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By Tam Tran

Most new gold mines in Australia are required to treat tailings to reduce cyanide levels before they are discharged to storage ponds to meet the stringent environmental management guidelines set by government statutory authorities. In New South Wales, the average level of weak acid dissociable cyanide allowed in open tailings dams is now limited to 20 ppm, As stringent environmental guidelines continue to be enforced in Australia as well as in other parts of the world, the management of cyanide wastes has emerged as a key issue for the gold mining industry. This paper provides a critical evaluation on technical aspects related to the use of ion exchange resins and affiliated processes in cyanide management and tailing treatment. Particular attention is given to the use of ion exchange resin technologies in the processing of mixed gold-copper ores, where cyanide usage is the highest. Information presented in this paper is heavily drawn from the experience on the application of ion exchange resin processes at May Day mine, in New South Wales, Australia and associated pilot plant test programs. Issues related to the management of thiocyanate, especially with respect to the recovery of cyanide from thiocyanate are also discussed.

Jan 1, 1998

By C. A. Rowland

Comminution efficiency can be expressed in three different ways. Theoretical Efficiency: actual energy consumed, in a comminution machine compared to the theoretical energy required to make the size reduction. Operating Efficiency: compares the operating work index, calculated from production comminution machinery operating data, to the Bond Work Index from bench scale comminution tests or calculated from pilot plant operating data. Economic Efficiency: income compared to planned income. Using the Bond Work Index and operating work index, this paper explains how to determine operating efficiency.

Jan 1, 1998

By S H. Marshall, H Hutcheson

Conventional batch cell and FASTFLOT pilot plant studies of reverse flotation of coarse marcasite and pyrite (100 - 400 μm) to reduce the sulphidic sulphur content of a rutile concentrate, were undertaken. The batch cell experiments found no significant improvement in sulphur removal with acid wash and copper activation of marcasite and pyrite. Batch cell trials also identified potential difficulties of conventional mechanical cell plants operated at 40 per cent w/w solids. The FASTFLOT 250 B-2 pilot plant trials indicated that with a 0.6 - 0.7 per cent w/w feed sulphur content, target product grade can be met on a routine basis by a three-stage FASTFLOT plant floating coarse marcasite and pyrite. The trials found that 150 g/t PAX dosage and 15 minutes conditioning time are adequate reagentisation for 40 per cent w/w solids feed to the FASTFLOT plant.

Jan 1, 1998

By James H. Owen

Because of price structure, ANFO is normally considered to be the most cost effective explosive used in quarry blasting. Results indicate that bulk smulsion can be more cost effective in applications where hole sizes range up to 6.5 inches in diameter while providing the simplicity of single product loading and storage. This can be accomplished without any fragmentation and/or movement loss usually in patterns which are about twice the size of ANFO patterns, allowing the combined drilling and blasting cost to be less when using bulk emulsions. Examples are presented supporting this concept using actual field results along with some simple calculations which take into account differences in the products such as density, matrix and detonation velocity.

Jan 1, 1998

This paper will first discuss the fundamental requirements for reliable discharge of backfill by gravity alone at high per cent solids. This discussion will include brief mention of the underlying principles of saturated solids flow contrasted to that of stirred tank or dilute discharge systems. Here the need to possess full knowledge of the flow properties of the stored material will be highlighted. In addition proper account must be made of the silo overflow weir and settling capacity to match plant throughput. Here opportunity will be taken to highlight the complexity of this multi-phase flow situation as well as the general yet paramount requirements for reliable solids flow. It will be shown that by proper attention to the multi-phase considerations gravity discharge of slurries as a consolidated bed with minimal water content is possible. Such high solids discharge results in greatly reduced demand for process water. In addition pumping costs are reduced as is the delay time associated with the mine drainage operation. Confirmation of successful applications will be highlighted by reference to several recent case studies. In the concluding phase mention will be made of the key yet very simple and effective operation techniques which enhance reliable discharge. The simplicity and reliability of properly designed gravity discharge backfill tank systems suggests increased application of this technology by the mining industry.

