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By B. Dimitriades

Experimental work has been done to refine and to confirm an analytical procedure by which gas-liquid chromatographic (GLC) spectra are interpreted from retention time data alone. The rationale of this spectra interpretation technique involves whether or not a given peak invariably represents the same component or component mixture; if not, what factors influence changes in peak identifications. To answer these questions, peak-identification procedures, based mainly on the use of subtractive columns, were developed and applied to interpret GLC spectra of several exhaust (and fuel) samples.

Jan 1, 1972

By Stephen R. Wilson

This paper is one of a series published by the Bureau of Mines on the mineral resources of the Nation. It describes briefly the occurrence of sodium sulfate in Salt Lake and Tooele Counties, Utah, presents data on sampling, and describes ex-traction and refining raw material and a mining research project that has been conducted on the deposits. ACKNOWLEDGEMENTS Acknowledgments are given to the Tintic Standard Mining Co., Salt Lake City, Utah, and Bartlett Chemicals, Inc., New Orleans, La., for permission to use data obtained by the companies. The authors also acknowledge the courtesy of J. A. Marsh and H. K. Thurber, geologists and mining engineers, for permission to use information in reports prepared by them.

Jan 1, 1957

Measure dangerously high concentrations (20 to 500 g/m3) of flammable, airborne dust. Approach Development of high concentration dust monitor (HCDM) which will measure mass concentrations of air borne dust by the principle of beta-ray attenuation. How It Works The HCDM is a battery powered, portable instrument that weighs 10.5 kg. It is capable of making continual (10 sec. time resolution) measurements of high concentrations of airborne dust and can record up to 8 hours of data in an internal memory. The data can be read out later on an analog or digital recorder. An internal pump pulls airborne dust into the sampling section, which contains a low-energy beta-ray source and a Geiger counter detector. No beta radiation escapes from the instrument, and no license is required for the operator. The mass concentration measurement is made while the dust is still airborne. Beta-ray attentuation is independent of particle size and composition of the dust, so the HCDM can he used with many types of dusts which may be airborne in flammable concentrations. A knowledge of the composition and minimum explosive concentration of the dust is necessary to understand the significance of the data from the HCDM. The HCDM was designed to measure air-

Jan 1, 1982

By Wilbur I. Duvall

In this report, the Bureau of Mines presents a theoretical solution for the stresses and displacements in an infinite elastic plate containing a circular hole the boundary of which is loaded by applied radial stresses over four separated arcs. The problem solved is a two-dimensional approximation of the stresses and displacements developed by a large tunnel-boring machine anchored in a circular tunnel. Analysis of the solution shows that the tangential tensile stresses induced on the boundary of the circular opening can be minimized in the roof and maximized in the floor of the opening by proper spacing and loading of the four arcs.

Jan 1, 1967

By Steven M. Shope

The Bureau of Mines electromagnetic trapped miner location and communications system requires a thorough understanding of through-the-earth electromagnetic wave propagation. An earth model incorporating a magnetic dipole buried in a three-layered earth has been developed. The dipole source is located in the second subsurface layer. By application of proper limiting values, the three-layered model is reduced to two different two-layered models and eventually to the homogeneous half-space model. The solutions are in the form of infinite integrals. A numerical analysis was carried out and a computer program written to evaluate the surface magnetic fields. Numerical values for the magnet- ic field at the point above the source are presented in a variety of models.

Jan 1, 1982

By John C. Edwards

A two-dimensional, time-dependent, mathematical model has been developed that describes fire spread along the walls of a ventilated duct. The model is based on the assumption that the leading edge of the fire zone propagating along the wall surface coincides with the isotherm for the fuel ignition temperature. The model includes gas-phase energy transport via radiation and forced convection inside the duct and solid-phase energy transport by conduction into the fuel lining. Product gases emitted from the fire zone are assumed to mix uniformly with the ventilation gas to produce an optically dense gas mixture at the combustion temperature that enters the preheat region. Numerical solutions of the model equations for a coal-lined duct (simulated coal mine entry) have been used to investigate the effects of tube radius, air velocity, combustion temperature, and optical density of the soot-laden gas upon the terminal fire spread rate.

