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Since early-2001, Kalgoorlie Consolidated Gold Mines (KCGM) has successfully operated an ultra fine grinding (UFG) circuit to supplement its roaster capacity for the treatment of the refractory gold flotation concentrate. A second UFG mill was installed in 2002 taking the total UFG capacity to over 20 tph while grinding to 11 to 12 microns and achieving over 90 per cent gold recovery. A development program in 2002/3 involving plant trials, pilot plants and laboratory testwork resulted in process improvements and a better understanding of the milling and gold leach processes that assisted in narrowing the gap between UFG and roasting. This paper details the operation of the ultra fine grinding process at KCGM as a non oxidative treatment for the extraction of gold from a refractory ores.

Jan 1, 2003

By A. Rodriguez-Prado, R. L. Legge, W. C. Lennox

ABSTRACT It is possible to adequately describe chemical reduction of hexavalent chromium, Cr(VI), in industrial and mining wastewater in constructed wetlands by applying different kinetic models (e.g., halforder, second-order). Accounting for hydraulic transport of contaminants in reduction equations can also improve such description. The authors developed an explicit advection-dispersion bulk flow equation and applied it to model Cr(VI) reduction in laboratory wetland mesocosms. The results indicated that the model adequately described wetland exit Cr(VI) concentrations and Cr(VI) reduction, representing an improvement over the commonly used graphic method and potentially improving the wetland design.

Jan 1, 2014

By Gilbert M. Farrior

The electrical resistivity the coefficient of electrical resistivity the Hall coefficient, and the absolute thermoelectric power were determined in this Bureau of Mines investigation for nine compositions of the TiB2-CrB2 sub-system. The numerical values of the electrical resistivity and the thermo-electric power were greater for the intermediate compositions than for the end members. The absolute values of the Hall coefficients and the coefficients of electrical resistivity were less for the intermediate compositions than for the end members. The electrical resistivities and Hall coefficients were about the order of magnitude of most metals--from 34 to 202 microhm-cm and from about 0 to -23.3 X 10-4 cuP/coulomb. The thermoelectric power was somewhat greater than that of most metals--up to 15.6 microvolts per 0 C.

Jan 1, 1965

An iridium oxide coated titanium electrode was tested as anode in copper electrowinning. Initial results confmed that the DSA-type anode was significantly more active for oxygen evolution than traditional lead anodes. However, during longer runs, the anode potential was observed to increase linearly at a rate of 220 mV/year. Scanning elecuon microscopy (SEM) and energy dispersive spectroscopy (EDS) showed that the anode passivation could be attributed to elecuochemical dissolution of the coating. The effect on the anode potential of organic additives (glue and thiourea) and lead in solution was also examined. A preliminary economic evaluation of the anodes is given.

