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By D. R. Boyle

"Abstract - The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite > arsenopyrite > galena > Bi-Sb sulfosalts > chalcopyrite > tetrahedrite group > sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was trans- ported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By Shuguang L, Jing S

Computer controlled truck dispatching systems is a newly-developed technical system in surface mines with shovel-truck technology. The real time dispatching criteria, as the core of optimal truck dispatching software, are analysed and a new criterion, complex dispatching criterion, is put forward. Dispatching criteria previously proposed include: 1. `Earliest Loading' (EL) - to assign a truck to the shovel at which the truck can be loaded earliest. 2. `Max Truck' (MT) - to assign a truck to the shovel at which the truck will have the shortest waiting time. 3. `Max Shovel' (MS) - to assign a truck to the shovel which has been waiting for the longest time. 4. `Minimum Saturation Degree' (MSD) - to assign a truck to the shovel at the branch where the truck flow saturation degree is minimum. 5. `Minimum Saturation Degree with Truck Cycle time consideration' (MSDTC) - as the MSD principle, with the truck travel cycle also considered. 6. `Fixed Dispatching' (FIX) - to assign trucks to fixed shovels. A system simulation model has been set up for truck dispatching system analysis. A few surface coal mines have been selected for case studies. Equipment waiting times and shift production of the system are obtained as the main outputs of the model. Simulation results show that each dispatching criterion has its own applicable range, no one can absolutely dominate the others. For example, when under-trucked, EL and MT criterion can obtain higher production than the MS criterion; when over-trucked, it is vice versa; while for MSD criteria, better results can be obtained no matter how the truck numbers fluctuate. From the view point of shovel output balance, large fluctuations occur for EL and MT criteria, while a good balance can be obtained for other criteria. In the light of dynamic change of mining system conditions, a single dispatching criterion is not necessarily reasonable. A complex dispatching criterion has been put forward to seek the complex optimum effect. Taking the advantage of each dispatching criteria, the dispatching result of a complex dispatching criterion dominates over individual dispatching criterion and a comprehensive optimum effect can be reached.

Jan 1, 1995

A geologic, petrographic and geochemical study has been performed on the pyroclastic flow deposits in the coastal area of East Zhejiang Province, Southeast China. This study leads to classification of the pyroclastic flow deposits into three associations: the extrusive type, the surge type and the ash flow type welded tuff associations. Through detailed investigation and comparison of the characteristics of these lithologic associations, with emphasis on the welded tuffs, a comprehensive model has been proposed to demonstrate the petrogenesis of the pyroclastic flow deposits.

Jan 1, 1995

In eastern China, most of the copper skarn deposits occur in folded troughs which are controlled by the EW-trending faulted fold systems (the Pal-Asian geotectonic domain), and the NNE-trending rift or fault zones (the Marginal-Pacific geotectonic domain), particularly the later. From the north to the south, there are four troughs hosting the main copper skarn deposits in eastern China: the Yanliao Trough, the Yangzi River Trough, The Qiantang-Yuanshui Trough and the Zichen Trough. There are more than 30 copper skarn deposits in eastern China, and ore reserves of each deposit are between 30 to 100 Mt with average grades over 1% Cu.    Most of the large copper skarn deposit-related intrusions are Mesozoic in age (170 to 100 Ma) and were emplaced during the Yanshanian Movement. Outwards from the intrusion bodies, both the skarn alteration and mineralisation show certain patterns of zonation. Mineral assemblages indicate a relatively high oxidisation state during metasomatic alteration and mineralisation. Sulphur isotopic work indicates that most d34S values of the sulphides are between ~4 to 3ë suggesting a common magmatic sulphur source. Fluid inclusion and oxygen isotopic studies suggest that early-stage fluid shows magma-related fluid characteristics although meteoric water was involved during late-stage alteration.

Jan 1, 1995

Our ultimate resources come from the Sun and the Earth System. At this time we face a world crisis in energy, water and soil resources. Global pollution problems are increasing in almost all nations. There is an urgent need to use our vast knowledge with a new wisdom and this requires new integrated teams of experts to provide the best alternatives for the needed new development problems. These teams must include economists, engineers and a broad spectrum of scientists. Today it is possible to produce clean energy, stop soil erosion, clean water and reduce and use wastes of many types.   There is a great need to improve science, natural science, education at all levels. All people must know how our planet works and that fluctuations, some inevitable, some controllable, are inevitable and that we must prepare for them. And it is clear that protecting the environment, eliminating pollution, preserving bio diversity is good economics. Ecology Economy cannot be separated.  

