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By Hu Long

Pyrite, as the host mineral in refractory gold ores and concentrates, has been treated by pressure oxidation in sulfuric acid solutions at temperatures above 180°C to liberate gold prior to cyanidation since the 1980's. However, no data is available on the kinetics of pyrite during acid pressure oxidation over the temperature range of 180 to 230°C which is the range employed by most commercial plants. The dissolution of pyrite (FeS,) in sulfuric acid solution under oxygen pressure was investigated at temperatures ranging from 170 to 230°C. The effects of temperature, particle size, agitation speed, oxygen partial pressure, and pulp density were evaluated. The effects of foreign ion addition and the concentration of sulfuric acid were also examined. The apparent activation energy was estimated to be 42.6 kJ/mol in the temperature range 170 to 230°C. The reaction orders with respect to particle size and oxygen partial pressure were found to be -1.5 and 0.5 at 210°C, respectively. Experimental evidence suggests that the kinetics are limited by the surface chemical reaction initially, and then also to some extent by the diffusion of ferrous ions away from the particle surface.

Jan 1, 1999

By N. Choi, W. D. Cho

Distribution coefficients of gold and silver between matte and slag during the pyrometallurgical treatment of nickel-copper sulfide concentrates were evaluated as a function of matte and slag compositions in the temperature range of 1,250oC to 1,300oC. It was observed that the composition of the matte phase, including matte grade and copper content in the matte, significantly affected the distribution behavior of gold and silver in the matte-slag system. Both gold and silver preferentially concentrated in the matte phase as the matte grade increased With increasing temperature and copper content in the matte, the distribution coefficients of silver increased, while the gold distribution coefficients decreased. It was also, found that slag additives such as CaO, MgO, and A12O3 caused a significant decrease in the solubility of both gold and silver in silica-saturated iron silicate slag. An activity coefficient of gold in matte was derived from the experimenta1 results.

Jan 1, 1999

By Tsuneyoshi Funazaki, Takayoshi Nakamura, Keizo Miki, Takashi Imaishi

The underground portion (about 10 km) of Tokyo Wan Aqua-Line consists of eight shield tunnels connected with Kawasaki Man-Made Island in between, at four underground locations. The connection work had to fulfill strict precision and safety requirements in the ground about 60 m below soft seabed, but was completed successfully in May 1997. This report describes the connection work in detail, featuring the method of investigating shield machines’ relative positions, ground freezing method and connection mechanism and procedures. It also mentions the present state of Tokyo Wan Aqua-Line that was put in service on December 18, 1997.

Jan 1, 1999

By O. C. Rojas

Improvements and modifications on lay out and process, from 1997 till 1998, are presented. Based on a Teniente Converter, started up 1993, a Strategic Development Plan was structured to increase the production efficiency and comply with the enviromental regulations, too. It considered the oxygen supplies to the Teniente Converter and Peirce Smith converters; reverberatory furnace shut down as a smelting unit; and the Teniente converter slag treatment through a combined process between a Slag Settler furnace and flotation. Also it included the off-gas handling and treatment.

Jan 1, 1999

By R. K. Hill

The Hidalgo Smelter successfully reduced operating costs by 25% compared to the previous two years through a focused holistic approach to development of its entire workforce. The first phase involved basic team training skills for natural work teams. The second phase provided leadership training via breakthrough education to 40 of the smelter leader-both hourly and salaried. The third phase stretched out the teams training to include rewards for performance that resulted in hourly teams converting to salaried status-part of a company wide initiative. The fourth phase saw 1998 become the "Year of Safe Cost Reduction" where 7 breakthrough projects focused on different areas of expenditure. Implementation of lean manufacturing as a tool for teams to truly get their arms around what they controlled, introduced accountability and responsibility for operating results at the team level. This will allow the release of experienced supervisors from this role, to a pool of technical expertise, where our future breakthroughs will be designed and implemented.

