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The paper will review the marked upsurge in the installation of new continuous metal coating lines, both hot dip and electrodeposition. Although some of this new capacity has been replacement for obsolete facilities or directed at traditional markets, eg building products, consumer durables etc, by far the major portion is targeted at the automotive industry. The reasons for the rapid growth of coated automobile panels are discussed. A comparison of the installed capacity with projections for this market indicate that a severe over-supply situation has arisen. Many coatings are now available for the automotive industry, each with their own strengths and weaknesses, but none as yet wholly satisfactory. Coating development has mainly been cost driven. This favours hot dipped coatings, providing surface quality and pressing problems can be overcome. The high cost per unit thickness of electrodeposited coatings has also seen pure zinc coatings being replaced by thinner, more corrosion resistant alloy coatings such as zinc-nickel and zinc-iron. Recently resin overlays have been introduced to improve the performance of electrodeposited coatings. Developments in coatings for the more traditional markets will be described. The fastest growing market in the last decade has been prepainted product for the building industry. This has led to the installation of extra painting capacity and again it appears an excess capacity situation has occurred. Over the same period the traditional zinc coatings have continued to lose market share to the zinc/aluminium alloy coatings, Galvalume and Galfan. These have been joined recently by '1'aiyo Crack-Free which has been taken up by some metal coaters. Galvalume is now widely accepted as being the best available coating for unpainted applications. It is also suggested that 'spin-off' coatings from automotive developments might find a niche in the consumer durable market. The end users of coated products, particularly the automotive industry, have demanded improvements in quality, such as surface smoothness, formability, etc. At the same time the new coating lines have to process wider strip and run at faster speeds. To reconcile these somewhat incompatible needs has required numerous process improvements, many of which need in-line instrumentation and computer control. The more important of these changes are discussed briefly. Finally the paper will describe the recent developments which have occurred in continuous galvanising in Australia and put them into context with the rest of the world.

Jan 1, 1993

By Charles D. Litton

This U.S. Bureau of Mines report describes the results of two large-scale tests conducted to evaluate a prototype nitric oxide (NO)-compensated carbon monoxide (CO) fire sensor, developed by Carnegie Mellon Research Institute (CMRI). In the tests, small coal fires were allowed to develop in the presence of diesel exhaust at relatively low ventilation airflows. These tests compared the response of the CMRI fire sensor with that of other fire sensors, including the Bureau's diesel-discriminating smoke detector. During the tests, CO, NO, and smoke levels were continuously monitored in order to determine the sensor alarm times and gas levels as the fire developed. The data indicated that the NO-compensated CO fire sensor was capable of suppressing the CO produced by a diesel engine and that the sensor responded reliably to the CO produced from the test fires. The tests also showed that the Bureau's diesel-discriminating smoke detector alarmed earlier than the prototype NO-compensated CO fire sensor.

Jan 1, 1993

By Charles Vaught, Henry J. Kellner, Michael J. Brnich, Henry P. Cole, William J. Wiehagen

In 1985, U.S. Bureau of Mines and University of Kentucky researchers began a series of studies relating to self-contained self-rescuer (SCSR) donning proficiency. During the next 5 years investigators examined a number of factors that have a bearing upon miners' ability to put on and use the apparatus in an emergency: the procedure being taught; availability and utilization of training models; opportunities to practice; hygiene; and on-the-job training. This report presents an overview of that research. It is concluded that companies should adopt a hands-on training protocol that allows them to integrate SCSR donning practice into other workplace routines such as fire drills.

Jan 1, 1993

Research programs have established the correlation between the basic mill operating parameters such as: size of crushing products, number of mill rotation, ore flow and quantity of ore in the mill, diameter of grinding media, and specific consumption of grinding media. Also, the mill efficiency has been determined in dependence of adsorption. Mathematical dependences and equations are presented in this paper.

Jan 1, 1993

The twin iron ore islands of Cockatoo and Koolan are located in the spectacular setting of Buccaneer Archipelago off the Kimberley coastline of WA.Cessation of ore shipments from Koolan in 1993 ended 42 years of continuous mining activity which began with the first shipment of ore from Cockatoo in 1951.