Jan 1, 1995

By Andrea B. Baldwin

In recent years, federal and state regulatory agencies have tightened air emission standards. Two of the acid gases, hydrochloric acid (HCI) and sulfur dioxide (SO2), are under heavy scrutiny for reduction. . Most traditional scrubbing systems, i.e. wet scrubbers and spray dryers, meet the standards but they typically are high in capital cost, have significant space requirements for equipment, and are difficult to maintain. Dry sodium injection (DSI) is a alternative technology that has been shown to be effective in HCl and SO2 removal while being the inverse to the problems listed with traditional systems. This paper covers the mechanics of dry injection scrubbing using the most effective sorbents, sodium bicarbonate and mechanically-refined trona (natural sodium sesquicarbonate). It presents DSI performance data for Chambers Medical located in Hampton, SC. This facility incinerates local medical and municipal solid waste. Chambers Medical has used mechanically-fined trona for HCl and SO2 removal since late 1991.

Jan 1, 1995

By S. K. V. Avasarala

This paper presents a case history of design, prediction, probe and production pile driving monitoring, loading tests and installation of over 3,300 prestressed concrete piles for a building complex consisting of 12, 5- and 6-story over parking buildings. The project was recently completed in three-phases over a span of 4 years. The subsoil conditions were explored by performing 25, Standard Penetration Test (SPT) borings throughout the site. Various types of driven pile foundations were considered and following an evaluation of high structural loads and site-specific constraints such as variable depth of bearing layer of Florida limestone and quality of clay and limestone layers, a prestressed concrete pile support system was selected as the most economical and effective foundation approach. The building foundations were designed for a pile capacity of 353 kN (40 tons) in compression, 45 kN (5 tons) in lateral capacity for a deflection of 0.64 cm (0.25 in.), and 133 kN (15 tons) in uplift capacity. The axial and lateral allowable pile capacity and lengths were predicted using SPT91 and LPILE computer programs, which are generally used in Florida. The validation of these capacities was derived from 144 probe piles and performance of 12 pile loading tests on selected probe piles. Prior to installation of probe or production piles, a termination criterion was established using 1-dimensional wave equation analyses in addition to the design pile embedment requirement. The predicted pile capacities compared very well with the capacities from the loading tests on probe piles. This information was effectively utilized as part of the overall quality control program to install a total of 4,186 prestressed concrete piles (including 144 probe piles) in different building areas across the project site to depths ranging from 8 to 21 m (25 to 90 ft) below existing ground elevation as part of foundation support system. This engineered, monitored, and tested foundation solution provided an effective and satisfactory basis for completion and approval of the foundation work for this 12, 5- and 6-story over parking building complex. A recent reconnaissance has indicated that all the building foundations are performing satisfactorily.

Jan 1, 1995

By Ritter K-C, Sturgul J. R, Filess T

The proposed Lihir open pit gold mine is located on Lihir Island in New Ireland Province, Papua New Guinea. The mine will be located within a volcanic caldera, part of which forms the adjacent Luise Harbour. Kennecott Corporation started engineering design work in 1988 and ended in 1993 when a Feasibility Report was submitted to the Papua New Guinea government by RTZ/Kennecott. The project will be managed by the Lihir Management Company. The mining operation will produce approximately 350 Mt of waste and 62 Mt of low-grade ore over the life of open pit mining. Landforms and traditional land use by Lihirians preclude storing mine waste and some of the low-grade ore on land close to the mine site. The mine waste will be composed of hard rock and soft soild like material which cannot be safely used to construct large land waste repositories by truck dumping. Submarine disposal by bottom discharging barges is the only safe disposal method. The barges will also be required to construct a waste platform along the shore for stockpiling low-grade ore. A simulation model of the waste handling system was written in GPSS/H¦ to assist engineers in selecting the optimum size and quantity of barges and loading docks by analysing the interaction between excavators, trucks and barges. The simulation model was written in enough details to model the various functions that will be encountered during mining. Input parameters allowed for variations in the size and number of trucks, shovels, barges and loading docks. Variations in loading, hauling, and dumping times were from user specified distributions. In order to visualise the interaction between the components of the waste mining operation, the simulation was animated using Proof AnimationT""'. It is believed that this is the first application of an animated simulation study for a mine still in the planning stages.

