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By Hiromichi Ohla

Precise thermal properties of molten materials are essentially required for analyzing the metal production process. These properties are also important as a clue to consider the dynamic structure of liquid materials. However, it is difficult to obtain the precise thermal diffusivity values of molten oxides at high temperature because of the experimental uncertainties arising from the bubble formation or the severe separation of radiative and conductive heat components. Recently a novel laser flash method has also developed for measuring thernnal diffusivity of molten oxides at high temperature. In this new technique, the sample is melted in a metal crucible and heated to the desired temperature. A single laser pulse is flashed on the bottom of the metal crucible and the infrared ray irradiated from the same bottom surface is measured for obtaining the temperature decay, from which the thennal diffusivity of the liquid sample can be estimated. The usefulness and validity of this new laser flash technique have been confirmed by obtaining the thermal diffusivity values of silicate melts in the wide temperature range between 773 and 1673 K.

Jan 1, 2003

By Shubin Wang

Copper(II) and nickel(II) are often recovered from ammoniacal alkaline solutions by solvent extraction using hydroxyoxime extractants: both copper(II) and nickel(II) are extracted from ammoniacal alkaline solutions and, from the loaded organic phase, nickel(II) is selectively stripped with a dilute acid followed by copper(II) stripping with an acid of higher concentration. Since a small portion of ammonia is co-extracted with copper and nickel, the extracted ammonia should be scrubbed using a dilute acid before metal stripping. In the present study, a mechanistic model has been developed in order to support design and control of this process. The equilibrium distribution ratios of copper(II), nickel(II), and ammonia at 298 K using LIX® 84-I (active component, 2-hydroxy-5-nonylacetophenone oxime) as the extractant are successfully correlated by considering the relevant equilibria. Based on these results, quantitative prediction of equilibrium distribution ratios in the process has been made possible, and suitable conditions for the efficient separation of copper(II) and nickel(II) are discussed.

By Robert W. Bruhn

A 125 foot high steel lattice frame tower supporting a 500 kV EHV transmission line and located over the gateroads of a longwall mining operation was subjected to ground movements from the mining of adjacent longwall panels. Under an agreement with the owner of the powerline, the mine operator was required to minimize mining impacts on the transmission line. In view of this requirement, the mine operator prepared a forecast of the expected subsidence ground movements prior to the onset of mining. These forecasts, in conjunction with finite element analyses of the tower superstructure under the imposed ground movements and wind loadings. suggested that the structural capacity of the tower would probably be diminished little, if at all, by mining. Ground movements determined by survey during mining of the two longwall panels were found to be in close agreement with predictions. Strains measured in selected tower members during mining generally agreed with values calculated by the finite element analyses. The study confirmed a methodology to predict subsidence and to assess its effects on steel lattice transmission towers.

Jan 1, 1990

By Hiromichi Ohta

Precise thermal properties of molten materials are essentially required for analyzing the metal production process. These properties are also important as a clue to consider the dynamic structure of liquid materials. However, it is difficult to obtain the precise thermal diffusivity values of molten oxides at high temperature because of the experimental uncertainties arising from the bubble formation or the severe separation of radiative and conductive heat components. Recently a novel laser flash method has also developed for measuring thermal diffusivity of molten oxides at high temperature. In this new technique, the sample is melted in a metal crucible and heated to the desired temperature. A single laser pulse is flashed on the bottom of the metal crucible and the infrared ray irradiated from the same bottom surface is measured for obtaining the temperature decay, from which the thermal diffusivity of the liquid sample can be estimated. The usefulness and validity of this new laser flash technique have been confirmed by obtaining the thermal diffusivity values of silicate melts in the wide temperature range between 773 and 1673 K.

