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By P. A. Riveros

Antimony is commonly found in copper electrolytes and can contaminate the cathode deposit. Several methods, such as ion exchange, solvent extraction and precipitation, have been developed to remove antimony from copper electrolytes. However, past research has been carried out almost exclusively with Sb(III), whereas the presence and behavior of Sb(V) in the electrorefining circuit have been largely ignored. In this study, the behavior of Sb(V) species was monitored and compared to that of Sb(III) species, using specially developed analytical and SEM-EDS techniques. Significant differences in the behavior of the two species were noted. Although the solubility of Sb(III) increases with temperature in synthetic copper electrolytes, the solubility of Sb(V) appears to be constant over the range from 30 to 80°C. Whereas Sb(III) forms several crystalline oxy-sulphate compounds, Sb(V) appears to remain as an amorphous oxide. Both Sb(III) and Sb(V) are extracted by aminophosphonic resins, and Sb(III) is readily eluted by HC1 or complexing agents. By contrast, concentrated HC1 elutes Sb(V) inefficiently and complexing agents, such as EDTA and tartaric acid, do not elute Sb(V) to any significant extent. This observation implies that in industrial practice, unless special measures are taken, Sb(V) will accumulate on the resin, eventually impeding the ion exchange process.

Jan 1, 2007

By David Morrison

Our present longwall problems in Cape Breton can be grouped under five main classifications. These are: (1) Roof control on the face and on the main roadways leading thereto. (2) Transportation of coal along face and levels. (3) Mechanical loading at the face. (4) Safe method of conducting and applying power at the working faces. (5) Dust nuisance. The usual layout for longwall operation in Cape Breton is to have three, and sometimes four, faces in line with each other, the length of face being from 400 feet to 500 feet (see Figure 1), and producing between 425 and 500 tons per face. Each wall is serviced by a well constructed roadway for transportation of coal, men, and materials, and is operated as an independent unit. Each wall works under a regular cycle of operations: first, cutting and boring; second, drawing hardwood chocks, building midwalls, and shifting panlines; and third, loading. The present method of roof control and operation of longwall faces has developed through trial and error since the commencement of longwall miring in Cape Breton. The basic method of roof control in all longwalls in Cape Breton is: rigid support of the roof in the immediate vicinity of the working faces by hardwood blocks, as shown in Figure 2, accompanied by a cushion support furnished by continuous midwalls, 12 feet wide, constructed of stone obtained from the waste and spaced at 50-foot centres. These midwalls are kept forward to within 4 feet to 10 feet of the working face and allow a gradual subsidence of overhead strata, thus preventing any sudden break at the working face.

Jan 1, 1947

By L. O. Cooper

IN THE operation of most mines, hoisting ropes, made of steel, play a very important part in the conveying of men and material between surface and the underground workings. It is obvious that, in order to maintain a maximum degree of safety, certain restrictions must be placed on the loads that may be carried by hoisting ropes, as well as on other factors that may affect the life of the rope. It is the purpose of this paper to suggest ?a new method of defining the necessary restrictions. The three main stresses in a hoisting rope are the static stress, bending stress, and dynamic stress. Crushing stresses, which are also present, are largely indeterminate and may best be allowed for by proper grooving of drum and sheaves, by adequate inspection of cross-over points, and by limiting the number of layers on the drum. They will, therefore, not be considered in this analysis. In the ?recent Ontario regulations, the limiting conditions for the main stresses are specified separately. The static stress is limited by setting a minimum static safety factor of 5.0 The dynamic stresses are allowed for by specifying a minimum capacity factor of 8.5, which has the effect of increasing the safety factor required at smaller depths in a uniform manner. The bending stresses are limited by calling for a drum-dia./rope-dia. ratio of at least 60 for ropes up to 1 inch in diameter and 80 for ropes greater than 1 inch in diameter. One disadvantage of this method is that the controls are too rigid and do not allow the operator sufficient freedom of action within safe limits.

