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By K. Murayama, M. Kawakami, T. Takenaka, S. Yokoyama

"Cokes play an important role of spacer in blast furnace. However, they degenerate during Boudouard reaction. Blast furnace cokes are reacted with pure C02 at I 072 to 1673 K. Reaction rate was obtained by the weight change of spherical specimen. The specimen after reaction was examined by microscopic observation. The reaction rate increased with temperature and was expressed by two Arrhenius type lines. The activation energy was 126 KJ/mol at higher temperature than 13 73 K and 202 KJ/mol at lower temperature range. At the higher temperature range, the reaction proceeded from the surface leaving unreacted core, whereas homogeneously whole inside at lower temperature. The porosity increased from the center to surface at higher temperature, whereas it was almost constant at lower temperature.IntroductionThe cokes have the function of fuel, reductant and spacer to keep gas and liquid flow in the blast furnace. Thus, the reaction mechanism of coke with several gas and the strength after the reaction should be important factor to control the blast furnace operation. The reaction mechanism of coke with C02 has been studied extensively. The rate equations were derived by Gadsby[ I], Ergun[2] and Turkdogan and Vinters[3]. They were compared and discussed by Kobayashi and Omori [ 4]. Effect of crystallization degree on the reaction rate was examined by Kashiwaya and Ishii[5]. Catalytic enhancement effect of ash componets have been clarified by Kashiwaya et. al. [6]. Although degradation of coke in blast furnace has been examined recently[7], however, the degradation of coke after the reaction with C02 has not been well clarified yet. In the present work, the metallurgical coke specimen was heated in N2 and C02 and the reaction mechanism and degradation behavior after the reaction was investigated."

Jan 1, 2000

By W J. Rankin

A study of refined metallic copper and nickel production was carried out using Life Cycle Assessment methodology to estimate the life cycle emissions of greenhouse and acid rain gases for these metals using data derived from the literature. Various processing routes were investigated which included a pyrometallurgical and a hydrometallurgical route for each metal. The effect of a number of process variables, namely ore grade, fuel type for electricity generation and efficiency of generation were also examined in the study. The results of the study, expressed in terms of total (or full cycle) energy consumption, Global Warming Potential (GWP) and Acidification Potential (AP), showed that the hydrometallurgical processes involving solvent extraction and electrowinning had higher energy consumptions and GWPs than the pyrometallurgical processes for both metals. Nickel metal production was shown to be several-fold more energy intensive than copper metal production. The significant effect that falling ore grades have on attempts to meet greenhouse emission targets was also highlighted in the study.

Jan 1, 2000

By J. F. T. Agapito

OCI Wyoming mines two flat-lying trona seams that are 3- to 3.5-m- (10- to 11.5-ft-) thick, about10 m (33 ft) apart and 250-m- (820-ft-) deep at its Big Island Mine in Wyoming. Continuous miners and a yielding-pillar system have contributed to improvements in resource recovery and productivity. The use of yield pillars minimizes the stresses transmitted from the upper to the lower seam. However, yielding must not impact the good, long-term stability needed to prevent subsidence for a large portion of the mine beneath the Green River channel.

Jan 1, 2000

By J. L. González-Chávez, A. Ballester, M. L. Blázquez, F. González

In recent years, the bioleaching of sulfidic raw materials has been of great interest. However, the application of this biotechnology is now very limited for many different complex reasons. The mechanism of the chemical and electrochemical reactions taking part in the process is not well understood. The application of electrochemical techniques is useful in its elucidation. Among the common sulfides, galena has been studied very little with respect to its behavior during bioleaching. Therefore, the electrochemical evolution of massive electrodes of lead sulfide in the presence and absence of' a mixed culture of mesophilic microorganisms was investi¬gated by the application of potentiometry, anodic and ca¬thodic polarization and cyclic voltammetry. The agitation rate, the use of pH control and the composition of the nutrient mediums did not have any significant affects on the oxidation of galena. However, the temperature (25 'to 45 °C), the scan rate (4 to 100 mV/s) and the acid used to adjust the pH were significant variables that influenced sulfide oxidation. There¬fore, the peak (600 to 1,000 mV) corresponding to the oxida¬tion of sulfide ions from the mineral was only detected in the presence of a complexing anion of lead. In the presence of bacteria, the peaks corresponding to galena oxidation de¬creased and, at the same time, new peaks appeared both during the oxidation at -300 mV and during the reduction of the mineral surface at 150 and -300 mV. These signals were more important when the attack time increased. The rest potential of bioleached mineral increased with an increase in leaching time, which was related to the electrochemical transformation of the galena surface.