Jan 1, 1977

By G. B. Fritts, A. C. Moschetti

"INTRODUCTION The act of Congress establishing the Bureau of Mines in 1910 delegated to the Bureau, as one of its principal duties and functions, the study of health and safety in the mineral industries with a view to devising and putting into operation means of conserving the health and safety of persons employed in the industries. One of the first health and safety activities of the Bureau of Mines was therefore organization of a trained force to promote instruction in first aid in the mineral industries. First-aid training has been an important activity of the Bureau of Mines since its establishment. The standard first-aid course requires a minimum of 15 hours of instruction and practice work. A person completing the initial training course is issued an engraved certificate and pocket card certificate; thereafter, only a pocket card certificate is issued for additional training.From 1910 to 1926 first aid was taught by trained Bureau of Mines employees; consequently, only a comparatively few persons were trained. In 1926, however, cooperative first-aid training was initiated, which provided the means to train the entire personnel of mines or plants within a short time in a single campaign. Many mines and plants have taken advantage of the cooperative plan, whereby keymen in a mine or plant, in addition to the initial training received, are given intensive training in first aid by a Bureau of Mines instructor. Those men who show an aptitude for teaching are selected as tentative provisional first-aid instructors. In order to qualify as a provisional instructor, a tentative instructor must, under the supervision of a Bureau of Mines instructor, train a class of at least six persons employed in the minerals industries in the standard Bureau of Mines course in first aid. After it has been determined that the class has been trained properly, a provisional first-aid instructor's pocket card certificate is issued to the class instructor. The first-aid instructor can renew his pocket card certificate each year by training or retraining at least six persons connected with the mineral industries to satisfactorily pass an examination given by a Bureau of Mines representative. After five yearly renewals of a provisional instructor's pocket card certificate, an engraved, permanent instructor's certificate and a permanent instructor's pocket card certificate are issued to the instructor."

Feb 1, 1955

By T. F. Anstett

The Bureau of Mines investigated the availability of platinum from known major deposits in market economy countries. Fifteen of these deposits contain demonstrated resources totaling 302 million troy ounces of platinum. Detailed geologic, engineering, and cost evaluations were performed on each deposit to determine its potential for platinum production. There are large amounts of demonstrated platinum potentially available from market economy deposits that were not analyzed owing to lack of adequate data or to technological limitations. These include 297 million troy ounces contained in the UG2 and Platreef of the Bushveld Complex, South Africa. This analysis indicates that about 11 0 million troy ounces (2.3 million ounces annually) of platinum are potentially available at the January 1980 producer price of $420 per troy ounce, nearly all from South Africa. An additional 85 million troy ounces occurring in Zimbabwean deposits would become available only through more than a quadrupling of that price. In order to meet projected world demand of 3.5 million troy ounces in 1990, platinum price may have to increase. Only one domestic deposit, the Salmon River in Alaska, is capable of producing platinum at $420 per troy ounce. Regardless of price, at assumed production capacities, domestic deposits could supply less than 10 percent of annual U.S. requirements.

Jan 1, 1982

Provide an inexpensive, simple means of supporting highly yielding ground In underground mines. Approach The Bureau of Mines developed a high capacity support post made from standard steel pipe which, when using a 60-inch post configuration, has a 45-ton capacity and a yield length of 24 inches. How It Works The post mechanism is a three-piece unit consisting of a top and bottom leg (made from standard steel pipe) and a separate foot bracket. During installation in the mine, the bottom leg is placed on a relatively flat surface on the mine floor and the top leg is placed over it until its flared end contacts an expansion ring attached to the bottom leg. As the roof and floor converge, the flared end of the top leg is forced into the expansion ring, causing the walls of the top leg to be deformed radially and along the axis. The mechanism will yield until the unit bottoms out after about 24 inches of yield.

Jan 1, 1987

By G. M. Molinda, J. P. Ulery

Since 1970, abnormally high methane emissions have been observed in eastern sections of the Federal No. 2 Mine operating in the Pittsburgh Coalbed in northern West Virginia. The nature and volume of these emissions indicate a source other than the coalbed. An investigation was undertaken to delineate probable methane sources. Gas well information and stratigraphic correlation of corehole data indicates that a sandstone directly above the main coalbed is an additional source of methane emissions. The sandstone body appears to be an ancient stream channel, infilled with fine-grained sand and organic matter. Coalification of the organic matter produced methane as a byproduct. Additional methane presumably migrated into the sandstone unit from the subjacent coalbeds. The methane became trapped in the porous clasticunit by the surrounding impermeable strata. Mine development near this unit creates a significant pressure gradient, triggering abnormal methane emissions into the mine along naturally occurring fractures. Pre-development methane drainage of the sandstone could be accomplished by completing vertical boreholes along its trend.