Jan 1, 2003

By Milorad Cirkovic

Kinetics of copper concentrate oxidation in roasting processes in a fluidized bed reactor has been studied at temperatures between 600°C and 720°C using particles of 0.038 to 2.5 mm in average size. The analysis of composition of samples has been done by chemical methods. Phase composition has been determined by Siemens X-ray equipment with Cu anticathode and Ni filters at a voltage of 40 kV and a current of 18 mA. The content of sulphur has decreased from 33.23 to 19.02 mass percent with the increase of temperature, but the content of Fe304 has increased from 0.15 to 17.14 mass percent. The new mechanism of copper concentrate oxidation in a fluidized bed reactor is proposed in this study. It has been shown from the mathematical model that the velocity of oxidation of copper concentrate between 600°C and 720°C is virtually controlled by the rate of diffusion of 02 through the layer of reaction product.

Jan 1, 1999

By Toshiyuki Nohira, Eiichi Takeuchi, Tetsuo Oishi, Hideki Ono, Hirokazu Konishi

The Dy-Nd-Pr-Ni alloy sample was prepared by cathodic potentiostatic electrolysis at 0.65 V (vs. Li+/Li) for 1 h using a Ni plate in a molten LiCl-KCl-DyCl3-NdCl3-PrCl3 system at 723 K. The highest mass ratio (Dy/Nd+Pr) in the alloy sample was observed to be 50 at 0.65 V. Anodic potentiostatic electrolysis at 2.20 V for 12 h was conducted using the Nd-Fe-B magnet electrode in a molten LiCl-KCl system. All elements were almost dissolved from the magnet, and the original form of the magnet disintegrated. After anodic potentiostatic electrolysis at 2.20 V, cathodic potentiostatic electrolysis was conducted at 1.00 V for 5 h using a Mo plate in order to remove the dissolved Fe from the bath. Finally, cathodic potentiostatic electrolysis was conducted at 0.65 V for 12 h using a Ni plate. The mass ratio of Dy/Nd in the alloy sample was determined to be about 18.

Jan 1, 2015

By L. Voisin, K. Mühlenbrock

A new pyrometallurgical process is proposed for cleaning complex copper matte and for recovering copper from copper scrap containing lead. In the process, a given amount of pig iron is added to the complex material under a reducing condition to produce two or three liquid phases at the equilibrium, depending on the content of sulfur in system, of copper-rich and iron-rich alloys, and matte, respectively. The novel process is proposed based on the experimental results obtained by performing laboratory scale tests in an electrical furnace at 1473 K followed by a quenching method on the final stage. The samples obtained from the experiments were analyzed by using Atomic Absorption Spectroscopy (AAS), Inductively Couple Plasma (ICP) and Carbon Infrared Spectrometry (CIS) techniques. The results were discussed on the basis of the distribution of lead as impurity in the miscibility gap where equilibrated phases coexist. According to the mass balance calculations, the elimination of lead into the iron-rich alloy phase as a harmless and smaller deposit might be feasible and the process proposed for cleaning the complex matte would be promising.

Jan 1, 2014

By Ker-Chang Hsieh

Four three-phase equilibria and one two-phase equilibrium in the FeNi- S-0 quaternary system in the vicinity of 1023 K and Pso2 = 1 atm were studied using the following emf cell 2 Pt,o2 (air)Zr02 .CaO/Pso2 = 1 atm, mixture of phases, Au The four three-phase equilibria are sp + (Fe,Ni )S + Ni 3s2, sp + Ni 3s2 + NiO, sp + NiO + N1S04 and Fe2 o3 + sp + (Fe,NOS04 -Y:he two-phase equilibrium is sp + (Fe,Ni)S. The two-.phase equilibrium was measured by using mixtures containing a major portion of one phase and a minor portion of the other. The results are presented in terms of oxygen potential as a function of YNi = nNi/(nN1+nFe) at constant temperature and pso2 = 1 atm. The stability diagram was also calculated using appropriate thermodynamic models for all the pertinent phases. The calculated diagram is in accord with the measured ones.

