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Laboratory scale flotation tests were done on mineral hematite and aspecular hematite ore using oleic acid and sodium oleate as collectors. The mineral hematite floated strongly in the neutral pH region, with an increased pH range of flotation at higher oleate additions. Concentrates with sufficient hematite grade to meet the paint pigment specification were produced using oleic acid and sodium oleate as hematite collectors on the specular hematite ore. Hematite recoveries of 70 per cent at 60 per cent Fe grade were obtained using stagewise roughing. The interaction between hematite and oleate was confirmed as chemisorption but the exact mechanism could not be determined, as two independent phenomena can be used to explain the fact that the pH of maximum grade increased with increasing oleate addition.

Jan 1, 1999

By Misra V. N

Upgrading of a Koolanooka magnetite iron ore sample provided by Kingstream Steel Ltd was investigated using low intensity magnetic separation (LIMS) and reverse flotation. The ore contained 38.6 per cent iron, 37.8 per cent silica, 6.5 per cent magnesia and 0.54 per cent alumina, with the main minerals in the ore being amphibole (42 per cent), magnetite (39 per cent) and quartz (14 per cent). The concentrate obtained after low intensity magnetic separation contained 66.6 per cent iron and 6.34 per cent silica with an iron recovery of 72 per cent. This concentrate was further treated by reverse flotation to increase the iron content and reduce the silica content to meet the requirements for direct reduction iron (DRI) feed grade.

Jan 1, 1999

By Don Rose

Steel-fiber-reinforced-shotcrete (SFRS) methods of testing and the wording of specifications vary from country to country. In the USA ASTM C1018 is widely used. The Canadians have taken a close look at C1018 and point out that exact determination of the first crack is very subjective, and they propose a method of design that eliminates this variable. The Europeans (EFNARC) have taken the principles of testing a step further than ASTM C1018, and have added a new step in measuring the effectiveness of SFRS. EFNARC uses an "energy absorption" of a plate loaded in its center, in addition to the principles of C1018. The principles of SFRS design are also used in Japan, Norway and elsewhere.

Jan 1, 1999

By Milorad Cirkovic

Kinetics of copper concentrate oxidation in roasting processes in a fluidized bed reactor has been studied at temperatures between 600°C and 720°C using particles of 0.038 to 2.5 mm in average size. The analysis of composition of samples has been done by chemical methods. Phase composition has been determined by Siemens X-ray equipment with Cu anticathode and Ni filters at a voltage of 40 kV and a current of 18 mA. The content of sulphur has decreased from 33.23 to 19.02 mass percent with the increase of temperature, but the content of Fe304 has increased from 0.15 to 17.14 mass percent. The new mechanism of copper concentrate oxidation in a fluidized bed reactor is proposed in this study. It has been shown from the mathematical model that the velocity of oxidation of copper concentrate between 600°C and 720°C is virtually controlled by the rate of diffusion of 02 through the layer of reaction product.

Jan 1, 1999

By V. T. Vacariu, P. D. Georgescu, N. Tomus

To assess the potential for radioactive pollution unique to the environmental conditions of the Bacau phosphogypsum waste dump, surface samples were taken, drillings were performed on the entire waste dump's height, and the Ra226 distribution on the height and surface considered to contain a medium content of the radium of 0.57 Bq/gr was studied. Thus, the waste dump's radioactive potential was estimated at 30-40 Ci in equivalent Ra226. Also analyzed was the granulometric composition of the phosphogypsum and the distribution of Ra226 on granulometric orders, which indicated that the radium was concentrated in the very fine fractions. Parameters were set up for the classification by hydrocycloning to obtain a fine class (less than 41 microns) having a radium content of more than 0.9 Bq/gr and a coarse class having less than 0.37 Bq/gr. A chemical process was devised for removal of the radium from the phosphogypsum with the possibility for recovering the contained sulfur.

Jan 1, 1999

By B Whiteley, B Gee

The Northside Storage Tunnel is a TBM driven rock tunnel system designed to collect and store sewage from four major storm overflow points along the existing Northern Suburbs Ocean Outfall Sewer. At present, sewage overflows during wet weather are the main source of pollution for Sydney Harbour. The tunnel system comprises a 16 km long by 3.8 m to 6.5 m diameter tunnel from Lane Cove to the North Head Sewage Treatment Plant and a 4 km long by 6.3 m diameter branch tunnel from West Chatswood. The tunnel will have a typical rock cover of about 50 m to 150 m. Most of the tunnel alignment is contained within the Hawkesbury Sandstone Formation which is generally an excellent tunnelling stratum, and offers few geotechnical constraints. However, the tunnel is required to pass beneath incised palaeochannels at Middle Harbour and Manly with each palaeochannel containing about 70 m of sediment.Innovative geotechnical and geophysical investigations were undertaken to examine the tunnel route and characterise the rock beneath the palaeochannels. These investigations have located zones of poor quality rock beneath one palaeochannel in particular, suggesting significant stress relief had taken place in the rock at times of lower sealevel producing structural features indicative of valley bulging. This paper presents the geotechnical model developed for the tunnel, and the models and constraints for tunnelling beneath the palaeochannels.

