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By B. McFadzean, J. Taguta

The enthalpy of immersion is the heat change arising from the replacement of the solid-gas interface with the solid-liquid interface when a solid surface is immersed in a liquid. Although immersion calorimetry has been established as a valuable and reliable means of determining solid surface properties such as wettability, it has seldom been applied in mineral processing research. In this study, precision solution calorimetry was employed to measure the enthalpies of immersion of different minerals in water. The enthalpies of immersion were then related to the first-order flotation rate constant as determined by the microflotation technique. The same measurements were also made on sulphide minerals whose surfaces were modified to different degrees of hydrophobicity using different percentage coverages of amyl xanthate collector. The enthalpy of immersion technique was capable of distinguishing and ranking minerals according to their wettability. All mineral types and collector-treated minerals conformed to the same relationship that was found between the enthalpy of immersion and the flotation rate constant. This conformed, empirically, to a power law equation. As the enthalpy of immersion decreased, there were large increases in flotation response for very small changes in hydrophobicity. In addition, a critical enthalpy of immersion (CEI) was found, above which no flotation could occur. The scatter in the data points could be corrected for by adjusting the rate constant using the density of the minerals to produce a robust relationship between the rate constant and enthalpy of immersion. These results have shown that the enthalpy of immersion is able to indicate both the natural mineral hydrophobicity and the extent to which collectors can render a mineral hydrophobic. This technique has considerable potential to be used as a sensitive and accurate measure of mineral surface wettability in order to predict flotation performance.

Jan 1, 2018

By Alberto Martín Ríos Carranza

"El presente texto señala la información técnica del proyecto de Santa Gloria. Dicho plan revisa las estimaciones de reservas, recursos y potencial exploratorio, información metalúrgica, infraestructura y otras generalidades. El proyecto se ubica en la provincia de Huarochirí en la región Lima, cuya infraestructura tiene permisos ambientales, certificado de operación minera (COM), uso de aguas, convenios para la utilización de energía eléctrica y buenas relaciones con las comunidades campesinas del entorno. Adicionalmente, cuenta con una planta de flotación para el tratamiento de mineral con una capacidad de 30 TM/día. La concentración de estructuras mineralizadas (vetas) está distribuida en tres áreas que se han denominado zonas Eleine, Tembladera y Santa Cruz. La mena de sulfuros tiene una recuperación alta en la planta de flotación (90.79% en plata) puesto que los sulfuros (tetraedrita y galenas argentíferas) no contienen minerales de manganeso."

Nov 1, 2016

By John Ralston, Jona Addai-Mensah, Patience Mpofu

The flocculation and dewatering behaviour of kaolinite (non swelling) and smectite (swelling) clay dispersions has been investigated using hydrolysable metal ions Mn(II) and Ca(II) and anionic polyacrylamide-acrylate copolymer (PAM) at pH 7.5 and 10.5. A pH-dependent, specific metal ion adsorption behaviour, accompanied by a marked reduction in particle zeta potential and slurry shear yield stress, was observed to have a profound influence on the colloid stability of both types of clays. Due to the differences in the cation exchange capacity, the smectite clay dispersion required a higher amount of metal ions than kaolinite dispersion to produce similar effects. The adsorption density of the anionic PAM at the negatively charged clay particle surfaces correlated well with metal ion hydrolysis and adsorption behaviour, all of which had a strong effect on slurry settling rate and extent of consolidation. At pH 7.5 where Mn(II) ions hydrolyse, metal ion and flocculant adsorption densities were both greater in the presence of Mn(II) than Ca(II) ions. At pH 10.5, however, where Ca(II) ions begins to hydrolyse, higher adsorption densities were observed for Ca(II) ions in comparison with Mn(II) ions, as the latter hydrolysed completely and precipitated. The metal ion mediated flocculant adsorption led to improved hydrogen bond driven particle bridging and facilitated charge neutralisation flocculation mechanisms which significantly enhanced the dewaterability of both clay dispersions.