Jan 1, 1951

By W. C. Ferguson

"This paper could be more appropriately titled ""The Application of Vacuum Filters to Underground Minewater Treatment. in a previous paper co-authored by the writer (1) the history and development of minewater treatment at the Sudbury District Operations of the International Nickel Company was outlined. It is the intention of this paper to dwell more specifically WIth the the application of the vacuum filter to a problem found in most, if not all, underground mining operations. In the preparation of this paper the writer has made liberal use of the illustrations and text of the paper previously noted.Last year we heard Mr. Nemeth discuss the basic mechanisms involved in vacuum filtration (2), and today Yr. Cunliff has exposed us to the selection of the filter media (3). I will now briefly review the various vacuum filter designs that generally lend themselves to metallurgical dewatering applications.DRUM FILTERSThe revolving drum-type which filters on its outside periphery is illustrated in Fig. 1. This is the Oliver or Drum filter and represents the first commercially available continuous vacuum filter. The original design dates back more than 50 years, but with the exception of the method of discharge, is identical to the units being marketed today. This filter is generally applied to slow filtering slurries. The cake may be discharged in several ways; strings, scraper blades, rolls or by passing the filter cloth over a small diameter discharge roller (belt discharge).THE DORRCO FILTERThe revolving drum type which filters on its inside periphery is illustrated in Fig. 2. Here the slurry lies in the drum and the cake discharges through a chute or conveyor. This type of filter is most often applied to fast-filtering slurries.THE DISC FILTERThe revolving filter which filters on the vertical plane of the disc is referred to as the Disc or American-type filter. This represents the most inexpensive design in terms of cost per square foot of filter area. This filter is widely applied, but is probably more suitable for slower draining pulps."

Jan 1, 1971

By E. Gervais

"In today's marketplace, heavy competition between materials is the norm. This is particularly true f or the base metals, which are being increasingly challenged by new or improved materials in all traditional applications. Current usage of base metals results from a combination of a metal's intrinsic properties, and technology. The future of the base metal industry rests with innovative, high-quality product development, its ability to take advantage of the results of worldwide, massive material R&D investments, and with the dynamism and effectiveness of its market development programs.The ZA casting alloys program is an illustration of the zinc industry’s efforts to protect and expand its market position in the casting field through state-of -the-art technological developments. The market potential f or these advanced engineering alloys is substantial, and their impact on traditional zinc die casting alloy consumption is particuarly important. The ZA alloys, in offering increased performance through zinc castings produced at low cost and by a wide range of moulding processes, have unlocked a multitude of new end-use applications.Following a review of the development of ZA alloys, of their key properties and of their performance characteristics, the numerous challenges that the alloys present to the zinc industry and to the R&D community are discussed.IntroductionZinc is anodic to steel and has a low, uniform rat e of corrosion; it has a low melting point, can be cast with precision , and is readily finished. In addition to its use in protecting steel and in the production of a wide range of castings, zinc is employed : (1) to produce brass, high-strength aluminum alloys and magnesium die casting alloys, (2) in the wrought state for coinage and in building products, particularly as roofing materials , and (3) as an oxide, in the rubber industry, in ceramics, glass, cosmetics, pharmaceutical products and as the starting materials for many chemicals.Zinc die castings are produced with accuracy at high speed, at low cost, are easily finished and have excel1ent mechnical properties . Car fuel economy, changes in automobile styling, competition from other materials, increased sophistication of design and miniaturization have all led to a dramatic change in the volume of zinc consumed for die-casting applications. This has been particularly notable in the United States. Throughout the 19505 and the I960s, casting was the fastest growing major use of zinc; it was firmly established, accounting for 35% of the total zinc consumption(1), By 1983, the volume of zinc being purchased for casting applications had dropped to less than 20% of all zinc consumed in the United States. In the western world(2), consumption for zinc casting application s is currently at about 15%; being nearly equal to the zinc consumed by the brass industry. Coating applications dominate with a consumption of more than 40% of the total market."

Jan 1, 1987

By Balmer Neilly

Early in my term of office it was announced that my Presidential Address would make particular reference to the subject of Mine Taxation in Canada. With this purpose in view there was drafted a Balance Sheet and Earnings' Statement of a Gold Mining Company. This in turn was submitted to the Dominion Income Tax Authorities in Ottawa and to the Minister of. Mines of each of the several Provinces of Canada. The response to the invitation was not as complete as we had hoped it would be, but the figures that were obtained will be presented during the present meeting, and they constitute, I hope, a sufficient basis for extended study and additional enquiry during the year to come ( 1) . In the form letter that accompanied our request to have the submitted earnings assessed, I made the following assertion: "In this work we have three objects in mind. 1.--We will get direct comparison between the different Provinces in Canada. 2.-We will in this way educate our members concerning taxation as it affects the mining industry. 3.-We will publish the details as to how the assessment is calculated by each body, so that a Mine Manager in the most remote district will have a ready reference to guide him in his annual return to the taxing bodies. As things stand, there is no intention of making this a basis for a critical attack on the present rates assessed. It is intended as an authoritative summary of actual conditions as they presently exist".

