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By Donald E. Ranta

Many portions of the mining industry are under intense pressure to reduce costs while commodity prices languish. In response, global Internet-based marketplaces to deliver business-to-business (B2B) e-commerce solutions are being established to reduce costs and improve efficiencies across the mining industry supply chain as well as with customers. Over time these marketplaces will likely evolve to create an integrated supply chain solution, layer in value-added services, and develop mining community portals with industry content. Significant opportunities to help reduce costs and create value are available in mining e-procurement as well as in on-line product sales. The supply chain for the industry is highly fragmented and many mining companies have numerous inefficiencies in procurement. An e-procurement marketplace (or "exchange") can immediately address these inefficiencies and offer numerous benefits to buyers and suppliers. These benefits include improved sourcing options, inventory cost reduction, transaction cost reduction, access to value-added services, lower customer and supplier acquisition costs, improved reach, and improved information flows.

Jan 1, 2001

By Michael A. Berdine

In early 1997, Twentymile Coal Company took a dramatic departure from traditional longwall recovery methods. Previously, Twentymile's standard longwall meshing procedure included the use of chain link fencing material. Beginning with the 9-Right to 8-Right longwall recovery operation, Twentymile incorporated a polyester geogrid mesh system supplied by DYWIDAG-Systems International. This paper discusses the subsequent utilization of the polyester geogrid mesh system at Twentymile.

Jan 1, 2001

By William R. Henkle

High-calcium limestone has been intermittently produced from the Monarch quarry since the late 1800s. Initial production was used in sugar processing and for a smelter located near Salida, Colorado. During the 1920s, Colorado Fuel and Iron Company (CF&I) began to exploit the deposit as a source of flux stone for its blast furnace steel operations at Pueblo. The deposit was operated for many years as a captive quarry by CF&I. In 1984, CF&I closed the quarrying operations at Monarch; flux stone was no longer required since the blast furnaces were taken off line in 198 1. In 1994, Colorado Lime Company, a subsidiary of United States Lime and Minerals, Inc. acquired the property. Limestone was mined from the Castle Butte Member of the Leadville Limestone (Lower Missippian). Some high- magnesium dolomite was also mined during WWII from the Redcliff Dolomite Member which directly underlies the Castle Butte. Past production was from both an upper and lower quarry at elevations ranging from 10,000 to 11,000 feet (3,048 m-3,353 m) mean sea level (m.s.1.). The reserves at Monarch quarry are in a dip slope deposit, occupying the northwest slope of Monarch Hill. The structural geology of the deposit is complex on both a region- al and mine scale. The reserves are located on the eastern limb of the Syncline Hill syncline. The beds on this limb of the structure strike to the northeast and dip to the northwest from 30 to 45 degrees. A major reverse fault separates the reserves into an upper and lower deposit. Numerous smaller normal and reverse faults cut the deposit, requiring a flexible mine plan. At the Monarch quarry, the Castle Butte Member con- sists of two stratigraphic units. The Upper unit (Mlu) is a thick-bedded, fine-grained crystalline dolomitic limestone from 0 to 300 feet (0-90 m) thick. The unit generally has an Si02 content of less than 4 percent. A bedded chert horizon and a karst horizon at the base of the unit locally raise the Si02 content as high as 20 percent. The underlying Quarry Stone unit (Mlq) is a light-gray, massive, bedded, calcilutite/micrite limestone from 90 to 130 feet (27-40 m) thick. The Quarry Stone unit is remarkably uniform chemically throughout it's entire thickness. Average analysis is CaC03 - 95 percent, MgC03 - 3.5 percent, and Si02 - 0.5 percent. The Footwall dolomite unit (Mld) of the Redcliff Member of the Leadville Limestone is a dark gray to black, blocky, medium-to-thick-bedded, calcilutite/micrite dolomite from 150 to 180 feet thick (46-55 m). The upper 100 feet (30 m) of the unit is a low-silica facies with an average Si02 content of less than 0.5 percent. MgC03 content is con- sistent at 39.8 percent throughout the upper 50 feet (15 m) of the unit but varies from 15 percent to 39.8 percent in the lower portion (50 to 100 feet [15-30 m]) of the low-silica facies. The lowest portion of the unit, 100 feet (30 m) to base of unit is high in silica and is not considered chemical grade. Current in-place, surface-minable reserves at the quarry are estimated to be 14 million short tons (st) (13 million metric tons [mt]) of limestone and 50 million st (45 million mt) of dolomite. A 1.4 million st (1.3 million mt) stockpile of finely crushed limestone is also present on the property. Colorado Lime is presently processing approximately 2,000 st (1,800 mt) per month from the crushed limestone stockpile. This material is pulverized and sold to underground coal mines for use as rock dust, some of this product is also used for environmental purposes. Limestone mining is scheduled to resume in spring of 2000.

