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By Z. Zhongwei

The leaching kinetic of mechanically activated sphalerite with acid FeCl3 solution was investigated. The result has shown that mechanical pre-treatment has greatly enhanced the leaching process. Comparing with the original concentrate, the activated one can be leached more completely at relatively lower temperature with diluter FeCl3 concentration within a shorter leaching time. The activation energy for the activated concentrate is 27 KJ/mol, while for the original one is 52 KJ/mol.

Jan 1, 1995

By N Merry, T Cocks

The mineral exploration industry is increasingly aware of the importance of the relationship between mineralogical data and geochemical assay results. However, until recently, the cost and time constraints of most techniques for analysing alteration mineralogy have precluded detailed alteration studies. These impediments have been reduced by the development of the Portable Infrared Mineral Analyser (PIMA), a field portable infrared spectrometer that allows rapid (in field) and cost effective analysis of alteration minerals including subtle variations in mineral crystallinity and composition.   A major application of this technology is in mapping mineralogical variations within hydrothermal alteration systems. Using actual case study examples this paper introduces two approaches to using the PIMA data: 1. for directly mapping alteration systems and using the PIMA data to provide vectors to mineralisation, and 2. for establishing empirical relationships between geochemical data and PIMA spectral data. These applications demonstrate that this technology can be an invaluable tool for targeting and mapping alteration and mineralisation.

Jan 1, 1995

By C. D. Chapman

Current regulations regarding the landfill disposal of asbestos containing wastes are inadequate to ensure there are no ground water or airborne emissions. Accordingly, there is growing recognition that asbestos wastes can only be safely disposed of by using techniques that destroy the hazardous fibres. An innovative high-temperature plasma arc technology (The MAGRAM Process) is being developed for the recovery of magnesium metal from asbestos together with supplementary magnesia containing feedstock. The furnace will operate in. open bath mode with aluminium and/or ferrosilicon being employed as reductant. An important advantage of the process is that magnesium vapour within the furnace will be generated close to atmospheric pressure rather than at reduced pressure under which existing processes operate. Thermodynamic modelling work has been undertaken to define the range of slag composition and furnace temperature under which magnesium production at atmospheric pressure is feasible. The effect of slag chemistry, reductant addition, and temperature on product quality and yield have also been investigated and key aspects have been tested on bench scale. A 300 kW pilot plasma furnace unit has been employed for the treatment of calcined asbestos wastes. Aspects of design and operation of the unit are detailed. Acknowledgement: This work is substantially financially supported by the European Communities under the Industrial and Materials Technologies (Brite EuRam H) Research and Development programme.

Jan 1, 1995

By S. Rick Gilbert

In the course of producing a final metal product, smelters, refineries, and other metallurgical facilities produce wastes which often come under the ?scrutiny of Federal and state regulatory agencies. Many of these wastes contain combinations on zinc, copper, lead, cadmium, nickel or other metals. Frequently in the form of reverts, dusts, or sludges, these metal-containing wastes are often buried in a landfill or speculatively accumulated for future action. Environmental liability can be reduced in many cases by selecting,-a recycling facility which can re-process the waste for.' metal recovery. Encycle, at its hydrometallurgical facility Corpus Christi, has Successfully processed a variety of metallurgical by-products and wastes and returned those contained metals to commerce.

Jan 1, 1995

By R. Y. Wan

Low grade sulfidic-carbonaceous refractory ore from Newmont Gold Company's Carlin deposit was microbially pretreated. The biological pretreatment process gave partial oxidation of the sulfidic components of the refractory ore but the preg-robbing carbon continued to be active resulting in approximately zero cyanide gold extraction. A 495 ton pilot plant test heap was conducted using acidic thiourea leach following biooxidation. Activated carbon and cation exchange resin adsorption were tested for gold recovery from the thiourea pregnant solution. The results obtained from the test heap were not satisfactory. Gold extraction was low due to slow reaction kinetics which was caused by relatively large particles and very low winter temperatures. Problems existed in the thiourea-test heap and are discussed in this paper. An alternative heap leach process using thiosulfate has been successfUl at the pilot scale for gold extraction following biooxidation pretreatment of refractory sulfidic-carbonaceous ores.

