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By Barry T. Kilbourn

A dominant characteristic of many derivatives of the lanthanides is stability at high- temperatures. Combine this with novel solid-state behavior under those conditions and there is the potential for new materials that can not only improve existing applications but also help create new technologies. These property themes will be traced through new uses ranging from efficient energy generation and raw material conversion to control of environmental emissions and temperature measurement. Conducting ceramics, methane conversion catalysts, sulfur oxide capture agents and phosphor hosts will be described. Some categories will account in the future for significant lanthanide consumption whereas others will remain commercially negligible but technologically vital. All uses will illustrate the versatility of those elements inappropriately termed rare.

Jan 1, 1992

As the theme of this conference is æRediscover OtagoÆ it would seem appropriate to revisit the era of the gold rushes and subsequent mining industry which rapidly advanced settlement and economic prosperity for Otago, and left permanent reminders in the form of historic mining sites, many of which are now encompassed within the Otago Goldfields Park. I have been invited to give a paper at this conference on the subject of æHistoric Goldfields of Central OtagoÆ. As well as having a working involvement with historic areas through my employment with the Department of Conservation, I have a personal interest in the early goldmining industry of Central Otago as my grandfather came out from Scotland in the 1890s to help construct gold dredges on the Molyneux. My grandfather made headlines in the local paper in 1920 when he believed he saw a New Zealand otter at Island Block near Beaumont - but that's another conservation trail that I will not pursue any further today! For this paper I intend to divide my time to cover the following topics. Firstly, I would like to sketch a mental picture of the characteristics that make up the Central Otago landscape, and the general perception that early miners must have had when viewing this foreign land. Then I would like to briefly discuss the changes and the consequences in the early gold rush to Central. Finally, I would like+ to discuss the establishment of the Otago Goldfields Park, which I will illustrate with several slides.

Jan 1, 1992

Results from current NERDDC funded research into the geotechnology of highwall trench mining methods have clear implications for mine planners in the areas of blast design, trench shape, location of the surcharge spoil and remnant coal pillar design.Adoption of successful smooth wall blasting techniques not only removes safety hazards from the trench face, but limits development of bedding partings at the seam contacts that interrupt the smooth transition of stress across the coal seam.

Jan 1, 1992

By A. A. Levinson, M. B. Kirkley, J. J. Gurney

"Scientific advances in the past decade have greatly clarified our understanding of certain concepts relating to the age and origin of diamonds. These advances are largely the result of geochemical studies of mineral inclusions in diamonds, made possible by modem analytical techniques which enable the accurate chemical analysis of micro-sized particles of the order of 200 microns in maximum dimension. As a generalization, the inclusions indicate that most diamonds formed from either of two rock types, peridotite and eclogite. Peridotitic diamonds have yielded ages of 3300 million years, whereas eclogitic diamonds areyounger and rangein agefrom approximately 1000to 1600million years. Kimberlite and lamproite, the two rock types usually associated with diamonds, typically are much younger than the diamonds they contain. Thus, it is now dear that kimberlites and lamproites are only the transporting mechanisms which brought diamonds to the surface and are in no way related to the formation of most diamonds. The latest concepts which developed during the past decade regarding the sources of carbon for the crystallization of diamonds from peridotite and eclogite, and the mechanisms of kimberlite and lamproite emplacement, IntroductionThe decade of the 1980s has seen major advances in our understanding of the age, origin and emplacement of diamonds. The information presented herein is applicable to virtually all natural diamonds, excluding diamonds related to meteorite impacts. There is still some question, however, as to the applicability of the new information to industrial grade ""fibrous"" or ""coated"" diamonds, and to microdiamonds (< 1 mm). In addition to drawing upon our own experiences, this review is summarized from a voluminous literature and for those interested in the original sources we recommend the books by Mitchell and Bergman (1991), Ross (1989), Nixon (1987), Mitchell (1986), Glover and Harris (1984) and Dawson (1980), and the review articles by Mitchell (1991), Gurney (1989) and Meyer (1985).are also discussed."