Jan 1, 2001

By Bill Shand

"Placer Dome - Campbell Mine is a gold mine located at Balmertown in the Red Lake District of North Western Ontario. During the last 50 years, the mine has produced over ten million ounces of gold.A change in ball mill grinding media was made in August 1998 from 1.5” diameter forged balls to 1.5” diameter, 18% chrome balls. This was done to reduce grinding media consumption and to potentially help flotation performance.A marked ball test done in September-October 1999 showed that, of the alloys tested, 18% chrome was the optimum for the ore at Campbell Mine. The test showed that consumption of chrome balls should be 3 times less than forged balls.In December 1999, the ball size was increased from 1.5” to 2” in an effort to reduce the amount of oversize rock discharging from the ball mill. This change in size was successful.Grinding media consumption for the ball mill decreased 73% from 1.20 kg/tonne before the use of chrome balls to 0.327 kg/tonne after the use of chrome balls. This clearly indicates that, for the ore at Campbell Mine, there is significant savings in grinding media by using chrome.Grinding ball costs were reduced by 59% from $O.88/tonne of ore milled to $0.36/tonne of ore milled representing a saving of $298,000 per year. This also clearly indicates that using chrome balls is a benefit at Campbell Mine.Test work to show that chrome grinding media is beneficial to flotation has been inconclusive so far but is still ongoing.No tests have been done to see if there would be a benefit with an even higher chrome percentage in the grinding media. Test work in this area is also planned for the future"

Jan 1, 2001

By G. Broadbent

It is an honour to be invited as a speaker to this ICCR conference and a pleasure to be with you here in South Africa. I have been asked to talk about the competitiveness of coal versus other energy alternatives. Coal supplies nearly one-quarter of the global primary energy. Its most direct competitors are gas, nuclear and renewables. Oil is predominantly for transport fuels. Fuel oil is competitive with coal when crude is below its long-run average price and has some niche opportunities. But I will confine my comments to nuclear, renewables and particularly natural gas as the most potent current competitive threat to coal. Competitiveness is more than just cost and price; there is environmental acceptability, security or reliability and increasingly image. These factors are more of a spectrum than discrete issues. Dollars and cents remain the key issue for competitiveness but one must recognize the impact of politics in sustainable development and energy security.

Jan 1, 2001

By D Judkins N OÆLoughlin

"Basin Minerals Limited commenced exploring for conventional strandline hosted mineral sands (rutile, ilmenite and zircon) deposits in the Murray Basin in April 1997. This has resulted in the discovery of a major mineral sands field in the Douglas Project area, located southwest of Horsham in the Wimmera Region of Western Victoria. After the successful completion of a pre-feasibility study on these deposits in September 2000, the Douglas Project has advanced to bankable final feasibility study. This study should be completed by mid-2002 to allow a decision to commence production in 2003 at an expected rate of in excess of 500 000 tonnes of combined mineral sands products per annum. The field comprises several mineralised strandlines. The main ones of economic interest are from west to east, the four strandlines, Acapulco, Bondi, Bondi East and Echo. These strandlines at August, 2000 contain total Inferred Resources of 443 million tonnes at 4.7 per cent HM at a one per cent HM cut-off; ie 20.8 million tonnes of heavy mineral concentrate which in turn contains 11.3 million tonnes of ilmenite and leucoxene, 1.3 million tonnes of rutile and 1.6 million tonnes of zircon. The heavy mineral concentrate is coarse-grained with mean diameter grain size of the strandline deposits ranging from 130 to 160 microns in size. Major controls on the formation of mineral sands deposits in the Murray Basin are discussed with reference to the main mineral sand bearing, strand plain domains; the Central Strand Plain, the New South Wales Strand Plain and the West Wimmera Strand Plain. The Douglas Project deposits on the West Wimmera Strand Plain domain are characterised by wide zones of mineralisation with high-grade cores (>10 per cent HM), low stripping ratios, and a valuable economic heavy mineral suite comprising 60 to 80 per cent of heavy mineral concentrate. Constituent mineralogy of the heavy mineral concentrate of the overall deposits is; ilmenite (40 to 58 per cent), leucoxene (five to seven per cent), rutile (four to ten per cent) and zircon (four to 14 per cent). The Douglas Project Area appears to be endowed with significantly enhanced levels of heavy minerals compared to other areas of the Murray Basin due to its unique palaeo-geographical position. Long shore drift to the south of the basin has caused large quantities of heavy mineral to be trapped against the palaeo-cliffs and headlands of a rugged palaeo-coastline which includes in a major embayment, the Grampian Mountains, the Black Range and the Glenelg Complex. To the east, major faulting and uplift has brought the fine-grained WIM offshore deposits close to the surface and has resulted in erosional stripping of mineralised strandline deposits. This mineralisation has been recycled and reconcentrated within the younger strandlines to the west within the adjacent Douglas Project Area. These strandlines are thought to be younger than other mineralised strandlines discovered to-date in the Murray Basin. The Project Area strandlines are described; ie their morphology, geology and patterns of mineral distribution. The mineralogy of each of the strandlines is distinctive and variations are noted along strike and section."

