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By Xiaohui Li, Lianyun Liu, Hongmin Zhu, Chunfang Zi, Kai Huang, Hongjie Li

"The dissolution kinetics of steelmaking slag in pure water was studied, and the relative influential factors were investigated. The dissolution behavior of slag particles in water was well described by Noyes–Whitney equation, and for this kind of sparingly soluble rigid mineral this simple model was extensively applicable to describe their dissolution process. Experimental data were also obtained to confirm the significant promotion effect on the growth of some algae.1 . IntroductionIt has been found that the population of phytoplankton distributed in the ocean was significantly related to the concentration of some elements [1]. For example, silicon and iron were very low in the high-nitrate low-chlorophyll (HNLC) areas, which was the main factor limiting phytoplankton and other biomass growth in these open ocean surface water [7]. The silicon and iron-rich test also confirmed that the supply of these elements had the direct effect on the growth of phytoplankton processes at HNLC areas [2-8]. So in order to promote the growth of phytoplankton in these ocean areas, providing some of these elements into these ocean areas is a natural idea for choice. Steelmaking slag is a good resource for consideration because it usually contains silicon, iron, phosphorus and other elements that are necessary for the growth of phytoplankton [8-10].Haraguchi has proposed the following idea that [5-6], if steelmaking slag can be spread to the open ocean, the trace components like silicate, iron and phosphate as the indispensable nutrients for the growth of phytoplankton, will be leached into the sea water, not only promoting the growth of phytoplankton, but also making good use of these huge amount of steelmaking slag produced every year. Based on this idea, they have carried out studies in recent years and they found that silicon and iron in the slag could be extracted into seawater effectively and play a positive role in the growth process of many algae. About the dissolution of the steelmaking slag, the Japanese scholars' research work mainly focused on the thermodynamic analysis of its dissolution possibility, and in the process of dissolution they tried to adjust the pH value of the seawater by continuously adding hydrochloric acid, which was deviated from the natural conditions of dissolution, and so the laws drawn under these special conditions can not give the identical guide to the practical application. Therefore, it is quite necessary to investigate the dissolution behavior of the steelmaking slag in the seawater at the normal pH range without adjustment to simulate the dissolution possibility under the natural conditions. In the present study, the silicon extraction behavior from the steelmaking slag was investigated and the dissolution kinetics in this process was also discussed in detail. Further studies were also performed here to evaluate the promotion of steelmaking slag on the growth of algae."

Jan 1, 2011

By C. A. Perez

Estimation of rock composition in mineral plants is important to determine rock size and grindability which in turn may improve control of the grinding process. Variations in ore grindability and size distribution directly affects mills power consumption and throughput. Therefore, it is desirable to develop new tools to estimate rock lithological composition. In this paper, a new method for lithological classification based on machine vision is proposed. The method is based on a single video camera and employs information about texture using several different spatial scales. Texture information is extracted from rock images using Gabor filters that can be adjusted at different spatial scales and orientations. After feature extraction, rock images are classified using support-vector machine (SVM). The method was tested on a database containing sub-images of 64x43 pixels of five ore types as follows: massive sulphide (MS), disseminated sulphide (DS), net textured (NT), gabbro (G), and peridotite (P). These ore types were assigned to three grindability classes: soft (MS), medium (DS and NT) and hard (G and P). The database was divided in 2 subsets for training, cross validation, and for test. Classification accuracy is compared with previously published results on a dataset with three different classes of rocks according to their hardness. Results show that our proposed method reached significant improvements (between 13%-20%) in classification accuracy relative to previously published results. Keywords: rock classification, lithological classification, grindability estimation, Gabor feature extraction, texture features

Sep 1, 2012

By P. K. Hofmeyr

Traditional fire assay dates back over 3000 years and has changed very little over that time. The only improvement is to replace the gravimetric finish with dissolution of the Precious Metal bead followed by AA or ICP analysis of the solution. The newly developed FIP A (Fast In-line Fire Assay) method allows full automation of the fire assay process from sample preparation to spark analysis of the Pb button. This results in fully quantitative analyses for Pt, Pd, Rh, Ru, lr, Au and Ag in typically less than an hour after a sample is entered into the system. Detection limits are theoretically Pt 0.08 ppm, Pd 0.002 ppm, Rh 0.002 ppm, Au 0.08 ppm and Ag 0.002 ppm but in practice the lower measurable limits are about double these figures. Few opportunities have been available to present data obtained using the FIFA system as all FIFA laboratories have been in the domain of a Pt mining company which prefers to keep all Pt analytical matters confidential. However, IMP has recently participated in the round robin exercise to establish recommended values for a new series of Merensky Reef and UO-2 Layer reference materials produced by African Mineral Standards. The precision of the results was excellent being on average Pt 2.05%, Pd 1.25%, Rh 4.08% and Ru 4.94% being expressed as Relative Standard Deviation. The excellent precision is a reflection of the efficient collection of POEs in the Pb buttons and the homogeneity of the Pb buttons. However, the accuracy was not as good. The poorer accuracy is interpreted as the calibration of the spectrometer not being as good as desired due to the difficulty in acquiring a suitable range of standards with reliable recommended values for the PGEs. The most recent spectrometer was calibrated with the greatest care and produced slightly better results for Pt, Pd and Rh and slightly worse for Ru.