Jan 1, 1993

By Y. Topkaya, R. E. Johnson, B. R. Palmer, R. B. Bhappu, A. E. Clark, R. P. Bush, L. E. Schultze

The U.S. Bureau of Mines conducted copper exchange capacity (CuEC) tests for six common clays under simulated in situ leaching conditions. Regression equations were obtained from the data expressing the CuEC as a function of Cu concentration, pH, and temperature. Further testing resulted in regression equations expressing CuEC's of Na and Ca montmorillonites and attapulgite as a function of Cu concentration, pH, and the concentration of metal ions which compete with Cu for exchange sites. Using these equations, an analysis was made of the impact each clay could have on overall copper recovery. The results suggest that Ca and Na montmorillonite clays could have a major impact on Cu recovery and that attapulgite and illite clays could have a smaller, but still significant, impact. Kaolinite and ripidolite clays pose little threat to loss of copper from in situ leaching solutions. Copper losses are decreased by the presence of competing ions, and A1 and Mg have the largest impact of those ions normally present in Cu leaching solutions.

Jan 1, 1993

By Linda C. Carrico

Those who manage the Nation's mineral resources rely upon a variety of organizations both public and private--to give them accurate mineral data, technical guidance, and expert advice. This directory provides a list of such organizations--a list that should prove a useful tool for those seeking mineral-related information and technical assistance. The directory lists Federal and State governmental agencies and national, regional, and State associations with activities in the mineral, metal, and material sectors of the economy. These organizations regulate mining, monitor mineral production, establish and enforce health and safety standards, identify and evaluate mineral resources, conduct scientific research, predict market trends, resolve environmental issues, and promote the interests of the mineral industry, its individual sectors, and its workers--to name a few of their functions. The listings in this directory--arranged by State--should help users who manage mineral resources identify agencies and organizations that can provide mineral-related information or technical assistance.

Jan 1, 1993

The environment has emerged as a permanent component of Australia's socio-political context, intricately linked with personal and future security.The implication of this powerful new influence on the Australian Minerals and Energy Industry sector has been a plunging public image.

Jan 1, 1993

By Yeliseyev AK, Shestakov AM

Comminution is the most power-intensive process in the technology for ferrous quartzite concentration. That is why improving comminution efficiency leads to the most appreciable economic effect on the concentration process. The trend towards reducing the lump size of crushed ore before charging the mill is considered to be of major importance in improving comminution efficiency. A considerable number of investigations have been performed in this direction. At the same time, a strong interest is also maintained in the increase of comminution efficiency due to optimisation of process taking place in the mill. Recently, investigations of the power intensity of the breaking process inside the mill have been carried out at the Krivoy Rog Mining Institute. It was ascertained that the routine conditions of comminution at a low mill ball charge ratio resulted in an unnecessarily high power consumption due to the force of impact of falling and milling bodies far exceeding the power required for comminution. For example, the power value for falling balls of 60 - 125 mm in diameter reaches 0.3 kNm, and the force and stress due to ball contact with the lining reaches 60 kN and 250 MPa respectively. These values exceed the force required for comminution by a factor of ten. Analysis of the mechanism of ore particle size reduction during comminution in the ball mill indicates that the size reduction is due to impact load, attrition load, and static load. The efficiency of size reduction is very low. During comminution in the ball mill, impact loads prevail and amount to 85 - 90 per cent of the total load. In this situation, not more than 10 - 15 per cent of destruction is due to attrition.

Jan 1, 1993

By E. R. Bauer

This report describes a U.S. Bureau of Mines investigation into the removal of gate road chain pillars in conjunction with longwall retreat mining. The research objective was to determine, through evaluations of the loads imposed on the gate road pillars and supplemental support elements in the entries, how the pillars, supplemental support, and entries were affected by the longwall abutment pressure. To achieve this goal, vibrating wire stressmeters and hydraulic flatjack pressure cells were installed in the support elements to monitor stress change caused by abutment pressure as a function of longwall face advance. The findings documented in this report are the result of information collected from instrumentation and observation at the mine. Pillar and support loading measurements and stability observations revealed that the roof and the sup- port elements remained stable during panel retreat, while the face progressed at a normal rate of advance. The ability to safely and efficiently mine chain pillars during panel retreat increases resource recovery and can provide several other benefits described in this report.

