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By Katsunori Yamaguchi

A new technique for the removal of tramp-elements from steel scrap has been required from the viewpoint of saving energy and protection of environment. In order to obtain fundamental information on the removal of copper, tin and zinc from molten iron, the extraction method by using of phase separation in the liquid Fe-Pb-C system was investigated at 1453K. A mixture of iron, lead and carbon melted in a carbon crucible separates into two phases of lead and iron containing carbon. The compositions on the miscibility gap in the Fe-Pb-C system are 95.4%Fe-4.5%C-0.1 %Pb and 99.9%Pb-0.I%Fe. The distribution ratios of copper, tin and zinc between the lead and the iron phases, Lx [mass%X in molten Pb]/(mass%X in molten Fe), are 2.2, 2.2 and 1.4, respectively. Seventy percent of copper and tin from iron scrap can be eliminated with comparable lead addition. Gold, silver and palladium are enriched in the lead rich phase, on the contrary platinum and rhodium are more distributed to the iron rich phase than to the lead phase.

Jan 1, 2003

Most processing plants use automatic samplers to extract ore aliquots along a producing shift. These aliquots are combined into a sample normally sent to lab analysis. The sampler used in the extraction of an aliquot from a continuous flow of ore, i.e. a belt conveyor is required to be both precise and accurate. Surprisingly, not all commercial automatic samplers exhibit these two mandatory properties. Consequently, it is recommended the development of a procedure able to check sample assays reproducibility obtained using a given sampling protocol. This paper uses the Gy’s sampling theory to evaluate coal quality control practices at a washing plant using an automatic sampler extracting coal increments from the ROM feeding belt conveyor. Gy’s theory provides the means to establish the precision limits for a given sampling protocol. Various ore properties are required to be determined in combination with sample mass and mass of the lot sampled. All this information leads to the definition of the precision limit. The precision limit obtained was checked via an experiment mimicking what happens in situations where both miner and consumer use the same and appropriate sampling practices. The experiment demonstrates that sampling theory precision limits were valid if unbiased samplers are used by both parties, i.e. miner and consumer. Keywords: sampling, quality control, coal

Jan 1, 2003

The unpaved road network on a surface mine is extensive, comprising numerous roads of varying construction and material qualities with highly variable traffic volumes. Existing haul road maintenance management systems (MMS) work well for predictable traffic volumes, but for complex mine road networks, the MMS becomes onerous. This results in sub-optimal road maintenance strategies with the attendant increase in total road-user costs and reduction in service. A real-time maintenance management system was thus sought to overcome the deficiencies of existing MMS for mine roads. Since most large mines operate trucks with on-board diagnostic data collation, linked through a centralized communication and GPS backbone, it was proposed that road condition could be monitored on a real-time basis through on-board vibration signature analysis. The aim of this paper is to present the development of a real-time mine haul road maintenance management system. Following are view of mine road maintenance practices, the real-time system architecture is introduced and the results of a field trial of on-board vibration signature assessment is presented. The trial results are discussed in the light of road defect signature recognition, analysis, signature repeatability and system limitations. This approach has applicability to other situations such as a network of district roads, subject to an analysis of the economic feasibility. The paper concludes that modern technology has the potential to apply maintenance as and where needed with possible reductions in authority cost and an improvement in service provided for the road user.

Jan 1, 2003

By A. Valenzuela

During the last years, Chile has been the largest copper producer, either as concentrates or cathodes. Copper obtained via pyrometallurgy is produced by seven smelters, which have carried out modernization plans to increase smelting capacity or to achieve environmental regulations established in the Chilean legislation. Thus, the present work updates technological innovations in smelters, environmental regulations and presents solutions for S02 handling, particulate matter and arsenic. Also, the authors emphasize the important role of CODELCO Chile, the most important state-owned copper company, in developing technologies such as El Teniente Converter and El Teniente Slag Cleaning Furnace.