Jan 1, 1992

By Guilian Gao

TbFeCo is a common choice for many rare-earth transition metal films currently used as the magneto-optic layer for magneto-optical: recording devices. Since the environmental stability of RE-TM alloys is typically poor compared with traditional metal oxide particle media, such devices rely on multiple functional overlayers (metallic and/or dielectric) and organic coatings for durability. This paper presents an electrochemical evaluation of the degree of protection of several candidates for the reflective layer, Al, AlCr and AIPt and for the dielectric layer, SiN, AISIN and AIN. Cyclic voltammetry In 0.2M K2SO4 solutions at room temperature revealed that AIPt film offers superior corrosion protection compared to Al and AICr films. Of the three dielectric layers examined, SIN seems to be the most corrosion resistant. Examination by optical and scanning electron microscope confirm the findings of electrochemical experiments. The corrosion resistance of single layers of Al, AICr and AIPt has also been examined and factors affecting their performance are discussed.

Jan 1, 1992

By Michael P. Meisel

Solinox is a physical scrubbing process capable of removing a number of noxious materials from off-gasses, especially SO2, hydrocarbons, halo¬gens, heavy metals such as dust, etc. As these materials are dissolved physically, (not chemically bound), the solvent is absolutely stable and no by-products are formed in the scrubbing cycle. The process has been installed in three plants up to now, treating from approximately 30 MMSCFD to approximately 100 MMSCFD. These installations are in a non ferrous metal smelting operation, in a cellulose factory, and in a roasting process.

Jan 1, 1992

By T F. Guerin

Explorationn and mining have shown to cause significant impacts to the terrestrial and marine environment. Current mining and exploration techniques are outlined in the light of their potential to impact upon the environment, ie negligibly, negatively or positively. A profile of five Australian-based gold producers is presented. The development of protocols to specifically deal with the highly regulated and ever changing, mining and environmental legislation. demonstrates mining companies can successfully opcrationalise the concept of sustainable development.

Jan 1, 1992

By H. K. Fredrickson

"Midwest Joint Venture (MJV) owns a high-grade uranium deposit in northern Saskatchewan. The deposit is located too deep below surface to be mined economically by open pit methods, and as a consequence, present plans are that it will be mined by underground methods. High-grade uranium ore of the type at MJV, encased in weak, highly altered ground and with radon-rich water inflows, has not before been mined by underground methods.The test mining phase of the project, completed in 1989, had three objectives: 1. to evaluate radiation protection requirements associated with the handling of large quantities of radon-rich water and mining highgrade uranium ore in an underground environment; 2. to investigate the quantity and quality of water inflows into the mine; and 3. to investigate ground conditions in and around the ore zone as an aid in determining the production mining method to be used.With information gained from the test mining project, a mining method for the production mine has been devised. Level plans have been drawn up, ventilation system designed, pumping arrangements made and methods of ore handling considered. All this is to be done in a manner that will be safe for those doing the work underground. Some of the mining methods planned are felt to be unique in that they are designed to cope with mining problems not known to have been encountered before. New problems underground have required new methods to handle them. Remote drilling, blasting, mucking and backfilling form the basis of the planned mining method."

Jan 1, 1992

By Marius B. Wechsler

A mathematical analysis is developed for the determination of the cases when HP-piles might be replaced by precast concrete piles. The analysis focuses especially on the "integral abutment-bridges" which are used on large scale in the Great Plains of the United States of America, The theoretical considerations are illustrated by a numerical example.

Jan 1, 1992

By P. D. Ferro

The direct oxide reduction (DOR) of plutonium oxide generates significant amounts of contaminated waste. This waste primarily consists of calcium oxide-saturated calcium chloride salt. This investigation explores the possibility of recycling the salt, by the electroreduction of the calcium oxide. Fused salt electrolysis of a simulated salt mix (CaC12 + ~10 wt. pct. CaO) is being carried out to electrowin calcium, and the process is being optimized in terms of the calcium solubility, cell temperature, current density and cell design to maximize the current efficiency. This work identifies the major concerns in the development of a process to electrowin calcium from this simulated salt mix.