Jan 1, 1993

By B. R. Casement

"Managing safety on the basis of after-the-fact reaction to accidents, can never be more than partially successful. Injuries will occur as long as the underlying potential for them still exists. Unless unsafe actions and conditions are systematically decreased, no program can have more than a short-term success.The pro-active Bullmoose loss control process, instead, focusses on heightening awareness of work habits, to prevent incidents by reducing their potential.Any safety program will be doomed to failure if the development of safe work habits depends on the safety supervisor or a safety committee. At Bullmoose the focus is on the critical actions out of which losses emerge. The successful application of performance-related feedback is achieved by taking safety, health, and environmental concerns into consideration on every level, and, by doing the right thing in every job done.What is an Exceptional Loss Control Program?If an accident in an organization creates a flurry of interest, resulting in ""cracking down"" on violations for a short period of time then an ""exceptional"" loss control program exists. Unfortunately, exceptional here does not refer to the effectiveness of quality of the program but to the fact that the organization is managing loss control by exception. The degree of management attention in an ""exceptional"" safety program varies over a period of time, remaining low as long as the rate of losses stays within management's acceptable control limit (Fig. I). When the losses rise above this, management becomes motivated to begin ""exceptional"" efforts to manage losses. When the rate falls again to within the accepted limit, efforts to control losses take a back seat.Such a strategy guarantees that losses will be tolerated or ignored as long as the actual rate is below the acceptable limit. Simply to lower the limit would not reduce losses, but would result in an increased number of flurries of management attention to loss control. This ""on-again, off-again"" style of management teaches supervisors and others that basic loss control is not as important as are statistics."

Jan 1, 1993

By Yu. A. Polozov, V. A. Lagunov, O. Yu. Lushinkova, Yu. I. Svirskiy, Eh. Ya. Kipko, Roy A. Williams

1.1 GENERALIZED METHODS OF SUPPRESSING THE INFLOW OF GROUND WATER DURING THE CONSTRUCTION OF SHAFTS, DRIFTS AND TUNNELS Various methods are used to prevent or minimize the inflow of ground water into underground workings during their excavation. The two most common methods include freezing the saturated rock and grouting using cement, sodium silicate, polyurethane and/or other chemicals. Each of these technologies for combatting the inflow of ground water is effective only under specific hydrogeological conditions. For example, although the freezing of saturated ground is among the more universally adopted methods, it is designed to provide only temporary protection during construction. Before the saturated rock thaws it is necessary to emplace a waterproof liner which is labor intensive, time consuming, and expensive. Consequently, freezing is used only in exceptionally complex hydrogeological conditions, namely in those cases where the water-bearing strata consist of unstable rock or the ground water has an anomalous hydrochemistry. The classical grouting of saturated rock, carried out from the surface or from the face of the underground workings for the purpose of limiting the inflow of ground water during excavation, utilizes both cement and a variety of chemical grouts. Cement grouting has been regarded as the main method of combatting the inflow of ground water in fractured rock throughout the world. In such countries as the Federal Republic of Germany (FRG), Canada, the Republic of South Africa and Great Britain, cement grouting is the main method of reducing the inflow of ground water during the excavation of mine openings. In Great Britain and the FRG, cement grouting has been used in 80% of all shaft excavations. In the Republic of South Africa cement grouting has been used in almost 100% of all the shafts that have been constructed. The installation of grout curtains into permeable water- bearing strata significantly reduces their permeability and increases the rock strength. Grouting has the greatest effect in fractured sandstones, certain well indurated shales, fractured granites, fractured quartzites, and karstic limestones or dolomites. The following principal factors must be considered when assessing the expediency of grouting rock with cement: the geometry of the network of fracture openings, the saturated hydraulic conductivity of the fractured rock, the hydraulic head acting on the water in the rock, and the chemical composition of the ground water. On the basis of the geometry of the fractures and the thickness of each hydrostratigraphic unit, the characteristics of the cement grout are selected. As a rule, the cementing of large fractured zones with high ground water velocities is carried out using inert fillers (sand, mill slag, loam, loess, crushed limestone), special types of cement, setting accelerators, and high cement concentrations in water. Calcium chloride, soda ash, sodium silicate, sodium nitrate, amino alcohols, tin bichloride, trisulphate nitrate, and lumnite are used extensively as the setting accelerators for cement grouts. In the FRG and Poland, special cement injection compounds that embody a mixture of cement and active cement metal salts, water additives and binding substances are being used for the cementing of saturated zones with rapid ground water velocities. These reagents accelerate the rate of structure-forming reactions. In spite of the wide variety of additives used for cement grouts, the effectiveness of the method in large fractures below the water table is either poor or it leads to a very large consumption of cement due to the erosion of the grout through the cracks before it hardens. At the present time, a large number of cement types and brands are being produced by various countries. These variations permit cementing to be employed in a variety of geological conditions. However, both pure cement grout and grouts with fillers constitute unstable systems with a high water loss rate. Therefore during the grouting of finely fractured rock the cement grout's premature loss of a large amount of free water causes its consistency to increase, whereupon the grout solidifies. Consequently, it inadequately penetrates into the fine fractures of the stratum. In addition the high water loss rate in the cement grout causes unreacted cement particles to remain, which greatly reduces the grout hardness and the resulting rock strength characteristics are weakened. As a result, the binding properties of the cement are utilized perhaps up to 60%. The remaining portion is left in the grout as a filler. All these conditions significantly decrease the efficiency of the isolation effort both with respect to strength and cost. In order to expand the cement grouting method, re- search is being conducted to improve the quality of cement grout, to increase its range of application with respect to permeability control, to reduce its water loss rate and to increase its capacity to withstand the erosive and corrosive effects of poor quality ground water. For example, mixtures of bentonitic clay, carboxymethyl cellulose, aerated sodium sulfide, sulphated alcohol distillery waste, nitrolignin, gip-