Jan 1, 2014

By R. O. Vernon

The Florida Peninsula has existed as a part of a much broader plateau, since at least the Early Cretaceous. This plateau, the Floridan Plateau, now consists of the present peninsula and a broad submerged shelf of equivalent size extending the length of the state and out into the Gulf of Mexico. Florida Peninsula was separated from the mainland United States by a negative area called the Suwannee Straits. To the south of this feature existed an environment similar to today?s Bahamo Banks where very pure calcium and magnesium carbonates with associated evaporites were deposited. Thus the Eocene and Oligocene contain little or no quartz sand or clay minerals except in the Panhandle west of the Suwannee Straits where some clastics were contributed by rivers from the north.

Jan 1, 1966

By Gökçe Törenli, Okay Tutar

"Predicting the performance of plant-scale comminution circuits is essential to monitor the energy use and product size distribution, allowing us to control and optimize the whole process. In the light of this issue, with the assist of recent technologies, simulation techniques utilize the chance of putting the theory into practice in the most accurate way. For this purpose, this study aims to evaluate and optimize the efficiency of a plant-scale ball mill circuit by using perfect-mixing ball mill model on a simulation environment. The comminution circuit is selected from a specific copper-ore processing plant in Turkey. The essential parameters which are required for this study such as fresh feed Bond work index, size distribution etc. are determined by laboratory experiments. The forecasted data which are calculated by third-party software will be compared by the industrial operating data, in order to determine the performance of comminution circuit. In addition to that, this methodology provides a greater ability to analyse, optimize and understand the comminution circuit of ore treatment plant. The authors believe this work will provide supplementary data for further studies on simulation and subsequent optimization of comminution circuits.INTRODUCTION By the assist of mathematical models of the grinding mills and classifiers, simulation of the grinding circuits become more common in comminution because it is relatively economical and able to consider many variables simultaneously. It’s proceeds depends on the accuracy of the models and capability of reflect real operations. Computer-based simulation studies would provide the quantified information about the effects of the proposed changes on the comminution circuit performance in terms of size distribution, mass flow rates, equipment efficiency etc. Then the mentioned data used in order to check the suitability of the current equipment to the modified conditions, and for equipment selection. The outputs of circuit could also be used to estimate downstream flotation circuit performance because the general aim in this study is to The aim of the study is to investigate optimum operating variables and achieve p(80) size of 57 µm and 64 % of -36 µm particle in hydrocyclone overflow stream, which is optimum for that porphyritic copper ore for best concentrate recovery after flotation process in specific copper ore comminution circuit by using modelling and simulation techniques. Sampling survey was carried on the fine ore bin in order to perform Bond work index test and determine work index value (Wi). Thereafter mass balancing, using the size distribution data and tonnages, models for ball mills and hydrocyclone were developed. Finally, the circuit performance were investigated by computer simulations via JKSimMet software."

Jan 1, 2018

By Elias Rigopoulos

In the present study the reductive behavior of dust from the rotary kilns (RK), in ferronickel production from nickeliferous Greek laterites, is investigated. The study concerns dust of various origins (washing towers, electrostatic filters, polycyclones) and pellets made from the dust. Reducibility was studied in the temperature range of 700 °C to 850 °C in a laboratory tube furnace. Experimental results showed that reduction degree increases with temperature up to about 800 °C. The rate of reduction is great during the first minutes, giving a reduction degree R% equal to about 25%, in only a few minutes. After this, the rate is decreasing until it diminishes to zero after about 10-20 minutes of reaction. Maximum reduction degree achieved is 26 to 28%. Rates and reduction degrees at various temperatures are higher for the dust samples than those of the respective pellet samples. Keywords: Ferronickel, metallurgy, laterites, pellets, reduction