Jan 1, 1998

By Alastair J. Sinclair, Asger Bentzen

Abstract - A simple linear model for interpreting duplicate analytical data for a range of values is described. The conceptual model can be quantified using a reduced major axis model rather than the inappropriate traditional least squares approach. The reduced major axis parameters (slope, intercept) and associated errors provide a quantitative basis for: (1) defining bias, and (2) comparing results within laboratories, between laboratories and between sampling/analytical methods. Application of the linear model must be preceded by extraction of obvious outliers or small groups of values that have an inordinately large impact on values of the statistical parameters defining the model. In addition, consideration must be directed to the presence of more than one population of sampling error, as in the case of multiple styles of mineralization being sampled.

Jan 1, 1998

By Rowan A' Murry Karstel

One way to ensure dragline productivity is by Increasing the size of the dragline bucket. In August 1994, Optimum Colliery in conjunction with Van Reenen Steel, Northwest Applied Technology, SSAB of Sweden and Barlows Equipment launched the new lightweight dragline buckets. Optimum built the first prototype bucket that was used for the deslgn for future buckets. After knowledge had been gained from measuring the input force of the bucket Northwest Technologies designed the new bucket with finite element analysis. Together with the knowledge of quenched and tempered steel from SSAB of Sweden and Barlow Equipment, the new Wrightech bucket was born.

Jan 1, 1998

By F. H. Froes, O. N. Senkov, N. Srisukhumbowornchai

"Mechanical alloying (MA) and thermohydrogen processing (THP) approaches were used to synthesize amorphous or nanocrystalline powders of the titanium-aluminide-based alloys and composites. Fully dense samples with nanocrystalline and bimodal structures were produced from these powders by hot isostatic pressing. The stability of the microstructures during continuous heating at high temperatures was studied. Characterization techniques including X-ray diffraction, scanning and transmission electron microscopy, energy dispersive spectroscopy, and differential thermal analysis were used in this work.IntroductionAs performance demands increase, so do the demands for enhanced mechanical property combinations at reduced overall weight; and reduced weight can most efficiently be realized by the use of low-density metals with high specific strength, such as titanium alloys and titanium-aluminum intermetallics [l]. The TiAl-based alloys are attractive for high temperature applications, however, they exhibit poor ambient temperature ductility and fracture toughness [2-4]. Incremental improvements can be obtained using ingot metallurgy processing [1,2] but more substantial developments require ""far from equilibrium"" (FFE) synthesis [5-8] which allows development of novel constitutional and microstructural effects, leading to enhanced physical and mechanical properties. Improved ductility of titanium aluminide intermetallics can be achieved by disordering, grain refinement and deoxidation of the matrix, while good elevated temperature properties are achieved due to a dispersion of fine, thermodynamically stable, second phase particles.The approaches for producing nanocrystalline and amorphous TiAl-based alloys and composites used in this work included FFE powder metallurgy techniques such as rapid solidification, mechanical alloying and thermohydrogen processing. The rapid solidification (RS) technique allows extension of solubility limits, production of novel phases, and much more refined microstructures (down to nanostructure or even amorphous range) than is possible using the ingot metallurgy technique [9]. Mechanical alloying (MA) is a process in which heavy working of powder particles results in intimate alloying by repeated deformation, fracturing and welding. This process can produce greater departure from FFE than RS, leading to greater refinement effects; and additionally allows production of a dispersion of second phase particles [10]. Thermohydrogen processing involves hydrogen as a temporary alloying element in titanium to facilitate processes, refine microstructure, and improve final mechanical properties [11]; it was used in the present work to improve MA process. The combination of these three processes was expected to control the final microstructure even better than either process used alone."

Jan 1, 1998

By R. Quintero

The HYL Direct Reduction Process was the first in the world to operate successfully at industrial scale. The results were so innovative and attractive that other steelmaking companies acquired licenses for the HYL Process. Now in its 40th year of commercial operation, the HYL process has evolved into a modem, highly efficient and economical technology -HYL III. The technology offers high productivity, minimum energy and water consumption, electricity co-generation, raw material flexibility, premium quality DRI/HBI, and is highly versatile for meeting the specific needs of each user. A historical review as well as recent developments and future plans are presented in this paper.