Jan 1, 1995

By Carl C. Nesbitt

A process has been developed to recover and recycle metals from wastes of brass foundries which contain copper, zinc and lead in various quantities. Tests were conducted to evaluate several leachants, including sulfuric acid, ammonia, hydrochloric acid, cyanide and acetic acid, and to determine the optimum leaching conditions, such as air flow rate, initial copper ion concentration, temperature, and agitation strength. Sulfuric acid containing copper sulfate with dissolved oxygen is the most successful leachant. More than 99% of the copper and zinc originally present in the waste was dissolved, while only 0.5% of the lead entered the solution after 14 hours of leaching. The leaching mechanisms of copper, zinc, and lead are proposed. The copper and zinc can be recovered from the solution by electrolytic processing. The unleached residue may be converted to a lead carbonate which can be converted to litharge at 400-450°C and to massicot at temperature above 500°C by calcination.

Jan 1, 1995

By J. M. Mutmansky, B. Kolonja

A PC-based simulation model using the software packages SIMAN and CINEMA was developed to simulate and animate truck-shovel operations. The model is capable of simulating one mathematical dispatching strategy using linear and dynamic programming and six heuristic dispatching strategies. Data were collected from an actual operating mine through time studies and analysis of historical records. Statistical analyses were performed, and appropriate theoretical distributions were fitted for various time events in the truck-shovel cycle. The model was then applied to study overall impact of these dispatching strategies on constrained and unconstrained mine productivity. The simulation/animation model developed in this study seems to be an efficient planning tool for choosing optimal fleets and finding an optimal dispatching strategy to produce an equilibrium between the quality and quantity of production.

Jan 1, 1995

By Olofsson O, Durance M-V, Villeneuve J

Modelling of the Sala Agitated Mill (SAM) using a simplified solution to the population balance approach has been carried out. The rate of breakage is modified by the mill power, providing predictions of the resulting product size distribution for different grinding conditions and mill sizes. The power of the mill is estimated by a physically derived function, using an assumption that the mill power consumption mainly arises from the ball to ball friction within the mill. The grinding efficiency, depending on the media ball size and pulp density is approximated in the model. Experimental work on grinding a complex sulphide ore using a pilot scale SAM 7.5 has been carried out. Good agreement has been found between the data from the test campaign and the simulated values. The model has also been validated with experimental data from a pilot grinding of calcium carbonate and from an industrial mill. The model is included in the USIM PAC simulation software.

Jan 1, 1995

By M. S. Klima

Tests were conducted to investigate the potential for recovering anthracite from preparation plant tailings. Samples were collected from tailings streams or slurry ponds of several anthracite cleaning plants. A washability analysis was conducted on each sample. The use of gravity-and surface-based cleaning processes for treating the 28x200 mesh tailings material was examined. Simulations were performed for various cyclone staging arrangements using published partition data for both water-only and dense-medium cyclones. Froth flotation testing was done on both precleaned anthracite and tailings material. Grade-yield curves were determined for various conditions.

Jan 1, 1995

By James R. Coldwell

Mining and processing cost analyses were conducted by the U.S. Bureau of Mines on stratiform zinc-lead-silver, coal, and stratiform barite deposit types that are found in the Colville Mining District. Reserves and gross revenues which would allow these deposits to be minable were modeled. A 15% Discounted cash-flow rate-of-return economic threshold was selected as the minimum acceptable return on investment for the three deposit types. The economic modeling indicated combinations of grades and tonnages for stratiform sulfide deposits that could be economically viable for orebodies ranging in size from 25 to 130 million metric tons. The gross revenues for a surface mine range from $200/mt for a 5,000 mtpd operation using the proposed South corridor to $140/mt for a 17,000 mtpd mine using the proposed North corridor. The economic modeling indicated underground coal mining was subeconomic for deposits ranging in size from 42 to 250 million metric tons. The required gross revenues ranged from $300/mt for a 2,200 mtpd mine to $21 D/mt for a 13,000 mtpd mine. The economic modeling indicated supplying projected in-state barite demand was subeconomic for the three seasonal surface mines modeled. The required gross revenues ranged from $600/mt for a 90,000 mtpy mine to $840/mt for a 6,000 mtpy mine.