Jan 1, 2003

By M. J. Latva-Kokko

This paper describes the behaviour of iron and the methods used for iron control in the nickel matte leaching process. OMG Harjavalta Nickel Oy processes approximately 10 000 t/y of iron, which enters the process with the nickel matte raw material. Iron dissolves and precipitates in several different stages of the leaching process. Compounds like ferric hydroxide, parabutlerite, goethite, hematite and jarosite are found. Iron removal is done within the leaching process, and this means that the dissolution of nickel sets the limiting conditions for iron precipitation. A leach residue consisting mainly of the iron precipitates is neutralized and stacked in the waste pond. When iron is precipitated from concentrated nickel sulphate solution, some nickel is lost by co-precipitation. Recent studies have shown that Ni-Fe ratios less than 1%, attributed to co-precipitation, can be obtained with jarosite precipitates, compared to 2-3% ratios typically found with hematite precipitates. Iron can be precipitated as jarosite under the optimal nickel leaching conditions by adding ammonium sulphate to the feed slurry of the autoclave.

Jan 1, 2006

By Lanre Oshinowo

Computational Fluid Dynamics (CFD) is used in conjunction with process modelling at HATCH to achieve a superior level of confidence in the process design of hydrometallurgical process plants. The use of these tools to evaluate designs through virtual prototyping reduces the risks associated with making design decisions. This paper highlights the development of a co-simulation strategy at Hatch for the seamless integration of process modeling software addressing different scales (process time and space): flowsheet level models and .equipment level models. With co-simulation, the process design engineers can improve design accuracy, troubleshoot and optimize performance and influence decisions impacting equipment operation by representing specific unit operations in the flowsheet model software with detailed CFD models. Specifically, this paper will focus on the co-simulation of a Ni/Co high-pressure acid leach (HPAL) process including heaters/heat exchangers and flash system, autoclave and quench/scrubber system. The knowledge developed can be transferable to other processes.

Jan 1, 2004

By Vicki Tschirhart, Bill Morris, McMaster University

A new method for mapping faults within basement rocks underlying the Thelon Formation and glacial overburden was developed and tested in the Aberdeen Sub-basin. This method utilizes newly acquired aeromagnetic data, the Blakely algorithm for defining magnetic source edges, a calculated dip-direction map, a digital elevation model (DEM) derived from the Canadian Digital Elevation Database, and the positions of identified, inferred and newly mapped faults that are within and adjacent to this sub-basin. Combining these data revealed three age groups of faults. One group is seen only on the DEM; these faults are young brittle structures that have no effect on the sub-Thelon basement unconformity, and are not visible on the dip direction map. A second group is evident on the dip direction map but not the DEM; these faults are old basement structures that did not propagate upward through the Thelon Formation. The third group is expressed on both the DEM and dip direction map; these faults are also old structures that propagated upward during and/or after deposition of the Thelon Formation. The latter group of faults may be of greatest interest for uranium exploration, with reactivation increasing their potential to serve as conduits to transport uranium-rich fluids and focus deposition at or near the unconformity surface. This methodology has promise for comprehensive mapping of basin faults and tracking the tectonic development of the whole Thelon Basin through time.

Jan 1, 2013

"SART technology is a useful tool for improving the economics of gold recovery from certain types of complex gold ores. SART liberates cyanide consumed by base metals such as copper, zinc and nickel, and enables the newly freed cyanide to be recycled to precious metals leaching while producing high-grade base metal sulphide concentrates for sale. The benefits of SART include the reduction in cyanide consumption, avoidance of cyanide destruction costs, minimization of risks of environmental non-compliance due to residues of cyanide destruction reporting to mine effluents, and generation of extra revenue from the sale of base metal concentrates. Concerns with SART typically include uncertainties around capital and operating costs and proper integration of SART into the overall metallurgical flowsheet. This paper presents two case studies addressing these concerns. The first involves actual costs of the full scale SART integrated into a gold heap leach operation and treating up to 500 m3/hr of leach solution at a mine in Mexico. The second involves field pilot testing and a preliminary cost estimate for integrating SART into a silver mine in Peru using Merrill Crowe.INTRODUCTION One of the current trends in the gold industry globally is the increasing importance of complex polymetallic gold deposits as discoveries of large Carlin type gold deposits become increasingly rare (Sceresini, 2005). The presence of cyanide soluble copper and zinc in complex gold deposits necessitates changes in traditional gold extraction metallurgical flowsheets. One of the tools available to the industry to help deal with interferences of cyanide-soluble base metals in gold extraction is the SART (sulphidization-acidification-recycling-thickening) process. SART breaks the weak acid dissociable (WAD) base metal-cyanide complexes, precipitates the metals as high-grade sulphide concentrates and makes the freed cyanide available for recycle. Although SART is a commercially available technology, it is still relatively new to the industry. Fewer than ten (10) full scale plants have been constructed in the past couple of decades. Some of these SART plants are small, most are located at remote sites, and the majority have not operated on a continuous basis. This has resulted in a general lack of information in the industry about the true costs, operability and metallurgical performance of SART. BQE Water has been involved in the design, construction, commissioning and operation of large scale SART plants in Mexico, Turkey and Chile and has conducted field testing programs as part of the technical assessment of SART integration into various metallurgical circuits. Having built and operated numerous plants utilizing selective sulphide precipitation of heavy metals, BQE Water has gained unique insight into the design and control of the sulphidization stage of SART to minimize costs and ensure high efficiency in cyanide recovery."

