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By Daniel Hodouin, Claude Bazin

"This paper examines the economic advantages of adapting the production grade and recovery targets of a flotation circuit as a function of metal prices. The study is periormed using a steady state simulator for a Cu-Zn differential flotation circuit operating under the following strategies of 1) Maintaining constant operating targets, 2) Maximizing individual circuit Net Smelter Return and 3) Maximizing the global Cu-Zn circuit efficiency. Results are compared to assess whether or not one of the strategies produces benefits significantly higher than the others. A discussion of the tools required to achieve such a kind of control completes the paper.Paper not Available at Time of Publication"

Jan 1, 1997

By William J. Campbell

These investigations were undertaken as part of a program to determine the optimum X-ray spectral lines to use for analyzing the wide variety of samples received by the X-ray Laboratory. Theoretical calculations and experimental data derived from these investigations show that longer wavelength spectral lines, > 2A, are very useful for many analytical problems. Because of the low fluorescence yield of the elements of atomic numbers 13-22 and the small depth of penetration of their X-ray spectral lines, these elements were originally considered to be insensitive; however, these studies show that the wide dispersion of their spectral lines, coupled with their weak beta lines, permits the use of wide collimation, thus increasing the line intensity. More importantly, the background due to scattered primary radiation is very low in the long-wavelength region.

Jan 1, 1959

By M I. Pownceby, M A. Rhamdhani, S Palanisamy, D Fellicia, B Satritama, G A. Brooks, A Ang

Metal production have long been using carbon sources as both reducing agents and energy sources. Consequently, the global extractive metal sector contributes significantly to greenhouse gas emissions, accounting for approximately 9.5 per cent. Hydrogen gas offers as a promising ecofriendly alternative to carbon in metallurgical processes, serving as both a reductant and energy supplier with a by-product being only water vapour. However, the implementation of molecular hydrogen faces certain challenges related to the thermodynamics and kinetics of metal oxide reduction. In addressing these challenges, researchers have explored the application of hydrogen plasma, generated by subjecting molecular hydrogen to high energy to produce atomic, ionic and excited hydrogen species. Hydrogen plasma offers thermodynamic and kinetic advantages over molecular hydrogen and carbon-based reductants, exhibiting lower standard Gibbs free energy of reaction and activation energy. Therefore, hydrogen plasma can produce metal in fewer steps, process any oxide feed and feed size and even be used to refine metals. Despite these advantages, challenges exist in utilising hydrogen plasma in extractive metallurgy, including electricity costs, potential reverse reactions and industrial-scale implementation. This study provides a mini review of prior research on hydrogen plasma for metal oxides reduction, particularly iron oxide, as well as state-of-the-art techniques for its use in extractive metallurgy applications by mentioning several reactor types. Future prospects and scale-up possibilities of the hydrogen plasma in extractive metallurgy will also be presented.

Aug 21, 2024

By Takahiko Okura

Most non-ferrous raw materials are associated with sulphur. To extract the metals, the sulphur is recovered typically as sulphuric acid or liquid SOz, On the other hand, natural gas may contain over 20% of hydrogen sulphide (HzS) and a huge quantity of elemental sulphur is produced through oil and gas refining processes in the world. A large fraction of the sulphur mined from natural sources is eventually returned to the earth as fertilizers, by-products of desulphurisation and neutralisation processes, or as fugitives to the atmosphere. However, the supply and demand for sulphur are in imbalance. Such situation urges to develop a new smelting process without sulphuric acid production. This paper briefly reviews the global sulphur balance and the technologies for recovering elemental sulphur. The core of this paper is a proposal to convert SO2 gas to elemental sulphur by using organic materials. Some results of thermodynamic calculations and experiments are presented.

Jan 1, 2003

By Jae-Chun Lee, Sadia Ilyas

We investigate the technical feasibility of bioleaching of metals from low grade sulphidic ore. Experiments were conducted with an adapted consortium of Sulfobacillus thermosulfidooxidans and Thermoplasm acidophilum in batch bioreactors (1.5 L), small columns (10 kg ore load, 8 % S0 sludge) and large columns (80 kg ore load, 12 % S0 sludge). Approximately 83 % Ni, 85 % Cu, 55 % Fe and 81 % Zn was leached out in batch mode while 93 % Ni, 89 % Zn, 81 % Cu and 65 % Fe was leached out in column reactors. Bioleaching potential improved by acid pre-leaching, adaptation of microbial consortium and periodic bleeding of effluents.