Jan 1, 1999

By S. Veeramasuneni

The recent nonequilibrium electrophoretic mobility measurements by laser-Doppler electrophoresis coupled with the stability and prevalence of collector colloids in soluble-salt flotation systems suggest that the selective flotation of alkali halides is due to the adsorption of oppositely charged collector colloids by heterocoagulation. Previously reported flotation results confirm this surface charge/collector colloid adsorption model. These results also indicate that the sign of the surface charge has a significant effect on the extent of particle dispersion/aggregation. In this regard, the nature of such particle interaction forces at high ionic strengths are examined to improve our understanding of these systems. Atomic force microscopy (AFM) is now being used to directly measure the interaction forces responsible for the stability of these alkali halide aggregates observed in optical microscopy studies. Results from this study indicate that, while repulsive hydration forces exist between similarly charged hydrophilic particles, attractive forces exist between oppositely charged hydrophilic particles in high ionic strength solutions.

Jan 1, 1999

By C. A. Rowland

Introduction Comminution efficiency, as measured by relating circuit performance to the consumption of energy and the time and money required, can be determined by the following comparisons: Theoretical efficiency: The theoretical efficiency is the actual energy consumed in a comminution machine compared to the theoretical energy required to perform the size reduction. Operating efficiency: The operating efficiency compares the operating work index of a comminution machine to the Bond work index of the ore, as determined from bench-scale crushing and grindability tests or pilot-plant tests. Economic efficiency: The economic efficiency is comparing income from production to predicted income. Key words: Comminution, Bond work index, Grinding, Crushing, Ball mills, Rod Mills. Theoretical efficiency In their book Process Engineering of Size Reduction - Ball Milling, Austin, Klimpel and Luckie (1984) stated that, "We have tried throughout this book to avoid the use of the term grinding efficiency because the degree of conversion of energy to useful size reduction is an ill-defined concept. In addition, the only efficiency, which is of real interest, is the meeting of product specifications at the minimum cost." The National Materials Advisory Board, National Re¬search Council (1981), in the abstract of a report titled "Comminution and Energy Consumption" stated that, "Up to 99% of the energy consumed in grinding these ores may be expended in the movement of machinery, with noise and heat the undesirable byproducts, thus leaving only 1% of the energy available for size reduction. Coupled with this is evidence that many of today's crushing and grinding techniques not only are antiquated but have little or no scientific base of understanding." Throughout the past 50-plus years, grinding efficiency has been referred to as being from 1 % to 10%. The measurable basis for these observations is difficult to establish, but they appear to be based on production performance compared to theoretical energy requirements for the work done. The theoretical energy requirements were determined from the energy required to break a single particle or a thin layer of monosized particles by compression or by a single impact from an impact-testing device. King, Tavaras and Middlemiss (1997), in a paper titled "Establishing the energy efficiency of a ball mill" described such a test. These batch single-breakage tests generally do not duplicate the continuous-breakage process in the comminution machinery used in ore concentrators. Operating efficiency The currently available crushers and grinding mills are fed at a controlled continuous flow rate, and they impart the breakage pattern needed to produce the desired size reduc¬tion. While theoretically inefficient, they are the most practical comminution machines available. The operation of this machinery is relatively simple and can be controlled with available control systems. The essential factors in determining the operating efficiency of comminution machines are energy, as consumed in the machinery, and the required energy, as determined from test work. Bond work indices, obtained from bench-scale or pilot-plant crushability and grindability tests are used in the following Bond equation (Bond, 1960) to determine the energy required to produce the required size reduction

Jan 1, 1999

By Kenneth L. Nash

The control of solubility of waste actinide ions, by conversion to highly insoluble mineral phases has been demonstrated in the laboratory. Actinide metal ions are removed from neutral pH solutions by a combined ion exchange-decomposition-mineralization process based on the application of the naturally-occurring hydrolytically unstable.polyphosphate organic compound phytic acid.

Jan 1, 1999

By Iwao Iwasaki

Since the oil crises in the 1970s, the mining industry in the developed countries has faced strong competition from developing countries. In order for the North American iron ore industry to remain competitive with high-grade overseas sources, research on low-cost beneficiation methods that ensure high-quality and uniform-quality products must be maintained in order to prepare for ever-tightening specifications on iron making raw materials for blast furnaces and also for the future iron- and steelmaking processes that can directly utilize finely ground concentrates.