Jan 1, 1992

By Z. Henderson, J. Saylor, L. R. Mendoza

"Diesel particulate Matter (DPM) is a byproduct of fuel combustion in diesel engines. It is classified as a carcinogen, with associated respiratory and cardiovascular health effects. The composition, size, and concentration of DPM is dependent on factors such as engine type, loading and fuel composition. Though a number of DPM abatement and control strategies currently exist, particularly in underground mining environments, occupational exposures remain a serious health concern. As a novel abatement approach, DPM scavenging by fine water or “fog” droplets has been proposed and a laboratory set-up has been built to test the efficacy on engine exhaust. Here, we describe a series of tests that varied engine load, system flow rate and fog drop number density. While none of these factors had overwhelming effects on the results within the ranges tested, the improvement in DPM mass removal attributed to the fog treatment was about 45% on average in comparison to no treatment. INTRODUCTION Diesel engines have seen widespread use for well over a century due to their relatively high thermal efficiency and fuel economy1. More recently, however, adverse health risks of diesel exhaust have become increasingly clear. Many of these risks are associated with the physical and chemical properties of exhaust components1–3. The term diesel particulate matter (DPM) is used to refer to the solid components of diesel exhaust, which are a mixture of elemental and organic carbon (EC and OC) and minor constituents including sulfates and metal ash3. The OC fraction of DPM results from unburned fuel and lube oil, whereas EC or soot is formed during the combustion of locally rich regions within the fuel. DPM is classified as a carcinogen6,7 and epidemiological studies have demonstrated a positive correlation between long-term exposure to DPM and other combustion-related fine particulate and increased cardiovascular and pulmonary diseases8,9. Diesel engines operate in relative fuel rich/oxygen lean conditions and are characterized by relatively high emissions of particulate as compared to spark-ignition engines2,3,10. Typically, these emissions range from 107 – 109 particles/cc and cover two primary size ranges: the nuclei mode where particles have diameters less than about <50 nm, and the accumulation mode where diameters are from about 50-10,000 nm. Most OC resides in the nuclei mode as semi-volatile compounds, while most EC is in the accumulation mode3. The physical and chemical properties of DPM vary with the type of engine, fuel (e.g., petro- vs. bio-diesel) and operating conditions such as loading (i.e., a function of torque and rotational speed)2,3,9,11,12. Loading is a particularly important factor with respect to DPM toxicity9,13,14, and on the effectiveness of after-treatment technologies2,3,15. Engine load alone can affect the EC/OC ratio, and the size distribution and number density of DPM. For diesel engines, the load is roughly proportional to the equivalence ratio3, defined as the actual fuel/air ratio over the stoichiometric fuel/air ratio for complete combustion. Light loads generally favor the formation of OC and small particles. As load is increased the volatiles are oxidized leading to larger soot particles (i.e., EC), but lower total number density of DPM. With further loading, the formation of soot offsets the decrease in volatiles, resulting in increased DPM mean size and number density3."

Jan 1, 2017

By G. L. Brooke

At present, there are two known cobalt deposits in the 48 contiguous states. This paper is a brief description of one of these deposits. It is a Mississippi Valley type deposit, but somewhat atypical in that the metal of greater interest is cobalt as opposed to lead, zinc, and copper. The history and present work are outlined along with a discussion of the geology and mineralogy.

Jan 1, 1981

By F. R. Cattoir

The Federal Bureau of Mines refined chromium from an aqueous electrolytic process in molten sodium chloride-chromium chloride electrolytes. Oxygen and nitrogen contents were reduced by a factor of 10 to 40, but most other impurities were little changed. The product usually contained a little more iron than the feed. Since iron was entering the bath from the iron pot and the graphite liner at a nearly constant rate, contamination of the chromium deposits by it was more serious at low currents and deposition rates. A few runs in an iron cell with a nickel liner yielded chromium containing one half as much iron as the feed, but up to 1.5 pct. nickel. In all cases the anode feed lay in the bottom of the container, which itself was used as the anode connection. With a 12-in. cell, variations in applied voltage from 0.05 to 1.5, in current from less than 10 to over 100 a., and in initial cathode current densities from less than 100 to over 2,000 a./sq.ft. had little or no effect upon the analysis of the metal produced) except for iron content. Changes in bath analysis from 3 to 11 pct. chromium were also without effect. These changes did bring about large differences in the physical forms of the crystals obtained. The thick heavy crystals produced at low voltage and current contained voids which made them difficult to leach free of chlorides. Easiest to leach were the thin leaf-like crystals obtained at around 1 v.

Jan 1, 1960

By Henry P. Ehrlinger

These are exciting times for those of us involved in the discovery, development, beneficiation, sales and end uses of industrial minerals. The known sources of traditional raw materials are rapidly being consumed or covered up with highways and urban developments. We would never knowingly cover up a source of gold, silver, diamonds, or even base metals with a shopping center, but it has been difficult to justify not locating construction atop a limestone, granite, or sand dune deposit. During the last ten or so years most of the users of significant amounts of industrial minerals have established task forces made up of geologists, mining engineers, beneficiation experts, ceramic and refractory scientists, and senior members of their purchasing departments whose duty it is to determine where the raw materials for their particular finished products will come from now and farther down the road, like 20 years from now. Likewise, these same ceramic and refractory scientists are developing new materials which require a never ending change into different raw materials and the traditional materials must be refined by selective mining, exotic beneficiation practices and expensive but necessary post-beneficiation treatments to produce minerals for commercial use that were either theoretical minerals or at best showcase specimens when most of us here today were in school studiously acquiring a vocabulary which included Calcite, Magnesite, Dolomite , Feldspar, (Labradorite had the play of colors the prof could see but which I rarely focused on) Wollastonite, Celestite, Chromite, Olivine, Barite and Lepidolite to name a few.