Jan 1, 2014

The transition from low stress to high stress conditions is a challenge eventually faced by most mines in Australia that extend to depths greater than (generally) about 1000 m. In areas with strongly adverse 'stress versus depth' gradients, such as some parts of Western Australia, significant stress-related problems have occurred at depths as shallow as 300 m below surface. The actual depth at which the 'transition' occurs is a function of the local pre-mining stress field, the strengths of the various rock types hosting the deposit and the layout and sequencing adopted in the mine. Stress-related damage can result in increased support costs, and delays associated with rehabilitation and disruption to production. In the worst case, where strong seismicity and associated damage occurs in active mining areas, 'exclusion' zones and 're-entry' protocols may be required. These can severely disrupt production. A key aspect of managing the transition is the recognition of the onset of stress-related ground behaviour. Damage mapping can be used to develop understanding of the relationships between mining activities and the local and regional response to them. Carefully documented case histories provide a basis for calibrating numerical models. This paper discusses some of the typical styles of ground behaviour observed in higher stress conditions in underground mines. A simple damage classification scheme is described to assist in 'damage mapping' of mine tunnels. An example of damage mapping is presented to illustrate an approach commonly used for recording stress-related damage.

Nov 25, 2010

By Brian P. Atkin

The NISOMI-81 opaque mineral searcil and identification system uses quantitative color values (Pe, dA, y) and VHN as its determinative para-meters. The system is designed to operate on a Radio-Shack TRS-80 micro-computer which is interfaced to a motorised diffraction grating mono-chromator (WILSCAN). Using an interfaced monochromator/photometer combination a typical identification including the measurement of the photometer data on both specimen and standard, calculation of color values and a computer search takes about 6 minutes. The data file contains 240 minerals at present but can easily be expanded as reliable new data become available.

Jan 1, 1982

By S. F. Kaplan, A. S. Dolotov, V. N. Kovalev

"At this point in time, autoclave recovery (POX) followed by sorption cyanidation (CIL) is one of the most promising technologies for the efficient processing of refractory and double refractory gold-bearing sulphide rock. This hydrometallurgical technology requires the use of a large amount of water (up to 5 tons per ton of used concentrate), resulting in highly saline water with high pH (pH 9-11), high content of cyanides (up to 300 mg/l), arsenic compounds, antimony and a number of heavy metals. In order to determine the possibility of using recycling industrial water in POX-CIL technology, several batches of experiments were conducted (using the double refractory flotation concentrate of the Mayskoye deposit). Urban water with a chloride ion content of 10 mg/l was used during the reference POX-CIL experiment as the liquid phase of the ??? feed pulp. At that, gold extraction rate amounted to 89.4 %. A full cycle of POX(200 ºC)-CIL was carried out during the first part of the experiments; at that, fresh concentrate of the untreated recycling water with cyanide ion content of 95.4 mg/l, left after the completion of the previous CIL cycle, was used for repulping. It has been established that direct use of untreated recycling industrial water is impossible due to a sharp decline in gold extraction (preg-robbing) down to 79.5%. The presence of chloride ions, cyanide ions and other ligands in the liquid phase provides effective complexion formation for the recovery gold; complex gold compounds are quickly and firmly sorbed by the natural carbonaceous substances of the concentrate at the stage of autoclave recovery; they are virtually not cyanized onwards, and gold is carried over to the tailings. During the the second batch of experiments, recycling industrial water with cyanide and chloride ions' concentration of 500 mg/l each was subjected to the reverse osmosis desalination (up to 6 times in a successive order). After each desalting cycle, such water was used as the liquid phase of the feed pulp in POX-CIL. 6 cycles of RO desalination enabled the extraction of 86.1% Au (which is close to reference recovery). During the third batch of experiments, recycling industrial water was diluted with distilled water (2, 4, 16, 32, 64 times); after each dilution cycle, this water was used as the liquid phase of the POX-CIL feed pulp. Gold extraction after 64-fold dilution amounted to 82.6%. The results of the conducted researches show that the use of untreated recycling industrial water in POX-CIL hydrometallurgical technology is absolutely impossible due to a sharp decline in gold extraction. Even the 64-fold dilution with pure water is inefficient both from the perspective of gold extraction and of rational use of water. Reverse osmosis desalination solves the problem of water treatment except for the removal of cyanide ion, which requires separate reagent treatment of water."