Jan 1, 2003

By Robert van Hille, Alison Lewis

The precipitation of a selection of metals from both a synthetic and an actual metal-rich effluent was investigated. The experimental aspects of this study were carried out in a two-stage process consisting of a pre-treatment clarifier and a fluidised bed (pellet) reactor. Each unit operation in the two-stage process was investigated separately. The pre-treatment clarification stage at pH ˜ 5 resulted in a 99.9% removal of iron and 97.3% removal of aluminium. The pellet reactor was used to precipitate nickel as nickel carbonate from a pure stream and a removal efficiency of 99.6% was achieved. The high local supersaturation at the reagent inlet points caused the formation of a large amount of fines, but these agglomerated onto the pellets up the length of the bed. For copper precipitated as copper sulphide from a pure stream, a maximum removal efficiency of 92% was achieved. The high local supersaturation at the reagent inlets also caused the formation of a large amount of fines, but the extremely sparingly soluble nature of copper sulphide meant that the fines were not agglomerated up the length of the bed. For removal of cobalt as cobalt carbonate from an actual stream, a stable cobalt removal of only 60% was achieved. This was found to be due to the presence of magnesium, which reduced the cobalt precipitation efficiency through the formation of the magnesium bicarbonate ion.

Jan 1, 2003

By Travis Davidsavor, Stanley: Dong Vitton

Concrete is a common construction material used throughout the world, and with increasing demand of fast-track construction, blasting and concrete casting are occurring simultaneously at many sites where rock is being excavated for concrete placement. However, there has been significant disagreement in the construction industry as to what intensity of shock vibrations green, or fresh concrete can tolerate. Peak particle velocities are often arbitrarily chosen, or are simply based on materials such as plaster and drywall that have been more thoroughly studied in relation to damage. Previous research on green concrete has used the concrete’s static strength subjected to shockwaves at different ages as the primary damage criteria. In addition, the static strength tests have been based on curing time. However, changes in temperature or humidity can dramatically alter the hydration rate, which affects strength development of different cements. To account for temperature changes and humidity the concept of concrete maturity is commonly used and allows the researcher to see where the concrete was in terms of hydration progress. In general, static testing determines the failure stress that the concrete’s macrostructure can handle, and often failure occurs in the natural materials first or along large defects in casting techniques. Dynamic testing or high strain rate testing, on the other hand, loads materials at such a high rate that larger defects do not have time to react and instead the microstructure is more highly stressed leading to higher strength and stiffness values. This is known as the material’s strain rate sensitivity. Since dynamic testing better tests the microstructural strength, it is believed that it may provide a better way to assess damage to green concrete. Testing includes both static and dynamic compression as well as static and dynamic splitting tensile strength to assess whether damaged has occurred to the concrete. No significant statistical evidence was discovered that damage to the concrete occurred at five different “green” maturities from peak resultant velocities ranging from 10.66 in/s (271mm/s) to 4.40 in/s (112 mm/s) with average intensity of 6.7 in/s (170mm/s).

Jan 1, 2003

MULSIM/NL and La Model are displacement-discontinuity programs which have been used quite successfully in the past to provide detailed structural models of various single and multiple-seam mining situations. However, both of these programs required fairly complex details of the mine plan and topography to be manually input into the program, often taking several days of work. Recently, automatic mine and topographic grid generation capabilities have been added to the MULSIM/NL and La Model programs, reducing the input time requirements from days to hours. This paper discusses the algorithms used for the automatic grid generation and demonstrates the utility of the new capabilities with a case study.

Jan 1, 2003

By A. R. Miller, G. Desrivières, M. C. Bétournay, D. L. Barnes, P. Laliberté

"Over the last four years, an international initiative, championed by Vehicle Projects LLC, the Fuelcell Propulsion Institute and Natural Resources Canada, has been active in carrying out research projects to prove out the concept of applying fuel cell technology to underground mining vehicles. These have been carried out by a consortium consisting of mining companies, equipment manufacturers, technology developers, national laboratories and consultants, with the participation of Canadian and U.S. mine regulatory agencies.This clean technology, which produces only water and electricity, would allow several advantages to be obtained, in the health area (by eliminating diesel emissions and reducing noise generation), in lowering production costs (such as reducing ventilation required) and lowering greenhouse gas emissions.This paper outlines the results obtained in several key areas, such as, the operation of fuel cells in underground conditions, risk issues related to underground and surface operation of hydrogen vehicles and hydrogen production and delivery systems, and the design and mining performance of the world’s first hydrogen mining vehicle, a mine production locomotive. The work to date on the fuel cell loader, designing the power plant and power transmission systems, operational requirements, and operating cost reductions is also presented."