Jan 1, 1995

By S. E. El-Alfy, John Starkey

"The Iron Ore Company of Canada treats up to 125,000 t/d of iron ore at its Carol Concentrator in Labrador City, NF.A complete water balance study in the concentrator was done to show how to reduce the consumption of fresh water, to improve metallurgy in the magnetic separation (mag) plant, and to help reduce maintenance costs for the reclaim water and tailing pumping systems.The study showed that more than 60% of the water used in the mill was internally recycled dirty water from dewatering cyclone overflows, and that water reduction was closely tied to the effective use of these internal reclaim pumping systems. In addition, new operating parameters were set for the 4 -15,000 USGPM reclaim water pumps which should save over $100,000 per year in maintenance costs.IntroductionThe study described in this paper was set up for the purpose of lowering water usage in the concentrator, and to reduce tailing and process water pumping costs (operating and maintenance). Another benefit was also expected, namely, to improve magnetic separation efficiency through better water and density management of magnetic separator feed streams.The procedures selected to perform this work were: ( 1) to prepare accurate, as built flowsheets of the entire iron recovery process, including fresh and process water systems, (2) to calculate normal material balances in all circuits at full production, (3) to use the computer spreadsheet model so generated, to evaluate specific ways to reduce water consumption and (4) to re-evaluate metallurgical performance and operating parameters in the light of this information.Overall control of the 28 spiral iron recovery lines was found to be excellent because automated start up and shut down of the individual lines had been incorporated in the design from the start. Because production rates can vary due to sales requirements, mine and mill maintenance delays and hardness variance, the mag plant (which treats spiral tailings) must deal with a wide variety of operating conditions. Good water management therefore is a key item in achieving high recovery of the fine free magnetite which is too fine for recovery in the spirals.In order to make the study as accurate as possible, process data for major flows was reviewed by metallurgical staff and then by mill supervisors. The operating picture of the concentrator so generated was judged to be a good estimate of the mill at full production. By changing key inputs, the variance of process water demand and tailing slurry produced for several other operating conditions were studied.The usefulness of this exercise has prompted this present presentation to be made. Older plants by nature have undergone many revisions as operators have worked through ore changes, market changes, labour cost increases and the availability of new equipment, to improve their operation. Sometimes therefore it is necessary to stop and reassess what is happening in a plant in order to continue the never ending work of process optimization. The techniques used here were ideally suited to the gravity/magnetic concentration flowsheets used, but there is no reason why similar studies could not be done in other process plants.The authors of this paper hope that this experience at IOC will be helpful to others who face similar challenges in the pursuit of excellence in their processing plants."

Jan 1, 1995

By Jeffrey E. Loney, Andrew F. McKnown

Recovery of contaminated groundwater migrating through bedrock can be very difficult due to the low transmissivity of many bedrock fracture systems. To overcome these difficulties, a system of controlled "trench" blasting has been used on several projects to assist in cutting off and collecting groundwater plumes in bedrock. By using a combination of trench blasting and presplitting techniques, linear "fracture" zones are created in appropriate locations to significantly increase flow into recovery wells and control plume migration.

Jan 1, 1995

By David R. Morrey

During the past 50 years, significant research has been performed in the ecology and physiology of plants that colonize soils containing elevated concentrations of heavy metals. Similar work has also been performed on plants that are able to survive acidic and saline environments. Efforts have focused on the ecological analysis of plant communities that occur over a range of metalliferous mining wastes. Investigations have been performed on the mechanisms that allow selected varieties of plant species to survive in normally phytotoxic environments and on the potential applications of metal-tolerant varieties of plant species. The purpose is the remediation and reclamation of mining wastes and soils that contain unusually high concentrations of so-called heavy metals. Characteristics of some mineral wastes Metalliferous mining wastes present special environmental restoration problems because of their toxicity. Potential toxicities are mostly caused by residual metals derived from weathering of low-grade ore or the waste products of mineral processing. In cases where pyrite forms a part of the mining waste, acid generation by oxidation may exacerbate the toxicity problem by promoting heavy-metal mobilization in aqueous solution.