Jan 1, 2017

By Richard A. Leiby

The recycling of lead-acid batteries in the United States has become a challenge as to how to balance ever increasing environmental regulation and cost with efficient operations. East Penn's captive secondary lead smelter has developed into a recycling facility producing lead, polypropylene, sulfuric acid, ammonium bisulfite, and non-hazardous discard slag. The emphasis has been to design a facility to comply with environmental regulations, to eliminate wastes, and to produce products, while at the same time, continuing to supply the company's battery manufacturing raw material needs.

Jan 1, 1993

By Frank L. Marley

Mexican silver mining operations have existed prior to the sixteenth century. Recovery processes throughout the centuries were developed at the many mining localities and have progressed through smelting, the patio amalgamation process to cyanidation and flotation. A study of the present silver mining zones is reported in which the ores are evaluated in terms of the mineralogical constituents, their state in the matrix and the effects these are noted to impose upon the efficiency of recovery. Silver mineral identifications were by quantitative ore microscopic and scanning electron microscopic energy dispersive X-ray analysis.

Jan 1, 1982

By E. M. Stiles

Introduction The papers that follow deal with recently completed major improvements in practices at the Sullivan operations in Kimberley. The papers have been prepared by members of the Consolidated Engineering Staff and outline the construction programme which has been in progress for the past three years, entailing an expenditure of some millions of dollars. Four major operational changes have been brought about in the mine and concentrator. They are: (1) A change in backfill procedure for filling stopes below the 3900 level. (2) A 12,000-ton,per-day sink-float plant at the concentrator. (3) A new haulage system from the mine to the concentrator. (4) A completely new crushing plant and ore storage facilities located underground. A brief outline of the background and history leading up to this overall project will be given to show how each started as an independent betterment and how they were finally co-ordinated into one major programme. The first of these, namely, the necessity for backfilling stopes below the 3900 level, was the most pressing problem. All filling to date bad been done above the 3900 level, where mining was carried on in an irregular pattern of open stoping. Stopes below the 3900 level were first opened in 1940 and are being worked on a regular pattern of panel sub-level open diamond drill stopes. The two areas are separated by a sill pillar traversing the entire length of the vein at the 3900 level elevation.

Jan 1, 1950

By Claudeir Carvalho Silveira

Para produzir os aços bifásicos galvanizados com revestimento de Zn-Fe as tecnologias de galvanização foram adaptadas visando à produção de aços com alta resistência, resistentes à corrosão e boa conformabilidade. Desta forma, e considerando as deformações obtidas na estampagem tornou importante a caracterização em laboratório da influência do nível e do caminho de deformação na geração de trincas do revestimento com Zn-Fe aplicado a um aço bifásico. O presente trabalho avaliou o efeito dos caminhos de Deformação Uniaxial, Deformação Plana e Estiramento Biaxial Simétrico na evolução das trincas do revestimento Zinco-Ferro (Galvannealed-GA) e sua conectividade considerando o aço base Dual Phase 600. Foi observado que aumento da área composta por trincas ocorre com o aumento do nível de deformação para todos os caminhos avaliados. O Estiramento Biaxial Simétrico foi o caminho de deformação que mais influenciou no aumento da área com trincas na superfície do revestimento e na conexão destas trincas com o aço base. Isso ocorreu em função do estado de tensão (tração-tração) imposta à superfície e à seção dos revestimentos. Mesmo sendo observada a conectividade das trincas com o aço base não foi verificado visualmente defeitos de desplacamento do revestimento tais como Powdering e Flaking.