Jan 1, 2018

By Achilles Dutra, Everton Santos, José Oliveira

The beneficiation of phosphate ores by froth flotation is the most efficient process used to separate apatite from gangue minerals like calcite, dolomite and quartz. However, the similarity of surface properties between apatite and calcite generally lead to non-selective adsorption of reagents, rendering the selective separation of these minerals a worldwide problem. The phosphate deposit of Itataia, State of Ceará, Brazil, studied in the present work, presents a complex mineralogical composition having uranium associated with the apatite mineral. The main gangue minerals are calcite and quartz. The bulk flotation of apatite and calcite with anionic collectors in an alkaline medium followed by the selective flotation of calcite at pH 5.5 using phosphoric acid as well as citric acid as depressant have been suggested for this ore. This paper presents the results of contact angle measurements obtained using jojoba oil, a natural reagent composed mainly of gadoleic acid (C20:1) and long-chain fatty alcohols (eicosenol and docosenol), as an alternative collector for the selective separation of apatite and calcite minerals. The hydrophobicity studies were carried out using a computer controlled contact angle goniometer. Additionally, the collector adsorption was evaluated via electrophoretic mobility and FTIR measurements. The results indicated that a high selectivity can be obtained by using jojoba oil as collector in a slightly acid pH range, without the use of depressant. The best results were achieved with a jojoba oil concentration of 200 mg.L-1 at pH 6.5, where the apatite was fully hydrophilic and calcite showed a high hydrophobicity (? > 60 º).

Jan 1, 2014

By A F. D C Varajpo, R C. Weba, C Volkmer-Ribeiro, C A. C Varajpo, N S. Gomes

This study relates to the spongillite deposits from the region of Jopo Pinheiro, in the north-west of the State of Minas Gerais, south-eastern Brazil. The deposits occur in shallow ponds (with a maximum depth of 3.5 m) on a karstic planation surface developed on rocks of the Spo Francisco Neoproterozoic Supergroup. Cenozoic detritic covers are associated with this surface. The field study of spongillite deposits from the Preguita and Avipo deposits revealed sedimentological and pedological similarities between the different deposits. They have a lenticular shape and contain different layers of sedimentary spicules intercalated with layers of quartz sand and clay minerals. Representative samples from the different layers investigated by X-ray diffraction, differential and gravimetric thermal analysis and infrared spectroscopy showed a range from three to 80 per cent of amorphous silica (opal) corresponding mostly to the sponge spicules in the sediments. Optical microscopic investigation determined that the spicules predominantly belong to the sponge Metania spinata. This species is represented by smooth megascleres (alpha type), prickly megascleres (beta type) measuring 240 to 450 mm in length, as well as the spiny microscleres; whereby the smooth megascleres are larger and thinner. The morphological variation of the spicules as well as the presence of more fragmented spicules towards the base of the deposits, portray a variation in texture and in the state of their preservation along the profile, suggesting environmental variations at the time of their formation and deposition.

Jan 1, 2008

By A. Ghosh

Commonly used predictors of ground vibration from blasting, being linear in log-log plot, do not model the underlying physics of wave attenuation. Amplitude of the wave decays with distance due to geometrical spreading and inelastic attenuation producing a nonlinear carve in log-log scale. The nolinear decay of seismic waves has also been observed from non-explosive sources, such as, pile driving, drop hammer, traffic, etc. The improved predictors, by explicitly taking these two mechanisms into consideration, model the data trend extremely well at all distance ranges. Actual field data from different studies have been used to validate the improved models.

