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By Tao Xuea

Gold frequently occurs in nature in the form of a gold-silver alloy. Thus, investigation of the electrochemical behavior of gold-silver alloys in cyanide solution has practical significance. In this paper, the potentiodynamic method is used to determine the anodic polarization curves of gold-silver alloys (Au-10% Ag and Au-50% Ag) in cyanide solutions. To facilitate the interpretation of the results, complementary experiments conducted in NaOH solution in the absence of cyanide are also reported. The results for the Au-Ag alloys are compared with the polarization behavior of pure gold and pure silver. With the aid of potential-pH diagrams for the Au- and Ag-CN-H20 systems and electrochemical kinetics concepts, the dissolution mechanism of gold-silver alloys, the effect of the presence of silver on the cyanidation of gold, as well as the factors which control the anodic reaction rate are clarified.

Jan 1, 1998

By D. Kang

The adsorption behavior of silver in ammoniacal solutions on to activated carbon has been studied. The parameters affecting the adsorption of silver on to activated carbon included temperature, agitation speed, concentration of cations and anions as well as that of ammonia. It was found that the adsorption of silver from ammoniacal solutions was dependent upon the initial silver concentration in the solution and other factors. The recovery of silver from ammoniacal solutions was found to be not so effective as the case with gold reported earlier. The adsorption rate was relatively slow overall, despite a rather fast initial adsorption. The apparent activation energy for the adsorption was measured to be 30.2 kJ/mol. It was believed that the kinetics of the silver adsorption on activated carbon was limited by a mixed control mechanism.

Jan 1, 1998

By Chikabumi Yamauchi, Masami Tashiro, Toshiharu Fujisawa, Hiroyuki Snano

"Rare earth metals usually contain large amount of oxygen because of their reactiveness, and therefore oxygen removal is one of the major problems on the purification of rare earth metals. In the present research work, halide flux treatment at high temperature under inert gas atmosphere was applied to the oxygen removal from neodymium. NdF3 was used as a halide flux. Deoxidation reaction and its mechanism were discussed based on the experimental results. Halide flux treatment is very effective for oxygen removal from rare earth metals.IntroductionSolid Sate Electrotransport (SSE) process has been successfully applied for the elimination of interstitial gaseous impurities from chemically active metals[l]-[5]. However, to achieve a higher effectiveness of the SSE process, it is required a very low initial impurity content in the metal. In case of rare earth metals, it is known that they usually contain large amount of oxygen that should be lowered as much as possible before applying the SSE process. In addition, if effective oxygen removal is achieved by simple process, it is significant also from the industrial viewpoint. In the present work, the application of a halide flux treatment is investigated to remove oxygen from neodymium by using NdF3 as a flux. At first, deoxidation reaction and its mechanism were discussed based on the phase diagram of the Nd-NdF3-Ndp3 quasi-ternary system. Based on the results, oxygen content in deoxidized neodymium was calculated theoretically and it was verified by deoxidation experiments."

Jan 1, 1998

By Guocheng Pan

"Although many factors play roles in the estimation of recoverable reserves, smoothing effect and conditional bias are considered major geostatistical issues in the estimation. This paper introduces measures for smoothing effect and conditional bias, and provides insights into their relation to the estimation of recoverable reserves. Both smoothing effect and conditional bias are intrinsic to the information effect and kriging estimators. For a given level of drilling information, however, it is possible to identify the optimal search radius that minimizes conditional bias. Furthermore, it is also feasible to define variance correction factor for reduction of the smoothing effect from exploration block models. Both of these components are key to the accurate estimation of recoverable reserves. IntroductionThe accurate estimation of recoverable reserves is critical to decision making in different phases of feasibility study and mine planning. Much attention for improving the methodology of estimation has been focussed on the effect of the change-of-support (Parker, 1980; Dagdelen, 1996). For example, it is essential to make a volume- variance correction to the estimate of multiple indicator kriging (Hoerger, 1992). When the size of block, b, in the geostatistical model differs from that of selective mining unit (SMU), v, a volume-variance correction is warranted for the prediction of recoverable reserves.Most mining plans and decisions are made prior to the availability of high density blast-hole samples. In most mining operations, the true SMU grade Zv is unknown at the time of selection. Instead, the selection is based on the estimate Z v**derived from high density blast-hole samples within the deposit G. Nevertheless, the estimate Z v * of recoverable reserves in the stage of mine planning is derived from exploration data. At the end, the production result must be reconciled to the estimate Z v * . In other words, the selection is based on Z v** from blast-hole samples, while the final production figures are reconciled to Z v * from exploration drilling. For a given preselected cutoff grade z0, the actual mining panels will consist of the units having the estimated grade Z v** =z0 rather than the true grade Zv =z0. The difference between Z v** and Zv is usually of less concern."