Aug 16, 2017

By A. B. Cecala

The Bureau of Mines has developed a pallet loading dust control system designed to lower the dust exposure of workers during the bag stacking process at mineral processing facilities. The system makes bag stacking much easier because the pallet height remains constant throughout the entire bag stacking cycle through the use of a hydraulic lift table. The system uses a push-pull ventilation technique to capture the dust generated during bag stacking. A low-volume, high-velocity blower system operating at approximately 150 cfm blows a stream of air over the top layer of bags on the pallet. The blower system is composed of two 3-in air jets (approximately 1,200-ftjmin velocity) directed toward an exhaust system on the opposite side of the pallet. As these air jets travel across the pallet, they entrain the dust generated during bag stacking. The exhaust ventilation system pulls approximately 2,500 cfm of air and dust through the exhaust hood. This exhaust air can then be dumped into a baghouse ventilation system, or filtered before being discharged outside the mill. During a laboratory evaluation, a 70-pct dust reduction was recorded for the bag stacker. The system was then evaluated in an actual working environment. The first field evaluation was performed at a silica sand operation in which one worker performed the entire loading and bag stacking process. This worker's dust exposure was lowered 76 pet when using the new pallet loading system. The second field evaluation showed only moderate dust reduction, but this was mainly attributed to an overriding problem associated with background dust and the cleanliness of the bags. From both the ergonomic and production standpoint, the system was well received by both the workforce and plant management.

Jan 1, 1988

By C Hawtin, B Miller, D Ashton

Ernest Henry mine (EHM) is an Iron oxide copper-gold sublevel cave mine located 30 minutes north of Cloncurry in North-West Queensland. The underground mine lies beneath open pit excavations, which were in operation from 1999 to 2011. Fault structures carry large quantities of water from the cover sequence aquifer into the underground mine area. The open cut excavations exacerbates vulnerability of the underground mine to the high intensity wet season storms of northern Queensland. These factors combine to make hydrogeological issues high priority for mine operation. Water-related risks include the cost of removing water from the mine, flooding risk and mud rush potential.Turnover of key technical staff in late 2015 at EHM resulted in the mine being left in an untenable position of losing the primary source of technical knowledge. Due to encouragement of cross-disciplinary activity coupled with workload and resource sharing, the management team were confident in utilising on-site personnel to offset loss of experienced personnel.Remaining geology personnel took additional responsibility for hydrogeological monitoring equipment and planning of upcoming work. Consultant input was limited to review only and an emphasis was placed on knowledge transfer to the geology team. Using this strategy, a 13 hole dewatering program was successfully implemented, achieving a significant water level drop in areas of elevated hydrological risk, whilst also upgrading the hydrological monitoring sensor array.Through a development program centred on cross-disciplinary exposure, the technical team was able to retain key technical knowledge despite staff turnover and produce strong results outside traditional training and roles. This paper serves as a case study on the methods, strengths and drawbacks of putting a focus on cross-disciplinary exposure as a method to combat staff turnover.CITATION:Ashton, D, Miller, B and Hawtin, C, 2017. Go with the flow – managing hydrogeological staff turnover at Ernest Henry mine, in Proceedings Tenth International Mining Geology Conference 2017, pp 129–136 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