Jan 1, 1934

By R. H. Keyes Duval

"The one point left off the table was pumping costs, i.e. the cost of pumping to the cyclones.At East Malartic 5 x 5 S R L pumps that had been used to pump the classifier overflow were used to pump the rod and ball mill discharges to the cyclones. Maintenance costs on the pumps rose from $105 in 6 months to $1000 per month. The pumps had to be operated at 1150 rpm and impellers lasted only 5 to 6 days. These pumps were replaced by 6 x 6 S R. L. pumps operating at 825 rpm, but at this speed the coarser sands settled and plugged the pipe lines and the speed was increased to 925 rpm. The maintenance cost is now $100 per m::rnth which is 0 003 cents per ton milled. The impellers now last 1 month and the casing linings 6 months.Density meters are often used on cyclone overflows and sometimes on the cyclone feed. Haliburton weighted tube density meters are used in some plants. They are cheaper than the radioactive density controller, $2500 as compared to $ 6000The angle of the discharge spray from the apex can be used to judge the quality of perform1nce of a cyclone.For ordinary metallurgical applications the inside slope of the cyclone is not too important but for fine separation steeper slopes are used.The cyclone is a versatile tool and will handle considerable variations in feed tonnage - probably up to 15%. Above this variation the number of cyclones used has to be increased or decreased or the tonnage fed to them has to be adjusted"

Jan 1, 1965

By J. Grant Spratt

THE Turner Valley gas-field, situated some thirty miles southwest of Calgary, Alberta, has been the topic of much discussion, particularly from a geological viewpoint. Several papers (1, 2, 3, 4, and 7) dealing with the structural and stratigraphical geology have already been published and are available for reference(l). In this article, the geological conditions will be treated only as they directly refer to the crude-oil prospects along the west flank of the anticline. HISTORY During the past twelve years, Turner Valley has been known mainly as a field which has produced a high-gravity naphtha from relatively large quantities of gas. For about ten years prior to the discovery of this naphtha-bearing gas, which is produced within the upper 450 feet of a dolomitic limestone of Carboniferous age, a minor production of light crude-oil was obtained from overlying sands of Cretaceous age. Up to June 1st of the present year, the field had produced 9,473,582 barrels of naphtha from approximately 829,000,000 M.c.f. of gas. For the past four years, the total daily production of 80 to 90 wells has averaged about 3,200 barrels of naphtha from 250,000 M.c.f. of gas. This is an average of 13 barrels per million cubic feet. The naphtha is extracted from the gas by ordinary gas-oil separators and absorption plants. After the naphtha has been recovered, about ten per cent of the gas is marketed for fuel to supply the cities of Calgary and lethbridge and intermediate cowns. The remaining ninety per cent is burned to the atmosphere, with the exception of some four to five million cubic feet per day which the Calgary Gas Company score in the depleted Bow Island gas-field.

Jan 1, 1936

By J. R. MacDonald

MINING literature contains very few descriptions of operations producing as little as 25 to 30 tons of ore per day. The purpose of this paper is to discuss the gradual development of a mining method for such a small-scale operation at the No. 2 mine of Central Patricia Gold Mines, Limited, and in doing so to review several systems of stoping applicable to narrow ve1ns. MAIN ECONOMIC FACTORS TO BE CONSIDERED (1) Overhead.-The outstanding feature of most mines operating on a single narrow vein is chat of small daily tonnage. The reason for this low output can be readily understood. The strictly limited ore-reserves present a condition unfavourable for a policy of large initial expenditures, with the result that the capacity of the plant provided must be governed by the? amount of ore in sight at the time when mill construction is planned. This is immediately reflected in the cost per ton, there being relatively few tons over which to distributed the more or less static charges, such as hoisting, heating, supervision, administration, pre-production expenses, and other write-offs. (2) Development.-In mining this type of orebody, the main factor contributing to high costs is unquestionably the small tonnage of ore made available by a given amount of development. Thus, for example, from the data tabulated below it can be seen chat, assuming a 12-in. vein and a drifting cost of $9.00 per foot, the development charge for this item alone would be 71 cents per ton. Add to this the charges for raising, cross-cutting, shaft-sinking, and pumping, besides charges arising from development in waste, and the figure will be very considerably higher than 71 cents.