Jan 1, 2001

Stope support systems, typically consisting of props and packs, are used extensively in the gold and platinum mining industry to stabilize the rock mass in the excavation vicinity and to reduce the hazard associated with rockfalls and rockbursts. The design of stope support systems was historically based predominantly on past experience and practices, and cost considerations. The recent development of a new and improved support design methodology, has led to the potential for significant increases in worker safety and support cost savings. This paper reviews some of the fundamental rock mass and support criteria that form the basis of the improved support design methodology. The considered design criteria are the height of potential fall; quasi-static stope closure rates; dynamic stope closure rates; compressive hangingwall stresses; discontinuity spacing, orientation and interface properties; effect of support length (stoping width); effect of compression rate; consistency of support performance; a real coverage; support spacing; and zone of support influence. The proposed support design methodology combines both the zone of influence and key block stability theories, resulting in optimized support systems for rockfall and rockburst conditions. The site-specific methodology consists of two stages: (i) a tributary area analysis, and (ii) a zone of support influence and a stability analysis, considering hangingwall failure due to buckling, shear and block rotation, which gives maximum safe spacing of individual support units. The methodology is suitable for designing support systems for both blocky hangingwalls and hangingwalls fragmented by face-parallel extension and shear fractures.

Jan 1, 2001

By P. Altounyan

Techniques used to safely control the roof in UK coal mines for some 10 years have been applied to a South African coal mine. This new approach known in the UK as advanced rockbolting technology, is based on applying four fundamental principles: ?Understanding the roof failure mechanisms ?Using an effective roof support system ?Designing this support using measurement ?Monitoring the performance of the system. The paper summarizes the approach in detail and describes how it is being applied by Anglo Coal, giving results obtained to date. Investigations at a number of South African coal mines, including stress measurements at two Anglo Coal mines, have confirmed that the mode of roof failure (lateral shearing due to horizontal stress) is the same as in other coalfields worldwide, and aspects of current world best practice, including the use of advanced technology rockbolting, are therefore relevant in South Africa. The stress measurements indicated a high level of stress field anisotropy and further investigation of stress conditions in South African coal mines is recommended. The most effective bolting system to resist shear failure is one with high bond strength and stiffness. Short encapsulation pull testing of existing South African systems confirmed that they have low bond strength and stiffness. An improved rockbolt system with the required performance, and features allowing rapid installation and installation quality and performance audit, has been developed and is currently under full-scale trial. Design by measurement and routine monitoring procedures including the use of a rotary telltale device are also under trial. It is anticipated that South African coal mines will be able to obtain significant safety and productivity benefits from the application of this technology.

