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By J J. J Chen, J C. Zhao

A water/air model was developed to simulate the refining of molten aluminium by the sparging of gas through an impeller. The optimal gas dispersion depends upon selecting the correct gas rate for a given impeller rotational velocity to prevent flooding or channelling. Correlations illustrating this flooding behaviour exist for standard impellers within standard tank geometries. However the validity of these correlations has not been substantiated for gas dispersion in high temperature molten metals with non-standard tank and impeller dimensions. Metal refining is most efficient when fine bubbles are generated and uniformly distributed within the treatment tank. The application of some measuring technique able to detect this distribution within a non transparent operating treatment tank would be invaluable, enabling the optimisation of gas flow and impeller speed.   A technique has been developed to measure the pressure fluctuation levels at specific points in the water model. Comparison of these pressure fluctuation data with photographic evidence obtained in the water model suggests that the flow regime in the metal treatment unit may be determined using this technique.

Jan 1, 1995

By Robert Irvine

Exploration activity for diamonds in Canada has recently experienced a dramatic increase. Disclosure of a diamond discovery exhibiting features of a potentially economic deposit contained in a kimberlite pipe in the Lac de Gras area of Canada's Northwest Territories has sparked substantial interest in-Canada and abroad and has triggered the largest staking rush in terms of area in the history of Canadian exploration. In this paper, we report on the nature and extent of current exploration activity in Canada for diamonds (with special attention to Arctic regions), the results of this activity to date, and the context in terms of current world markets for diamonds.

Jan 1, 1995

An understanding of the way that solutes are transported in mining or natural environments is essential to the development of sound strategies for managing waste disposal. Research on miscible pollutant movement in unsaturated porous media is carried out both experimentally and numerically. Results of numerical modelling are obtained by solving the groundwater flow equation and the solute transport equation. The finite element method is employed and comparisons between simulation results and experimental data are found in remarkable agreement.

Jan 1, 1995

By J. N. Hryn

This paper describes some of the work done in Phase 1 of a multi-year, five-phase program aimed at demonstrating the economic feasibility of producing commercial-scale quantities of commodity materials derived from salt cake residue-oxide. The amount of salt cake generated annually in the U. S. is estimated to be 510,000 tons, including 340,000 tons of residue-oxide. Used beverage can (UBC) processing accounts for the majority of residue-oxiae that could be made available for further processing into commercial products. To characterize the composition of residue-oxide. eight residue-oxide samples from various secondary processors were obtained and analyzed. Surprisingly, the composition of residue-oxide was found to be independent of source or alloy family being processed, with? the exception of slightly elevated silicon levels in 3XXand UBC residue-oxide samples. Major phases detected in the residue- oxide were? alumina, spinel, and aluminum hydroxides. Preliminary economic analyses indicated that the refractory market appears to be the best choice for high value-added products produced from residue-oxide with minimum processing. Bench-scale tests indicated that low silicon containing residue-oxide is ready to enter this market, but the elevated silicon content of UBC and 3XX residue-oxide preclude this possibility. A separation technology should 'be developed to remove silicon-containing . species from the alumina and spinel values Present in residue-oxide. This technology would then allow UBC and 3XX residue-oxides to be converted to significantly higher value-added products.

Jan 1, 1995

By G. V. Basham

"Environmental audit" is a phrase that can raise the blood pressure of otherwise cool and calm corporate personnel. There is widespread concern that any organized effort to find environmental problems will do so and may result in the imposition of substantial liability against the business that engages in such activities. However, such audits can reduce rather than enhance possible liability. Relevant issues include: the role of the attorney in the process, liability risks associated with environmental audits, steps to maximize confidentiality of audit results, reporting requirements and use of audit results in a proactive manner.

Jan 1, 1995

By David A. Rice, Scott A. Shuey, William K. Tolley

The U.S. Bureau of Mines (USBM) is developing new dewatering technology to permit the recycling of iron values contained in wet steel plant sludges. In laboratory tests, Q-BOP fume sludge was dewatered to 12% moisture by displacing water with acetone in a plate-and-frame pressure filter. Acetone is reclaimed through distillation at lower cost than conventional thermal drying of the sludge. The projected additional energy requirement for acetone treatment of the sludge, including acetone recovery, is $5 to $7 per dry ton.