Jan 1, 2003

By Patrick R. Taylor

A kinetic study of the fluosilicic acid leaching of galena was performed under the presence of different oxidants. Fluosilicic acid concentration, agitation speed, concentration of solids and particle size, type and concentration of oxidant, and temperature were the variables studied. Hydrogen peroxide was found to be the most effective oxidant, its effectiveness being proportional to its concentration. As expected, an increase of leaching temperature increased the overall extraction and extraction rate. The same was found by decreasing the galena particle size. It is thought that leaching using hydrogen peroxide is controlled by fluid film mass transfer due to the calculated apparent activation energy. Reaction by-products such as sulfur and sulfur compounds retard the leaching rate. A mathematical model is proposed and compared to experimental results.

Jan 1, 2003

Kosaka Smelter & Refinery has a history of more than a century as a metallurgical department belonging to Kosaka mine. It has treated for a long time the "Black Ore" or the complicated concentrates dressed from it. The "Black Ore" is composed of black sulfides. It contains not only valuable metals such as gold, silver, copper, lead and zinc but also some impurities like arsenic, antimony and bismuth. With the development of Kosaka's floatation technology, five kinds of concentrates (copper, zinc, lead, pyrite and barite) have been separated from the "Black Ore" but the separation was not complete and each concentrate contained some unfavorable impuritie. In 1980s the highly appreciated yen and the drop of the metals priees forced many domestic mines to close their operations. Since then Kosaka Smelter has changed its way of operation to a custom smelter. Now more than 95% of copper concentrates are imported to take advantage of this technology of "Black Ore" treatment. It mainly treats the raw materials that contain high gold and silver like the "Black Ore". Recently, Kosaka has been working on the recycling of the metals from the printed circuit board scraps and sludge which contain some precious metals. The volume of the recycled metal is continuously increasing.

Jan 1, 2003

By H. P. Ehrlinger

The Illinois State Geological Survey added Minerals Processing to its capabilities in 1966. Subsequently, the Minerals Processing Team and several Geologists collectively thought what neither would have thought of separately. The results included a number of projects. discussed here are: 1) The Utilization of the Fines from Kitty Litter as a Bonding Agent for Iron Ore Pellets; 2) Separating Plant Waste from a Commercial Silica Sand Producer into two marketable products, including a closely sized Silica Sand; 3) Marketable Feldspar Sand and Silica Sand from Dune Sands near the Kankakee River; and 4) A Method for Making Metallurgical Grade Fluorspar more desirable as Blast Furnace (Steel) Feed.

Jan 1, 2003

By Francesco Vegliò, Luigi Toro, Francesca Pagnanelli

"Different hydrometallurgical processes have been studied in order to recover manganese(II) from oxidised minerals such as MnO2 (Vegliò and Toro, 1994). An innovative acid reductive leaching carried out in soft experimental conditions was here considered using agro-industrial wastes containing carbohydrates as reducing agents (Vegliò et al., 1998).The leaching process was investigated from a kinetic and equilibrium point of view in order to optimize the experimental conditions and obtain high purity and concentrated MnSO4 solutions.The overall leaching process (not considering the complex network of intermediate oxidation reactions of the carbohydrates in hot sulphuric acid medium (Vegliò and Toro, 1994)) can be described by the following reaction:24 MnO2 + C12H22O11 + 48 H 24 Mn2+ + 12 CO2 + 35 H2O (1)A Shrinking Core Model (SCM) was modified by a variable activation energy term to take into account both the variable reagent concentrations and the reaction rate change with respect to the manganese dioxide conversion. The influence of the particle size in the kinetic model is discussed with the support of SEM analysis and BET surface measurements before and after leaching.Manganese extraction yield was maximised (170-190 g/L) using appropriate carbohydrates and acid excesses, while impurity concentrations were kept low (Fe<10ppm and Ca<300ppm) pre-treating the ores, using hydroalcoholic leaching medium and different combinations of down-stream processes. In particular precipitation, solvent extraction and adsorption onto active carbon were tested to eliminate Fe and Ca from MnSO4 solutions."