Jan 1, 1976

By N. Hamlef

In this study, the effects of heat treatment on phase formation and surface morphology of the Cr-Pt coated system are investigated using X-ray diffraction and electron microscopy techniques. The CrPt andCr4Pt (Cr3Pt - A15 type) phases were formed after heat treatment of the coated samples. Heat treating at 1000°C renders a distinct island coating morphology that is non-continuous in nature. A diffusional model is proposed for this coated system with regards to the surface morphology formation after heat treatment.

Jan 1, 2014

By C MacRae, N Wilson

CSIRO Minerals has recently developed an electron microprobe (EMP) based imaging (or mapping) method for characterising ilmenite concentrates. The method requires an electron microprobe analyser to collect elemental X-ray maps which are then processed via an in-house developed software module (CHIMAGE). The type of information readily available from EMP mapping includes; primary phase identification, modal analysis of phases, chemical analysis of individual phases, textural information (eg the alteration stages in the formation of leucoxene or pseudorutile from primary ilmenite and the development of macro-porosity), and the identification of coatings or pore-fill material. All of these parameters will impact on the choice of future downstream processing options considered for any particular ilmenite concentrate. The method has been demonstrated to be a sensitive analytical tool for assessing the distribution of aluminosilicate minor impurities in ilmenite feedstocks from the West Coast of Australia and also for characterising the complex chrome-spinel gangue phases common in East Coast ilmenite concentrates from the Murray Basin.

Jan 1, 2001

By F. Sorenson, P. A. Castellarini, F. Garbarino, M. N. Garcia

"Recently, significant efforts to improve productivity from the tight intervals of the Mulichinco Formation within the Sierra Chata Field in the Neuquén Basin have been ongoing. Because conventional high quality reservoirs were being developed in this field, a proper reservoir understanding and completion approach was applied. After developing these high permeability reservoirs, the operator began evaluating the tight intervals and new areas within the field, but a completely different approach was necessary to achieve motivating production improvement.An extensive study to help enhance reservoir understanding and identify key factors controlling productivity of these tight intervals (which tend to be in the range of 5 µD) has been ongoing. Some of the issues discussed in this study are 1) petrophysical review, 2) rock properties calibration, 3) geomechanics understanding, 4) faulting and micro faulting/lineaments description, 5) stimulation and completions review and, 6) understanding key production drivers.As in many other tight reservoir projects, a considerable area of the reservoir must be effectively stimulated during the hydraulic fracturing process to achieve economic productivity. Two critical issues hinder these objectives. First, the low permeability in addition to a pore pressure close to or even lower than hydrostatic are critical characteristics when attempting to flow back the well and clean up fractures. Second, very high horizontal stress anisotropy resulting from a strike slip stress regime promotes the generation of simple planar bi-wing fractures. It is well-known that this fracture geometry will contact much less reservoir area compared to more complex fractures, as the operator would normally intend to create at very low permeability reservoirs.This paper discusses these issues and how they were addressed. A pilot drilling and completion program was initiated during 2012 to validate this study. Key factors include well location relative to formation unconformities, their orientation relative to the far field principal stresses, hydraulic fractures generated, and overall completion design."