Jan 1, 2000

By Larry M. Southwick

There is much ongoing work in research and development of new processes for the recovery and recycling of met.a.ls and other materials from various waste and scrap streams. Commercialization of such new technologies requires the bringing together and successful execution of a considerable effort involving a variety of activities. These include process conceptualization, research and development, detailed design and construction, and then plant startup and operation. Processes evolve through all of these steps by engineering due diligence, making objective and critical analyses of results, and troubleshooting processing steps to, hopefully, arrive at a sequence that has the best chance to succeed operationally and economically. After a summary review of the above steps, several processes will be described in more detail that provide mostly successful examples of the above procedures. Finally, some observations will be made on areas that will become critical in the near future to the success of new processes for wastes and residues.

Jan 1, 2000

By Takeo Fujino, Nobuaki Sato, Junichi Hasegawa, Masato Nakazawa, Kohta Yamada

"Tantalum oxide thin films were deposited on quartz substrates by laser ablation of Ta2O5 target using Nd:YAG pulse laser. Deposition-was observed when a laser light energy higher than 200 mJ and its repetition rate higher than 3 Hz. A thin film of 0.1 µm thickness was obtained by the ablation using a laser light of 300 mJ and 6 Hz for 2 sec. The thickness of the film increased with increasing energy, repetition rate and irradiation time of laser. By the SEM observation, it was found that many island-like particles were deposited on quartz substrate forming a thin film. The obtained thin film, which was identified as ? Ta-O by X-ray diffraction, was oxidized to Ta2O5 by the heat treatment in air at I273 K for 3 h.IntroductionTransition metal oxides have a potential to show special characteristics in electrical, magnetic and/or optical properties. When such compounds are fabricated in the form of thin film, the special properties would be improved or new characters would appear in comparison with bulk materials. Tantalum penta-oxide is widely used as a capacitor since Ta2O5 shows high dielectric constants up to high temperatures. The tantalum solid capacitor has been fabricated by the electrical oxidation of sintered Ta metal cylinder followed by MnO2 film coating. However, further improvements, reduction and layered structure formation, are required for compacting the devices. The layered structure of thin films would be applicable for the above requirements. The formation ofTa2O5 film by low pressure CVD1), photo CVD2) and magnetron sputtering3l were reported. The laser ablation -method is one of the most convenient techniques for the deposition of thin films from their compounds, such as oxides. Formation of Ta2O5 film by pulse laser deposition (PLD) method using ArF excimer4), Nd:YAG (533nm)5) and TEA CO2 6 lasers was reported. In these PLD studies, ablation was carried out in relatively high oxygen pressures resulting in formation of Ta2O 5 film. In this paper, the deposition of tantalum oxide thin film by the laser ablation of Ta2O 5 using Nd:YAG pulse laser was examined at a viliety oxygen pressures ranging from 10-8 to 10 Torr. The morphology of the films was also investigated in relation with substrate temperature and oxygen pressure."

Jan 1, 2000

By Daniel Hodouin, Antoine Berton

Mineral processing plants are monitored and controlled using measurements that are usually processed by on-line material balance calculation techniques. However, gross errors, due to sensor biases or failures, may corrupt all the process variable estimates. On-line gross error detection methods are required to ensure efficient mass balance evaluation. In the proposed approach, material imbalances and raw measurement corrections are tested by statistical techniques designed to detect and isolate sensor problems.