Jan 1, 1995

By F. P. Hassani, J. F. Boily, A. M. O. Mohamed, M. Hossein

The optimal geochemical parameters required to form ellringite in a lime-remediated site have been investigated with the use of thermodynamic modelling. The speciation of sulphate and 10 metals analyzed in samples of a mine tailing from northern Quebec was calculated with a computer model. The model also includes calcium, which would result from the addition of lime to the system. Two speciation calculations were done. The first one is a hypothetical speciation before the onset of precipitation and was used to devise the stability fields of minerals susceptible of forming in high pHs. The stability fields were determined by building activity ratio diagrams with sulphate, aluminum and calcium species concentrations for pHs ranging from 4 to 14. The investigation was carried out for a 25°C solution with an ionic strength less than 0.12. Thermodynamics predict that an optimal stability field for ettringite in the mine tailing samples containing 10-3 mol/L SO4-2,10-2 mol/L of AI(OH)4 requires at least 10-2mol/L of Ca+2 and a pH larger than 11.6. The sulphate contents of the mine tailing samples, however, limit the precipitation of ettringite and monosulphate could be an end-precipitate. The second speciation is in equilibrium with precipitates and provides information on the speciation of the residual metals. If ellringite could be precipitated as a stable form, it could serve as a sorptive agent for residual metals, and, due to its binding properties, consolidate tailings.

Jan 1, 1995

By Boland J

Prediction of rock cuttability by various excavation machines such as tunnel boring machines, road headers, rippers, picks, roller disc cutters, excavators, etc is of major concern to both civil and mining engineers and rock mechanics. In principle, the design of a rock cutting tool is based on achieving maximum excavation with minimum input energy, minimum applied force, minimum equipment weight and volume and, more importantly, minimum tool wear. When a rock material is indented by the force of a cutting tool and then unloaded several material zones form underneath and around the tool. As the tool moves into the rock the volume of its associated rock cavity (ie volume of displaced rock) expands and depending on the indenter's shape various phenomena may occur. Immediately beneath the tool a small zone in which the stress state is more or less hydrostatic, is formed which is underlain by an inelastic, or damaged, material zone. Both size and shape of this damaged zone control the magnitude of the indentation force and the chip formation mechanism during unloading. The rock is unable to store the whole strain energy induced by the tool and consequently the extra energy is expended either in forming new fracture surfaces and/or in plastic deformation in the damaged zone. Therefore, it is not surprising to see that both perfect-elastic and rigid-plastic constitutive models are not generally suitable for modelling indentation of rocks. In contrast elastoplastic constitutive models are more appropriate as they can include both elastic and plastic deformations (Kral et al, 1993). Elastic solutions for several half-space indentation problems can be found in most text books on elasticity and in particular in Timoshenko and Goodier (1951), Sneddon, (1951), Poulos and Davis (1974) and Johnson (1985a). If a failure criterion, eg the Mohr-Coulomb failure criterion, is applied to delimit elastic solutions for indentation problems, a lower bound limit of the applied indentation force (for a given indentation depth) can be estimated. It may be noted that elastic analyses, without any delimiting failure criteria, normally overestimate the indentation force. Plastic solutions for a few indentation problems may be found in Hill (1950), Johnson, (1985a) and Alehossein et al (1992). When analysing the behaviour of indented rocks the choice of an appropriate constitutive model describing effectively the behaviour of the rock at various stages and phases during indentation is a challenging issue. Several questions need to be answered before starting an effective analysis. The first question is of course: Which one of these is more appropriate for modelling zones underneath and around a cutter, elasticity or plasticity theory, continuum damage mechanics or fracture mechanics, and what is the bridging link between these various theories? Which mode is more dominant in fracturing rock, tensile or shear mode? What governs the mechanism of chip formation? What is the function, shape and the behaviour of the pulverised zone that forms just underneath a cutter? Is the hydrostatic stress state assumption reasonable for this zone? How does the rock change during the absorption and dissipation of the input energy and how does the indentation energy vary with rock type and depth of penetration? How can we model the damaged zone under the indenter? Furthermore does a plastic material form beneath the pulverised zone? When and how do radial and ring cracks form around and under an indenter?