Jan 1, 2015

By Brian D. Barkauskas, Terence P. Holman

A major combined nuclear and coal-fired power plant, located in on the western coast of Florida has undergone multiple upgrades in recent years to increase power output and enhance environmental controls. Construction of new elements within the existing plant structure required working in highly congested conditions and heavy crane lifts with large picking radii. The largest crane pick involved the use of an 1800 metric tonne capacity Mammoet PTC ring crane for a single long-radius, high altitude lift of a precipitator unit. Original bid tender documents had called for drilled shaft foundation support, but the presence of many critical utilities and unfavorable access for cost effective construction led specialty contractor Moretrench American Corporation to propose an alternate micropile foundation on the basis that high capacities could be achieved in the weak limestone geology and that the smaller size of micropiles would allow for more surgical installation in the utility-congested areas. This case history describes the design and construction of seventy three (73) high capacity micropiles for the value engineering alternative and the crane foundation for this critical lift. Each micropile was founded in a competent dolomitic fossiliferous limestone unit at typical depths of 23 m below existing ground surface. Strain gauge instrumented load testing was used to validate the geotechnical design parameters in the weak limestone bedrock and resulted in the finding that the entire test load was being carried in the upper half of the bond zone. Construction of the production micropiles required numerous relocations due to utility conflicts and local reanalysis and redesign of the 1.2 m thick reinforced concrete ring beam cap. Crane foundation performance was satisfactory and the effective life of this temporary foundation was only 6 months before decommissioning and demolition.

Jan 1, 2017

By Andrzej Luszczkiewicz, Magdalena Duchnowska, KGHM Polska Miedz S. A., Witold Pawlos, Jan Drzymala, Alicja Bakalarz, Przemyslaw B. Kowalczuk

Numerous data in the literature confirm that the chemical composition and consumption of grinding media influence electrochemical properties of flotation suspension as well as effectiveness and selectivity of upgrading processes. During a milling process, attrition of grinding media is observed. Depending on the susceptibility to abrasion, the grinding media influence, to a different extent, the redox potential, pH as well as flotation efficiency. As a result, different upgradeability of sulfide minerals is observed. The paper presents laboratory scale flotation results, obtained for the copper sulfide ore from Polkowice Region of KGHM Polska Miedz S.A. in Poland ground in the presence of forged steel, highchrome iron and stainless steel as the grinding media. The investigated flotation feed contained 36 g/t (ppm) of silver and 1.86 % of copper. Several flotation tests were conducted using fixed amount of frother and a mixture of sodium ethyl and isobutyl xanthates as the collector at three different doses of 75, 100 and 125 g/t. A comparison of the obtained results confirmed that the application of grinding media with different chemical compositions influenced the electrochemical properties of the suspension and recovery of silver and copper in the final concentrate. The highest values of redox potential were observed for the stainless steel as the grinding medium. Moreover, in the presence of this type of grinding media, regardless of the collector dosage, the best silver upgrading was observed. For the forged and high-chrome iron media, the recovery of silver depended on the collector dosage. It is indicated that higher levels of the redox potential, together with smaller amount of iron released from the grinding medium, improve the flotation of the silver-bearing mineral compounds from the copper sulfide ore.

Jan 1, 2016

By John W. Crawford

The title of the paper which I have been asked to present is somewhat misleading it infers in fact that there is a definite coalbed height below which raps or canopies cannot be applied to electric face equipment. Although this may be so with regard to certain pieces of existing equipment under certain conditions, to date we do not have enough experience to determine this magic number. Therefore MESA is continuing to hold the line on the time frames stipulated in Section 75.1710-1 of the Mandatory Safety Standards - Underground Coal Mines, which at this point in time requires these protective structures in mining heights of 60 inches or more. In order to give you an idea why we are taking such a firm stand on this matter, I believe it is necessary to describe some of the background work that was done prior to promulgation of the regulations and to give a resume of our experience since the requirements have become effective. Initially MESA made field investigations of all underground mines to determine what the state of the art was in the use of cabs and canopies for protecting equip¬ment operators from falls of roof. These studies revealed that the application was basically in its infancy and what progress had been made was due to the impetus of the mine operators themselves. Manufacturers of electric face equip¬ment provided these structures only on the direct order from the mining company and built them to their specifications. In talking to the operators and the miners in mines where cabs or canopies were in use, it was the consensus that these structures did improve safety and that although originally there was some reluctance on the part; of the miners to work in the confines of a cab or canopy, mast would not work without them once they had been adapted to the equipment.