Jan 1, 1999

By Garland Likins

Where soil conditions are favorable, augercast piles have significant economic advantages, but they also have some uncertainty due to the in construction methods. To confirm structural integrity, static testing can be performed on a small sample of piles. Other Non-Destructive Evaluation methods like Pulse Echo are frequently specified for a large percentage of the remaining production piles. However, such NDE methods require testing the pile after the grout/concrete has hardened. If problems are found, then the repair or replacement can be relatively expensive. The confidence in the quality of these piles can be improved by automatically monitoring the grout pumped as a function of depth during the grouting phase of installation. If a low grout volume is detected, the pile can be redrilled and regrouted immediately while the piling rig is still in place and the grout still fluid. This considerably reduces remedial costs. To be effective, such installation monitors must accurately determine both grout volume and depth during installation and be rugged simple to operate. Such an equipment can be of great help to the installation crews. The assurance gained may reduce the need for subsequent NDE tests. The quality of inspection of driven piles depends heavily on the inspection personnel. While inspection is critical in a good installation, it is sometimes assigned a low priority. Inspection personnel in many cases are technicians with little pile experience. They may not understand the project needs or even how the pile driving equipment works. The task is often monotonous and any distraction makes accurate record keeping difficult. In some cases inspection is totally ignored for lack of qualified personnel. Electronic systems can automatically and accurately monitor driven pile installations and include documentation of certain hammer performance parameters. This paper describes equipment available and routinely in use for automated monitoring of both augercast and driven piles and demonstrates applications on typical construction sites. The paper also discusses benefits and limitations of the alternative NDE tests. KEYWORDS: Augercast Piles, Piles, Installation Monitoring, Pulse Echo Method, Integrity Testing

Jan 1, 1999

By Leslie Burnside

Homestake Mining Co. set out to complete final reclamation at a former open-pit gold mine in west central Nevada. The goal was to exceed regulatory standards by satisfying the company's own high corporate standards for successful reclamation. Homestake's completion requirements challenged available technology due to the unsuitability of heap material as a growth medium, the harsh environmental conditions of the site and the region's lack of native growth medium. Accomplishing these goals required enlisting a multidisciplinary project team to develop, test and implement appropriate and cost-effective revegetation alternatives.

Jan 1, 1999

By E. M. R. Santos

Acid mine drainage (AMD) is a serious environmental problem in mining activities. Prediction is the first step for evaluate the potential of acid generation and there are some possible methods to estimate it. They are described as static tests, which examine the balance between acid producing and acid consuming materials, and kinetic tests, which attempt to predict drainage quality over time. Static methods are very simple and give a qualitative classification of the ores based on their potential to generate acid drainage. The characterization of ores to determine their acid producing potential is vital for the prevention of long term environmental liabilities. Laboratory tests were conducted under different methodologies to predict the acid producing potential of sulphide overburden, ore materials and tailings from a deposit of copper ore.

Jan 1, 1999

By D. A. Robbins

The application of remote sensing for environmental measurements is already being utilized. Aircraft mounted imaging spectroscopy has been utilized to evaluate areas of historical mining operations as well as active mine sites. To the extent that remote sensing can provide more sensitive, cost effective, and timely monitoring potential, the technology is of interest to the industry. Questions remain about the application and validation of the data and the availability of the technology in the private sector. This presentation will discuss some of the potential uses, benefits, and concerns related to remote sensing and efforts to monitor the technology's development.

Jan 1, 1999

By H. Savasci, G. Yarim, J. S. Chung

As part of ongoing deep-ocean mining research, hydraulic transport systems as well as status of deep-ocean mining systems are reviewed in the aspects of manganese nodules and crusts from 8006,000-m depth. The emphasis of the investigation of hydraulic transport is placed on the shape effect of particles on the pressure gradients and flowrates. Series of tests are being conducted to study the lift characteristics of a 2-phasevertically upward hydraulic transport of 2 types of small solid particles in a PVC pipe of 1-in (2.54 cm) diameter: irregular-shaped silica sands and equivalent spherical glass beads. Pressure drops and mass as well asvolumetric flow rates were measured by electromagnetic(EM) flowmeter and mass flowmeter. The particle sizes used are 8-10 mesh. The results in turbulent flow range of 101045Re show that pressure gradients or friction factors are smaller for the spherical beads than the sands. The larger the concentration of the particles are, the larger the pressure gradients become. The larger the particle concentration is, the less the effect of particle shape on pressure gradients becomes. The shape effect is greater for the minimum particle transport velocities than for the settling velocities.