Jan 1, 2003

By B. J. Jody

This paper describes a one-step thennal-treatment process, developed at Argonne National Laboratory, to remove all organic contaminants from the glass-fiber waste that is generated during the glass-fonning process. The recovcred glass fibers can then be recycled into new glass fibers or new glass products without adversely impacting the operations of the glass industry or the quality of its products. Our process involves shredding the waste to a manageable size and then processing it at temperatures below its melting point to remove the polymeric-coating layer. The glass industry generates more than 60,000 tons of glass-manufacturing waste annually in the glass-forming process alone. Recycling of this waste stream can keep this non-biodegradable waste out of the landfills. In addition, use of recycled glass lowers energy costs, by an average of about $5 per ton as compared to using virgin raw materials to make virgin glass fibers. This process will also reduce the emission of C02 by 17,400 tons a year and it will also reduce the emission of nitrogen oxides. Economic analysis of our process shows a potential payback of less than 2 years.

Jan 1, 2003

By R. Kus´

The paper presents the comments on the advantages of implementing an integrated system of managing mining exploitation in hard coal mines, as well as the comprehensive integration of information on the process of deposit exploitation with economic data, so as to achieve an optimum technical and economic effects. The principles of constructing the production management system have been presented, thanks to which the management boards are provided with reliable technical and economic information on a mining company via information technology. The strategic direction of a company’s operation may currently be verified according to the external conditions that change over time (the information on the deposit, force majeure events, changing expectations of customers, etc.).

Jan 1, 2003

NIOSH is conducting research to reduce the silica dust exposure of workers at surface coal mines. One goal of this research is to evaluate the relationship between drilling parameters, rock strata and silica dust generation. This study involved measuring blast hole emission dust from a rotary drill rig which required sampling high concentration dust (>400 mg/m3) for silica content in a high velocity airstream. To measure dust initially, traditional sampling methods using personal sampling instruments were attempted in and around the shroud area of the drill with no success. Variations in the dust cloud concentrations under the shroud, the condition of the shroud and its orientation over the hole, and ambient air conditions prevented consistent and accurate dust measurements from being obtained. Amore consistent dust cloud is necessary for accurate measurements. An area of the drill’s dust collector system that consistently draws the emitted airborne dust from the hole is the collector tube. This tube connects the drill collector’s vacuum and dust filtration system to the shroud area. Assuming the collector system is working as designed, sampling from the collector tube would enable more consistent and accurate samples to be taken. However, current personal samplers are unable to sample in the concentrations and velocities experienced in the collector tube, so another method had to be devised. To achieve the desired results, an in-stack cascade cyclone was used. Preliminary field testing shows positive results.

Jan 1, 2003

By M. Barsky, E. Barsky

A study was conducted to elucidate the relationship between the hovering velocity and the particle settling velocity. The experiments were carried out in a water medium on five materials ranging in density from 1.070 to 4.000 kg/m3. Analysis of the results with allowance for the distribution of stream velocities over the cross section of the pipe revealed that the final settling velocity of the particles was equal to their local hovering velocity (on the stream axis), and not to the average velocity of vertical flow as is generally believed. It therefore follows that the kinetic structure of the stream must be taken into account when constructing theoretical models of the process for purposes of computation. In addition, the optimal stream velocity is not always equal to the hovering velocity and in fact is governed by other factors as well. Illustration is provided by the results of a study conducted in a vertical cascade classifier comprising eleven identical stages. The feed material was introduced at each stage successively beginning with the topmost (i* = 1 ) and ending with the lowermost (i* = 11). First, the stream velocity that yields optimum separation conditions at each stage of the cascade (i.e. k=50%, k being the yield of a given size class in the fines for a single stage) was sought. Subsequently the conditions of optimal separation for the instrument as a whole were determined (i.e. F(x) = 50%, F(x) being the yield of a given size class for the entire instrument). The results of the study are presented in the table.