Jan 1, 2004

By Abraham Lindo

Taboguilla is a small island located 10 miles outside the Panama Canal Pacific Entrance. In 2002 a fuel distribution facility was installed in order to supply fuel to vessels passing thru the canal. The current capacity of the tank farm is equivalent to 1,100,000 barrels. The demand for marine diesel at this location still exceeds the current capacity, thus an expansion project is currently underway to increase the available space for diesel tanks. There is a total of 800,000 cubic meters to be excavated in order to create the new space. 400,000 cubic meters of that total is basalt rock which will need to be blasted

Jan 1, 2011

By Lj. D. Andric

By the micronization-milling of the material, the size and the structure of its particles are changed and it comes to the increasing of the potential energy of the system as well as to the chem-ical activity of the material what is the result of an increased free surface and of the concentration of the grate defects, that is of the internal energy of the system. All these changes that are reached, show that new characteristics of treated materials are got by micronization process. Controlling the process of the micronization and by purpose directing of the new characteristics of the activated materials, we can have the positive effects and use them in more technologies. Talc is important nonmetallic mineral raw material that is widely used as either the basic raw material, or as filler. This has stimulated its technological investigation, as well as the investigation of its physical-chemical characteristics. In this paper are shown experimentally reached results of the physical-chemical characteristics of the talc during the process of the micronization in high energetic mill. In this paper, the optimum conditions of miconization of talc in high-energy-speed rotary mill and its influence micronization on a degree of Fe2O3recovery by hydrometallurgical methodes, are presented. The X-ray analysis of the obtained products showed that high quality talc with low content of can be obtained by these physical-chemical processes In this paper, the principles and application or fine and ultra-fine grinding high-energy attriton mill with small balls, enabling fast, efficient grinding, low energy consumption, short grinding time and easy handling will be described.

Jan 1, 2014

By Robert K. Jones

Filter media can be defined as that material which effects the removal of finely divided solids from a fluid. Thus the removal of dust from air or turbidity from water, for example, can be the result of passing the fluid through a properly supported filter media. Since filtration in one form or another has been practiced since pre¬historic times filter media have been made from an extremely wide variety of materials. Vegetable and synthetic fibers (used loose, or formed into papers, felts or cloth) sand, ground coal, diatomite, perlite, wire cloth, porous metal, and bonded aluminum oxide are among the more important materials used today.

Jan 1, 1961

By R. S. Sanford

The Muir Inlet or Nunatak molybdenum deposits arc in the Glacier Bay district, Muir Inlet, miles northwest of Juneau. The deposits were examined by Bureau of Mines engineers, and the area was mapped by a field party of the Federal Geological Survey during the summer of 1942. 5/ The following year the Bureau of Mines began developing the deposits. A total of 217 channel samples were taken, and 2 diamond drill holes totaling 256 feet wore drilled. The samples were sent to the' Bureau's laboratories at Rolla, Mo. for beneficiation.

Jan 1, 1949

By Ritva Tuunila, Antti Häkkinen

"Wet stirred milling is one of the most effective grinding methods in producing very fine powders in large scale production, but it is a very energy-intensive process, especially when pigments or even nanosize particles are produced. Therefore, optimization of the process parameters is important. The specific energy consumption is a function of stress energy, which describes the effect of tip speed and media characteristics on grinding, and is related to the number of stress events during milling. In effective grinding, a large number of stress events are necessary. The stirrer configuration influences the number of stress events and their intensity, because the motion of the media and the suspension are caused by a rotating stirrer. The effect of three different stirrer types: a pin, disc and blade stirrer, on the grinding rate, i.e. product fineness and specific energy were investigated in this study with a batch laboratory stirred mill with two tip speeds. The material used in the experiments was calcium carbonate. The results obtained with the smaller tip speed showed approximately similar grinding rates and energy consumption for all stirrer types. When looking in closer detail, the blade stirrer seemed to give the finest product with all grinding times compared to the pin and disc stirrers, which both produced almost the same product fineness with the same grinding times. The specific energy consumption was the smallest with the disc stirrer, but not very big differences were obtained. With a higher tip speed, greater differences occurred both in grinding rates and specific energy consumption. The blade stirrer was the most effective in grinding, and the pin stirrer the next. The net energy consumption for the blade and pin stirrers was almost the same, but it was slightly higher for the disc stirrer."