Jan 1, 1999

By G. Gerbeth, Y. Gelfgat, A. Cramer, A. Bojarevics

The production of highly porous metallic substrates requires an effective and well controlled production of metallic fibres with diameters in the range of 50 to 200 microns. The melt extraction, where a quickly rotating wheel extracts fibres directly out of the inductively heated melt, is a promising technology for that purpose. The main limitations of this process are due to turbulence within the melt and a wavy motion on the surface. Both effects give rise to strong and time dependent deformation of the melt surface which, in turn, causes non-stationary conditions of the contact zone between the extraction wheel and the melt. In the patent literature many examples can be found which try to overcome these problems by submersing mechanical parts directly into, or placing them at least in close vicinity to the melt, aiming at a stabilisation of that contact region. Even made of heat resistant ceramics they suffer from corrosion or cracks and do not work reliable at all. The present work describes a non invasive control mechanism by means of a magnetic field. Model experiments were carried out to study the calm down of the turbulent surface of a inductively stirred melt. The stabilisation of the melt surface has been demonstrated in practise by the installation of a solenoid at a working extraction facility under rough industrial conditions like a powerful induction heating and vacuum.

Jan 1, 1999

By Guerry H. McCullen, Bruno Despujol

Quartz and phosphate grains from concentrates and ores from Atlantic Coastal Plain sediments often are wholly or partially coated by humates. Coatings were studied in situ using infrared microscopy, by transmission Fourier transform infrared of extracts, and scanning electron microscopy. The 14C age of the coatings is about 20,000 years, much younger than the mineral substrates. Coatings on double flotation concentrates indicate that the conditioning pH may be too low, allowing coated quartz grains to follow phosphate grains through beneficiation. Organic matter from coatings may contribute to processing problems as well as affect final product quality.

Jan 1, 1999

By Tor Lindstad

Specific C02-emissions are given for the production of silicon-metal, ferrosilicon, ferromanganese and silicomanganese. Emissions taken into account come from reduction materials, from coke production and generation of electric energy. C02-emissions can be abated by direct and by indirect methods. A direct method is to replace fossil carbon as reduction material wholly or partially by endogenous carbon (biocarbon, charcoal). Another possibility is to produce metals by electrolysis instead of the present electric smelting furnace. Indirectly CO2-emissions can be reduced by energy recovery, thus saving coal, oil or natural gas for heat generation. Some reduction in global C02-emissions can be obtained by giving credit for the use of silica dust partially replacing cement in concrete. In addition to give an overview of possible methods, costs will be discussed.

Jan 1, 1999

By K Le Bron

Fatalities that occurred because of rock falls in off-reef excavations (excluding shafts) over the last three years range between ten per cent and 20 per cent of the total number of fatalities that have occurred due to rock falls in the South African mining industry. These rock falls, mostly exacerbated by blasting practices, occur because of failure on discontinuities within the rock mass. Among other reasons of their occurrence is insufficient support installation or the incorrect assessment of rock mass conditions. This report presents qualitative analysis intended to outline rock stability conditions in tunnels subjected to dynamic loading. Seismic waves including those created by firing an explosive charge in tunnel rocks are considered. The rock behaviour is monitored using geophones and extensometers variably installed to record the near and far effects of roof bolt support units on a dynamically loaded rock. The paper discusses the results of field investigations.

Jan 1, 1999

By T. Tamagawa

A gaseous chlorination process for hydrometallurgical treatment of a chalcopyrite concentrate was investigated. The overall process is visualized to consist of low temperature chlorination-selective oxidation, followed by aqueous chloride leaching and SX-EW for producing electrolytic copper elemental sulfur and ferric oxide. In this article, the chlorination phase of the processes is described. Initially, the chlorination behavior of chalcopyrite-concentrate micro-pellets was investigated using a small batch-type fluidized bed reactor. The optimum conditions thereby established was used in continuous chlorination tests. The chlorinated products thus prepared were used in the selective oxidation phase of the investigation.

Jan 1, 1999

By K. Terhaar

The objective was to determine operating protocols for a lead and silver column flotation cleaner, being considered for installation at Sunshine Mining & Refining Co.'s Kellogg mill in Northern Idaho. In this column, tetrahedrite and galena were floated, and pyrite and other gangue minerals, including siderite and silica, were depressed. The procedure was to develop a dynamic simulation using a linear transfer function approach. The transfer function related cause and effect variables such as the influence of collector and depressant dosages on recovery and grades. Bench-scale flotation tests followed by pilot column testing provided the data used to develop a linear transfer function. The transfer function was derived using a spreadsheet. This model was applied to simulate how the flotation column could be made to respond to disturbances in feed grade. The results were that xanthate, zinc sulfate, and sodium cyanide were found to be suitable controls for grade and recovery. Simulations showed the best sequence of manipulations of these reagents, and these sequences were useful for future operator training. The conclusion was that linear transfer functions were able to simulate lead and silver recovery, develop scenarios for operator training, and provide a foundation for future on-line control.