Jan 1, 1991

By K. Hanna

Early identification of adverse geologic conditions and high stress concentrations during the high-speed extraction of coal using modern mechanized long wall systems is a major challenge facing the mining industry. Often, unexpected geologic anomalies that affect rock mass quality are encountered more rapidly, leaving the mine operator with insufficient time or information to deal with the changing ground conditions. The RockVision3DTM seismic tomographic system, developed by NSA Engineering, Inc., offers substantial benefits over conventional geologic/stress-detection methods and has been used successfully in coal mines worldwide. Tomographic images, produced economically and in near-real time, are easy to interpret, allowing mine operators to deal with potential hazards on a day-to-day basis. This paper focuses on the application of RockVision3DTM technology for delineating hazards caused by stress and geologic anomalies. Case studies for two bump-prone coal mines will be discussed. For example, (1) in a German deep (>1,130 m) mine, the drilling-yield method was used to verify the effectiveness of this technology in detecting stress anomalies ahead of longwalling; (2) in a Polish mine (-500 m deep), two longwall panels 4 km apart were monitored to assess structural and stress-related factors contributing to differences in mining conditions and magnitude of structural failures.

Jan 1, 1999

By J. B. Cabezas

The metallurgical processes that are frequently applied today use strong solutions and are of alkaline, acidic, or organic nature. These play a very important part in recovery of values from many ores. These solutions are of such a chemical nature that they are generally corrosive, flammable, and contaminating. In most cases, they are highly dangerous to the environment. Within the extractive metallurgical industry, it is also very common to have to deal with the handling of contaminating solutions with a high content of cyanide, arsenic, mercury, lead, copper kerosene, acid and many other components whose temporary or permanent confinement within the process must be adequate and absolute.

Jan 1, 1986

By T. Majcherczyk

Shaft lining reinforcing analysis of two shafts under construction has been presented in this study. The first shaft was driven from the surface, while the second was deepened. Mining and geological conditions have been studied with respect to the lining capacity. The improvement of shaft stability comprised two elements, i.e. reinforcement of the shaft lining capacity and improvement of the strength properties of the rock mass. In both tested cases, the particular hazard was connected with non uniform loadings of the lining, which could generate shearing stresses within lining structure. Thus such elements as armored concrete with high strength properties, bolting and injection sealing of the rock mass, and the use of special ring reinforcing the shaft lining have been used in order to reinforce the shaft-rock mass system. Practical conclusions related with new technological solutions, allowing the rock mass and shaft lining reinforcement, have been included for the present study. Practical conclusions related with new technological solutions, allowing for rock mass and shaft lining reinforcement, have been also included to the present study.

Aug 1, 2013

Jan 1, 1934

Power consumption of stirred media mills has been studied by an approach developed from work on stirred reactors. Relationships between torque required to rotate both disc and pin impellers immersed in dense particulate media as a function of speed, impeller and tank dimensions, and other relevant variables are evaluated. Data collected during numerous different experimental conditions are analyzed. The results can be summarized and presented in the form of characteristic plots, general equations and dimensionless group correlations involving power and modified Reynolds numbers. Special attention is directed towards the rheological properties of the media, which is considered as non-Newtonian liquids and hence, the equation of power law liquids is employed. Procedure for estimating parameters of effective viscosity and scale-up guidelines with respect to power consumption are put forward.

Jan 1, 1994

By John L. Miller

The synthetic fluormicas may be divided on the basis of silicon content into tetrasilicic, trisilicic, and disilicic. Properties of lead and barium disilicic fluormicas were determined to characterize these two representative members of the disilicic group. Properties described include unit-cell parameters from X-ray diffraction, optical data, chemical composition, density, melting point, and mechanical and dielectric properties. Both the lead and the barium micas were typically monoclinic; neither was sufficiently cleavable to yield usable mica splittings. Both yielded polycrystalline, machinable ceramics with excellent mechanical and dielectric properties.

Jan 1, 1963

By Åke Saudström

An EAF dust sample generated in a scrap based steel mill was treated by a combination of hydro- and pyrometallurgial techniques. The EAF dust contained mainly ferritic spinels forming solid solution phases according to the general chemical formula (MnxZnyFe1-x-y)Fe2O4 and other oxide phases such as ZuO. CaO and Ca2Fe2O5. The EAF dust was first treated by hydrochloric acid leaching at p8=3 which dissolved 63% of the zinc. The pyrometallurgical treatment of the leaching residue was studied using an induction heating system to simulate some important operations of EAF smelting of the residue in combination with steelmaking. The leaching residue was mixed with carbon powder to obtain a mixture with 52.1% ZnFe2O4 and 175% carbon. The mixture, scrap, and slag former were charged together in a crucible and heated to attain a melt temperature around 1650°C. The effects of different amounts of mixture on the zinc balance and iron recovery were examined. Based on the test results, suggestions are made for the EAF recycling procedure of the leaching residue.