Jan 1, 1993

By W. J. Mitchell

During the months of April and May 1992, the Phelps Dodge Hidalgo smelter underwent a major turnaround. This was the third such turnaround in the life of the facility which was commissioned in 1976. During the third furnace campaign, the smelter processed 5.2 million tons of concentrate producing 2.6 billion pounds of anode copper over a 7.5 year period. The critical path on the fifty-nine (59) day turnaround schedule was the reconstruction of the Outokumpo flash furnace which integrated some modifications with standard rebuild practices. Modifications included incorporation of horizontal cooling jackets throughout the furnace settler as well as the installation of castable refractory in the reaction and uptake shafts.

Jan 1, 1993

By Charles L. Kimbell

This study is intended to serve three roles. First, it is the second annual edition of this study in a separate volume that represents a global overview and summary to supplement and complement the five regional volumes that now constitute the U.S. Bureau of Mines international, geographically arranged studies. In this regard, it also extends previous works under this title that appeared in the inter-national volume of the Minerals Year-book from the inception of that volume (the 1963 edition) until it was subdivided into six separate volumes in 1989. Following the traditional format of past chapters under this title, the basic statistical presentations herein deal chiefly with 1990, and in a few instances with 1988 or 1989; these latter two only because more recent, comprehensive global statistics simply are not yet available owing to delays in data collection and processing in some countries and continued governmental suppression of data in others. The second role of this study is to provide an update to the coverage of events impacting on the world's mineral industry that have occurred between the end of 1990 and the preparation of this study. Inclusion of this update is almost essential because of the potential effect of some of these events on global mineral industry activities.

Jan 1, 1993

By Dendyuk TV

The possible use of combined (flotation/magnetic separation and magnetic separation/flotation) technologies involving the new flotation reagent systems for upgrading the iron ore concentrates, low grade manganese products and beneficiation of graphite-bearing dusts from integrated iron-and-steel works has been shown. It has been found that the absence of magnetic flocculation phenomenon worsens the reverse cationic flotation of oxidised iron ore concentrates and direct flotation of low-grade manganese products which require the use of modifiers possessing the flocculating properties. The synergetic mixtures of polymers have been proposed to be used as modifiers, ie polyacrylamide (PAA) with carboxymethyl cellulose (CMC) and polyacrylamide with industrial lignosulphonates (LST)