Jan 1, 2000

By V S. Svinin, V V. Rybin, V A. Maltsev

In large-scale mining, large-sized intermediate pillars, or block-pillars, are generated on the horizon or between closely located mines. These pillars are mined under high rock pressure that results from the stress concentration zones superposition from closely located working excavations. This problem becomes much more complicated if high tectonic stresses occur in the rock mass inducing a rock-burst risk situation. Mining experience gained in mining seven block-pillars at three Khibiny mines in Russia under the geomechanical situation like that described aboveÆ is discussed in detail. It has been shown how safe mine of block-pillars depends on their width, location relative to significant geological failures and uncaved rocks of the hanging wall, the order of pillar recovery, and application of special measures for rock mass stress relieving. Basing on the analysis of the mining experience and special scientific researches, the basic principles are worked-out for safe block-pillar mining under rock-burst prone conditions.

Jan 1, 2000

By Jerry Demchuk, Allan Flemming, Stephan Day

Luscar Ltd. is currently developing open pit mining plans for the Telkwa Coal Project. Most waste rock is predicted to be non-acid generating but a proportion (less than 20%) is potentially acid generating. The waste management plan includes in-pit and ex-pit disposal of blended and till-capped waste rock, segregation and in-pit encapsulation of strongly potentially acid generating materials, and in-pit underwater disposal of coarse and fine tailings. The paper will present the steps used to design the waste management plan including the development of geochemical design criteria using various tests and theoretical and practical knowledge of waste behaviour.

Jan 1, 2000

By V. B. Achanti, A. W. Khair

This paper deals with the effects of various bit geometric parameters on the failure characteristics of rock material. Improving the rock-cutting efficiency of continuous mining machines has proven to be an interesting research topic during the last few decades. In the current study, an automated rotary rock-cutting simulator, duplicating a continuous miner, was used to study these parameters in the laboratory. The improvement of bit performance in terms of its life, cutting efficiency, dust production and energy consumption has drawn widespread attention. Research has demonstrated that optimizing bit parameters can result in efficient fragmentation of rock. Indiana limestone rock material was used in this study. The bit tip angle, bit tip size, bit spacing, depth of cut and cutting velocity of the rotary drum were varied to investigate the failure characteristics. The cutting pressure, penetrating pressure and the depth of cut were monitored on the simulator during the cutting process. Airborne dust and settled dust were measured for each experiment. Then, the specific airborne dust and specific energy were determined for each type of bit. Triaxial tests were carried out to correlate the failure angle of the rock in the static case to the dynamic cutting process failure. The physical and mechanical properties of the rock were also determined to assess their influence on the wear characteristics of each bit.

Jan 1, 2000

Environmental conflict management approaches and procedures have been used to successfully address and resolve a variety of issues, problems, and conflicts related to the extraction of natural resources. Companies in the mining industry have been involved in a range of controversies over planning, siting, permitting, environmental, and enforcement issues. Through the use of conflict resolution case studies, this paper will present approaches and procedures that can help companies and other involved parties to successfully manage and resolve differences in a mutually acceptable manner.

Jan 1, 2000

By Osvaldo Bascur, Laurent Garrigues, Nouna Kettaneh, Svante Wold

The chemical, oil, semiconductor, mining, and paper and pulp industries, as well as most other modern industries, are rapidly expanding the range of measurements used to characterize raw materials, process steps, intermediates, and final products. In addition, process variables such as temperature, pressure, and flow become more and more numerous, providing extra information on the state of the process. However, no matter how many sensors are added, the underlying sources of variations that drive the process behavior remain constant. On the other hand, the measuring frequency of these data has increased from once a day or once an hour to once, ten, or even hundred times a minute. This gives masses of data that are swelling in both directions (more variables and more observations). These data need to be properly stored, managed, and analyzed to provide diagnostics about the state of the process as well as an understanding of the relationships between different parts of the process and the product properties. Projection methods such as PCA (principal components analysis) and PLS (projection to latent structures) compress process data to informative summaries of the original variables. These can be shown on line, providing an efficient, graphically oriented suite of diagnostics regarding the "health" and performance of the process. The power of these methods is illustrated by two examples of industrial data in the mining industry.