Jan 1, 1998

By R. J. C. MacDonald

"The first recorded discovery of placer gold in Canada was on the Chaudiere River in Quebec's eastern townships in 1832 and the first major production came from placer deposits in British Columbia in 1858 (Verity 1974). Placer deposits were the major source of gold until the late 1890's, although lode deposits were found in Nova Scotia in 1862. In 1896 the Klondike Gold Rush commenced with the discovery of gold by Henderson and Carmack in the Yukon. The peak was reached in 1900 when over one million ounces of gold valued at approximately $22.3 million were recovered. With the exhaustion of the easily accessible deposits, more capital intensive operations were necessary such as those initiated in 1906 by the Yukon Gold Corporation. This giant dredging operation continued to produce until 1966. Today only a few small operations remain.The development of Canadian lode gold mining began in earnest around 1900 when the railroads were opening up the interior and western part of the country. At this time many discoveries occurred, particularly where mineral outcroppings were near surface. Tremendous impetus for exploration and the reopening of former producers followed the elimination of the gold standard by Great Britain around 1931, and more importantly the United States in 1933, with subsequent stabilization of the price of gold at $35 per ounce in 1934. Prior to this the price of gold was basically unchanged since 1717, approximately, $20 per ounce (Verity, 1974; Green, 1973).The depression of the 1930s adversely affected most industries, however for the gold producers it was a very profitable time. Prices of materials and equipment declined and labour was cheap and plentiful. Interest in gold mining was further stimulated in 1936 when a three year tax exemption was declared for all new metal mines. In 1938 a decline in the value of the Canadian dollar relative to the U.S. dollar benefitted the industry. The second world war provided yet again further incentive for gold production and in 1941 Canadian gold production reached a high of approximately 5.4 million ounces. This figure was not surpassed until 1991 when approximately 5.6 million ounces were produced (Natural Resources Canada, 1996 )."

Jan 1, 1998

By M. Vandewalle

What separates the support of mining openings from the support of similar civil engineering structures is the fact that mine openings have to survive large deformations as a result of changing stress conditions induced by progressive mining. Steel fibres impart to concrete and shotcrete a high degree of ductility which not only allows the shotcrete and concrete linings to absorb important rock movements but also to increase its bearing capacity by a redistribution of the loads. A range of applications will be discussed technically and economically.

Jan 1, 1998

By C M. Stewart, P Bowen

McArthur River Mine, in the Gulf Country of the Northern Territory, exploits one of worldÆs largest deposits of zinc, lead and silver. It was officially opened in September 1995, 40 years after its discovery in 1955. This paper describes the geological, engineering and metallurgical assessments which made up the feasibility study. It then relates how these study components compare with the first two years of operation. The challenges that had to be overcome before the McArthur River Mine became economically viable included the metallurgical problems associated with extremely fine grained ore and the development of an effective mining process.