Jan 1, 1998

This paper describes the application of the Total Productive Management (TPM) technique as a performance improvement initiative for a coal mining operation. It discusses the objectives of TPM, with the driver for improved production performance being the Overall Equipment Effectiveness (OEE) of the equipment or process, and with the development of "ownership" as the behavioral approach to equipment management and continuous improvement through cross-functional and area-based teams. It illustrates the concept of equipment management as defects management.The scope for application of TPM to the coal mining industry is immense. The harshness of the operating environment can be a major generator of equipment defects, and a current paradigm in the industry accepts these defects as an unavoidable outcome defining maintenance costs in this environment. However recent benchmarking studies have highlighted that maintenance costs per operating hour in some mining operations are more than double the vendor's estimate of "best practice". The paper refers to these studies which also compare maintenance costs of fixed and mobile plant and equipment to "best practice" outcomes in comparable process industries.

Jan 1, 1998

Silver has the highest electrical conductivity of all metals and consequently this property is an attractive feature which makes it a leading candidate for use in electronic devices. The research conducted was focused primarily on the development of a process for obtaining a deposited silver-coating onto alumina, for applications related to electrical-conducting devices and, ancillarily, catalysts. Alumina balls and plane substrates were utilized for the investigation. The coating process employed an aqueous arnmoniacal silver-nitrate electrolytes with a formaldehyde solution as the reductant. Modifying additives - an activator which would be expected to promote good deposition-characteristics onto the (dielectric) substrate and an inhibitor which would obviate homogeneous reduction (precipitation) of silver was observed when the activator-containing silver-electrolyte reductant constituents were combined. However, the silver-electrolyte/reductant system with inhibitor could be employed (at 80°C) to achieve a viable (subject to future research optimization) coating on alumina. The influence of the processing temperature on the deposition process was delineated during the course of the research. The morphology of the deposited-silver on the alumina balls was assessed by SEM imaging. A tape-peel test was employed, with the plane substrates, to semi-quantitatively characterize the adhesion to the alumina.

Jan 1, 1998

By P. Grotjohann

In processing heavy mineral sands, the low feed concentration and respective high value of the desired minerals require high capacity production and sharp classification/separation techniques to reduce the specific production costs. The allflux® separator, a new process system introduced to the heavy mineral industry, meets these criteria in an economical way. Its two-stage process, a combination of rising current and fluidized bed technology, allows the treatment of extremely high massflows in a single unit. Using concepts that have proven successful in processing concrete sands for many years, testwork in coal, iron ore, and heavy minerals looks very promising.

Jan 1, 1998

By Zenjiro Asaki, Teruo Tanabe

"To clarify the formation of light rare earth (R =Ce, Pr, Nd or Sm) -Fe compounds in the reduction-diffusion (RD) process, two kinds of experiments were carried out: (a) RD experiment in which briquettes composed of R oxide powder, Fe (particles or wire) and CaH2 were reacted, and (b) immersion experiment, where an Fe plate was immersed into R-Fe melt having the composition of Fe-side liquidus line in Fe crucible. The compound formation was examined by using XRD, SEM and EPMA. The formation rates of RzFe17 measured by the RD experiment were compared with those obtained by the immersion experiment. The growth rates of compounds obtained in the RD experiment for Pr-Fe and Nd-Fe systems were much lower than those obtained in the immersion experiment. This result was explained by the difference of the reduction rates of R oxides by Ca. The parabolic rate constants for the formation of RzFe17 were separated in two groups of (a) Pr-Fe and Nd-Fe systems and (b) Ce-Fe and Sm-Fe systems. This was discussed in connection with the difference of their crystal structures and the driving force of diffusion. The parabolic rate constants for the formation of compounds in Ce-Fe and Sm-Fe systems decreased in the order of RFez, RFe3 and RzFe17.IntroductionTo understand reaction behaviors in the production of rare earth (R) -iron intermetallic compounds, which have excellent magnetic properties, is very important from engineering point of view. And the reduction-diffusion (RD) process<O has recently attracted attention as one of the promising processes to economically produce R-related materials. A few fundamental studies on the compounds formation in the RD process have previously been reported. Qi, Hino and Yazawa(2) observed the formation of R(Nd, Sm)-Fe and R-Co compounds in the process from various view points. Song and Ogawa(3) measured the growth rates of Nd-Fe and Sm-Fe compounds by using Nd or Sm vapor supplied from Nd-Ca or Sm-Ca melts. The authors have also carried out fundamental studies (4)-(8) to clarify the rate and mechanism in the production of R-Fe intermetallic compounds."