Jan 1, 2014

By Saskia Duyvesteyn

Ion flotation is a technique applicable to the removal of metal ions from dilute solutions, using ionic surfactants.- While there are a number of physical and chemical parameters that influence the ion flotation process, this paper focuses on two of the important chemical ones, namely frother concentration and ionic strength. The effect of several frothers, including ethanol, iso-propanol and MIBC at concentrations ranging from 0% to 0.4%, was studied for the model Cd-dodecylsulfate and Cu-dodecylsulfate systems. The ionic strength, as well as the effect of monovalent and multivalent counter ions, was also studied in the range of 1@3 - 1 M, at constant pH. The results are discussed in terms of applicability to a range of effluents from minerals and materials processing operations.

Jan 1, 1994

By L. Tafaghodi, S. Sarbishei

"Following the depletion of nickel sulfide ores, laterites are considered as one of the main sources for producing nickel and cobalt. One of the primary steps in pyrometallurgical extraction of nickel from laterites involves partial reduction of the ore at temperatures below 1000°C. Studying the kinetics of laterite reduction provides valuable information on reducibility of nickel laterites using coal as a reductant. The present study investigates the reduction behavior of a nickel laterite by thermal gravimetric analysis and differential scanning calorimetry. Non-isothermal reduction tests and X-ray diffraction analysis were performed to find the main reactions that occur during the process. The kinetic parameters were calculated by Coats-Redfern method. The general model of simple reaction f(a)=(1-a)n was used for calculating kinetic parameters.INTRODUCTION Nickel (Ni) naturally occurs in the form of sulfide and laterite ores. Laterite ores are mainly available in tropical regions. Weathering phenomena during millions of years has led to the formation of several layers with specific mineralogy (Butt & Cluzel, 2013). The three main layers downward are limonite, smectite, and saprolite (Crundwell et al., 2011). Although laterites are the most available nickel ore resource (70%), their share in the overall Ni production is limited to 40% (Crundwell et al., 2011). The main reasons for not materializing the full potential of laterites are as follows (Ray et al., 1985): •,Laterite ores contain high water content (free and combined) which in turn results in high energy consumption of the extraction process. •,As Ni is present in the form of solid solution in laterites, physical upgrading methods such as flotation are not effective in increasing the Ni content before the extraction process. •,Extracting Ni from sulfide ores involve exothermic reactions which are beneficial due to decreasing the overall energy requirement of the process, however there is not efficient release of energy in the process of extracting Ni from laterite ores."

Jan 1, 2017

By Jafar Safarian, Merete Tangstad, Leiv Kolbeinsen

"Silicon and its binary alloys have several applications in metallurgical, chemical, photovoltaic and semiconductor industries. Silicon goes to its liquid state within its production, refining and when it is alloyed with other elements. Therefore, the characterization of silicon melts thermodynamics is important and useful. The liquidus and activities in several silicon binary systems have been recently calculated by the application of two liquidus constants, which were established using the experimentally determined liquidus data. In the present study, the thermodynamic properties of six silicon binary melts, which are simple eutectics, are calculated by analytical approaches. In this case, the changes in the partial and integral Gibbs free energies and enthalpies of mixing are calculated and compared with the experimental data in literature. The enthalpies are calculated by two methods and the calculation results are compared to the data from the literature. It is shown that thermodynamic properties of silicon binary melts can be accurately predicted without the use of complicated thermodynamic software.IntroductionSilicon and its alloys have several industrial applications. Silicon is used for making aluminium-silicon alloys to produce cast parts, mainly for automotive industry. Silicon in the form of ferro-silicon is used to deoxidize and alloy steel and cast iron. The photovoltaic (PV) industry has had a rapid growth in the recent years and silicon is the dominant material used for the fabrication of solar cells. Silicon is primarily produced through carbothermic reduction of quartz in electric arc furnaces and the produced metallurgical grade silicon (MG-Si) contains around 1 wt% impurities. It is further refined to produce solar grade silicon (SoG-Si) with above 99.9999 wt% Si to fulfil the chemical requirement for PV application. Since molten silicon is processed all along the metallurgical route, obtaining fundamental thermodynamics knowledge about silicon melts is valuable for the related industries."