By James P. Ludwig

While we are all aware of the need for reclamation of mine sites, few managers and engineers seem to be aware that good reclamation begins with the earliest plans for mining and processing of ores. Far too often the attitude that reclamation is an add-on to worry about at the end of the mining process dominates the thinking of mine engineers and management, A common result is that the reclamationist can be faced with mining and waste disposal designs that are nearly impossible to deal with effectively from an ecological perspective. Everyone of us has been victimized by the down time and maintainence cost that resulted from the purchase of an outwardly attractive, but poorly designed piece of equipment. When confronted by design defects in equipment, a distraught owner can always trade it in, call a consumer advocate, or follow up one of the "lemon laws" at either the federal or state level. A poorly designed mine for reclamation purposes usually cannot be treated either with ease or cost effectiveness. Good reclamation can be effectively prevented by the designs used when the mine was planned. The purpose of this paper is to share some of the experiences our firm has had with reclamation projects at mines in the Upper Midwest as these were influenced or controlled by mine design decisions. My aim is to sensitize mine planners and managers to planning processes they should consider, and hopefully use, early in the mining process to assure successful reclamation during and after mining. Many of the examples I will cite are from experience gained at the recently closed Jackson County Iron Company taconite operation at Black River Falls, Wisconsin. I am particularly grateful to Mr. Vern Metzger, mine manager at JCIC, for his unflagging support of good reclamation practices, employee training programs (which have included reclamation techniques), and his forebearance to put up with our group of ecologists. I realize that this was a time when there were significant internal and external pressures to cut all costs including reclamation efforts. The collaboration has been successful as you will soon see.

Jan 1, 1984

By Marco Quirion

The Daniel-Johnson dam, formerly named Manicouagan-5 (Manic-5), is located 800 km northeast of Montreal (Quebec) in Canada. This is the largest multiple-arch concrete dam in the world consisting in 13 arches and 14 buttresses. Since its construction in 1969, various type of cracks have appeared on both downstream and upstream faces of almost all the arches of this concrete dam. As a part of the Daniel- Johnson’s dam safety assessment program, Hydro-Québec is currently performing structural analysis of the dam with advanced numerical models to better understand and predict the dam behaviour. Because the buttresses transmit all the arch loads to the rock mass, determination of the properties of the dam foundation should not be neglected in dam global safety analysis and also to insure that reliable input parameters are used in the dam numerical simulations. This paper summarizes the past and the more recent investigations of this foundation used to assess its safety and stability. Moreover, the use of rock mass classification to estimate the deformation modulus, based on empirical equations, gives values in the range of 30 to 40 GPa that are higher than expected values. Using those values in the numerical simulations for dam structural analysis gives an excellent correlation with displacements monitoring of the buttresses.

Jan 1, 2015

By L. C. George

Addition of an acid waste to an alkaline cyanide waste was investigated for five different combinations of electroplating wastes. At the optimum final pH values of the mixtures, metals and cyanides were almost quantita¬tively precipitated. No evolution of hydrogen cyanide was detected by a few additional processing steps, significant amounts of variable metals were recovered for recycling the waste-plus-Waste step is attractive because no reagents are required, metals arc concentrated, and a relatively harmless effluent that meets most water quality Standards for cyanide content is produced.

Jan 1, 1970

By Y Ren

The algorithms employed by the commercial tools are either heuristic algorithm or iterative optimisation of a subsystem. This often results in a suboptimal schedule. In this paper, the author presents a new scheduling algorithm that incorporates with a novel stockpile configuration system, an improved algorithm on multiple processes and a mixed-integer linear programming (MILP) global optimisation model. It can simultaneously optimise stockpiles, blending, multiple processes as well as multiple mines. In addition, it allows the user to interact with the solution to adjust the solution to be practical and desirable.CITATION:Ren, Y, 2013. A simultaneous optimisation tool for open pit mine scheduling, in Proceedings World Gold 2013 , pp 427-432 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By T A. Carter

In 2010 Agnew Gold Mine (AGM) struggled to produce the required tonnages from its stopes. The longhole rises used to create void in stopes were unreliable and often failed to gain the designed rise height. The number of firings per stope was having an adverse impact on the ground conditions at the stope brows, impeding stope productivity.Through practical experimentation with longhole drill rigs, box hole rigs and development drill rigs as well as trialling new methods in conjunction with reviewing drill hole data, drill hole accuracy was observed to be an issue on-site. Innovative dragging methods such as the reverse drag, combined with a slope instead of a vertical face on the rear of stopes, have improved dragging and a reduction of firings per stope, enabling larger production blasts.The methods trialled and subsequently implemented at AGM have facilitated the mine achieving budgeted targets for six consecutive quarters. This paper documents the use of these methods in a key lode of AGM’s operations to improve drill and blast practices in order to achieve production targets.CITATION:Carter, T A, 2014. Improving production drilling and blasting in the Kim South orebody at Agnew Gold Mine, in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 251–258 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