Jan 1, 1995

By A. D. Zunkel

The zinc in electric arc furnace dust (EAFD) arises from the fuming and oxidation of the zinc present, mainly as galvanizing, in automotive scrap. The dust is collected from the electric furnace offgases in bag filters and is classified by the EPA as a hazardous waste (K061). As more zinc is used in galvanized sheet on automobiles and more automobile scrap is recycled via the EAF, the more zinc will be available for recovery and recycling. EAFD will become a more prevalent and important source of zinc compared to the traditional zinc sulfide concentrates ifit can be cost effectively processed.

Jan 1, 1995

By Katsutoshi Inoue

The sulfuric acid leaching of spent hydrodesulfurization catalysts yields an acidic solution rich in rare metals such as molybdenum, vanadium, cobalt, and nickel in addition to aluminum. For the purpose of separating and recovering the rare metals from the solution, basic solvent extraction characteristics of the metals involved with commercially available acidic organophosphorus reagents like TR-83, PC-88A, PIA-8 and CYANEX 272 as well as aliphatic alpha-hydroxyoxime LIX 63 from sulfuric acid media were investigated in the present work. It was demonstrated that CYANEX 272, PIA-8 and LIX 63 possessed excellent selectivity for molybdenum and vanadium over the other metals at comparatively low pH. Further, recovery of molybdenum and vanadium from the total leach liquor by the selected extractants was discussed. Additionally, in order to achieve preferential separation and recovery of cobalt and nickel over an appreciable amount of aluminum from the raffinate obtained after recovering molybdenum and vanadium, a systematic investigation was conducted on synergistic extraction behaviors of the mixed solvents of LIX 63 in combination with a series of acidic extractants such as CYANEX 272, PIA-8, PC-88A, D2EHPA, TR-83 and OPEHPA for cobalt, nickel and aluminum. It was elucidated that all of these mixtures could exhibit a good synergistic effect for extraction of cobalt and nickel, and that the lower the pKa of the acidic extractants, the greater the synergism. Contrarily, the extraction of aluminum, was considerably suppressed by LIX 63. Effective extraction of cobalt and nickel away from aluminum was accomplished from the sulfate solution at low pH (1.0 - 2.5) with the mixtures. In particular, the mixtures consisting of LIX 63 and CYANEX 272 or PIA-8 appeared to be the most feasible and economic from an industrial point of view, yielding acceptable separation efficiency for cobalt and nickel over aluminum and .a low acidity requirement for stripping cobalt and nickel as well as negligible degradation of LIX 63. Aluminum can be readily recovered as sulfate salt from the raffinate obtained after recovering molybdenum, vanadium, cobalt and nickel as outlined above by conventional crystallization method.

Jan 1, 1995

By G. Atesok, M. S. Celik, G. Onal, I. Yildirim

A new coarse cleaning device, the Stripa, has been developed for processing of coal in the size range of -100+10 mm. The Stripa is an auotogenous heavy medium separator originally developed for processing of iron ores. Although it has been employed in concentrating ores such as chromite, it has not been applied in coal cleaning. In this study, a pilot plant scale modified Stripa and its counterpart alternative, a diaphragm jig, are compared using subbituminous and lignitic coals. The separation performance of the Stripa and the diaphragm jig has been established in the light of washability properties of the coal samples. Comparison of the performance of the Stripa with that of the jig indicates that the Stripa can be used in coal preparation circuits as an alternative to jigs in the size range of -100+10 mm. Simplicity, low initial investment, and low operating and maintenance costs make the Stripa a plausible candidate for coarse coal cleaning. More importantly, Stripa due to its short residence time, has a superior capacity over jig.