Jan 1, 1995

By Virgil J. Stachura, Calvin L. Cumerlato

The U. S. Bureau of Mines is conducting research on blasting methods that reduce highwall overbreak and the associated rockfall hazards. This paper presents the results of tests using a low-density water gel to improve the quality of air-decked presplit blasts at a surface coal mine in New Mexico. The explosive's specific gravity averaged 0.50 and was bulk loaded using a modified truck which injected the gassing agent. Reductions in overbreak and resulting rockfall were achieved in comparison to a highwall presplit with ANFO. The test sections used 15° angled blast holes and resulted in 1,119 m (3,672 ft) of air deck presplit highwall using a low-density water gel which was then compared to 894 m (2,934 ft) of highwall shot with an ANFO air decked presplit design. The total quantity of explosives per hole ranged from 68 to 113 kg (150 to 250 lbs) and the 27 cm (10-5/8in) holes were 19- to 33-m (62- to 108-ft) deep on 5.5 m (18-ft) centers. Periodic visual examination and photographic surveys of the highwall test areas were used to document the amount of rockfall. In addition, laser profiles of selected sections were conducted to further delineate the damage and highwall contour differences.

Jan 1, 1995

By I. Jackman

"Gold is present in different forms and associations in different ores. Flotation is used to recover gold and minerals associated with gold, but the applicability and type of flotation vary. The purpose of flotation in a gold recovery plant is largely dependent on the mineralogical association of the gold, and environmental and economic considerations. In this paper, the role of flotation in the recovery of gold is reviewed. The paper will describe examples of gold recovery by flotation including flotation of native gold, gold associated with sulphides including specifically copper sulphides, gold associated with tellurides, gold ores containing carbonaceous material and gold contained in tailings.INTRODUCTIONFlotation is widely used in the recovery of gold. However, the objectives and the mode of application are quite variable dependent on the type of ore, the gold association(s), other metal values, marketing considerations and environmental requirements. In this paper, a range of different applications of flotation incorporated in the recovery of gold are discussed. The reasons for each particular application are outlined and metallurgical results are presented.The mineralogy of the ore and the gold associations are fundamental influences on gold recovery. The use of flotation to concentrate gold is dictated by the mineralogy of the ore and gold. The fundamental factors are mineral/gold size, liberation size, association of the gold and type of gangue minerals or other valuable minerals. Gold can exhibit a range of sizes in a host from relatively large size (+50 µ) to refractory size (1 µ and sub-micron size). Similarly, the gold can occur in a number of phases in the same host. For example, the gold was present as petzite (AgAu telluride), calaverite (AuTe2) and native gold in a gold telluride ore and each of these minerals was associated with the pyrite host.Understanding the gold mineralogy and association is important in establishing the correct process route. The gold mineralogy is established by good mineralogy, use of diagnostic tools such as diagnostic leaching and assay by size fraction analyses and basic metallurgical testwork."

Jan 1, 1995

By Omar A. Muhtadi

Brohm Mining Corporation, in conjunction with Geobiotics, Inc. has nearly completed a pilot heap biooxidation test on sulfidic ore from the Gilt Edge Mine near Rapid City, South Dakota. Some results from the pilot testing have shown the correlation between the extent of biooxidation and the increase in cyanide gold recovery seen in the laboratory. Bench scale testing showed approximately a 1: 1 correspondence between percent biooxidation and percentage increase in gold recovery. The economics of large scale biooxidation were also evaluated in terms of increased gold recovery versus the time and cost of biooxidation. In the pilot test, the rate of biooxidation became limited by the acid water neutralization system. Later in the test, measures were taken to overcome this problem. Results from bench scale column bioleach testing showed that the Gilt Edge sulfide ore is quite amenable to biooxidation with a substantial increase in gold recovery with just partial biooxidation. Direct cyanide gold recovery of 51 % on ore crushed to -3/8" was enhanced to 82-85% after oxidation of37% of the sulfide as measured by iron. Laboratory experiments also showed that the slow rate of biooxidation of this ore could be accelerated by removal of metal sulfate build up from the leach liquor. The combination of these normally non-toxic metals became inhibitory to biooxidation if not removed by the neutralization circuit.

Jan 1, 1995

By W. M. Cross

Optical fibers have revolutionized the telecommunication industry, because of their ability to transmit large amounts of data over long distances. Without optical fibers many of the communication technologies on which business, industry and research rely would be impossible. In addition to their use as communication devices, optical fibers are often used as sensors. Despite the great promise that optical fibers have for the development of many types of remote sensing devices, few remote sensing devices have been built for use in the mineral industries. This paper will describe the use of optical fibers as sensors for surfactant adsorption at mineral surfaces.

Jan 1, 1995