Jan 1, 1984

By Howard E. Parkinson

The mine pager phone to public telephone interconnect system permits mine paging telephones to be interconnected with the public phone system, thereby providing emergency and off-hours communications. The system, a push-to-talk, push-to-listen system, is compatible with any mine paging system utilizing dc voltage on the line to enable paging. A tone generator of the proper frequency enables an outside caller to page over mine pager system loudspeakers. A caller inside the mine can make an outgoing call to a preselected, preprogramed number with the use of a proper frequency tone generator. The system includes an automatic hangup timer that restricts the time off-line due to a wrong number or incorrect hangup to 20 seconds and 6 minutes, respectively.

Jan 1, 1974

By Erica E. Hall, Robert H. Peters, Charles Vaught, Jon C. Volkwein

Coal Workers Pneumoconiosis is the leading cause of death due to occupational illness among coal miners. This disease is caused by miners’ exposure to respirable coal mine dust. A Personal Dust Monitor has recently been developed to provide near real time feedback to miners regarding the number of milligrams of respirable coal mine dust in the air they breathe. This paper was prepared by the National Institute for Occupational Safety and Health to document coal miners’ reactions to this new device, and how they make use of the information it provides. Structured interviews were conducted with 30 coal miners at four mines. A four-stage conceptual model of miners’ decision processes with respect to how they interpret and respond to the dust exposure numbers from their personal dust monitor is proposed. The stages are: Diagnosis, Action Planning and Intervention, Evaluation, and Institutionalization. The interview responses provide considerable support for the model. Most miners paid attention to Personal Dust Monitor feedback and made efforts to reduce their dust exposure. Their efforts included: changing where they positioned themselves, making ventilation system improvements, and using respirators more often. The 29 miners who reported having experience wearing both the old and new type of dust monitors were asked which dust sampling system they preferred. Eighteen (62%) preferred the new monitors, 7 (24%) preferred existing monitors, and 4 (14%) had no preference. The most frequently cited advantage of the new monitor is its ability to provide relatively quick feedback on dust exposure. Miners provided several suggestions for improving the design of the instrument.

By Robert G. Yewen, Ronald S. Conti

Underground mines rely on alarm systems, such as stench gas, audible or visual alarms, pager phones, telephones, and messengers to warn miners of a fire or other emergency. These systems are often slow, unreliable, and limited in mine coverage. This report describes the evaluation of a wireless signaling and warning system for underground mines. This system is applicable to both coal and noncoal mines. The work was conducted by the National Institute for Occupational Safety and Health in cooperation with TeleMagnetic Signalling Systems (TSS) under Cooperative3Research and Development Agreement No. BOM-CRDA-6200-0119. A TSS wireless ultra-low-frequency electromagnetic signaling system was installed at the Experimental Mine at Lake Lynn Laboratory near Fairchance, Fayette County, PA. A commercial smoke sensor was interfaced to a remote portable transmitter, and the alarm of the sensor was used to trigger the central evacuation and paging transmitter system during experimental mine fires. The underground/surface receivers flashed cap lamps and activated remote devices, such as strobe lights, within 30 to 40 s after the encoded signal was received. Evaluation results showed full-mine coverage of the electromagnetic field and that the encoded signal was received at the farthest point underground and on the surface perimeter.

Jan 5, 1997

By Basil Dimitriades

The association of automotive fuel composition with exhaust reactivity was studied in an experimental program that involved testing with different automotive engines and with gasolines of varied composition. Results showed clearly the exhaust reactivity to increase with increasing levels of polyalkylbenzenes in the fuel. No other systematic patterns of high significance were detected in the association of exhaust reactivity with several broadly defined groups of fuel components. For the purposes of this study, had it been possible, fuel composition should have been defined and expressed in terms of component groups such that the potential for exhaust reactivity would be the same within each group and different from group to group. Classification of fuel components in terms of the paraffins-olefins-aromatics groups does not meet the latter requirements. For appropriate classification of fuel components more information is needed on the combustion .of hydrocarbons in the multicylinder internal combustion engine. Statistical analysis of the mass emissions data showed significant car and fuel effects on hydrocarbon, carbon monoxide, nitric oxide, total aldehydes, and formaldehyde emission levels and on total photochemical reactivity. Car-fuel interactions were not significant at the 90-pct level. Correlations were found between mass emission parameters and fuel composition.