Jan 1, 2001

By Anibal Gajardo

Clays for building bricks and roofing tiles in Chile are classified as common clays and ball clays, with deposits of sedimentary and residual origin, both Cenozoic in age. Deposits are known from north to south, through 11 of the 13 Chilean Administrative Regions, 18° to 39° South latitude, and from west to east, through three of Chile's main geomorphic features, namely the Coastal Plains, Coastal Range, and Intermediate Depression. Alluvial and lacustrine sedimentary common clay deposits are located in the northern and southern Intermediate Depression. The average chemical composition of clay deposits in I and I1 Regions, is 58 percent Si02, 16 percent A1203, and 4 percent Fe203 by weight; the primary minerals are sericite, quartz, feldspar, and albite. The average chemical composition of clays in Metropolitan, VI, and VIII Regions, is 52 percent Si02, 16 percent A1203, and 6 percent Fe203 by weight; the primary minerals are montmorillonite, quartz, and plagioclase. Residual common clay deposits occur in the Intermediate Depression and in the Coastal Range internal basins, VII, VLII, and IX Regions, and they represent surficial alteration of pumice beds and crystalline rocks. The average chemical composition of clay deposits derived from crystalline rocks is 58 percent SO2, 17 percent A1203, and 9 percent Fe203 by weight; the primary minerals are sericite, quartz, and clinochlore. Clay deposits formed from pumice beds contain 47 percent Si02, 24 percent A1203, and 10 percent Fe203 by weight; the primary minerals are kaolinite, feldspar, and cristobalite. Sedimentary ball clay deposits are located in the Coastal Plains and Coastal Range, VI, VII, VIII, and IX Regions, between 34" and 39" South latitude. The average chemical composition of the ball clay deposits is 51 percent ,902, 28 percent A1203, 5 percent Fe203 by weight; the primary minerals are kaolinite, quartz, and sericite (illite?). These clay deposits supply the Chilean building sector with over one million metric tons (mt) (1.1 million short tons [st]) of material per year. The average growth rate of clay consumption during the period 1993 through 1997 was 10 percent annually. The clays are used by both mechanized plants and handcraft facilities.

Jan 1, 2001

By N. K. Mendiratta

Diethylenetriamine (DETA) is known to be an effective pyrrhotite depressant in pentlandite flotation. It has been reported recently that its performance becomes more consistent when the reagent is used in conjunction with sulfur dioxide (SO2). In the present investigation, the effects of DETA and SO32- ions on the changes in the hydrophobicity of pyrrhotite electrode have been studied at pH 6.8. The results show that both DETA and SO32- can reduce the water contact angles of pyrrhotite; however, the contact angles can be reduced to zero only in the presence of the SO32- ions. This finding may be attributed to the ability of the SO32- ions to reduce the polysulfides formed on pyrrhotite by superficial oxidation, which may in turn provides an explanation for the robust performance of DETA/SO2 combination.

Jan 1, 2001

By Scott Jones, Tony R. A. Durkac, David W. Stephens

Williams Mine was considering spending a large amount of capital to install a pumping system underground to rid the mine of slimes; with the introduction of Delvo Stabilizer this challenge would be met. This paper will address the process to introducing the Delvo Technology into the Cemented Roddill Program. Some areas that were worked on included: testing of the mix design, bet dosage rate for an economical solution, temperatures at different levels of the mine, the amount of time needed once the grout was put to sleep, preventing plugs in the delivery system A controlled dosage that gave the Operator a 12 hour window of flowable material was developed and an added feature to the introduction of Delvo was also noted; an increase in MPa strength over the design. Collectively with the help of operators at the batch plant and the underground miners involved with the program all concerns where addressed and all goals met. A cost effective program was implemented thus increasing productivity, preventing costly plugs, and improved the actual maintenance on the entire delivery system, which included the batch tanks, aggitator tanks, all pumps required in the system and of course reducing buildup of slimes at the cones.

Jan 1, 2001

By R Soong

The Wharekirauponga (WKP) epithermal gold-silver deposit is located about 10 km north of Waihi in the Hauraki Goldfield east of Auckland. WKP is notable for its sheeted to stockwork quartz veins hosted in rhyolitic rocks, that have attracted exploration interest as a low grade, bulk tonnage exploration target. Exploration between 1978 and 1993 included 23 diamond drill holes totalling 5505 m. The mineralisation occurs in a rhyolite dome complex (Miocene), consisting of flow-banded rhyolite and rhyolitic pyroclastic rocks, with minor andesite. Fifty four drill core samples were collected from six exploration drill holes and analysed by semiquantitative XRD techniques. Hydrothermal alteration of the rhyolitic and andesitic rocks has developed secondary mineral assemblages of quartz, adularia, albite, chlorite, illite, sericite, interlayered illite-smectite, carbonate, halloysite and pyrite. The main zone of mineralisation is characterised by quartzadularia alteration, which grades oiItward to quartz-clay (illite, local halloysite and/or interlayered illite-smectite) alteration. Propylitic alteration is present at the southern end of the drilled area of the prospect. Depth-related changes in mineralogy include a decrease in illite and appearance and increase in quantity of chlorite with increasing depth, and the localisation of halloysite and interlayered illite-smectite in the shallow parts of some drill holes.