Jan 1, 1998

By Katsumi Ogi, Hiroto Uchida, Masamitsu Sato, Atsushi Itsuki

"(BTMSE)Ag(hfac) (BTMSE = trans-bis(trimethylsilyl)ethene) was chosen as a suitable precursor for the XeCl laser (308nm) MOCVD of Ag. Iso-propanol solution of (BTMSE)Ag(hfac) was used as a liquid source for the liquid delivery method, high deposition rate 9nm/min at substrate temperatures of 100°C and 120°C were obtained at the vaporizer temperature of 90°C. This deposition rate is three times faster than by conventional bubbling method and life of the source and reproducibility of the deposition were also improved. Electric resistivities of the laser deposited film shows significantly low resistivity of 10-6Q-cm compared to 1 o-3Q-cm of thermal MOCVD film. These results indicates that the laser MOCVD is one of the effective method for the preparation of the high quality silver film.IntroductionSilver films are a potentially important metallization material in electronic and photonic devises due to their lowest resistivity (1.6µ0-cm) among the metals, high optical reflectance and chemical stability. The MOCVD technique has advantages to sputtering or evaporation in the point of conformal growth and better coverage on sharp steps and narrow gaps[l-2]. For MOCVD application, silver precursors must have sufficient vapor pressure without decomposition at their evaporation temperature. To achieve stable precursor gas supply, liquid delivery of precursor material is promising[3-4] especially for materials that have not enough heat stability and high vapor pressure like silver complexes[S-10]. Several new silver complexes for MOCVD and UV irradiation effect to their MOCVD silver film quality were reported by same authors[5]. In this paper new solvent system for liquid delivery system of silver MOCVD were investigated to suite XeCl(308nm) laser MOCVD application."

Jan 1, 1998

By Luis Dr. Sobral

In this study, the removal of zinc, cadmium and copper from an aqueous sulphate solution, derived from the biomass desorption process, was examined by using a reaction system with a three-dimensional high surface area electrode (RNiF). This reaction system was found to be extremely effective in reducing metal concentrations to the ppb range. The effect of cathode potential and flow rate were studied for three different nickel foam porosities. In addition, current- potential curves were recorded, at a rotating vitreous carbon electrode, to deter- mine the possibility of depositing the aforementioned metals separately.

Jan 1, 1998

The mining industry has been slow at adopting the latest management philosophies from other industry sectors, such as manufacturing, and in retrospect, with good cause. With the plethora of three-letter-acronyms such as TQM, JIT, TPM and now, BPR each touted as the panacea for profit improvement, you wonder if you must choose one or attempt to embrace them all! In truth, each new insight into organisational behaviour bears some investigation. This paper looks at the underlying principles and elements of successful change strategies, and how several mining companies, including coal mines, in Australia, Chile and Canada, are applying these principles to their operations. These examples illustrate the need to think radically, and to view mining as an overall process delivering value to the customer rather than a collection of functional silos. They also show that often, a continuous improvement initiative is not enough when a fundamental redesign, a paradigm shift, is needed for a performance breakthrough.