Jan 1, 1995

By J. Méndez-Nonell

The thermodynamic and chemical properties of SrSO4 and SrS in a gaseous flow of CO and CO2 at high temperature are discussed. The thermodynamic analysis of the system was made using data from the literature. The results obtained from the thermodynamic analysis were experimentally verified using the thermogravimetric technique. The experimental results suggest the formation of a complex compound between SrO and SrSO4. It was also found a change in the chemical mechanism of the process between SrSO4 and CO-CO2 and in the chemical mechanism of the process between SrS and pure CO2.

Jan 1, 1995

By P. Bevilacqua, G. Ferrara

The paper discusses the problem of accuracy in the determination of the partition curve of gravity separation processes, which is strongly affected by both the sharpness of separation of the density analysis system used and the width of the density range selected. The problem is important when the density analysis of the separation products cannot be performed using heavy liquids, but has to be performed using heavy suspensions or using other systems such magnetogravimetric separation. The imperfect separation given by these systems and the use of large density ranges lead to the determination of apparent partition curves instead of actual partition curves for the process. In the paper the relation between apparent and actual partition curves is studied under different conditions through a simulation program. For different input data, special diagrams are given which, once the apparent partition curves and the sharpness of the density cuts are known, allow calculation of the actual partition curves and the related parameters.

Jan 1, 1995

By S. M. Spottiswoode, A. J. Jager, N. C. Gay, J. A. Ryder

The South African mining industry is at present planning to extract orebodies at depths of up to 4 km. To do this cost effectively and, at the same time, ensure safe working conditions for mining, the personnel will require both the development of new strategies and the implementation of current rock-engineering technological developments on a wide scale. This paper covers most of the technological developments likely to be required for mining at very high stresses, but it is clear that improved regional support systems will need to be developed to ensure defective stability of the rockmass during mining operations. Similarly, it is clear that improved strategies for mining in large-scale geologically disturbed areas, where slip on faults or dykes can result in wide-spread rockburst damage, will have to be addressed

Jan 1, 1995

By Victor C. Bryan

"One of the more challenging issues facing operators of U.S. mines and quarries is blasting in an environmentally acceptable way. It is quite important that industry management understand and apply guidance, discipline, and control in the exercise of blasting operations. This presentation is a discussion of problems related to that environment away from the blasthole that may or may not be adversely affected by blasting and the steps management may consider in resolving resultant problems. In any case, one of the main concerns that will continuously be brought up is thatmanagement procedures inherent to good blasting is a uxporate responsibility of the mine or quarry business entity; and can not be delegated to the explosive manufacturer or supplier. This management attitude, based on education, training, and the comprehension that the process of production begins with drilling and blasting and consumes a significant amount of overall production costs."

Jan 1, 1995

Although the last decade has seen the growth of many new licencing and approval requirements for the exploration and mining industries, there remains in each State of Australia and the Northern Territory a predominant "Mining Act" containing provisions for the grant of exploration and mining tenements. What then are the rights and duties of tenement holders either by virtue of a Mining Act or through other approval and licencing mechanisms? What rights and duties does a person acquire when he is granted an exploration licence or a mining lease? In this paper I will attempt to cover these types of questions using in particular examples from New South Wales. I will also refer to a range of other subordinate approvals and licences which today's society requires and the need for ethics and recognition of liabilities.

Jan 1, 1995

By Dale A. Zuck

Recovery of aluminum metal from drosses? is a major factor in the recyclability success story enjoyed by the United States aluminum industry. Today's modern dross processor uses the latest technology to maximize metal recovery at the lowest cost while complying with all environmental laws and regulations. Most dross processors, however, pay little attention to the resulting saltcake, the end residual of dross recyCling, and rely on landfills for .disposition of this material.. The alternative is to recycle the saltcake, but the success of this technology is dependent on the development of reliable outlets for each of the saltcake constituents. This paper discusses the evolution of an aluminum dross oxide processing technology that ,produces an economically attractive source of alumina for the production of portland cement.