Jan 1, 1998

The following are abstracts from papers presented at the 4th Symposium on Respirable Dust in the Mineral Industries and· were produced through research funding under the Generic Mineral Technology Center for Respirable Dust. Full articles appear in the proceedings published in July 1996 in Applied Occupational and Environmental Hygiene. (Volume 11, Number 7). The two addresses included in the proceedings point to the progress, prospects, problems, and perspectives on control of respirable dust and dust-related disease in the mineral industries. The symposium papers deal with respirable dust issues that are longstanding such as characterization, health effects, control of airborne coal dust, new and emerging issues such as iron toxicity, diesel particulates, and sampling. The papers were grouped into the following topics: continuous dust monitoring, encompassing the development of a fixed-site monitor that will provide continuous information on instantaneous and time-weighted respirable dust concentrations; mechanisms involved in the generation of dusts in mine environments, important for dust control at the source; characterization and control of diesel emissions (particularly diesel particulates) in mine atmospheres; mining systems effects and models; dust control in mine working faces and in milling environments; characterization of the physical, chemical mineralogical, and biological properties of the dust and their relevance to health effects and sampling; dust-lung interactions, encompassing results from several biomedical studies dealing with acute and chronic inhalation of airborne dusts and associated lung responses; the role of iron in causing lung injury; and therapeutic strategies for ·the control of pulmonary disease. All papers submitted to the organizers were peer-reviewed. In the proceedings, we have not differentiated among the platform and poster papers; rather, they have been grouped into the above topical areas. Taken together, these papers reveal significant progress in the control of dust generation, characterization of dust, understanding of dust-lung interaction, and mining and milling practices to reduce dust exposure - all essential for reducing dust-related occupational hazards at the workplace.

Jan 1, 1998

By Leonard Harris

The 1980s marked a boom in gold mining and exploration in the United States particularly in the state of Nevada which lifted this country to second place in the world, after South Africa, in gold production. With this boom came many positive aspects such as increased employment, increased investment, increased payment of federal and local taxes, higher purchases of goods and services and higher expenditures on social and economic uplift programs. With the arrival of Minera Yanacocha in Peru in 1992, the gold mining boom shifted to this country which has lifted Peru to first place in Latin America in 1996 and ninth place in the world in gold production. As in the case of the United States in the 1980s, similar positive impacts are being felt throughout Peru in the 1990s.

Jan 1, 1998

By Jikai Rong Changai Liu

The dig instrument by blasting is a,new product we developed(See Fig. 1) It is an apparatus to dig hole at the ground. It is composed of combustor A, combustor B, charge pipe and shock head. Work characteristics of Combustor A are that combustion time is 1. 5 seconds, driving force is 725kg. Work characteristics of combustor B are that the combustion time is 1. 3 seconds, driving force is 460kg. After the combustor is ignited, the charge pipe is drived into ground immediately. Then, whole dig instrument is threw out automatically, but explosive in charge pipe is left in ground and blast in the twinkling. The diameter of vertical hole formed by blasting is 3cm to 60cm which is controlled according to engineering requirement. The maximum depth of the hole diged by using the dig instrument is 2M. It applies to blindage of single solidier in military affairs, and hole planting pole as well as sewer in civil use and so on. The two shots are charged in combustors to dig a hole. The maximum weight of shot is 490g, minimum is 130g. The whole process diging hole is completed automatically in about ten seconds.