Jan 1, 1999

By M. Misra, J. Nanor

The precipitation and removal of arsenic from process waters can be accomplished with addition of lanthanum chloride alone or in conjunction with ferric sulfate. The long term stability of these corresponding precipitated compounds is critical from the disposal stand-point. In this paper the characterization of ferric, lanthanum and lanthanum-ferric arsenate compounds formed at room temperature in acidic and alkaline pH is presented. The characterization techniques used included zeta potential, XRD and SEM. Zeta potential measurements of ferric and lanthanum hydroxides in the presence of arsenate indicate that oxyanions of arsenate are chemically adsorbed onto the positively charged surfaces of these hydroxides. In alkaline pH there is desorption of arsenate species from the ferric hydroxide surface, hence the product is thought to be unstable. On the contrary, lanthanum arsenate is stable in alkaline pH. XRD patterns show that the ferric arsenate formed in acidic and alkaline pH is amorphous, whereas lanthanum arsenate and lanthanum-ferric arsenate formed in acidic and alkaline pH are crystalline.

Jan 1, 1999

By G Munro

he Melbourne City Link project will complete a missing link between two existing major freeways in the Melbourne road network, providing a much needed bypass of the Central Business District for through traffic. The project, which is being financed under a BOOT arrangement with the Victorian State Government, involves the upgrading of significant stretches of existing freeway and the construction of new sections involving viaducts and tunnels. The tunnel sections, which are the focus of this paper, are beneath residential and business areas, the Yarra River, the Royal Botanic Gardens and significant sporting facilities where surface construction would be either impossible or unacceptable (reference Figure 1). The shorter, 1.62 km west bound Domain tunnel comprises two cut and cover sections through Olympic Park then the Yarra River, the driven section of 0.68 km length and exits through a common cut and cover section with the east bound tunnel under St Kilda Road and Sturt Street. The longer 3.76 km east bound tunnel commences at the common portal, through cut and cover under St Kilda Road then 2.86 km of driven section before exiting at a cut and cover section at Burnley. The longer Burnley tunnel has an access and ventilation shaft at approximately its mid point.

Jan 1, 1999

By Alireza Zakeri

To evaluate the behavior of minor elements in the copper smelting process, activities of silver, selenium and tellurium at minor concentration were determined at 1473 K within the miscibility gap of the Cu-S-Me (Me = Ag, Se, Te) and Cu-Fe-S-Me systems varied in Fe/Cu ratio. Phase relations between the immiscible metal and matte phases in the foregoing systems were first established by a quenching technique at 1473 K to supplement the activity measurement data. A Knudsen-effusion mass spectrometer, capable of handling complex gaseous systems and relatively small vapor pressures, was adopted for activity determination. Using a multiple Knudsen-cell, the ion intensity of minor element in the sample under study was measured simultaneously with that in a reference sample. Activity was obtained from the ratio between the measured ion intensities as well as the known activity value of the minor element in the reference sample. Limiting activity coefficients of the minor elements were correlated with composition of the matte. Based on the experimental results, the vaporization behavior of the minor elements has been discussed.

Jan 1, 1999

By Lynn I. Kelley

Industrial-mineral production contributes on the order of CDN$1.5 billion per year to the economy of Saskatchewan, Canada. Potash is the primary industrial mineral produced in the province, followed by aggregate, sodium sulphate, salt, potassium sulphate, peat, clays, silica sand, calcium-chloride brine, and "clinker." Potentially economic deposits of kaolin, diamond, and building stone are under evaluation. All of the major deposits of commodities discussed here are located south of lat 56°30'N. Most of the locations are presented on Figure 1 POTASH Saskatchewan supplies approximately 30% of the world's demand for potash. Eight conventional underground mines and two solution mines produced an all-time high of more than 13 million metric tonnes of potash (KC1) (8 million tonnes K2O equivalent) in 1997, valued at over CDN$1.4 billion. All of the mines exploit the middle Devonian Prairie Evaporite. The four potash-bearing members of the Prairie Evaporite underlie much of southern Saskatchewan and extend southward into North Dakota and Montana and east- ward into Manitoba (Fig. 2). Halite and anhydrite separate the potassic members. The evaporite beds locally are interrupted by solution structures (anomalous ground). Some of the structures may be related to deep-seated tectonic features.

Jan 1, 1999

Simulation models were developed at the Julius kruttschnitt Mineral Research Centre to provide accurate estimates of power consumption for a wide range of equipment. With the models, a range of circuits and operating conditions can be compared by simulation for a particular ore type. Accurate models of classification allow for the interaction between classifier efficiency and target product size (e.g., P80 or percent passing 150 /an) to be considered. This paper considers a range of circuit types and overall energy efficiency in the context of case studies where different circuit types were treating similar ore types.