Jan 1, 2001

By Y. Wang

China is a big mining country with a long mining tradition and history. At present, there are nearly 200,000 different mines and 21 million workers. The total production value of mining makes up 6% of GNP. With the development of economy, the mining industry has played a more important role in our economic market, supplying more than 95% non-reusable energy, 85% of industrial and agricultural raw materials, over 75% of fertilizers and 30% industrial and agricultural water.

Jan 1, 2001

By Joseph P. Gildner, Michael S. Kucker, Robert A. Robinson

Considerable controversy seems to exist over the extent and nature of information that should be provided in design-build type contracts. Much of this controversy may relate to the types of owners, ranging from private industry to state and federal agencies that are implementing design-build. Philosophies for the development of geotechnical information ranges from no information to a thorough investigation approaching that needed for final design. Several recent projects, such as the Channel Tunnel in Europe, Whittier Tunnel in Alaska, Tren Urbano in Puerto Rico, and Sound Transit in Seattle have taken varying approaches to providing and interpreting geotechnical information for bidders. The pros and cons of these various methods are discussed and assessed.

Jan 1, 2001

By Nick Barton

A recent analysis of 145 TBM tunnels of more than 1000km total length has helped to quantify the time dependence of utilization (U). In fact U = Tm, where T is time in hours and m is a negative gradient of deceleration. In poor quality ground, gradient m has a strong dependence on rock mass quality Q, for example m ˜ -0.5when Q = 0.1. Good investigation is critical for ensuring faster TBM tunneling then drill-and-blasting, which tends not to slow down (in m/hr) as the tunnel length increases. Anew design model called QTBM allows more reliable prognoses be made, and occasionally will disqualify the TBM solution.

Jan 1, 2001

By H Aral

A rotating magnetic field can be produced in a magnetic separator by using a magnet rotor fitted with alternate north-south magnetic poles, similar to the rotors currently used in modern eddy current separators. Rotation of the magnetic field causes ferromagnetic particles to rotate during magnetic separation. The particle rotation can then be used simply to remove entrapment during a conventional attraction magnetic separation (RMF lift separation), or it can be used to roll particles away from non-rotating particles, and to move them out of the separator under their own rotation (RMF rotation separation). RMF (rotating magnetic field) separation is a separation for ferromagnetic particles. These particles have a very ordered magnetism that is locked into directions of easy magnetisation in the crystal. As a result, if the external field rotates, the particles attempt to rotate with it. RMF separation uses this fact to rotate the ferromagnetic particles in a rotating field. In contrast, paramagnetic particles have a magnetism that can point in any direction with almost equal ease, and these will not rotate in a rotating field. By making use of this difference in magnetic properties, RMF rotation separation can separate ferromagnetic particles from paramagnetic, even when the particles have similar susceptibilities. Some particles such as both chrome spinel and ilmenite can contain ferromagnetic regions within a paramagnetic matrix. These ferromagnetic regions can vary from very small regions dispersed throughout the crystal, through thin lamellae, to larger more bulky regions. Although most natural ilmenite is ferromagnetic and generally has a higher magnetic susceptibility than paramagnetic chrome spinel, the susceptibility ranges for the two minerals overlap considerably (Allen, 2000a) due to the presence of these ferromagnetic elements, frequently making the conventional magnetic separation of these two minerals impractical. It is known that roasting a mixture of ilmenite and chrome spinel particles increases the magnetic susceptibility of the ilmenite while leaving the spinel susceptibility substantially unchanged. This makes the use of conventional (susceptibility attraction) magnetic separation more practical for the separation of these two minerals. However, very little is known about the effects of roasting on the response of ilmenite and spinel particles to a rotating magnetic field. For example, although the optimal ilmenite roasting conditions for conventional magnetic separation are quite well established such conditions may or may not be optimal for RMF rotation separation. Low intensity conventional magnetic separation on the basis of magnetic susceptibility can be made more accurate if it is carried out in a rotating field, because the rapid spinning of the separating particles prevents the formation of magnetic flocs, and reduces entrapment and entrainment. Medium intensity RMF rotation-only separation (no attraction component) has the ability to separate rotating (ferromagnetic) from non-rotating (paramagnetic) particles, irrespective of their relative magnetic susceptibilities. RMF rotation separation is of particular interest in this case because ilmenite particles generally rotate much better than the mainly paramagnetic chrome spinel particles, and roasting could enhance this difference further. Further information on the use of RMF to separate minerals can be found in Allen (2000a; b and c). The aim of this series of tests on a number of Australian ilmenites was to compare some different oxidising and reducing roast methods and to establish whether the use of RMF rotation separation improves the chrome spinel rejection.