Jan 1, 1995

By R. D. Willette

The Hector Mine deposit in the California Mojave Desert has a magnesium-rich clay that formed when lithium and fluorine were introduced into isolated fine lacustrine volcanic sediment during the Pliocene. The intensely deformed deposit has been supplying the highest grade thixotropic clay to the coatings industry for over half a century. A thixotropic clay displays the property of changing from a gel to a sol when shaken, and increases in strength upon standing.

Jan 1, 1995

By R. F. Dawson, A. S. Bagnall, K. Barron

"At Smoky River Coal Limited (SRCL), economic occurrences of structurally thickened coal deposits form attractive surface mining targets. These steeply dipping, structurally complex deposits require that special attention be given to pit wall design and operational practices.Where anchor support is feasible, there is potential for reducing footwall waste requirements and/or increasing coal recovery. SRCL has used rock anchors to support footwall slopes since 1985. This paper outlines design considerations and performance of rock anchor support systems at SRCL.Three case histories are included that illustrate the design process for supporting steeply dipping footwall slopes using rock anchors.IntroductionWestern Canada contains vast reserves of high grade coking coal largely located in two belts within the Rocky Mountain Foothills straddling the Alberta/British Columbia border. There are about one billion tonnes of ""clean"" coking coal reserves (Romaniuk and Naidu, 1986) situated near existing mining infrastructure. Within the reserve areas shown in Figure I, a total of six producers operate 10 large mines linked with ports situated on Canada's west coast. Al! of the producers operate conventional shovel truck surface pits.Surface mineable reserves within some of the mountain coal mines are located on dip slopes or where the geologic structure has thickened the coal near the surface, creating low strip ratio targets. Footwall slopes in these mines are developed parallel to bedding, thus minimizing waste extraction and preventing undercutting of potentially unstable strata. The base of the mineable coal measures in both north and south regions is marked by massive quartz sandstone units (Torrens Member and Moose Mountain Member) which often form the footwall. Footwalls developed within this basal sandstone unit can attain very high unbenched heights often with little risk of instability. In cases where the footwall is developed on weaker strata above this basal unit, stability considerations control slope height when bedding dips exceed about 30°. In these situations it is desirable to assess the benefits of artificial support to increase the unbenched footwall slope height."

Jan 1, 1995

By Robert D. Schmidt

The US Bureau of Mines is cooperating with Cyprus Mineral Park Mining Co., Columbia University, and the US Geological Survey in investigating the feasibility of applying in situ leach mining methods to fracture-hosted, supergene copper sulfide (chalcocite) ores. This paper presents the initial findings of mineralogical, hydrogeological, and geochemical characterization studies conducted at the Mineral Park mine, located in the Wallapai mining district of northern Arizona. A design for in situ leaching is proposed that would minimize the need for blasting prior to leaching, and would enable economical development of deep reserves at the Mineral Park mine. The in situ leaching design would also reduce the potential for long term acid rock drainage.

Jan 1, 1995

By Jacek Kolacz, Knut Lyng Sandvik

Fine grinding in an air swept and a grate discharge ball mill working in closed circuit with a forced vortex air classifier has been investigated in continuous laboratory scale. Minerals with different physical properties were ground down to 40, 20, and 10 micron top size. The shape of the product particle size distribution curve was investigated and specific surface (BET) was measured. During production of material with top size of 40 microns in an air swept mill, the capacity was up to 25% higher when compared to a grate discharge mill. This difference dropped to 180A during production of 10 micron top size material. A corresponding decrease in power consumption was observed. An important finding is that by regulation of the air flow rate through the mill, it is possible to achieve products with different specific surfaces and particle size distribution curve steepness. During production of the 10 pm material, the specific surface could be varied in the range 3 to 4.5 m2/g. Such powders could hardly be produced in a grate discharge mill because fine particles coated the grinding media and the lining. On the other hand the internal classification in the air swept mill kept the size distribution of the mill content relatively free of fines. This prevented a similar slowing-down of the air swept grinding process.