Under the AMIRA P9 project the three-product cyclone-an off-shoot of the conventional hydro-cyclone-that produces three distinct products has been developed. The three-product cyclone shows great promise as a classifier in mineral processing. Industrial and pilot plant trials performed to assess its performance in the classification of the UG2 platinum ore, indicate that the presence of an extra overflow product stream that captures the mid-sized particles, provides improved classification efficiency. To assess the split on component density, samples from the feed and product streams were screened and assays by size for chromite (? = 4.8) and silica (? = 2.65) were obtained. Results from tests performed using this type of hydrocyclone in a number of applications indicates that it can be applied successfully in circuit configurations where the conventional hydrocyc-lone is not suitable. Utilising the three-product cyclone to classify the UG2 platinum ore resulted in an intermediate overflow product stream containing the mid-sized low density silicates and relatively fine high density chromite particles while the finer overflow contained mostly fine silicates and chromite particles. The coarse chromite and silicates reported to the underflow. Due to the increased number of products, the method of using efficiency curves was extended to cater for the increased number of products in the three-product cyclone. Although significant differences in the classification performance of the three-product cyclone were noticed with variations in machine variables a consistent method of assessing the performance was applied. The efficiency curve was adopted and applied and separate efficiency curve properties were obtained for each product stream. The methodology was applied to the component data, and efficiency curve proper-ties for each key component were obtained and compared. This paper discusses the application of the efficiency curve to cyclones producing more than two products and extending the methodology to the different components in the feed.

Jan 1, 2014

By Z. S. Abisheva

Rare and rare earth metals use quite often is an indicator of national economy development. The world structure of the rare-earth metals manufacturing countries in 2015 was presented as follows: China – 94.2%, India – 2.0%, Russia – 1.8%, the USA – 1.2%, Brazil – 0.5%, Malaysia – 0.3%. In Russia, large reserves of rare-earth metals, which reach nearly 28 million tons, are revealed. Kazakhstan, possessing a raw materials source of rare-earth metals, has all prerequisites for development of branch. Rare metals are manufactured in Kazakhstan incidentally by non-ferrous metals production. The production of indium, thallium, cadmium, selenium, tellurium, bismuth is made at the Ust-Kamenogorsk lead plant; tantalum, beryllium, niobium and molybdenum – at the enterprises of “National Atomic Company Kazatomprom” JSC. Production of a titanium, magnesium and vanadium is adjusted on “Ust-Kamenogorsk Titanium-magnesium Plant” JSC. Capacities for beryllic production yield are available on “Ulba Metallurgical Plant” JSC. The main producer of perrhenic production and osmium-187 is "Zhezkazganredmet" RSE. The single producer of gallium in Kazakhstan is “Aluminium of Kazakhstan” JSC; the capacity of enterprise is 25 t a year. In Kazakhstan innovative technologies for rare and rare earths mineral raw materials processing are created. The technology has been developed and a vacuum distillation apparatus has been created to purify crude selenium, which makes it possible to obtain a metal with a main component content of 99.9-99.99%. Technologies for processing of technogenic wastes and byproducts of the copper industry are developed. Implementation of technologies allow to obtain ammonium perrhenate, perrhenic acid, osmium isotope -187, tribasic lead sulphate, silver-concentrate. The technology of complex processing of black shales of Balasauskandyk deposit with the production of gold, vanadium, rare earth elements, uranium and ferrosilicon has been proposed. The processing was carried out using methods of autoclave leaching, sorption, extraction, precipitation. A highly profitable sorption technology for recovery of rhenium from solutions of underground leaching of uranium ores containing 0.2-0.4 mg/L of Re has been created. The organization of ammonium perrhenate production from solutions of uranium ore will significantly increase the volume of its production in Kazakhstan.

Jan 1, 2018