Jan 1, 2001

By Mostafa O. El-Bealy

"To estimate the interdendritic cracking tendency in casting processes, a new model for interdendritic cracking criteria has been proposed. The model combines a concept of the alloying element effect on the interdendritic strain generation and therefore on the susceptibility of interdendritic cracking phenomena. A susceptibility of interdendritic cracking is modeled by using El-Bealy's interdendritic cracking susceptibility function ""BJCSF' and the opening displacement between the dendrites ""EIA "". These concepts are modeled based on the previous experimental observations and ElBealy' approach. The model is implemented numerically for a one-dimensional model problem with some similarities to the casting of steel. The variation of some key parameters that are known to influence the frequency and severity of the interdendritic cracking is then studied.I. INTRODUCTIONInterdendritic cracking ""hot tearing"" commonly encountered in both ferrous and nonferrous castings (1,2]. It is generally believed that interdendritic cracks start to nucleate and develop in the interdendritic strain region within the mushy zone [l-5]. The interdendritic strain region is then definitely coherent, but continuous films of liquid still exit (4,5]. This distinguishes interdendritic cracks from cold cracks forming during the casting process after complete solidification (6,7].Much effort has been put into the understanding of the interdendritic cracking phenomena, and several theories have been proposed. Fellini [8] stated that interdendritic crack ""hot tear"" will result if the material is subjected to too high of accumulated strain within so called vulnerable part of the solidification interval. Kinosita et. al. [9] and Campbell (10] also emphasized the role of tensile stresses in the forming of interdendritic cracks. Most interdendritic cracks criteria simply consider the size of solidification interval, stating that solidification range is associated with a lager interdendritic cracking susceptibility than a short range. Clyne and Davies (11] formulated a more refined such criteria based upon the time spent in different regimes of the solidification interval. They defined a vulnerable region in which thin continuous films of interdendritic liquid exist, and the permeability is low. When thermal strains are induced in this region, the film is not able to sustain the stresses, and an interdendritic crack will form."

Jan 1, 2001

By George K. Burke

Single axis soil mixing is a mechanical method of blending soil in situ with a reagent binder to achieve improved character. Generally this achieves a design compressive strength or shear strength and/or permeability, but can be used to immobilize and/or fixate contaminants as well as a treatment system for chemical reduction to a more "friendly" substrate. The reagent binder can be a variety of materials, including cement, fly ash, slag, lime, and an assortment of additives. Usually this reagent is delivered in a slurry form (combined with water), but the Dry Mix Method uses pneumatic conveyance.

Jan 1, 2001

By A. Cobbii, M. Kasliki, W. Birchi

The Department of Mining and Mineral Engineering at the University of Leeds has a long history of research into the environmental impacts of blasting from quarries and opencast mines. This paper gives an outline of a detailed case study into the structural damaged induced in a rock walled tunnel with a brick lined crown due to close proximity quarry blasting. The test site Taffs Well Quarry is located in South Wales in The United Kingdom and has a disused railway tunnel situated within the south eastern comer of the quarry site. Quarry development plans included the working of this area and therefore the deliberate destruction of the central section of the tunnel.

Jan 1, 2001

By M. D. Stephens

A new, one-step process for extracting titanium from titaniferrous materials has been demonstrated. In the process, depleted uranium tetrafluoride (DUF 4), a solid, is mixed with ilmenite (FeTi03) and heated to 900°C. Titanium is extracted in the vapor phase as titanium tetrafluoride (TiF4) and the DUF4 is converted to uranium-iron oxide. The process has been found to selectively fluorinate the titanium in ilmenite and is capable of producing high purity TiF 4 with very low iron content. TiF 4 can be collected by condensation or through reaction with a fluoride salt such as NH4F, KF, or NaF. The TiF4 produced from the process can be used to make titanium metal, titanium oxide, or fluorotitanate compounds. Since the fluorination process is highly selective for titanium, it avoids many of the separations and waste issues common to other titanium extraction processes.

Jan 1, 2001