Jan 1, 1985

By Amjad Asad, Boyd Davis, Kinnor Chattopadhyay, Rüdiger Schwarze, Christoph Kratzsch, Donghui Li, Lei GAO

Sodium (Na) and Lithium (Li) are produced using molten salt electrolysis. The electrochemistry of the electrolyte is well-researched; however, there are benefits to understanding the melt flow and implications on it for cell design modifications. The basic configuration of alkali metal cells is the Downs cell. This consists of a central anode surrounded by a cathode, and this geometry was the basis for this mathematical modeling study. The behavior of gas bubbles in molten electrolyte was studied in both Na and Li cells through the use of computational fluid dynamics (CFD) techniques. The distance between the anode and the cathode was varied in the CFD model to ascertain whether strong circulatory flows would change significantly in the cell. The standard k-ε turbulence model was used to mimic turbulent flow, and a two-way coupled Discrete Phase Model (DPM) was adopted to simulate flotation behavior of chlorine bubbles and liquid metal droplets. The liquid metal distribution on the free surface was predicted using the Volume of Fluid (VOF) multi-phase model.

Mar 1, 2017

By Gustavo Furigo

A Metalurgia do pó surgiu como uma tecnologia incipiente no início do século passado, e desde então é objeto de inúmeros estudos acadêmicos e industriais, utilizada de forma crescente na indústria metal-mecânica desde a década de 1960. No caso particular de corpos a base de ferro sinterizado e suas ligas um tratamento termoquímico de Oxidação a Vapor, também denominado “Ferróx”, tem sido objeto de pesquisa e estudos por ser uma alternativa muito atrativa do ponto de vista técnico e econômico, melhorando as propriedades tribológicas e promovendo a vedação da porosidade interconectante. Este trabalho tem por objetivo estudar comportamento do tratamento de Oxidação a Vapor em peças de média densidade com composição básica de Ferro, Cobre e Grafite, sinterizadas em condições industriais com diferentes temperaturas. Determinar o comportamento da permeabilidade em função dos parâmetros de processo (temperatura de sinterização, atmosfera e tempo de tratamento de ferrox) e através da Lei de D’Arcy, calcular o coeficiente de permeabilidade (k) dos componentes sinterizados em função dos parâmetros de processo.

Aug 7, 2018

By Moo Eob Choi

A new process for converting sulfur dioxide to elemental sulfur by a cyclic process involving calcium sulfide and calcium sulfate without generating secondary pollutants was developed at the University of Utah. In this process, sulfur dioxide is reacted with calcium sulfide to produce elemental sulfur and calcium sulfate. The latter is reduced by hydrogen to regenerate calcium sulfide. In the present work, the effects of different pelletization conditions for the initial reactant calcium sulfate on the strength and reactivity of the pellets were determined. These conditions include the type, amount, and impregnation method of catalyst, binder amount, and sintering. Experiments were also performed to determine the effects of temperature in the range of 973-1173 K, pellet size, cycle repetition, and water vapor or carbon dioxide content in sulfur dioxide stream on the reaction rates of the cyclic process. Nickel-catalyzed fired pellets produced by the use of molasses or cement as a binder showed good reactivity as well as high compressive strength during the cyclic tests. The binder amount did not significantly affect the reaction rate.

Jan 1, 2006

By Túlio César Nogueira

Este trabalho teve como objetivo estudar a resistência ao crescimento de trinca por fadiga de juntas soldadas de aços inoxidáveis ferríticos do tipo UNS S40910 e UNS S41003, com entalhe na ZTA. Os ensaios de fadiga foram realizados em juntas soldadas com alta e baixa energia de soldagem realizadas pelo processo GMAW, tendo como metal de adição o consumível austenítico ER 308 LSi, e em amostras do metal de base de ambos os aços. Os ensaios foram realizados sob controle de carga com a amplitude de carregamento constante, e razão R entre tensões de 0,1. Os resultados foram obtidos na forma de curvas (da/dN) vs. ?K, com caracterização das regiões I e II do crescimento de trinca por fadiga. Analisou-se também os aspectos microestruturais e fratográficos por intermédio de microscopia ótica e microscopia eletrônica de varredura, respectivamente, como suporte para se justificar o comportamento sob fadiga das amostras. Embora os dois aços tenham comportamento distinto, pode-se concluir que as juntas soldadas não apresentaram efeito do aporte térmico, não sendo influenciados pelas alterações microestruturais existentes na ZTA.