Jan 1, 1941

By Gordon Thompson

"Development of the unique Mine Games exhibition at Science World British Columbia is the largest ever collaboration of many interests to present the story of mining and the issues of mineral development delivered to the public by a science education centre.IntroductionMineral education programs have long been a major focus of the British Columbia mining community. Mine Games and its tremendous potential to enhance industries image and the public's awareness of mining is unequalled in the field of Issue Based Education Exhibits.The main goal of the exhibition is to look at the future of resource industries in a rapidly changing world of economic activities, new technologies, and growing public concern for the environment. Three challenges were the aim of the exhibition: to increase participation, to serve as a tool to increase interest in science and technology, and to draw an increasing number of school students to the interests of geology and the earth sciences. Mine Games is to serve as a meeting place for discussion of issues and where reliable information can be shared and new ideas explored.The exhibition is designed to develop new approaches to hands on learning that encourages visitors to explore and generate discussion and thinking with respect to resource development activities.The role of author, beginning in 1993, was, with senior industry leaders, to coordinate the raising of $1.3 million to complete the funding of the $1.6 million project total. The second and most interesting challenge was to work with the many minds that were collaborating to create the exhibition and to assure that the facts and science were correct. This involved the coordination of ""expert groups"" that verified the science and technology and the issues that the creative design team at Science World planned to use in development of each exhibit module."

Jan 1, 1995

By A. Atef

Vulnerability is a measure of the extent to which a community, structure, services or geographic area is likely to be damaged or disrupted by the impact of particular hazard. Current asset management practices focuses on studying factors that affect performance of isolated infrastructure networks and model a set of actions to control the expected performance of these networks. This approach ignores the underlying spatial and functional interdependencies among these infrastructure networks and their vulnerability. The purpose of this paper is to introduce a new method that recognizes the effect of spatial and functional interdependencies on vulnerability rating of water, sewer and road networks. The proposed method consists of: 1) risk assessment model, 2) interdependency assessment model and 3) vulnerability assessment model. The risk model is composed of two modules: 1) water and sewer risk module and 2) road infrastructure module. The water and sewer risk module will cluster these assets into three risk categories based on environmental, social, operational and economical factors. The road infrastructure module will cluster road assets into three risk categories by using rational factorial technique based on road type, serviceability index, traffic load, and freeze and thaw index. The interdependency model will deploy the risk ranking to perform geospatial analysis in ArcGIS which results in determining the interdependent layers of waters, sewers and roads. The vulnerability model will deploy fuzzy neural networks technique to determine the vulnerability rating based on spatial and functional interdependencies. The fuzzy neural networks are utilized to overcome the lack of historical data and incorporate experts? preferences for establishing the knowledge base for vulnerability assessment. The expected contribution of this framework is to aid decision makers in understanding the interdependencies between civil infrastructure assets and to which extent such interdependencies can compromise assets performance.

Aug 1, 2013

By Alfredo Bambaren

First Encounters between Communities and Mining 1. Importance, meaning and process 2. Antamina?s study case 3. ?Self-organization? theory (NLP) 4. The story we tell, the values we live 1. Importance, Meaning and Process ? First encounter stays in mind as a model. ? First encounter means foundation. ? First encounter builds the story.

May 1, 2010

By Michael Farley, Paul Dufour

"Relationships, Partnerships,Marriages (RPM)RPM has a nice musical ring to it, but it is in fact synonymous with science and technology, university-government -corporate links and the more genera l issue of university roles in technology development. Pick up any report on one of these issues, and chances are that you will find one of these key words in the title. Play it, and you will find that the revolutions per minute are increasing. It is difficult to keep track of the wide variety of institutional experiments now developing in Canadian universities in attempts to marry science and research with technology commercialization and technology transfer.Why is the role of Canadian universities in this matter important? There are at least five good reasons:1. It is important because these knowledge institutions are producer s of scientific research, a major component of technology. Today the gap between the two is rapidly shrinking.2. It ' is important because Canadian industry is turning to universities for tech no logy development and new knowledge. Figure 1 shows that universities are becoming an important source of technology available to Canadian firm s; more important in fact than government. Figure 2 illustrates this trend more graphically in showing that university collaboration is one of the preferred methods of industry participating in co-operative R&D efforts:3. The role of Canadian universities in technology development is also important because the provincial and federal governments have embarked on various programs and policies for promoting the use of technology and science for economic benefit. Universities are playing an increasing role here. For example, the submission of IDEA Corporation (a venture capital operation funded by the government) in Ontario to the Bovey Commission on the Future Development of Ontario Universities clearly spelled out its ideas for commercialization of university research in Ontario . Among other things, the brief suggested that Ontario's universities need to be better equipped to transfer technology, and the reward structure in university research must incorporate industrial interests."