Jan 1, 1973

By J. D. Dixon

The Bureau of Mines has developed structural design data for unreinforced concrete tunnel linings in the form of stress and deflection coefficients from which bending, axial, shear, and boundary stresses, moments, thrusts, and shear forces, and structural deflections can be determined at any point on the lining. Results were obtained by structural analyses of nine concrete-lined tunnel configurations subjected to 22 biaxial load conditions. The tunnel configurations include three basic shapes, circular, rectangular, and horse-shoe, with dimensions based on designs evolved by the mining industry. These analyses were made by the direct stiffness matrix method, a computer-oriented procedure. Numerical results agree closely with those obtained experimentally.

Jan 1, 1969

By C. W. Dwiggins

The Bureau of Mines characterized the chemical and physical properties of metallo-organic materials in petroleum to determine their effect on petroleum production and refining. The structures and physical properties of porphyrins and materials that normally contain metalloporphyrins such as crude oils and asphaltenes were investigated using elemental analysis, NMR analysis, absorption spectrometry, and small-angle X-ray scattering. Petroleum fractions greatly enriched in metalloporphyrins were obtained using asphaltene precipitation, liquid extraction, and large-scale liquid-solid chromatography. Selected fractions containing porphyrins were further purified by chromatographic methods, crystallization, and demetalation followed by chromatography. Nonporphyrin metals could not be appreciably concentrated from the bulk of the asphaltene.

Jan 1, 1969

Large quantities of combustible materials are often found in underground metal and nonmetal mines, with support timber predominating. Wood lagging and timber, wires and cables, brattice cloth, hose, paper products, cardboard cartons, and wooden containers are additional combustible materials commonly found in underground storage areas. Shorted or overloaded electrical cables, worn sockets and plugs, spontaneous combustion, careless smoking, and welding and cutting are common fire ignition sources. Inexpensive, reliable fire detection and suppression systems are available to provide early warning and to extinguish fires that originate in underground storage areas.

Jan 1, 2011

Develop an alternative to water bath exhaust conditioners (water scrubbers) for permissible diesel equipment used in gassy mines. Background Water scrubbers are a safety device used on diesel-powered vehicles in gassy mines. Exhaust from the engine passes through the scrubber, where it is cooled, and any flames or sparks present in the exhaust are extinguished. This prevents the ignition of combustible mine dust or methane that may be present. Unfortunately, water scrubbers consume large amounts of water and require frequent maintenance. Approach Methods that do not require water replenishment and frequent maintenance were investigated. The dry exhaust conditioning system was selected for investigation because no water is consumed and existing heat exchanger technology can be adapted to underground mine vehicles. In accordance with U.S. Mine Safety and Health Administration (MSHA) requirements, the system was designed to cool exhaust and trap flames and sparks. The U.S. Bureau of Mines (USBM) developed and evaluated a system for large engines and evaluated a second system for smaller engines. Both systems were evaluated on an engine test bed; if warranted, the system was then tested underground.

Jan 1, 1993

By E. J. White

Data from oil well logs and core analyses were used to quantitatively evaluate formation porosity and water saturation of heterogeneous carbonates and to study the pore geometry and performance characteristics of cores from these formations. Logs and cores from the Madison limestone from 233 wells in three fields in the Williston basin were used in the investigation. A comparison of log and core analyses shows that log porosities are consistently larger than core porosities, and the differences are correlatable with core porosity ranges. Water saturations from logs are usually smaller than the corresponding core saturations by summation of fluids, but the difference is attributable to mud filtrate invasion into the cores during drilling. Petrophysical studies show that the low permeabilities and high residual water saturations in these reservoir rocks are due to their fine crystalline texture and complex pore geometry (heterogeneity). It is concluded that both log and core analyses must be used for reliable evaluation of these carbonate formations.

Jan 1, 1971

Promote safer and more efficient mine operations by providing communications between personnel located anywhere in the mine. Approach A radio communications system was designed which takes advantage of existing mine wiring such as telephone lines or electric power cables. The existing wiring distributes radio signals throughout the mine, making communications possible between roving miners, vehicle operators, dispatchers, and other personnel. How It Works Research has shown that medium frequency (MF) signals (300 KHZ-3 MHZ) can couple onto and re-radiate from nearby conductors. This effect is known as parasitic coupling and re-radiation. In a mine, these conductors include electric power cables, control lines, telephone lines, trolley lines, as well as metal water and air pipes Since all underground mines require these conductors for normal operations, the necessary network already exists and expands automatically as the mine is developed. A radio communication system has been developed that uses the parasitic coupling and re-radiation characteristic of MF. Using this system, whole mine radio coverage can be achieved without the need to install or maintain communication lines. The system consists of mobile transceivers for roving personnel and vehicles, and fixed-location base radio stations and repeaters.

Jan 1, 1982