Jan 1, 1993

By R. L. Merrifield

Cominco Snip is a 60: 40 joint venture of Cominco Ltd. and Prime Resources Group Inc. Cominco manages the operation. The mine site is located in a narrow mountain valley where Bronson Creek enters the Iskut River in Northwestern British Columbia. Access is by air only to the company's 1,500 meter airstrip. Milling at a designed feed rate of 300 tpd began on schedule in January 1991. Tonnage and gold production in the form of bullion bars from the gravity circuit and gold bearing float concentrate have exceeded design forecast. This presentation will examine many of the factors that influenced the final plant design inclusive of exploration findings, bench scale and pilot plant test results, environmental and social considerations, capital and projected operating costs and product transportation alternatives such as the operation's Hovercraft.

Jan 1, 1993

By F. N. Kissell, C. D. Litton

This study predicts the level of smoke that miners might meet while trying to escape a coal mine fire and describes how smoke would impede their safe escape. For this study, the authors assumed that miners exit through an escapeway adjacent to the burning entry, that some air would leak from the burning entry to the escapeway. The following conclusions were made: • A very low amount of air leakage to the escapeway can produce a critical level of visual obscurity from smoke. This shows that intake airways may be as susceptible to smoke visibility problems as return airways. • This critical level of smoke obscurity is reached much before a critical level of carbon monoxide is reached. • Small fires can cause a severe sensory irritation that further limits vision. Thus, reliable eye protection is very important. These results show that methods to guide miners through dense smoke will contribute greatly to saving lives during mine fires.

Jan 1, 1993

By B Moynihan

The Roa Opencast Coal Mine is situated at the north-eastern end of the Greymouth Coalfield. It lies on an eastern flank of the Paparoa Range, 16 km north-east of the town of Greymouth on the West Coast of the South Island. Road access is via a sealed road from Blackball to Roa, then by a 5.3 km all weather, gravel road, which gains 340 m in elevation from 190 m RL at Roa to a maximum height of 530 m near the opencast.

Jan 1, 1993

By Takiuchi T, Kurita M, Owada S

This paper describes the possibility of the application of flotation to the separation of monazite from xenotime and of columbite from ferberite, which have been said to be difficult with generally used physical beneficiation methods. For Malaysian monazite and xenotime samples, a great difference is observed between the flotation recoveries at pH 7.5 using 1.0 x 10-4mol/1 dodecylammonium chloride (DAC). The grade and recovery of columbite in the binary flotation with both minerals result in 85 per cent and 67 per cent in the cleaning froth and 91 per cent and 51 per cent in the re-cleaning froth, without adding any scavenging stages. For monazite samples from various localities, the flotability is dominated by the electrostatic interaction between mineral surface and collector ion using DAC as collector, but the singular decrease of flotation is observed in the sample of which the crystallinity is low and the surface structure is rugged and complex. Otherwise, ferric ion in the flotation system probably dissolved from mineral is found to activate the flotation using sodium dodecylsulfate as collector. For columbite and ferberite, the separation is judged possible at pH 3.0 using 1.0 x 10'3mo1/l sodium oleate (NaOl) from the single flotation results of each mineral. In the binary flotation, however, columbite recovery in the froth is greatly diminished below that expected. This would be because NaOl is prevented from adsorbing on the columbite surface of which the charge is transformed more negative side by the specific adsorption of the tungstate ion dissolved from ferberite.

Jan 1, 1993

By F. M. Doyle, Robert G. Robins, E. Peters

Stability diagrams for the Cu-S-H2O system have been widely applied over many years. Stability diagrams for aqueous systems generally, have been generated by computer, but with the programs for Potential-pH diagrams in particular, a common routine leads to error in multi-element systems. In this paper these errors, and some misinterpretation of diagrams are considered. In most of the published diagrams for the Cu-S-H2O system there has been no account of the sulfide complexes of copper. Here, the free energies of formation for the various species in the system have been re-evaluated for consistency, and some diagrams for the Cu-S-H2O system ( generated with the program DIASTAB Vers.5 ) are presented.

Jan 1, 1993