Jan 1, 2003

By Dai Xi

In the present work, the viscosities of molten FenO-MgO-SiO2 and FenO-MgO-CaO-SiO2 semi-synthetic slags for nickel flash smelting were measured in the temperature range from 1473 to 1723K by a rotational viscometer. The ratio of Fe to Si02 was fixed at 1.2, calcium and magnesium oxide contents varied in the range from 2 to 8 mass% and 9 to 12 mass%, respectively. The results showed that silicate anions became smaller by increasing CaO content, which results in a decrease of the viscosity of the slag. In the case of MgO addition the viscosity behavior was complicated. At MgO content below II mass%, the viscosity increased with the increase of MgO at all temperatures tested. However, when the MgO content was above II mass%, the viscosity decreased slightly for FenO-MgO-CaO-SiO2 system. At higher MgO contents, low-viscosity slags can be obtained by adding CaO. At a given composition, .the viscosity decreased with increasing temperature. The higher the temperature, the more MgO can be added before saturation. The effect of Fe3O4 on the viscosity was quite significant. The viscosity of slag increased by 300mPa-s at 1573K when Fe3O4 content varied from 3 to 9 mass%. The viscosity values are presented as the functions of temperature and composition. A comparison between FenO-MgO-SiO2 and FenO-MgO-CaO-SiO2 systems is given in this study.

Jan 1, 2003

Water is a key resource input to copper heap leach operations in both quality and quantity. A number of recent developments in analysis of the technology have shown that water consumption can be optimised. The leach consumption has been generally considered in terms of minimisation of the evaporative loss by changing the application method (drippers or wobblers). Modelling of the irrigation effects on leach rate has shown that the poorer surface coverage from drippers has an adverse effect on the leach extraction rate. This is particularly evident in the early part of the leach. The use of different irrigation systems during alternate parts of the leach cycle can have benefits in minimising the water consumption without an unacceptable outcome from extended extraction times. By combining the leach rate effect with the evaporative loss estimates, an economic decision matrix can be generated to allow the operator to select an appropriate leach irrigation strategy, combining both irrigation delivery and irrigation rate. In the SX-EW plant, the total quantity of EW bleed and SX scrub stage bleed (both for iron control) can be reduced to an absolute minimum. The economic minimum may be different depending on the cost of producing the high-quality water used to replace the bleed streams. Adjustment of the SX process, in particular use of multiple entrainment control steps, can provide significant reductions in the total bleed and make up requirements.

Jan 1, 2003

By Wolfgang Schott

The propagation velocity of in-seam seismic (ISS ) waves depends on frequency which is also known as dispersion. This dispersion is not only determined by the thickness of the coal seam and its dirt hand content (i.e. thickness and position), but also by the rock type and its condition (soft or compact) above and below the coal. A coal panel completely surrounded by roadways was investigated using the in-seam seismic transmission survey technique. Along the roadways the immediate roof was either sandstone and shale- The seam thickness varied between 1.20 m (sandstone in the roof) and 1.40 m (shale in the roof) and a fault system (normal faults) crossed the panel with a total throw of about the seam thickness. Below this coal seam another coal scam with a thickness of about 80 cm exists. Its interval shown by exploratory drilling changes from about 60 cm to more than 6 m (scam splitting). Tomographic inversion was applied to the dispersion of the measured ISS waves and velocity distributions were calculated at frequencies found to he most sensitive to changes in the seam thickness and the distance to the coal seam below. By correlating the velocity distributions with known values along the roadways approximate distributions of the coal seam thickness and the seam splitting within the panel were produced. The mining of the coal panel had already been finished and comparison was made between the survey results and the actual situation as far as it was documented. Prediction by the seismic survey was partly in good agreement with the actual held conditions or showed at least the same trends.

Jan 1, 2003

The advantages of quantitative environmental risk assessment techniques over the more commonly used qualitative approach is widely accepted. One important parameter related to the level of risk is the extent and geographic spread of pollutants. Geographic Information Systems (GIS) provide a powerful and highly flexible tool that increases the sophistication of the risk assessment methodology. Through spatial representation, the estimated risk becomes more comprehensive, thus facilitating the decision making process. In addition, valuable qualitative information can be incorporated into the risk assessment procedure with the help of GIS. This paper illustrates a methodology for quantifying risks posed to human health, by exposure to contaminated land, in a manner, which gives a measure of the uncertainty in the assessment and preserves the spatial distribution of the risks. The case study utilised to illustrate the methodology is a large industrial area around a number of decommissioned minerals production and processing sites with known high heavy metal loads at Lavrio, Greece. The spatial distribution of Pb concentration in soils was derived from 425 soil samples collected over a total area of 120 km2. Indicator kriging was used to quantify the spatial distribution of the risk and related uncertainty and the results displayed in map form using GIS.

Jan 1, 2003