of NBs, the flotation efficiency was significantly improved. However, in the presence of NBs, surface chemistry analyses (Fourier Transform Infrared Spectroscopy and High-Performance Liquid Chromatography) illustrated that the collector adsorption on the surface of phosphate particles decreased. A comparison between outcomes of various phosphate flotation conditions indicated that increasing the flotation efficiency in the presence of NBs may be due to the aggregation of fine particles by the generated NBs, and also selective adsorption of NBs (hydrophobisation) on the surface of particles. In other words, generating NBs by selective collectors may increase efficiency and decrease the collector consumption of a flotation process. Keywords: Phosphate, selective separation, fine particles, collector-frother, efficiency, mechanical flotation cell

Jan 1, 2020