Jan 1, 1995

By S. Kelebek, S. O. Fekete

The flotation process developed at Falconbridge laboratories utilizes sulphur dioxide and diethylenetriamine (DETA) reagent combination in the depression of pyrrhotite to allow its separation from pentlandite and chalcopyrite. DETA by itself has failed to produce flotation selectivity with samples from plant and pilot plant streams which showed relatively high redox potentials. However, DETA was found to function effectively on laboratory-generated samples under certain conditions. The results of poor depression are in keeping with thermodynamic calculations which indicate that in the presence of sufficient xanthate and DETA, the formation of ferric dihydroxy xanthate and dixanthogen is possible under oxidizing conditions. The use of sulphur dioxide alone has also resulted in a rather poor depression of pyrrhotite. However, the combined use of these reagents has resulted in an efficient and consistent separation of pyrhotite from pentlandite and chalcopyrite. Various aspects of this selective flotation system are presented along with a discussion on possible operating mechanisms.

Jan 1, 1995

By Quast K. B

Laboratory batch rod and ball milling tests were conducted on samples of Heavy Medium Separator (HMS) sinks from Renison Tin Limited. The product size distributions for this heterogeneous material were very different to similarly sized homogenous material previously reported by the authors. The effects of pulp density on product size distributions were only evident at pulp densities greater than 80 per cent solids. At high solids density, the major weight distribution product peak fell and broadened indicating less efficient breakage, particularly for rod milling. Tin distribution in the ground products was also affected by pUlp density, and there was always less cumulative per cent tin than cumulative per cent weight, ie there was no tendency for cassiterite to slime down to 10/lm.

Jan 1, 1995

The Golden Cross mine is a Joint Venture between Coeur Gold New Zealand Limited, as Manager, and Viking Mining Limited. The mine is targeting Zero Lost Time Accidents as a goal.   The Golden Cross operation produces gold and silver from both underground and open pit. The mine is based on an epithermal gold-silver deposit. Treatment of ore is on a campaign basis for each ore type (i.e. underground or open pit). Milling is conventional SAG Mill and Ball Mill grinding circuit followed by carbon in pulp recovery of gold and silver. All tailing materials are treated through the Cyanisorb process to reduce cyanide levels prior to being discharged into the tailings dam.

Jan 1, 1995

By Maurício L. Torem, Isabella A. Scorzelli

Taboca Mining is one of the largest producers of tin in the world. In its pilot plant, significant amounts of a middling of 90% xenotime (YPO4) and 10% zircon (ZrSi04) are produced. Until now, these minerals of this ore body could not be separated successfully. This paper presents some aspects of the fundamentals of xenotime and zircon flotation with anionic (fatty acids) and cationic (amine acetate) collector, as well as the influence of the superficial leaching of the minerals with cold HCI and HNO3 on the floatability. The mineralogical studies showed that both minerals are optically liberated in -212+106 µm size fraction. Surprisingly, SEM analysis indicated that both xenotime and zircon contain very small inclusions (1-5 µm) of thorite (ThSiO4). On the other hand, zircon is fairly metamictizated giving rise to malacon. Zeta potential tests showed that the isoelectric points of xenotime and zircon correspond to a pH value of 4.5 and 4.7, respectively.The pretreatment with HCI and HNO3 displaced the isoeletric point (IEP) of the minerals to the left. The microflotation tests indicated that the floatability of both untreated and treated minerals are quite similar in the presence of the collectors studied in this work. Adsorption mechanisms are also suggested.

Jan 1, 1995

By Gyasi-Agyei Y

In recent years rapid advances have been made in the technology used for hydrology and erosion modelling of rural catchments. These advances have been driven by the growing availability of digital terrain maps that can be used to automatically define catchment properties that previously had to be manually extracted from contour maps. In addition, these models have, in principle at least, more powerful predictive capability. The author is involved in a number of projects to migrate and further develop these models for application to mine rehabilitation assessment. Current technologies for hydrology and erosion assessment (eg CREAMS, ANSWERS) are reviewed, underlying principles highlighted and deficiencies in the context of mine rehabilitation design assessment addressed. The advantages and disadvantages of the new digital terrain map tools (eg WEPP, SIBERIA) are discussed. Current work integrating these new models with existing rehabilitation design tools (eg ACIRL's ARGUS computer package) highlights the advantages of an integrated approach using digital terrain maps; cheaper, faster, lower impact and more flexible rehabilitation design. The use of novel visualisation tools to aid the design process is discussed. The paper is illustrated by applications to mine sites in Queensland and the Northern Territory.