Jan 1, 1992

It is not often that mines have as much warning of the approach of bad ground conditions as was the case at the Western Mining Corporation, Kambalda Nickel Operations Lafranchi/Schmitz Decline. Most aspects of this operation are in fact quite unique and like the best solutions, the answer to the problem of weak and foliated ground conditions was relatively simple; requiring the use of readily available explosives although the idea of using it in this manner may not be the most obvious.The use of high shock energy POWERGEL 2131 cartridges proved to be the correct answer, in conjunction with small changes in drill pattern design. The resulting lack of overbreak bears testimony to the success of the concept and the commitment of the miners to achieving a safe working environment.

Jan 1, 1992

By Jae-Chun Lee

Di-2-ethylhexyl phosphoric acid (D2EHPA) is widely used for separating rare-earth elements. In commercial plants, rare-earths are usually stripped from loaded extractant streams using mineral acid, then precipitated as oxalates. Many rare-earth uses demand specific powder characteristics, which are obtained by secondary processing. This paper demonstrates the feasibility of combining the stripping, precipitation and powder processing stages, thereby achieving considerable savings. MEHPA solutions were loaded with yttrium, then emulsified with oxalic acid-HC1 solutions to precipitate yttrium oxalate, which was readily calcined to yttrium oxide. The precipitation kinetics and yield were sensitive to process conditions. The morphology and size of the yttrium oxalate powders varied with the concentrations of D2EHPA and oxalic acid, and the presence of SPAN 60, which affected nucleation, growth, and the emulsion characteristics.

Jan 1, 1992

By Armstrong M

The Clermont Coal Mine will export steaming coal from the Wolfang Basin in Central Queensland, Australia. It is expected to be developed in the mid-1990s.The majority of the reserves lie in the 30 m thick Wolfang Seam. Overburden depth varies from 80 m at the subcrop line to 190 m in the centre of the basin.

Jan 1, 1992

By Robert B. Parsons

"The Department of Finance introduced draft amendments to the resource allowance regulations on July 23, 1992 that effectively nullify the decision in the Gulf Canada Limited case. Prior to the amendments it appeared that only ""directly"" related general and administrative, capital cost allowance and scientific research expenditures had to be deducted from resource profits. Now ancillary expenditures are required to be deducted. Consequently, the ability of taxpayers to claim the resource allowance is curtailed.IntroductionOn October 25, 1990 it was almost certain that taxable mines were going to get a break. The Federal Court-Trial Division had just decided in Gulf Canada Limited&apos;s favour to allow it to claim resource related tax benefits larger than what Revenue Canada evidently wished. Revenue Canada appealed first to the Federal Court of Appeal and then to the Supreme Court of Canada. On January 10, 1992 the Federal Court of Appeal agreed with the Federal Court decision and on July 2, 1992the Supreme Court declined to hear any further appeal. A mere three weeks later, on July 23, 1992, the Department of Finance issued draft ""clarifying"" measures to amend the calculation of the resource allowance. These measures effectively nullify the benefits that arose under the decisions of the Federal Court."

Jan 1, 1992

By W. Cholewa, T. S. Golosinski, J. Wedzicha

"Power requirements of belt conveyor drives are usually estimated based on the calculated belt tension which equals the sum of unit resistances to motion which the belt has to overcome. In most situations, the value of various unit resistances can be accurately predicted using published information (5,6,8,12). A simpler approach calls for use of standard formula and tabulated values of related factors which reflect various features of both the conveyor and the transported material (2,3,7) . None of these approaches is reliable when materials with unique properties are conveyed, nor if applied to conveyors working in extreme climatic conditions. Such is the case of oil sand mines in northern Alberta.There the bitumen content of oil sand causes it to behave in a unique manner. Furthermore the conveyors operate year around, with winter temperatures often lower than - 40°C. It was the objective of presented investigations to quantify the power requirements of conveyors, and related resistance to motion for the conveyors used in oil sand mines during winter operations.The other objective was to quantify the drive power requirements of oil sand conveyors during start-up. These requirements are usually much higher than those during norm al operation, and their quantification is of paramount importance for operation of large conveyors."