Jan 1, 1998

By S. K. Varma, Miriam Regalado, Daniel Salas, Erica Corral, Erika Esquivel

"Age hardenable 2014 aluminum alloys and composites containing 0.10 and 0.15 volume fractions of alumina particles (VFAP) have been solutionized at 540 and 550°C for up to 20 hours. The solutionized samples, heat treated for 5 and 20 hours, have been subjected to room temperature rolling until cracking develops. The work hardening curves have been compared to determine the effect of solutionizing time on the rolling characteristics from both hardness and the microstructural evolution points of view. Solutionizing at two different temperatures results in differences in the extent to which the composites can be rolled until fracture. The microstructural characterization by TEM has been performed to understand the room temperature rolling behavior.IntroductionThe effect of solutionizing on the age hardening response of 6061 and 2014 aluminum alloys and composites reinforced with 0.10, 0.15 and 0.20 volume fractions of alumina particles (VFAP) have been reported in the literature [1-4]. A comparison of the monolith and composites indicates that particles promote the aging process through differences in the microstructures in solutionized condition. The first effect of solutionizing is to produce a grain growth process which follows a grain growth law (square of grain diameter as a function of solutionizing time). It appears that it is possible for vacancies to be emitted during grain growth period as they try to minimize the total grain boundary surface area by increasing their diameter. This may be common to both the monolith and the composites. However, the second effect must be exclusively considered for the composites. The particles generate dislocations during the solutionizing process due to the differences in the values of the coefficient of thermal expansion (CTE) between the particles and aluminum base metal. It has been determined [1] that the dislocation density increases with increase in solutionizing time in the composites of 6061 aluminum alloys reinforced with 0.10, 0.15 and 0.20 VFAP. The improved bonding between particles and matrix can give rise to additional generation of dislocations due to curvature effects [1] with the result that the dislocation density continues to increase with increase in solutionizing time even after the CTE effect is considered to have been stabilized."

Jan 1, 1998

By R. W. Reisinger

An historic underground copper mine in Wyoming is discharging neutral but copper-laden water into a pristine creek. The EPA-deferred site qualifies for reclamation by the Wyoming Abandoned Mine Land (AML) program; restoring the discharge so that the creek can eventually support a trout fishery is the cleanup goal. Hydrological and geochemical investigations underground have suggested two sources of mine water: one clean and the other copper-containing. Results of bench-scale and pilot-scale tests support the viability of using low-cost passive treatment techniques to reduce copper concentrations in the near-freezing mine discharge.

Jan 1, 1998

The Mineral Sector Development Project, sponsored by the World Bank, has been set up to revise the legal, regulatory and fiscal framework for the minerals industry in Tanzania, with a view to attracting mining companies and investors to the country and facilitating future minerals development. One component of this project, the Environmental Management Framework for the Mineral Sector, was awarded to Wardell Armstrong of the UK and ENV Consult of Tanzania. In developing a new framework of environmental regulations, emphasis was placed on developing realistic standards which reflect local conditions and prevailing values. The main corner-stones of this approach are; effective environmental impact assessment procedures; establishment of environmental management procedures; and monitoring and auditing of companies? performance. The favoured approach involves a three-tier framework, as follows: ?Framework environmental provisions within the new Mining Act; ?Regulations covering more detailed environmental requirements ?Guidelines and/or Codes of Practice, which may in future become regulations in their own right. Careful consideration has been given, in developing the framework, to the limited resources likely to be available for implementation to the Ministry of Energy and Minerals and this has influenced the approach that has been adopted. This paper outlines the main components of the environmental management framework and discusses some of the important issues raised by these proposals.

Jan 1, 1998

By M. W. Grabinsky, P. B. Tomory, J. Carvalho, J. H. Curran

Many underground mining operations use Split Set friction stabilizer bolts for rock support. Currently, however, little has been done to quantify the effects of various rock mechanics and operational parameters on the capacity of frictional support systems. The strength of Split Sets is usually measured by means of a pull test wherein a jacking force is applied to the bolt and a slip load is obtained. In order to evolve a rational design procedure for this type of support, an extensive database of over 900 pull test results from more than 50 mines through- out North America has been assembled and analyzed. Associated relevant rock mechanics parameters (rock type and quality) and operational details (drilling method, bit size, drive time, time to pull test) were also obtained, as completely as possible, for each test. Analysis of the information has yielded several charts that relate pull-out strength to relevant parameters and simple statistical analyses were conducted where necessary. Quantified distributions for pull-out strength were also produced for several operating conditions. The factors that most significantly affect bolt strength have been identified and specific applications to design are discussed. The information presented will assist mining engineers in designing safer and more economic support using Split Sets.