Jan 1, 1986

By W. A. Grell

"The oxygen meter has been in use at MacLeod Cockshutt Gold Mines for over a year, At MacLeod about 200 tons per day of reground concentrate containing roughly 10% pyrrhotite and 20% pyrite is cyanided in four 181 x 18' Dorr agitators. A survey by the Department of Mines showed that oxygen content of some of the agitators was rather low. Experience with our oxygen meter indicates that the oxygen content must at times have been too low for good gold dis solution.We have found that in winter, when pulp temperatures drop to about 50° F, oxygen saturation in the agitators is not difficult to maintain. In summer, however, when pulp temperatures rise to 70or 75°F, the oxygen content will drop very readily. It was found that a high oxygen content can be maintained readily if the pulp is sufficiently dilute. Thus at 50° F, a pulp of specific gravity 1. 75 i.e., about 55% solids, will saturate; but at 70 or 75° F, the specific gravity must be decreased to 1 .45, equivalent to about 40% solids, in order to maintain saturation. Very thick pulps, such as thickener underflows, are noticeably difficult to saturate in the laboratory, and lose their oxygen rapidly.Clear solutions, on the other hand, absorb oxygen readily and hold it. The primary thickener overflow, before agitation, is 100% saturated; after storage of 3 to 4 hours it is still 100% saturated at re clarifier tank. Barren solution after spraying in a launder is 100% saturated.We have not yet attempted to determine what percentage saturation is necessary for good extraction, but it is known that there is a point at which extraction decreases rapidly. So far, the measures required to maintain over 80 or 90% saturation have coincided with measures required to hold the reducing power to the point believed necessary."

Jan 1, 1964

By Staff

Introduction The Hedley mine, perhaps better known as- the Nickel Plate mine, is one of the outstanding properties of southern British Columbia. Discovered in 1898 by Woollison and Arundell, prospectors, the property was bonded in 1899 to M. K. Rodgers for the Marcus Daly Estate, of Butte, and development was started the same year. From the high grade of the ore outcrop, and its colour, due to oxidation of the arsenopyrite, it was not difficult to open up and trace the showing. The Nickel Plate ore-shoot, which apparently had been easy to follow on surface, was more difficult to trace underground. In 1903, prospecting on an adjoining property, the Sunnyside, showed commercial ore at surface, but it was only after two years' work that the ore-body was defined and shipments started. From this property, $1,200,000 have been taken out. Prospecting was also carried on on the IXL, Climax, Copper Cliff, Mound, Bulldog, Exchange, Silver Plate, Gold Plate, and other properties, all of which had surface showings, but up to date only the Nickel Plate, Iron Duke, Morning, and Sunnyside have produced commercial ore. In 1904, the Bulldog looked like a very promising mine, but it failed to make good. In 1905, the Sunnyside No. 1 was in the limelight, but it also failed to make the grade. In 1906, an outcrop on the Sunnyside No. 3 looked interesting. Subsequent work. on this claim produced $840,000, and at the same time ore which yielded $400,000 was mined from the Sunnyside No. 4. In 1908, the Nickel Plate ore-body entered a lean zone and, as the diamond drill failed to give satisfactory results, the Daly Estate, after making a profit of $1,151,000, sold the property to the Hedley Gold Mining Company, Limited, for $760,000, retaining, however, a large interest.