Jan 1, 1999

By B. W. Cavender

Capital investments are made for a variety of reasons, ranging from providing incremental capacity at existing operations to developing and implementing new technologies intended to radically improve a company's capabilities. These projects generate very different business opportunities and create value in distinctive ways. For incremental improvements, the capital budgeting process assures at least a loose fit between short-term goals and readily available resources. However, the criteria used to evaluate capital projects often prevent a company from committing to more aggressive goals, which lie beyond the firm's current abilities or resources. Such projects may not have clearly identifiable future cash flows, and the degree of interaction with other projects and the nature of the risk incurred may be difficult to estimate. Additionally, by focusing only on quantifiable benefits, the budgeting process often fails to recognize "soft" improvements such as increased operating flexibility or new knowledge generated by such projects. By rejecting these projects, the capital budgeting process may actually harm the company's future competitive position.

Jan 1, 1999

By B. Q. Li, H. C. de Groh, X. Lu

"A fully 3-D, transient finite element model is developed to represent the magnetic damping effects on complex fluid flow, heat transfer and electromagnetic field distributions in a metallic melt. The model development is based on our in-house finite element code for the fluid flow, heat transfer and electromagnetic field calculations. The numerical model is tested against numerical and experimental results for water as reported in literature. Various numerical simulations are carried out for the melt convection and temperature distribution with and without the presence of a transverse magnetic field. Numerical results show that magnetic damping can be effectively applied to stabilize melt flow, reduce turbulence and flow levels in the melt and over a certain threshold value a higher magnetic field resulted in a greater reduction in velocity. Also, for the study of melt flow instability, a long enough running time is needed to ensure the final fluid flow recirculation pattern. Moreover, numerical results suggest that there seems to exist a threshold value of applied magnetic field, above which magnetic damping becomes possible and below which the convection in the melt is actually enhanced.1. INTRODUCTIONThe imposition of a DC magnetic field on a moving, electrically conducting fluid, such as molten metal or semiconductor melt, produces an opposing Lorentz force that results in a reduction of flow velocity in the liquid. This effect has been explored in both the semiconductor and metals industries to control natural convection and/or surface tension induced Marangoni convection as well as thermally induced flow instability during solidification processing of these melts [1-6]. A mathematical model can be of great use in developing both fundamental understanding of the fluid-magnetic field interactions in these magnetically-assisted processing systems and basic guidelines for process design, control and optimization.This paper presents a 3-D mathematical model for magnetically damped fluid flow and heat transfer in a melt cavity, which is useful for interpreting results for unidirectional solidification processes at slow solidification rate, and some preliminary results concerning the magnetic damping effects on the flow instability in the melt. The model development is based on the finite element solution of the Navier-Stokes equations, energy equations and equations for induced electric field. The model is tested against reported results and is then applied to study the fluid flow and thermal distribution in the metallic melt with and without an external magnetic field."