Jan 1, 1992

By Mats Keisu, Bengt Niklasson

The Sofia project has increased the level of knowledge and technique within tunnelling, drifting and contour blasting.

Jan 1, 1992

By Evans A, Jones O

Surface subsidence resulting from "total extraction" of coal in the Collie Basin first occured in 1987 when Western Collieries Ltd trialled the Wongawilli mining method. Because very little quantitative subsidence data existed for the weak, Permian sediments, a research program was set up prior to the extraction of the first panel. The objective of the study was to be able to predict subsidence characteristics and effects prior to mining future total extraction panels. Attempts at predicting subsidence began using existing subsidence models from other coal mining regions, however, as more site information became available, it became clear that it was necessary to develop a separate, she specific predictive model for the Collie Coal Basin. Analysis of extensive field monitoring data for both surface and subsurface subsidence has produced a series of empirical models which can predict the shape of surface subsidence troughs and corresponding tilts, and strains for rectangular panels and describe the sequences of ground movement from the mine roof through to the ground surface.

Jan 1, 1992

By Donald Leroux

For the last few years, the grinding model first proposed by Andrews and Mika (1975) has regained attention from the scientific community. Though sophisticated identification algorithms have been developed, the number of its parameters that have to be estimated remains huge. Most of these constants (often more than 90%) are for the breakage function. This paper describes a new method for reducing efficiently the number of the breakage function parameters of the Andrews-Mika grinding model. It makes use of second-order statistics and of a stereostochastic model for liberation (for instance, BooKing).

Jan 1, 1992

By Yael Miron

Two recent unplanned detonations occurred during blasting operations in sulfide-bearing ores in a Nevada gold mine. Other premature detonations have also reportedly occurred at other Nevada, California, and Arizona operations within the past few years, with increasing frequency. Unplanned or premature detonations can be extremely hazardous to life and can cause extensive property damage. A miner was injured in one of these occurrences. This report, by the U.S. Bureau of Mines, is intended to acquaint personnel involved in such mining activities with the basic causes for these accidents. These causes include the exothermic oxidation of pyrite (FeS2) and formation of ferrous sulfate (FeS04), the exothermic and energetic reaction of the ferrous sulfate with ammonium nitrate-fuel oil (ANFO)-based explosives, and the associated elevated temperatures that can set off detonators and explosives in the boreholes. Recommendations for safe operation by the Mine Safety and Health Administration, the Bureau, and the mine involved with the recent incidents include monitoring temperatures in the blast holes, analyzing for sulfate and ferrous ions, and limiting the time between loading and firing in accordance with conditions in the blast holes. Other procedures for safe operations should fit specific conditions in, the mines.

Jan 1, 1992

By T. M. Hanna

The results of using a simple analytical solution and a relatively complex numerical model to estimate ground-water inflow to an open pit mine are compared. The analytical solution assumes lateral, radial flow to a fully penetrating pit in an idealized confined aquifer, whereas the numerical model simulates fully three-dimensional flow to a partially penetrating pit from a water table aquifer. The latter is obviously a more realistic simulation of the problem, but the former method is significantly easier to use, Comparison of the results obtained with the two methods for some typical hydrogeologic conditions encountered in mining yields ratios between them in the range of 0.15 to 0.60. These values can be used as a coefficient in the Pit Flow analytical solution to produce reasonable estimates of in-flow even when there are significant differences from the idealized conditions implicit in its application.

Jan 1, 1992