Jan 1, 2000

By D. H. Diering

The paper takes the reader into the depths of a modern ultra-deep South African gold mine and gives a perspective on the vertical and horizontal extent of the tunnel networks in such a mine. Depending on the mine design layout employed, tunnels once excavated are subjected to various levels of stress change over their life time, and the support requirements are explained. It is suggested that shotcreting is the only viable ultra-deep level support medium, and after looking at the latest developments, the logistical problems are put forward. In an effort to overcome most of these problems, the South African ultra-deep mining industry embarked on a collaborative research programme in 1998. The importance of tunnelling and in particular tunnel support as a critical technology for future successful ultra-deep level mining is stressed. While not yet fully ?on top of? these problems and challenges, our industry is now fully addressing them and we expect to make significant progress during the next 4 to 5 years.

Jan 1, 2000

By P. N. Calder, D. B. Apel, S. D. Butt

Mine-wide (MW) microseismic systems use widely spaced transducers to determine the source location and parameters of stronger microseismic events, while high frequency (HF) systems use fewer transducers to monitor local areas for the weaker events that can precede stronger events. Previous monitoring at the Creighton Mine indicated that an HF transducer located 120 m away from an active stope recorded two types of activity in response to production blasting: the first occurring at the same time as the production blasts and associated with the passage of the direct seismic waves from the blast through the local area, and the second occurring several hours later and associated with the arrival of a slower moving stress change through the rock mass (which was identified by the mine’s MW system). Interpretations of locally increased stress levels, based on analysis of the recorded HF events, correlated with the nearby occurrence of two strong seismic events. These results were applied to a similar monitoring trail at the Kidd Creek Mine where the transient stress changes induced by several development blasts were monitored. It was observed that increases in HF activity corresponded with the occurrence of MW events near the transducer location, and that fewer HF events were recorded the longer this occurred after the blast. Local geological features appeared to influence the number and occurrence of both HF and MW events.

Jan 1, 2000

By G. A. Irons, G. S. Hanumanth

A three-dimensional mathematical model for the electric furnace of Cominco's Kivcet process was developed to compute the electric field intensity, power dissipation, temperature and velocity distributions in the furnace. A number of simulations of the electric furnace operation were carried out for various electrode immersion depths and electrode currents. The results showed that the current penetrated the bullion layer, generating high current densities in a layer approximately 0.3 m thick located in the slag/bullion interface region. An increase in the electrode immersion depth increased the furnace power as well as slag temperatures, and generated more vigorous bubble stirring and thermal homogeneity in the slag. For a given applied current, the computed power was in reasonable accord with the measured power input. The calculated temperatures were in rough agreement with the tapping temperatures of slag and bullion.

Jan 1, 2000

By N. Parra, M. N. Herrera, T. Vargas, B. Escobar, C. Gonzalez

originally published May 1998, Vol. 15, No. 2, pp. 15-1 9 Discussion by G. Rossi, University of Cagliari Reply by T. Vargas, University of Chili

Jan 1, 2000

By B. R. Reddy, Y. V. Swamy, B. V. R. Murthy

Chromitiferous overburden containing nickel in oxide form is reduced with CO-CO2-N2 gas mixtures. This converts the nickel oxide to metallic nickel and restricts the iron oxide to the magnetite state to extract the nickel. Reduction experiments were carried out on 500-g samples in a bench-scale vertical reactor. The tests were run to establish the process parameters, including the optimum partial pressure of CO, the reducing gas flow rate, granule size and roasting time. The reduced calcine is then subjected to an ammonia-ammoniacal carbonate leach to extract nickel selectively as its amine complex. More than 90% of the nickel could be extracted with a volumetric CO/(CO+CO2) ratio of 0.57 at 750°C and a roasting time of 90 min. The addition of 2.5% (by weight) charcoal to the granules improved nickel extraction by 11 % to 19%. Nickel leaching efficiency with ammoniacal solution is compared to the bromine-methanol method.