Aug 7, 2018

By Lloyd R. Nelson

Selective carbothermic reduction is the preferred method of treatment of electric arc furnace (EAF) dust (listed hazardous waste, K061). The process maximizes the recovery of recyclable constituents by concurrent production of saleable zinc metal (directly condensed from the furnace off-gases), an innocuous, disposable iron oxide-rich slag, and some metallic iron. Results of a mineralogical investigation of a foaming slag produced during selective carbothermic reduction treatment of EAF dusts are presented. Wiistite and tricalcium silicate were identified by reflected light microscopy as the primary crystalline phases contained in a glassy matrix, but this technique failed to reveal any solid phases that could have significantly contributed to foam stability. It was concluded therefore, that the foam had been unstable, and had been primarily generated by copious gas evolution associated with the sudden reduction of the slag by an inadvertent addition of carbonaceous reductant. This is consistent with the susceptibility to foaming, when subjected to sudden excesses of carbon, of the slags produced by selective carbothermic reduction, because they still contain unreduced components such as iron oxide.

Jan 1, 1994

By Fan Yang, Meigui Yi, Lan Xiang, Zhuoying Yang

This paper reported the calculation of the reaction heat in titanium-bearing blast furnace slag (abbreviated as TBFS)-H2SO4 system based on estimation of thermodynamic data of CaTiAl2O6 by mechanical mixture model. The thermodynamic analysis indicated that CaTiAl2O6 was more stable than the corresponding ternary oxides as CaO·TiO2, CaO·Al2O3, and Al2O3·TiO2. TBFS-H2SO4 system was highly exothermic since all of the reactions involved in the system were exothermic. For example, the increase of temperature from 25 to 200°C led to the increase of the release of the reaction heat in TBFS (100.0g)-H2SO4 system from 181.28 to 189.73kJ. Eighty-five to 90%of the reaction heat in TBFS-H2SO4 system was contributed by the reactions among CaTiAl2O6, CaTiO3, CaMgSi2O6, and H2SO4.

Feb 1, 2021

By P. I. James, M. R. Baker

This paper examines new copper production from waste-grade ore using Blue Planet Strategies’ DEMET™ (Dynamic Electrode Mining Effluent Treatment) technology, which aims to bridge the practical weak pregnant leach solution (PLS) processing gap in heap leach-solvent extraction/electrowinning (SX/EW) operations by electrochemically removing metals from weak streams and generating product streams strengthened in target metals in a functional analog to SX. Weak PLS treatment was studied and used to estimate the economic and production impacts for a representative hypothetical brownfield copper heap leaching and DEMET-augmented SX/ EW operation to utilize "waste ore." Copper removal at 86% plating efficiency to below 0.1 g/L copper with power consumption of 0.55 kWh/lb copper and product strengths of over 10 g/L copper are presented. Modeling yielded approximately $2/lb total copper production and = $1/lb treatment costs with an immediate operation gross margin increase of 12% for the augmented brownfield. Potential mine life extension with an average 38% gross margin on "waste ore" augmented production at copper values of $3.25/lb was also indicated.

Jan 1, 2014

By K Knorr, S Birch

The mineralogy of new certified-reference-materials (CRM) for X-ray fluorescence from Western Australia (ASCRM 030 to 035) was analysed by X-ray diffraction using the BRUKER energy dispersive one-dimensional detector LYNXEYE-XE. The samples were studied using standard-less quantitative phase analysis, based on the Rietveld method. This method delivers the relative amount of crystalline phases. All materials were found to be high-grade iron ore predominantly consisting of hematite and goethite and very low amounts of magnetite. In addition, the gangue mineralogy was characterised. It consists of low-per cent amounts of carbonate (siderite/calcite), quartz, kaolinite, chlorite and gibbsite.Furthermore, all samples were analysed with the external standard method. This is an elegant way to probe for amorphous content without adding an internal standard. All six samples were found to contain up to 16 per cent amorphous or nano-crystalline material.CITATION:Knorr, K and Birch, S, 2013. Mineralogy of new Australian x-ray fluorescence standards, in Proceedings Iron Ore 2013 , pp 269-274 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By K J. Lownie, T Rafferty