Jan 1, 1998

By D. Eugene Rannels, Sarah E. Dunsmore

"Dunsmore, Sarah E., and D. Eugene Rannels. Extracellular matrix biology in the lung. Am. J. Physiol. 270 (Lung Cell. Mol. Physiol. 14): L3-L27, 1996.-The lung and other organs are comprised of both cellular and extracellular compartments. Interaction of these components modulates physiological function at the organ, cellular, and subcellular levels. Extracellular components in the gas-exchange region of the lung include both noncellular interstitium and basement membranes. Connective tissue elements of the interstitium in part determine ventilatory function by contributions to tissue compliance and to resistance of the diffusion barrier. The basement membrane underlies cells of both the alveolar epithelium and the capillary endothelium; basement membrane components exert biological effects on adjacent cells through receptormediated interactions. This review emphasizes current knowledge concerning the composition and biological activity of extracellular matrix in the alveolar region of the lung. Matrix synthesis and turnover are also considered. Directions for future research are suggested in the context of current knowledge of the lung and other model systems. EXTRACELLULAR MATRIXEXTRACELLULAR MATRIX is a general term that encompasses components of the basement membrane and interstitial connective tissue. The extracellular matrix has many functions. It provides structural support, compartmentalizes tissues by separating epithelium or endothelium from interstitium, and serves as a physical barrier. Both in vivo and in vitro studies show that extracellular matrices also affect cell shape and function. The matrix elicits a variety of cellular responses, including adhesion and spreading, changes in cytoskeletal organization and differentiation, formation of focal contacts and stress fibers, stimulation of proliferation and migration, induction of polarity and gene expression, alterations in metastatic activity, and outgrowth of cell processes (for review see Refs. 387, 462). Cellmatrix interactions play roles in embryonic development and organogenesis (for review see Refs. 1, 91), in wound healing (for review see Refs. 145, 327), iri metastasis (for review see Refs. 430, 431), and in angiogenesis (for review see Refs. 185, 186). The extracellular matrix is the subject of a large volume of literature. In 1994, over 1,000 articles contained extracellular matrix in the title or abstract. After a brief discussion of key aspects of extracellular matrix biology, this review will focus on the extracellular matrix of the lung."

Jan 1, 1998

By L. K. Daneshmend

The mine of the year 2020 will need to be based on a new way of mining. It will employ technology in a paradigm that assumes responsibility for sustainable development: taking account not only economic but also ecological and social issues. This will require a holistic approach to mine design and planning, considering all controlling factors and impacts (technical, economic, environmental and social). A national collaborative strategy is required to address the several options that exist for the development and application of 2020 mining technology. Key issues in implementing 2020 mining technology will also relate to human resources, in terms of employment, skills and education. A need exists to proactively prepare for 2020 through development of a comprehensive education and training strategy.

Jan 1, 1998

By Geoffrey S. Plumlee

The Summitville gold mine, located in southwestern Colorado, received tremendous publicity in the 1980's and 1990's for leaks of cyanide solutions from its heap leach facility. As is typical with cyanide spills, real time, geochemically rigorous assessments of the environmental effects were not performed. Past United States Geological Survey (USGS) research used simple mixing experiments to model the influx of alkaline cyanide heap leach solutions from Summitville into a nearby stream, whose waters were highly acidic due to severe acid-rock drainage (ARD) from the mine. These experiments indicated WAD cyanide rapidly degraded due to formation of Fe-Cu-CN solids and lesser HCN volatilization. The alkaline heap leach solutions also precipitated hydrous iron-and aluminum, oxides and hydroxysulfates (iron and aluminum 'supplied by the acid. rock drainage (ARD]), which then sorbed copper and other heavy metals from the ARD. These results indicate that mixing of cyanide heap leach solutions with ARD may be a cost-effective remedial method at mine sites where treatment of both is required. New experiments are currently in progress to further refine a potential remedial process.