Jan 1, 2000

By W D. Rech, K W. Keskimaki

As an integral part of the conversion from rail haulage to conveyor haulage at Henderson, over six kilometres of drifting and several large complex openings were mined. The deepest of these areas was nearly two kilometres beneath the surface, bringing all of the challenges of rock stress and heat that come with mining at these depths. Though many mines operate at these depths, the development of the infrastructure necessary to support a 36 000 tonne per day caving operation brought some unique challenges to the development mining activity. The issues handled include: finding experienced staff for a æfast trackÆ development program; rock bursts and ground conditions; inflow of 50 degree centigrade water; acceleration of the project completion; large diameter raise boring and difficult muck handling.

Jan 1, 2000

By Barnaby J. Watten, Sibrell. Philip L., Brian J. Vinci, Andrew E. Friedrich

We evaluated a new process for remediation of acid rock drainage (ARD). The process treats ARD with intermittently fluidized beds of granular limestone maintained within a continuous flow reactor pressurized with CO2. Tests were performed over a thirty day period at the Toby Creek mine drainage treatment plant, Elk County, Pennsylvania in cooperation with the Pennsylvania Department of Environmental Protection. Equipment performance was established at operating pressures of 0,34,82, and 117 kPa using an ARD flow of 227 L/min. The ARD had the following characteristics: pH, 3.1; temperature, 10 OC; dissolved oxygen, 6.4 mg/L; acidity, 260 mg/5; total iron, 21 mg/L; aluminum, 22 mg/L; manganese, 7.5 mg/L; and conductivity, 1400 uS/cm. In all cases tested, processed ARD was net alkaline with mean pH and alkalinities of 6.7 and 59 mg/L at a CO2 pressure of 0 kPa, 6.6 and 158 mg/L at 34 kPa, 7.4 and 240 mg/L at 82 kPa, and 7.4 and 290 mg/L at 117 kPa Processed ARD alkalinities were correlated to the settled bed depth (p<0.001) and CO2 pressure (p<0.001). Iron, aluminum, and manganese removal efficiencies of 96%, 99%, and 5%, respectively, were achieved with filtration following treatment. No indications of metal hydroxide precipitation or armoring of the limestone were observed. The surplus alkalinity established at 82 kPa was successful in treating an equivalent of 1136 L/min (fivefold dilution) of the combined three ARD streams entering the Toby Creek Plant. This side-stream capability provides savings in treatment unit scale as well as flexibility in treatment effect. The capability of the system to handle higher influent acidity was tested by elevating the acidity to 5000 mg/L with sulfuric acid. Net alkaline effluent was produced, indicating applicability of the process to highly acidic ARD.

Jan 1, 2000

By Todd A. Duex

The Richmond Hill Mine has recently completed a reclamation plan to mitigate Acid Rock Drainage (ARD) which was identified at the toe of the former waste rock pile in 1992. Reclamation activities began in 1994 with the removal of ARD material from the waste rock pile and placement of this material in the former pit. This material was then isolated from the near surface environment by a low permeability capping system designed to minimize water and oxygen flow into the material. The capping system consists of, from bottom to top, six inches of limestone, 18 inches of low permeability clay liner, 4 and one-half feet of thermal barrier/drain layer, and six inches of topsoil. This capping system was completed in 1995. An extensive program is in place to monitor the effectiveness of the reclamation plan, and includes measurements on moisture content movement, temperature, oxygen content, and groundwater impacts. Monitoring has been ongoing since the completion of reclamation. This monitoring plan is demonstrating the success in isolating the material from the near surface environment and minimizing the impacts to the surrounding environment.

Jan 1, 2000