Jan 1, 2012

By F. Awotwe-Appiah, P. Koshy, J. Dankwah, J. R. Dankwah

This research investigates the generation of an effective carbonaceous material from waste ‘pure water sachets’ and their subsequent utilisation as reductants for the reduction of the Opon Mansi iron ore. Composite pellets of Opon Mansi iron ore and pulverised carbonaceous material generated from waste pure water sachets were heated from room temperature to 1200 °C in a gas fired furnace for seventy minutes. The reduced pellet was analysed chemically for its oxygen and carbon content using a LECO Oxygen/Nitrogen and LECO Carbon/Sulphur analysers, respectively. It was observed that nuggets of metallic iron were readily produced with the carbonaceous materials acting as an effective reductant and source of chemical energy. XRD analysis of waste ‘pure water sachets’ revealed that the polymer was semi-crystalline with peaks that were identical to those of high density polyethylene (HDPE). Gas emission behaviour of the iron ore-PWS pellet was studied in a horizontal tube furnace at 1200 °C using an infrared gas analyser; the results revealed an exhaust gas rich in the reducing gases CO and CH4 along with CO2.

Jan 1, 2015

By Gabriel Plascencia

Copper was oxidized in the temperature range from 300 to 1000 GC under different pressures of oxygen. In the range from 300 to 500°C, copper oxidizes following the logarithmic rate law; while in the range from 600 to 1000°C oxidation follows the parabolic rate law. Transition from logarithmic to parabolic growth occurs at about 525°C. X-ray diffraction was performed on oxide scales to account for the CuO/Cu2O ratio at different temperatures. Activation energies found in this work are in good agreement with reported values.

Jan 1, 2003

By Z. W. Zhang, Songsong Xu, Jinhui Li, Yun Zou, Yu Zhao

High strength low alloy (HSLA) steels with high strength, high toughness, good corrosion resistance and weldability, can be widely used in shipbuilding, automobile, construction, bridging industry, etc. The microstructure evolution and mechanical properties can be influenced by thermomechanical processing. In this study, themomechanical processing is optimized to control the matrix microstructure and nano-scale precipitates in the matrix simultaneously. It is found that the low-temperature toughness and ductility of the steels are significantly the matrix microstructure during enhancing the strength by introducing the nano-scale precipitates. The effects of alloying elements on the microstructure evolution and nano-scale precipitation are also discussed.

Jan 1, 2016

By André Caetano Melado

Neste trabalho foi avaliada a influência da porcentagem de austenita retida nas propriedades mecânicas de um ferro fundido nodular submetido ao processo de Têmpera e Partição (T&P). O tratamento térmico consiste do aquecimento do material à 880ºC por um tempo de encharque de 2h para completa austenitização, seguida de têmpera em óleo até a temperatura de 170ºC, intermediária às temperaturas Ms e Mf, para formação de uma quantidade controlada de martensita atérmica. Em seguida, o material foi reaquecido até 375ºC (tratamento de partição) por diferentes tempos (15, 60 e 120 minutos), sendo subsequentemente resfriado ao ar até a temperatura ambiente. Foram utilizadas as técnicas de microscopia óptica (MO) e eletrônica de varredura (MEV) para a caracterização microestrutural do material obtido. Ensaios de tração e impacto (Charpy) foram realizados para obtenção das propriedades mecânicas do material. Para longos tempos de partição, foi verificada uma diminuição na fração volumétrica de austenita. Com a diminuição da porcentagem de austenita retida observou-se uma diminuição nas propriedades como alongamento e resistência ao impacto do material.

Aug 16, 2017

By Hugo Montalvão Gontijo

O complexo de extração, beneficiamento e transporte de minério de ferro denominado Minas-Rio, de propriedade da Anglo American, consome na moagem primária uma grande quantidade de corpos moedores (bolas metálicas). Recentemente, foi desenvolvido em 4 etapas um trabalho para automatizar a reposição dos corpos moedores e estabilizar o grau de enchimento do moinho. Na etapa A, com a reposição sendo realizada com auxílio de um operador. Na etapa B, com a reposição sendo realizada automaticamente de acordo com uma taxa de reposição predefinida. Nas etapas C e D, com a taxa de reposição sendo alterada por meio do sistema de controle avançado OCS-4D©, considerando a potência do moinho como indicação indireta do grau de enchimento. É possível verificar após a implementação das modificações uma maior estabilidade da potência e consequentemente maior estabilidade do grau de enchimento.

Oct 30, 2017

By Marcos Antonio Barcelos

O uso de tratamentos termoquímicos assistidos por plasma tem apresentado grande crescimento nos últimos anos em consequência dos excelentes resultados obtidos na modificação de superfícies em materiais de engenharia. Neste estudo será utilizado o aço inoxidável AISI 304 que apresenta boas características de resistência à corrosão, tendo vasto campo de aplicação nas indústrias têxteis e químicas. Será realizado tratamento termoquímico de cementação a plasma com temperatura fixa, variação de tempo e mistura gasosa (CH4).

Aug 7, 2018