Jan 1, 2003

By A. L. Mackie

Arsenic is a highly toxic element and a known human carcinogen. It is often a contaminant in mine water discharges, particularly from gold mining and roasting operations, and has been found at concentrations as high as 4 g/L. Increasingly stringent controls on the concentration of arsenic allowed to be discharged into the environment cannot always be met by current treatment processes and thus enhanced technologies are required to achieve low treated effluent concentrations at reasonable costs. A novel two-step physicochemical treatment process was developed and tested at the bench-scale using synthetic mine water solutions (SMWs) in order to reduce arsenic concentrations in treated effluent to exceed current discharge regulations. The process includes chemical coagulation with ferric sulphate and ballasted flocculation for enhanced solid-liquid separation. The SMW contained 59 ± 2 mg/L arsenic with a slightly alkaline pH. The effect of arsenic speciation on the process was tested by using either arsenite, As(III), or arsenate, As(V), in the SMW solutions. Tests were performed at cold temperature (3 ± 1 °C) to ensure the process? efficacy year-round in northern climates. Arsenic in As(V) SMW solutions was removed to a final total concentration of 0.0054 ± 0.002 mg/L, almost half the current recommended allowable drinking water concentration of 0.010 mg/L. As(III) was removed to a concentration below the Metal Mining Effluent Regulations? (MMER) current limit of 0.50 mg/L, to 0.32 ± 0.06 mg/L, with double the coagulant dose used in Stage 1 for As(V) removal. Oxidant addition at a concentration of 5 mg KMnO4/L in Stage 2 resulted in final total arsenic concentrations of 0.017 ± 0.002 mg/L and pH adjustment with lime in Stage 2 resulted in 0.0415 ± 0.0007 mg As/L in treated As(III) SMW. Both of these modifications to the process reduced arsenic concentrations to below proposed new MMER limits (i.e., 0.10 mg/L). This two-stage treatment process was shown to reduce arsenic concentrations to well below current treatment guidelines while reducing or eliminating chemical oxidant demand.

Aug 1, 2013

By Yan Beygelzimer, Alexander Spuskanyuk, Victor Varyukhin

"A cellular model of the plastic deformation of polycrystalline aggregate is proposed and comprehensively described. Representative volume element (RVE) of a solid body, that is being deformed, is described as a population of interconnected units that, in turn, can consist of lower scale level units. Sliding along the various allowed sliding systems deforms simple units, which do not have an internal structure. For consideration of stress distribution within the limits of components, the approach of self-consistent field is used. Rotation of units and moment stresses connected with it are taken into account. Results of computer experiments are analyzed.1. IntroductionMicromechanical models of polycrystals are a link between the research of plastic deformation on micro and macro levels. Computer simulation of inelastic strain of polycrystals has found a great deal of interest as well. Despite the fact that this approach does not allow to obtain macroscopic constitutive relationships that are used in deformed solid body mechanics, it clarifies essential features of the phenomena in many aspects. First of all, it concerns effects stipulated by interdependence of micro-level and macro level of plastic deformation processes. Also, with the computing mechanics, instead of constitutive relationships, the adequate computer models can be used. Broad possibilities for computer simulation of various processes are opened by cellular automata approach. By means of numerical experiments, the cellular automata allows to study the macro behavior of the whole ensemble of cells depending on the local microscopic laws that define evolution of each cell and its interaction with the closest environment.We propose a mathematical model of a polycrystalline aggregate (the cellular model) based on a self-consistent scheme and on the interaction law similar to the one by Berveiller and Zaoui [1]. Our original solution is the self-similar structure of cellular automata that allows modeling of the fractal nature of real materials (Figure 1). The goals of this work are to present the major structures and relations of cellular model of polycrystal and to test this model for its adequacy as for describing known effects and dependencies. Identification of the model and its application for studying of concrete polycrystals are put aside for the future research."

Jan 1, 2001