Jan 1, 1975

By Andrew Thomson, Peter Wright

"A section of a London Underground expanded segmental lined tunnel constructed in the 1970’s progressively deteriorated after 2001, with extensive radial joint spalling and mid-segment cracking. As part of the PPP contract Tube Lines Ltd and their partners carried out various analyses of the tunnel, including analysis of laser scans of the tunnel, geotechnical testing through the tunnel walls, geotechnical desk studies, real-time monitoring and even full-scale segment testing. This paper discusses the behaviour of the tunnel lining in this setting, the causes of failure and the lessons that can be learnt from this rare example of a tunnel which was progressively failing in service. It is finally noted that a replacement tunnel lining was installed during night-time possessions and completed in 2015. INTRODUCTION In 2003, Tube Lines Ltd. was established under a Public-Private Partnership (PPP) scheme to provide maintenance services and upgrade projects for London Underground (LU). The Deep Tube Tunnel Knowledge and Inspection Programme comprised the assessment of all tunnels, shafts and other underground structures. This included a number of lengths of tunnel constructed using segmental concrete linings. First used by LU in the 1960s, the savings both in cost and speed of construction led to concrete linings replacing cast iron for new tunnel construction in all but a few cases. During the initial scoping phase of this programme, inspections identified potential issues with the expanded concrete segmental linings on the Jubilee line. The inspections found a number of segments with surface spalling (Figure 1a), which did not appear on the post-construction defect records. These were generally relatively shallow, up to 40mm deep, spread over a wide area of segment. These were different to spalls caused by handling damage, which are typically localised at segment corners. Subsequent inspections over the following years identified an increasing number of segments with these types of spalls as well as an increased incidence of longitudinal mid-segment cracking (Figure 1b). The increasing occurrence of these defects was hypothesised to be caused by tensile stresses developing in the vicinity of the joint."

Jan 1, 2016

By M. Kunst

The creep behavior of three AJ62 alloys was investigated in a wide range of stresses and temperatures. Multi-level tensile creep tests revealed a distinct primary creep stage and a high stress exponent up to a value of 10. The threshold stress concept which is commonly used in combination with high stress exponents was utilized in the analysis of creep behaviour. This resulted in an effective stress exponent for the AJ alloys indi¬cating dislocation climb as the dominating creep mechanism. In addition, microstructural observations of the lamellar eutectic and of the a-Mg-matrix were carried out using opti¬cal microscopy, SEM and TEM. The creep properties of the alloys are discussed in the context of microstructural parameters such as phase volume-fraction, stability and solute supersaturation.

Jan 1, 2006

By C Niemann-Delius

The problem of long-term open pit mine planning is a large combinatorial problem, which canÆt be solved easily by mathematical programming models because of the large problem size. In this paper a new metaheuristic algorithm, which has been developed based on the ant colony optimisation (ACO) and its efficiency, have been discussed. To apply the ACO process to a mine planning problem, a series of variables is considered for each block as the pheromone trails that represent the desirability of the block for being the deepest point of the mine in that column for the given mining period. During implementation several mine schedules are constructed in each iteration. Then the pheromone values of all blocks are reduced to a certain percentage and additionally the pheromone value of those blocks that are used in defining the constructed schedules are increased according to the quality of the generated solutions. By repeated iterations, the pheromone values of those blocks that define the shape of the optimum solution are increased, whereas those of the others have been significantly evaporated. By using this algorithm a high degree of complexities could be considered in objective function and constraints of optimisation model. In addition it can improve the value of the initial mining schedule up to 34 per cent for some cases in a reasonable computational time.

Sep 26, 2011

By D. P. Gold

Major sources and reserves of Cb/Nb, Ta, REE, Y, Sc, Zr, Hf, Cu, apatite and vermiculite may be concentrated in primary and secondary minerals associated with different stages and depths of emplacement in carbonatite complexes and kindred alkalic intrusive rocks. Exploration targets include: apatite and pyrochlore (Nb) in the plutonic and hypabyssal core and ring-dikes: bastnaesite (REE), strontianite, barite and fluorite in hydrothermal veins and cone-sheets (subvolcanic setting): thortveitite (Sc,Y) and vermiculite in metasomatized aureoles (fenites): high grade eluvial deposits of apatite and pyrochlore, and secondary REE, Nb, Ti. and V-minerals in supergene and weathered zones.