Jan 1, 1999

By R. K. Rajamani, A. Datta

An appropriate scale-up methodology is very useful for ball mill design and optimization of the grinding circuit. To date, the scale-up is based on the selection and breakage function model using lab mill data. However, a major drawback of that approach is that the charge motion in a lab mill is vastly different from that in a large industrial mill. Therefore, in the methodology proposed here, first the energy of individual collision in the mill is computed employing the discrete element method (DEM). Then the breakage of particles as a function of collision energy is studied in a separate experiment. Together, this information constitutes what is known as collision energy based population balance model. The appropriateness of this model is shown for different batch grinding mills.

Jan 1, 1999

By J. Partinen

Drying is a unit process which has numerous applications in metallurgical process industry. Kumera Technology Center, being a worldwide equipment and process supplier, has developed sophisticated solutions for both direct and indirect drying. In conventional direct drum drying, the energy is taken from combustion of fossil fuels, requiring energy input and emitting considerable amount of off gases. In modem copper smelters, thermal energy from the off gases is recovered in waste heat boilers making the steam available. Using that steam as the energy source for concentrate drying, the total volume of off gases can be considerably reduced and releasing of harmful combustion gases into the atmosphere can be avoided. Kumera Technology Center has recently developed and promotes a new steam drying process for drying of copper concentrates. In the development of the new dryer, Kumera's approach has been to combine the best properties of both the steam dryers and the drum dryers. In the design special attention has been paid to overcome problems of excessive wear and clogging and to reduce the required maintenance operations. In this paper the environmental issues and energy consumption related to both direct and indirect drying processes are discussed. The estimated operation costs and emission levels are compared, based on calculations and the data collected from industry. Finally, the development project of the Kumera Steam Dryer is briefly reviewed

Jan 1, 1999

Inpit tailings disposal has been undertaken at a number of mining sites within Australia. This paper presents a brief history of the experience of inpit tailings disposal at the Marymia Gold Operation in Western Australia, including geotechnical aspects of the design. Regular monitoring of the inpit tailings disposal into the K1SE Pit at Marymia has allowed the operators of the mine to assess the performance of the tailings storage against its predicted performance during the design phase. Results of this monitoring indicated that the predicted performance was exceeded and the results have been incorporated into the design of another large inpit tailings disposal, the K1 Pit. Monitoring of tailings disposal to both the K1SE Pit and K1 Pit has allowed the mine operator to make substantial savings from inpit tailings storage when compared with above ground tailings storage facilities. The inpit method of tailings disposal at Marymia has proven to be acceptable from an environmental perspective by reducing the water resource requirements of the project, backfilling pits, which would otherwise collapse with time and eliminating the need for disturbing additional areas of mining leases, which usually accompanies construction of above ground tailings storage facilities.

Jan 1, 1999

By W. J. Schlitt

The Namibian Copper Joint Venture has been formed to undertake development of the Haib copper deposit, one of the largest undeveloped copper resources in Africa. The development programme includes extensive hydrometallurgical testwork that is being managed by Kvaerner Metals (formerly Davy International).Various parts of the programme have been contracted to four third-party laboratories. The testwork involves sample selection and characterization, amenability tests, and a parametric study on the leaching variables. All portions of the programme are described and the results a represented. The ores selected for testing are quartz feldspar porphyries. The amenability tests include ?mapping? studies to assess optimum leach conditions, tests at high oxidation potentials, oxidation with various bacterial strains, and heap leach modelling. The parametric programme includes such variables as ore grade, leach temperature, crush size, pH, and ferric iron content of the lixiviant. Testing was done on both whole ore and concentrate. Results show that bacterial leaching is effective and that ore grade and temperature are key variables. Crush size and pH have less impact on copper extraction. For mid-grade ore, about 0.25 per cent copper, extraction is projected to reach 50 per cent after two years when heap leaching tertiary crushed ore at 60°C and pH 1.5. The heap leach operation would fit well with the proposed roast-leach operation used to treat higher grade ores. The latter could supply the low cost heat and acid needed in the heap leach.

Jan 1, 1999

By M. M. Botz

Cyanidation tailings which are disposed in a surface impoundment experience a loss of cyanide due to natural degradation, frequently reducing the cyanide concentration to very low levels. Quantifying cyanide losses in terms of pond geometry, local weather conditions and feed solution chemistry has been largely empirical though in many cases mining operations rely on surface impoundments to reduce cyanide to below an internally regulated concentration or an effluent limitation. To permit a more quantitative evaluation of cyanide losses in an impoundment, a computer simulation was developed to estimate the losses of free, WAD and total cyanide due to dissociation, photolysis and volatilization. Results of the model are compared against data collected for a North American tailings impoundment during 1998.

Jan 1, 1999