Jan 1, 1929

By A. M. Bell

"Hallnor mine is in the township of Whitney, Porcupine district. To date, its production of gold has been second largest in the east Porcupine field. Ore was discovered in the property in 1936 by diamond drilling in overburdened country. This drilling was undertaken by Noranda Mines following the discovery of ore in conglomerate at Pamour 1 mile to the east.Milling commenced at the Hallnor in June 1938, and to the end of 1945 432,000 oz. gold had been produced from 889,000 tons of ore, giving an average recovery of 0.49 oz. a ton.The West mine of Pamour, the Broulan orebody, and the veins on the Hallnor and Bonetal are all parts of a mile long vein system that has been separated into three sections by cross faulting. In consequence, they could well have been described in one paper. In treating them individually the viewpoint obtained from each may lead to conflicting opinions, and any conclusions advanced in this paper on the general structure should be modified by the conclusions advanced in papers on the neighbouring properties.GENERAL GEOLOGYRock FormationsThe Hallnor orebodies occur within 400 feet of the contact between lavas and sediments, and may lie in either lavas or sediments. The lavas near the ore consist of flows of pillowed andesite and one flow of more acid and less sheared and chloritized lava locally named trachyte. These flows strike east-west and dip steeply. At the surface on the east side of the property the volcanics have been intensely altered to a massive carbonate rock having a north-south thickness in excess of 1,000 feet . This carbonate body extends west across the property with a plunge of 45° (Fig. 1)."

Jan 1, 1954

By Asbjørn Solheim

The service life for aluminium reduction cells is often limited by the cathode carbon, due to preferential wear along the periphery of the cell leading to the so-called "W" wear pattern. The reason for this preferential wear is not well understood. Two mechanisms are suggested in the present paper; 1) non-stationary dissolution of aluminium carbide into a layer of sludge that periodically forms and disappears, and 2) electrochemical formation and dissolution of aluminium carbide within an aluminium carbide layer containing bath-filled pores. The latter mechanism may be related to the high local current density at the periphery of the cathode.

Jan 1, 2011

By Jason A. McLennan

Conditional bias is an infamous problem with estimation methods including kriging. Changing estimation parameters will mitigate, but not remove, conditional bias. The conditional bias of kriging is well understood; however, there is widespread confusion in the literature and among practicing geostatisticians regarding the conditional bias of geostatistical simulation. There is no conditional bias of simulation when the simulation results are used correctly. The correct use of simulation for recoverable reserves estimation is to (1) generate multiple realizations conditional to all available data at a small scale, (2) linearly average all realizations to the chosen block size and (3) calculate the probability of each block being ore and the ore grade of each block. The ?probability of ore? and the ?ore grade? are conditionally nonbiased.

May 1, 2002

By L. Fernandes

A factorial study was performed to investigate the relative effects of temperature, copper concentration and meso-2,3-dimercaptosuccinic acid (DMSA) concentration on the performance of thiosulfate leaching of gold. A total of 24 leaching experiments were performed representing eight unique combinations of high-low levels of the three factors performed in triplicate. All investigations were performed in an electrochemical cell with an electrolyte composed of 0.1 M sodium thiosulfate with a combination of copper (either 0 mM or 1 mM) and DMSA (either 0???or 1µM). All leaching investigations were conducted under open circuit while the electrolyte, which was open to the atmosphere and mechanically stirred, was maintained at either 25°C or 50°C. After 1.5h of leaching the amount of gold in solution was quantified using ICP-MS analysis from an aliquot of the electrolyte. Results indicate that DMSA addition improved gold leaching performance, most notably at 50°C and with addition of copper. Under this unique condition, the quantity of gold in solution was reproducibly and significantly above the average response of all other factors studied.

Jan 1, 2014

By H. Kuboyama

The synergistic effects of polymer additives such as gelatin and polyethylene glycol) (PEG) and Cl- on Cu electrodeposition have been investigated by measuring the polarization curves for Cu deposition, by rotating ring-disk electrode technique and by AC impedance measurements. The cathode potential for Cu deposition was greatly polarized in solutions containing both Cl- and gelatin or PEG, showing evident synergistic effect of polymer additives and Cl- on Cu deposition. The cathode potential was shifted to the less noble direction with increasing the concentration of Cl- in solutions containing polymer additives and showed the maximum polarization at Cl- concentration range between 0.1 and 1 mmol/L. The rotating ring-disk electrode technique revealed that Cu deposition in solutions containing small amounts of Cl- proceeded with initial formation of adsorbed intermediate CuClad. The Cole-Cole plots obtained by AC impedance techniques suggest that the reduction of CuClad is suppressed by polymer additives. The morphology of Cu deposited from solutions containing both PEG and Cl- showed the compacted surface composed of smaller grains due to an increase in the overpotential for Cu deposition.

Jan 1, 2007