The in situ testing of mine ventilation fan systems has been a contentious issue for many years. Site testing was generally undertaken by adapting standards that were developed for the laboratory testing of fans using standardised airways. The deficiencies inherent in this practice have been widely recognised by informed practitioners, and this led to the first stand-alone document specifically intended for the in situ testing of large fans (ISO 5802:2001 Industrial fans - Performance testing in situ).This paper describes the structure of the International Standards organisation and the processes that are followed in the course of preparing such a standard.The application of ISO 5802:2001 is briefly outlined together with how test data is assessed for compliance with the suppliers guarantee. This paper must be read in conjunction with ISO 5801:2007, ISO 5802:2001 and ISO 13348:2007.CITATION:Lownie, K J and Rafferty, T, 2013. A review of ISO 5802:2001 industrial fans - performance testing i n situ, in Proceedings The Australian Mine Ventilation Conference , pp 149-154 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By Edwin Adoyi Ali, Zainab Shehu Aliyu, Adele Dzikwi Garkida, Muhammad Dauda

Feldspar from Matari, Nigeria was analyzed using SEM, XRD and XRF techniques for microstructural analysis, mineral phase analysis and chemical composition analysis respectively. Qualitative and quantitative XRD analyses revealed the presence of microcline 59.6%, albite 34.7% and quartz 5.71%. The XRF results showed that the feldspar contains 67.32% SiO2, 17.54% Al2O3, 11.33% K2O, 2.75% Na2O, 0.12% CaO, 0.01% MgO, 0.02% MnO2, 0.10% Fe2O3, 0.00% Ti2O, etc and 0.14% LOI. SEM/EDX analysis shows the presence of microcline feldspar as the dominant phase, exhibiting lamellar twinning. The XRD has also revealed that potash has the highest peak, indicating its high concentration. The 0.10% Fe2O3 present is within the permissible level (0.1-0.3%) for glass making and also within the potash feldspar specifications (0.17%). The Matari feldspar is a microcline type, rich in potash, alumina and silica, enabling it meet the standard specifications for alumino-silicate glass.

Jan 1, 2015

By J Bolen, I Cameron, M Huerta, M Okrutny, K O’Leary

As greater amounts of fine iron ore concentrates enter the marketplace, new investments in iron ore pelletising capacity are inevitable to deliver these concentrates to steel industry consumers. When investors assess the two well-proven pelletising technologies, the straight grate and grate-kiln, the most appropriate choice may not be immediately evident. Certain technical, market and site-specific factors will favour one technology over the other; investors need to be aware and understand these factors in order to make the best investment decision. Hatch has compared the merits of both technologies regarding plant configuration; type of iron ore processed; energy consumption and flexibility to use a variety of fuels; ability to produce the required pellet quality; required plant capacity and scale; operating and capital costs and environmental performance. A technology assessment checklist that investors should consider when making a new pellet plant investment decision is presented.CITATION:Huerta, M, Bolen, J, Okrutny, M, Cameron, I and O’Leary, K, 2015. Guidelines for selecting pellet plant technology, in Proceedings Iron Ore 2015, pp 45–52 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

In line with mining operations throughout Australia, Western Mining Corporation Limiter' is striving to increase productivity by intro-ducing mechanized mining techniques wherever possible. Kambalda Nickel Operations' (K.N.O.) largest operating nickel mine, Long Shaft, is currently introducing mechanized cut and fill methods which must provide flexibility to cater for an orebody that variesconsiderably in width, both along the strike and up dip.This has resulted in modifications to the previous approach to primary level develop-ment, and intermediate stope development, and in the type of development and production equipment being employed. Electric-hydraulic diesel jumbos and diesel loaders have now been mated with conventional rail equipment and production airtrack machines are being utilized.The transition to mechanized methods is in its preliminary phase and is being monitored closely to ensure any productivity gains are not offset by a substantial drop in mine grade. The precise method ofmechanized mining has not been finalized and selective methods will be used, according to the ore width and ground conditions, which vary throughout the mine.

Jan 1, 1985