Jan 1, 1995

By H. M. . van der Donk

In this work an overview is given about the techniques available for the removal of metallic impurities from molten aluminium. The overview is focused on the removal of iron. Also, some experimental results are given about the creation of iron-rich intermetallic compounds in an aluminium system, which are subsequently removed by gravity segregation and filtration techniques. This work is part of an ongoing research project of three major European aluminium companies who are co-operating on the subject of recycling of aluminium packaging materials recovered from household waste by means of Eddy-Current techniques. Using this technique the pick-up of some contaminating metals, particularly iron, is almost unavoidable.

Jan 1, 1995

By H. Dho

Two aromatic-type chelating agents, 1,10 phenanthroline (phen) and 8-quinolinol (quin), were tested as specific depressants for magnetite in the cationic silica flotation of magnetic taconite concentrates. Micro and batch flotation tests, along with zeta potential and adsorption measurements were used. In the presence of a cationic collector, dodecylammonium chloride (DAC), the Fe/phen surface chelate electro-statically repelled DAC, and magnetite was depressed. The negatively charged Fe(quin)2(OH)2-on the magnetite surface attracted the cationic collector and made magnetite floatable.

Jan 1, 1995

By B A. Mowat, T M. Leach

The Morobe Goldfield inPapua New Guinea has produced in excess of 120 tonnes of gold from predominantly alluvial sources. Hardrock gold has been mined historically at Wau (23 t) and Edie Creek (4 t) and geological resources have been established at Hidden Valley (78 t), Kerimenge (36 t) and Hamata (30 t).Numerous prospects have also been identified within the goldfield. Primary gold mineralisation is related to intrusion of dacitic to andesitic Edie Porphyry (2.4 to 3.8 Ma), often with associated diatremes, which have intruded along major regional structures. A full spectrum of deposit styles from proximal (mesothermal) to distal (epithermal) to the porphyry source is recognised. The transition between the proximal and distal styles is recognised both between deposits and within an individual deposit. The deposit styles should be termed porphyry related gold mineralisation rather than given the generic epithermal and mesothermal labels.   It is proposed that magmatic fluids which evolved from parent melts to the high level Edie porphyry stocks mixed with convecting meteoric fluids and were channelled along major structure and diatreme contacts. Proximal to the intrusives, gold mineralisation is associated with deposition of pyrite-hematite-quartz+/-magnetite-gold (Hamata) and pyritebasemetals-quartz-gold (Wau). The mineralising fluids were hot, and periodically saline due to pulses of magmatic fluid. Gold is non-refractory and occurs as 20 to 30 micron blebs within the pyrite.   More distal from the intrusives or under late cooler conditions, mixing of cool dilute meteoric and magmatic fluids resulted in gold deposition associated with arsenic rich pyrite-and arsenopyrite-mineralisation (Kerimenge, Hamata and Edie Creek). Gold is refractory and occurs within the sulfides either as sub-micron inclusion or within the lattice.   CO2 and H2S gases which evolved off the upwelling hydrothermal fluids as a result of boiling and pressure reductions, condensed within superficial groundwater and formed cool oxygenated bicarbonate fluids. These fluids percolated back down the structures depositing manganocarbonate in the upper parts of the hydrothermal system. At deeper levels in the system mixing of the descending bicarbonate fluid with upwelling mineralised fluids deposited manganocarbonate-quartz-sulfides nonrefractory gold (Hidden Valley, Wau and Edie Creek).   At Kerimenge the cool bicarbonate fluids have also quenched a late stage magmatic fluid rising along high permeability structures. The quenching has resulted in deposition of non-refractory gold mineralisation associated with hessite (Ag2Te)-tennantite-chalcopyrite deposition.   Within the Morobe Goldfield, a transition from deeper level pyrite-quartz+/-hematite-magnetite to intermediate level quartz sulfide and quartz-carbonate-sulfide deposition to upper level, massive manganocarbonate deposition is recognized. Gold mineralisation can occur within all levels up the system.