Jan 1, 1998

By M. D. G. Salamon

It has been noted in recent years that the pillars in some bord-and-pillar workings scale or spall. In due course this process may result in the collapse of the affected panels. This paper presents a methodology for assessing the long-term behaviour of such workings, employing a simple model of pillar deterioration by scaling. It is assumed that scaling causes a gradual reduction in pillar width, hence the safety factor of pillars reduces in time. It is also postulated that the process of scaling will be arrested if the coal rubble around the pillar reaches a critical height. The probability that the pillars will survive for a certain period of time, or indefinitely, can be estimated. This can be accomplished by using the log-normal distribution proposed by Salamon and Munro4todescribe the distribution of the apparent safety factor values at failure. If an estimate of the rate of scaling is known, it is also possible to quantify, using a Monte Carlo technique, the expected life of the pillars. The method also facilitates pillar design by specifying a probability of survival for a given number of years or, alternatively, for an indefinite period. Using the limited pool of available data, analyses show that the proposed model does not appear to be inconsistent with observed behaviour of pillars in the Vaal Basin. The crucial parameter is the rate of scaling. Back calculations from eleven cases suggest that the rate of spalling in the Vaal Basin is about 0.2 m/year. It is noteworthy that two further cases in the same area give significantly higher rates (0.85 m/year). Some underground observations in the Witbank area indicate considerably lower rates in the order of 0.02?0.04 m/year. Further areas for study are recommended. These include a study of old workings to determine the extent and rate of scaling in the various coal fields, an investigation into the possible relationship between scaling and the chemical composition of the coal. In addition, model studies will be required to assess the practical impact of the research findings.

Jan 1, 1998

By Tingkan Lu

To understand the reinforcing mechanisms of the fully grouted resin bolt and clarify its performance in weak roof strata, the field monitoring investigation using instrumented bolts has been conducted in a coal mine. The total time of monitoring was around ten months. In the first 8 month period, the rock bolt performance relates to the initial development of the gateroad and subsequent time dependent strata response. After 8 months, the rock bolt performance relates to the effect of the approaching longwall mining operation, up to the point where the measuring station was destroyed due to the mining operation.

Jan 1, 1998

By M. Grenon

"The presence, size, orientation, nature, and persistence of geological discontinuities dictate the behaviour of a rock mass. Block size, which is defined by discontinuity spacing, by the number of joint sets, and by the persistence of the discontinuities delineating potential blocks is an important indicator of the degree of fracturing of a rock mass. Consequently, block size is represented either explicitly or implicitly in all rock mass classification systems employed for analysis and design of surface and underground mining structures. Insitu block size distributions may provide a better means to describe the structural complexity of a rock mass. These are the distributions that would be derived if the in-situ rock mass was separated into its constitutive blocks, delineated by existing discontinuities, and each block measured. This paper presents the results of a field campaign at Louvicourt Mine aiming to characterize the rock mass using different methods for determining block size and block size distributions. IntroductionGeological structural data are used to provide input data for analysis and design methods for surface and underground structures. As the collection of structural data involves considerable investment of time and effort, it is sometimes overlooked, thus denying an important source of information for mine design. What is somewhat surprising, however, is that when structural data are available, they are not used to their full potential. Recent work has shown that data on block size have potential applications in different areas of rock engineering:• Blasting — Hudson (1993) has described the excavation process as the change of a preexisting natural block size distribution to the debris fragment size distribution (Fig. 1). Lizotte and Scoble (1994) have reviewed previous efforts on integrating site specific geological conditions into blast design. Grenon et al. (1997) provide a case study where in-situ block size distributions are compared to photogrammetric studies of blasted rock.• Rock mass classifications — Block size is used in the majority of rock mass classification systems either explicitly, as in the RMi classification system Palmstrøm (1995), or implicitly, such as in the NGI system, Barton et al. (1974)."

Jan 1, 1998

By Callcott R

Prediction of raw coal size distributions and those generated by processing are examined using spreadsheets and the matrix analysis of breakage processes. Run of mine coal size distributions are predicted from the lithotype properties using a

Jan 1, 1998