Jan 1, 1999

By A Madera, R Watt

The Tampakan deposit is a strongly telescoped high-sulphidation-epithermal/ porphyry deposit pair which is hosted by a sequence of probable Pliocene age subaerial andesite flows. These host units lie on the western flank of a deeply dissected andesitic stratovolcano within the northernmost portion of the Sangihe Arc in southern Mindanao. The deposit was discovered by WMC geologists in 1992 and is currently undergoing resource evaluation. Preliminary resource estimations indicate a total inferred metal content of 12 million tonnes of copper metal and 16 million ounces of gold. Using a 0.2 per cent Cu cut-off grade, the deposit has a current mineral resource of approximately 2.5 billion tonnes with an estimated grade of 0.48 per cent copper. At a higher cut-off grade of 0.5 per cent Cu, the mineral resource is approximately 900 million tonnes with an estimated grade of 0.75 per cent copper. Mineralisation is open both to the west and at depth. The Tampakan district is centrally located with respect to a 100 km wide zone of left-lateral strike-slip deformation represented by the trans-Mindanao Cotabato Fault Zone. The district is transected by several WNW-striking wrench faults which represent strands of the regional Cotabato Fault Zone. High-sulphidation epithermal mineralisation within the Tampakan deposit is strongly controlled by NNE-trending faults which lie along a dilational orientation within the Pliocene stress field associated with the Cotabato strike-slip fault zone. The mineralisation is broadly hosted by a gently-dipping, tabular zone of partial to massive silicification which displays multi-phase brecciation, acid-leaching, related vuggy porosity and which is developed within a district-scale advanced-argillic and argillic lithocap exceeding 90 km 2 in area. High-sulphidation epithermal mineralisation is associated with a silica-pyrophyllite-dickite-alunite-diaspore¦sericite alteration assemblage which is transitional downward to sericite-chlorite alteration and relict potassic biotite-chlorite-magnetite-anhydrite alteration associated with pervasively developed but weakly mineralised porphyry quartz stockwork veins. The high-sulphidation mineralisation is dominated by disseminated, vein and vug-filling enargite-bornite-digenite-chalcocite-covellite ¦ molybdenite which has overprinted an earlier phase of porphyry copper stockwork veins associated with high-level porphyritic hornblende diorite stocks. The distribution of high-sulphidation alteration and mineralisation reflects strong stratigraphic and structural controls. The high-sulphidation mineralisation covers a surface area of approximately 1.6 km by 2.0 km and forms a tabular, flat-lying to gently-dipping body between 200 and 500 metres thick. It is intersected at RL-1200 m ASL (at surface) in the northern portion of the deposit and extends down to RL-600 m ASL at the southern end. The deposit has been diamond-drill tested to a depth of 400 - 500 metres where low-grade chalcopyrite-bornite-pyrite mineralisation is hosted by pervasive quartz stockwork veins. This deep-level mineralisation represents the outer portion of a porphyry Cu system hosted by both andesite flows and the uppermost portions of high-level hornblende diorite stocks. Deep drilling to test for higher tenor porphyry Cu mineralisation is planned.

Jan 1, 1999

By David J. McDougall

"The production of pig iron, wrought iron bars and castings in Quebec during the 18th and 19th centuries has been so closely identified by historians with Les Forges du St. Maurice on the St. Maurice River a few miles north of Trois Rivieres (Three Rivers), that one is sometimes left with the impression that it was the only iron works that ever operated in the province. There were however, about twelve others, one of which was so completely re-built that it should probably be considered as a separate entity. All but two were constructed after the midpoint of the 1800s, coinciding with the growing Canadian demand for ""charcoal pig"" for railway car wheels and castings for industry, and about half of them were technically, if not economically, successful. The misconception about Les Forges du St. Maurice may have come about either because of its long history of somewhat less than continuous production over a century and a half, or a tendency of Quebec historians to concentrate on events in the French-Canadian milieu, but whatever the reason, the other Quebec iron works have been generally ignored. All but one of the Quebec blast furnaces could be described as ""pre-industrial"" with capacities ranging between three and ten tons per day, the exception being the Radnor furnace built in 1892 with a maximum production of about 35 tons per day and an alleged capacity of 50 tons per day. Until a railway network was completed in the 1880s, the location of all the Quebec iron works except the Grantham Iron works was dictated by close proximity to adequate ore reserves because horse transport was of little use beyond a ten-mile radius. The other essentials of forest resources (mainly soft woods) for charcoal, limestone for flux and water power, were generally available except within a few miles on either side of the St. Lawrence River. Among the dozen iron works established in Quebec between 1732 and 1880, seven used bog iron ore in charcoal-fired furnaces. Five of these, including Les Forges du St. Maurice, were located on or near the St. Maurice River which enters the St. Lawrence River from the north, and two, the St. Francis Forges and the Grantham Iron works were on or near the St. Francis River which enters the St. Lawrence from the south. In a general way deposits of bog iron ore in the St. Lawrence lowlands of Quebec were contained within the limits of the post-glacial Champlain Sea, with many clustered along the flanks of the St. Narcisse recessional moraine which is crossed by the St. Maurice and other near-by streams, and the Drummondville recessional moraine which is crossed by the St. Francis River."

Jan 1, 1999