Jan 1, 1991

By Srinath Viswanathan, Adrian Sabau

"In general, the occurrence of microporosity during metal casting is due to the combined effects of solidification shrinkage and gas precipitation. The governing equations for fluid flow and hydrogen evolution indicate that porosity formation and fluid flow are strongly coupled. However, in most studies on microporosity, it is considered that the porosity formation does not influence the fluid flow in the mushy zone. In this study, a computational methodology is presented for the numerical simulation of interdendritic fluid flow and microporosity evolution. The solution algorithm presented includes a fully coupled, implicit treatment of microporosity and local pressure in the mushy zone. The effects of microporosity evolution due to the local pressure drop in the mushy zone, and pore expansion in casting regions where liquid feeding alone cannot compensate for the solidification shrinkage are also considered. It is shown that neglecting the effect of porosity formation on the pressure in the mushy zone yields higher pressure drops. By its growth, microporosity partially compensates for the solidification shrinkage, reducing the feeding demand. A reduced feeding demand requires less fluid flow to compensate for solidification shrinkage, and results in smaller pressure drops in the mushy zone. Therefore, in order to accurately describe casting defects, comprehensive models of fluid flow, heat transfer, and solidification must include the effect of microporosity as well.IntroductionIn the terminology commonly used by foundrymen, porosity is usually considered to be either ""hydrogen"" or ""shrinkage"" porosity. Hydrogen porosity is the term given to porosity that is generally rounded, isolated, and well distributed. Porosity that is interconnected or clustered, and of an irregular shape corresponding to the shape of the interdendritic region, is usually termed shrinkage. In general, the occurrence of microporosity in aluminum alloys is due to the combined effects of solidification shrinkage and gas precipitation [1]. Continuum models [1, 2- 7] have been used to predict the level of porosity in castings. A number of other studies have also attempted to understand the phenomena of porosity formation and pore growth [8-10] and pore morphology [11].The governing equations for fluid flow and hydrogen evolution indicate that porosity formation and fluid flow are strongly coupled. However, in most studies [4, 9, 10], it is considered that the porosity formation does not influence the fluid flow in the mushy zone. Kubo and Pehlke [3] presented a methodology for the prediction of microporosity distribution in shaped castings by considering the effects of both the hydrogen precipitation during solidification and the pressure drop in the mushy zone. In their approach, the local pressure and porosity were computed in an uncoupled manner based on a ""flux of interdendritic liquid"" criterion, i.e., either pressure or porosity was first computed using the other variable at the previous time step. Their approach has been used with little change in numerous studies [6, 12, 13]. Recently, Kuznetsov and Vafai [14] presented a fully coupled, one-dimensional model for the computation of pressure and porosity. They showed that neglecting the effect of porosity formation on the pressure in the mushy zone yields higher pressure drops and an over-prediction of final porosity. They also showed that the influence of porosity formation on the pressure is larger at lower pressures in the mushy zone."

Jan 1, 2001

By S. Heusermann, S. Fahland, J. Behlau, A. Schäfers, J. Hammer

In the course of the deep subsurface use, the Federal Institute for Geosciences and Natural Resources has been carrying out extensive geological and geomechanical research and practical project work on domal salt structures, to prove their suitability e.g. for the disposal of radioactive wastes. Recent work on disposal sites has been taking into account the 3-D geological and geomechanical modelling of the underground structures. The geological models are generated using the special-construction openGEOTM code to improve the visualisation and interpretation of the geological data basis, e.g. borehole, mine, and geophysical data. For the geomechanical analysis of underground structures the JIFE finite-element tool has being developed to analyze large 3-D structures and to consider coupled THMC processes. The results of finite-element calculations, i.e. stresses, strains, displacements, and dilatant zones, are basic values for the evaluation of the stability of the structures and the long-term integrity of the geological barrier. As an example, the results of geological and geomechanical investigations of the Morsleben repository are presented including three-dimensional modelling of the entire geological structure of the central part of the mine as well as three-dimensional geomechanical model calculations to provide the necessary results for a long-term safety prediction.

Jan 1, 2015