Jan 1, 1998

By S. Rajendran

The area of the Exclusive Economic Zone (EEZ) of India is about 2.014 million km2 and the resource evaluation of placer deposits is one of the objectives of Government of India. Placers are detrital metallic minerals found on beaches and in the near shore areas. Quantitatively more important are placer deposits of light heavy minerals such as zircon, ilmenite and rutile. Rivers and other drainage channels are the main carriers of the placers which contain heavy minerals like magnetite, ilmenite, garnet, zircon, monazite, rutile etc. The present beach as well as part of the shelf was land during Pleistocene as a result of the world wide lowering of the sea levels. The coast line shifted a number of times. Hence, the heavy mineral placers on the beaches are expected to extend to offshore areas chiefly with Pleistocene lowered sea level strands. India has extensive deposits of heavy mineral placers along the beaches. Placer deposits of heavy minerals occur in discontinuous patches on the beaches along many parts of the east and west coasts. Along the central west coast of India (12??N - 19? N lat.) the placer containing 14 - 17% ilmenite form an estimated reserve of 4 million tons. On the Ratnagiri coast of Maharashtra, the proportion of heavy mineral varies between 54 and 70% in the bulk samples, consisting mainly of 14 - 39% magnetite and 16 - 30% ilmenite. The National Institute of Oceanography (NIO) surveys show that the sediments off the central west coast consist largely of silty sand, sand silt and clay. The core samples show that a reddish brown clay overlay olive gray clay which in turn overlay heavy mineral rich sands. The heavy mineral concentration ranges upto 90% and has mainly ilmenite and magnetite with minor quantities of apatite, rutile, zircon, kyanite etc. Siddiquie et al. reported 42 - 75% TiO2 in the ilmenite.

Jan 1, 1998

By C. F. Feng, L. Froyen

"In-situ processes have emerged as new and promising techniques for metal matrix composite fabrication. They offer significant technical and economic advantages over conventional processing. One of the in-situ processing routes that have been used is reactive free sintering of a mixture of powder reactants. However, materials synthesised via this route are always porous because of density differences between reactants and products. An example are the porous Al/(TiB2+Ah03) MMCs obtained by heating powder mixtures of Al+ Ti02+B with Ti02 and B in stoichiometric ratios for forming TiB2• In this study, porous Al/(TiB2+Ah03) composites were further processed by hot-pressing at temperatures above 600°C. This processing cycle was designed so that the composites could be densified. Furthermore, the reaction kinetics of the in-situ processing are studied by means of DSC analysis measured at different heating rates. The activation energies of the three intermediate steps that are involved in the reactive processing for preparing AV(TiB2+Alz03) MMCs are determined to be 923 kJ/mole, 241 kJ/mole and 235 kJ/mole respectively.XRD proved that the hot-pressed products consist of Al, TiB2 and Al203- Properties of the products are assessed by microstructural characterisation (LOM, SEM and EDS), microhardness, Young's modulus and bending tests. The results show that good microstructures, elastic properties and strengths, as well as acceptable ductilities were achieved. For the composition 79.74wt% Al-15.95wt% Ti0z-4.31wt% B, after the reactive free-sintering and hot-pressing cycles, Young's modulus is 105 GPa, bending strength is 509 MPa and maximum strain is 5.0%; for composition 88.73wt% Al-8.87wt% Ti0z-2.40wt% B, they are 89 GPa, 311 MPa and 8.2% respectively. It can be seen that the properties of products can be tailored by adjusting the relative amounts of reactants in green samples. Furthermore, for comparison reasons, Al and a binary system Al-Ti02 were identically processed as the ternary systems. Their microstructures and properties were studied."

Jan 1, 1998

By Larry Howe

Second, or retreat mhng with Mobile Roof Supports (MRS) has now been part of coal mining in the United States for a decade Their utilization has evolved into mining applications which vary in seam heights from 38 inches to 170 inches, and overburden depths from outcrop to beyond 1200 feet This paper will detail the pillaring plans, lift sequences, and mnchky utilized in these operations and the rational for the plans A comparison of the current productivities achieved will be outlined

Jan 1, 1998