Jan 1, 1995

By Y. C. Kim

Using an exhaustive data set of Walker Lake, four different kriging techniques plus the inverse distance squared weighting were compared with regards to each one's performance in accurately estimating the block grades. The North-West quadrant of the Walker Lake data area was used because of its extreme variability of values and its distinct contour of the values. There were 1900 exhaustive data points in the selected area from which a total of 121 samples were drawn following the sampling strategy given in Isaaks and Srivastava (1989). The average of 5 x 5 exhaustive data points was treated as the true, known block grade. A total of 780 blocks, each block corresponding to the average of 5x5 exhaustive data points, were then estimated using the 121 sample points. The resulting estimates were then compared with the true known values to determine each technique's prediction performance. For this particular portion of the Walker Lake and for the given sampling strategies used, the obtained results for the global estimation are mixed. For the variable U which is much more variable, the rankings are; 1) Jackknife Kriging (JK), 2) Indicator Kriging (IK), 3) Inverse Distance Square weighting (IDS), 4) Ordinary Kriging (OK), and 5) Log-Jackknife Kriging (LJK). For the variable V, the results are; 1) OK, 2) IK, 3) JK, 4) LJK, and 5) IDS. When we apply several cutoff grades to the estimates to determine the conditional mean grades and tonnage, the above rankings generally get shifted around. Two exceptions to these cases are; a) UK for U and b) IDS for V. These two consistently ranked at the bottom.

Jan 1, 1995

By Vince Newberry

Alcan Rolled Products at Oswego, New York, commissioned Recycle II during May of 1995. Recycle II is an advanced technology UBC recycling facility designed to meet the most stringent environmental standards enforced to date in the United States, particularly with respect to NO, and particulate emissions. This paper addresses the exacting requirements and strategies of Alcan's Recycle II project andThorpe Technologies' design considerations and solutions for the supply of environmentally favorable melting furnace and delacquering systems. The furnaces are equipped with low NOx regenerative burners and furnace pressure and hearth gas flow controls designed specifically for processing the hearth gases through baghouses. The delacquering system is a new generation Apros concurrent flow unit designed for low NOx emissions.

Jan 1, 1995

By Malcolm Scobie

"This paper reviews the evolution of Canadian surface and underground mining automation, principally relating to: advances in communications, initial development of machine teleoperation from line-of-sight remote control, and islands of automation. The eventual role of teleroboties and minewide robotic mining remains to be resolved. The progress and approaches adopted have tended to vary within each sector of the mining industry. Recent information technology advances have made possible the Digital Mine; in which information associated with all mining processes, however dispersed, would be integrated with support systems using new communications technology. The Digital Mine will provide the information infrastructure to serve as the foundation for minewide automation. This paper concludes by reviewing the issues likely to govern implementation success, relating to: mining process design, machine design, machine intelligence, and mine planning and control.IntroductionSignificant advances have recently been made in underground hardrock mine communications and teleoperation. Subsequent R&D efforts are mainly focussing on control systems for various types of machines. In underground potash mining, the realization of automated continuous mining systems appears to be imminent. Recent advances in surface mine dispatching, machine monitoring and global positioning systems (GPS) have tended to reactivate some of the initial R&D enthusiasm developed in the '70s for surface mine automation. Mines at large are approaching a major milestone: the implementation of comprehensive communications infrastructure which proves to be sufficiently reliable and economical to support the automation of routine mine production, either using teleoperated or autonomous machines. This then should motivate a deeper commitment to real time monitoring and management. The communications advances make possible the Digital Mine; in which information associated with all mining processes, however dispersed, would be integrated with support systems using information engineering. The Digital Mine will provide the information infrastructure to serve as the likely foundation for a wide range of automation scenarios. This paper surveys the status and directions of automation development in both surface and underground Canadian mines, pointing to what are seen to represent key technology development issues."

Jan 1, 1995