Jan 1, 1995

By A. E. Boudreau

Abstract-It has long been recognized that platinum-group-element (PGE) deposits in layered intrusions preferentially occur in intrusions that crystallized from high-Mg parent magmas. Recent studies suggest that evaluation of any given intrusion for economic PGE potential should also include assessment of the PGE, sulfur and chlorine concentrations in the cumulates and potential parent liquids. PGE: Magmas that contain relatively abundant Pt and Pd are the best candidates for forming economic deposits. Although analyses of coeval sills and dikes are the best indicators of primary magmatic PGE concentrations, analysis of the cumulates themselves is also valuable. For example, within the Stillwater complex, background PGE values in cumulates from the ultramafic sections of the complex contain, on average, several 10s of ppb Pt and Pd. Background concentrations of this order are suggestive that the magma was not depleted in the PGE. Sulfur: Conventional petrogenetic models for the formation of PGE deposits in layered intrusions require the PGE to have been concentrated during a magmatic sulfide-saturation event. In contrast, some hydrothermal models suggest that sulfur and the PGE were mobilized from footwall cumulates by upward- migrating, high-temperature hydrothermal fluids. Both models suggest that significant PGE deposits are likely to occur at and below the level where stratigraphic increases in whole rock sulfur concentrations occur. Chlorine: In both the Stillwater and Bushveld complexes the cumulate sequences below the major PGE-bearing zones contain anomalous Cl-rich apatite. The chlorapatite component of apatite in these rocks may exceed 40% and, in the Stillwater complex, typically exceeds 90%. It is stressed that pristine igneous mineral analysis and not whole rock data be used, as whole rock Cl concentrations may be affected by very localized (grain boundary), low-temperature alteration. Intrusions that crystallized from high-Mg, high-Cl magmas appear to have the best potential to host significant PGE deposits.

Jan 1, 1995

By C. DeLong

"The Mt. Milligan porphyry copper-gold deposits are in central British Columbia, 155 km northwest of Prince George. Mineralized outcrops and float were discovered in the Mount Milligan area by prospecting. The most recent discoveries, which utilized lithogeochemistry, were in 1983. Areas containing the outcrops and float then were investigated by geological mapping, soil and lithogeochemical sampling, ground and airborne geophysical surveys, trenching and diamond drilling. This work led to the discovery of the Mt. Milligan Main deposit in 1987 and the Southern Star deposit in 1989. Extensive diamond drilling continued until 1991 and delineated a measured and indicated resource of 299 million tonnes grading 0.45 g/t Au and 0.22 % Cu from the combined deposits.The Mt. Milligan deposits lie within the Early Mesozoic Quesnel Terrane and are hosted by porphyritic monzonite stocks and adjacent volcanic rocks of the Takla Group. The Mt. Milligan Main deposit is centred around the MBX stock and Rainbow dike, and the Southern Star deposit around the Southern Star stock.Potassic alteration is extensive within the stocks and in volcanic rocks adjacent to the MBX stock and Rainbow dike. Propylitic alteration surrounds the potassic alteration and decreases in intensuy away from the stocks. Mineralization consists mostly of pyrite, chalcopyrite, lesser magnetite, and minor bornite, molybdenite and gold.Mineralogical zoning is well-developed within the deposits. A biotite-rich subzone forms the core of the potassic alteration zone and hosts most of the copper and gold. Numerous polymetallic veins lie within the propylitic alteration zone just beyond the limit of porphyry-style copper-gold mineralization."

Jan 1, 1995

Lithocaps are potentially voluminous zones of advanced argillic and associated argillic alteration located above the subvolcanic intrusive environment. They constitute exploration objectives for epithermal and porphyry-type deposits. High-sulphidation epithermal deposits may be sought within lithocaps, whereas low-sulphidation deposits may exist on their edges. Porphyry Cu-Au/Au deposits may be accessible beneath lithocaps if systems are telescoped sufficiently. Oxidation of the basal, pyritic parts of lithocaps may promote supergene sulphide enrichment under appropriate tectonic and climatic conditions.

Jan 1, 1995