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By M. Syamujulu

In 1994, Nkana smelter commissioned a multimillion US Dollar Chilean Teniente converter (CT) in its operations in order to improve its smelting technological base. The main objective was to reduce the overall smelting energy costs and increase the sulphur capture for sulphuric acid production to support the company?s leaching operations at Nchanga tailings leach plant. A decade of CT operations have since ensued following its installation and start-up. This paper provides a technical and operational audit of the performance of the CT in the first 10 years of its operations at Nkana smelter.

Jan 1, 2005

By Chaoxun Zhao, Daniel Tao, Craig Blue, Narendra B. Dahotre, Rick Honaker, Bhupendra K. Parekh, Hongyang Han

Equipment wear and corrosion have significant adverse impacts on the operating cost and efficiency of mineral processing plants. In this project advanced surface enhancement technologies are being investigated to decrease the wear and corrosion rate of metal surface. Enhanced metal surfaces are achieved through surface conversion, enrichment, and coating by use of advanced High-Density Infrared (HDI) and other technologies. Studies have been done to determine the effects of process parameters on surface properties and identify optimum conditions. The microstructure of the enhanced metal surfaces was characterized by SEM, EDS, and microindentation. Laboratory wear testing was carried out to investigate the wear performance and the viable coating candidate was determined.

Jan 1, 2005

By M J. Kelleher

CREAM is an acronym for coal recovery, evaluation, analysis and management and is a business improvement project at BMAÆs Goonyella Riverside mine that is focussed on maximising coal recovered. In August 2003, Goonyella Riverside was set a challenge to quantify coal loss and dilution and their relationship to cost, revenue and ultimately profit. While the mine was confident in its site forecasts of recovery (and loss), it was clear that the traditional measurement and analysis systems were inadequate to firstly, identify key loss areas and mechanisms and secondly, successfully quantify the benefit of various coal recovery initiatives. The path that BMA Goonyella Riverside has travelled to maximise coal recovered can be divided into four key steps: Mapping the process û This step involved the development of a coal flow process map for Goonyella Riverside that stepped through each component of the process from the coal reserve to the customer and identified key measurement points for the purposes of reconciliation. Understanding coal loss and identifying opportunities û This step involved conducting two detailed Reserve to Customer projects at the mine site to track a block of coal from the reserve to the customer and to gain a greater understanding of the relationship of dilution, coal loss mechanisms, revenue and costs associated with recovering additional coal. Coal data systems development û Two important coal data systems have been developed and implemented at Goonyella Riverside in the past twelve months, namely SnowdenÆs Coal Reconcilor and SeamFix. These systems enable coal losses and dilution to be quantified and reconciled back to the initial coal reserve. Implementation of loss reduction initiatives û This step involved the formation of a business improvement project referred to as æCREAMÆ in August 2004, for the purposes of improving pit coal recovery and maximising business value. To date a series of coal recovery trials have been run in a number of pits at Goonyella Riverside that have yielded significant improvements in business value. The key to the success of this project has been the discipline to follow a defined process map, management commitment through resourcing and shared key performance indicators, a successful acceptance strategy resulting in holistic ownership and the implementation of sustainable reconciliation systems. Coal loss and dilution are now quantifiable and their relationship to cost, revenue and ultimately profit is well understood. This paper discusses the process that Goonyella Riverside has adopted to maximise coal recovered.

Jan 1, 2005

By Chi M. Phan, Anh V. Nguyen, Geoffrey M. Evans, Graeme J. Jameson

Surfactants are used to control the interfacial properties of the gas-liquid and liquid-solid inter- faces inflotation. This paper investigates the dynamic adsorption of surfactants at the gas-liquid intelface. The dynamic adsorption process was modeled by considering the surfactant mass transfer to the gas-liquid interface by dimion and the Langmuir and Frumkin adsorption isotherms. The numerical computation was applied to solve the non-linear governing equations. The dynamic adsorption was measured in tenns of the dynamic surface tension using the pen- dant drop method. The theoretical modek were compared against the experimental data obtained with non-ionic (Dowfroth 250) and ionic (sodium dodecylbenzene sulfate, SDBS) surfactants. The theoretical results agreed well with the erperimental data for SDBS, but not for Dowfrother 250, especially for the initial stage. Reasons for the variation in results are given in the paper.

Jan 1, 2005

By W. R. Tyson

Pipelines for the transport of gas and oil are being designed to operate at increasing pressures in increasingly harsh environments. The steel used to construct these pipelines must have adequate toughness to tolerate weld imperfections (i.e. withstand bending strains) and to arrest running cracks (i.e. to prevent propagation of axial fractures). The problems posed in specifying suitable toughness parameters and the approaches currently being used to measure them are discussed.

Jan 1, 2005

By J. Gao

We present results from our investigation of the concept and practice of using surface-charged latex nanoparticles as building blocks for conductive membranes. Nanoparticles were synthesized by free-radical co-polymerization of two hydrophobic monomers, butyl acrylate (BA) and methyl methacrylate (MMA), a crosslinker, N, N'- methylenebisacrylamide (BIS), and a charged monomer, sulfonate styrene sodium salt (NaSS), in water. The resultant nanospheres were characterized with static and dynamic laser light scattering. Thin films were cast from concentrated particle dispersions, followed by incubation at ?110 °C. Conductivity, water uptake and final charge content were measured. The membranes have higher conductivities than both amorphous films cast from sulfonated BA-MMA-Styrene copolymer chains and BA-BIS-MMA-NaSS gel films. TEM images and neutron scattering spectra confirm the particulate structure of the membranes.

Jan 1, 2005

By Y. Huang

Corrosion of GaAs in aqueous electrolytes is a major limitation in implementing GaAs-based photoelectrochemical solar energy conversion systems, In this work, the corrosion behavior was investigated by electrochemical methods and surface analysis approaches, in both H2SO4 and NH3?H2O solutions, Open-circuit measurements showed that the cleaned GaAs surface was very sensitive to water/air, Impedance measurements for n-GaAs showed that an inductive loop only appeared at a high corrosion rate because a reaction intermediate is the oxidant for a further decomposition step in combination with chemical reaction with water, The results suggest that the same corrosion/decomposition mechanism occurred on n-GaAs in the two solutions, When the surface-hole concentration was low, the hole injection or generation process was the rate-determining step, At large reverse bias on n-GaAs, with high-hole concentration, the corrosion rate was limited by a Faradaic adsorption process, involving an adsorbed intermediate, The different surface compositions after corrosion in the two solutions can be explained by the dissolution of As(0), Further oxidation of As(0) to As(III) in NH3?H2O solution is still slow, as suggested from X-ray photoelectron spectroscopy (XPS) analysis,

Jan 1, 2005

Inco Limited has been evaluating options for streamlining the overall flowsheet at its Sudbury, Ontario operations to improve productivity and to minimize the cost of at¬mospheric emissions reduction. Some of the flowsheets being considered include vari¬ous levels of copper/nickel separation at the Clarabelle Mill where all Inco's Sudbury Basin ores are processed. This paper reports on the laboratory and miniplant studies car¬ried out during the flowsheet development for a commercial Cu/Ni separation plant. There are two potential feed streams for Cu/Ni separation. It was determined that Cu/Ni separation from the rougher concentrate requires no regrind, and a very clean copper concentrate is produced, but the recovery of copper is limited to about 70% from ore. Cu/Ni separation is more difficult from the bulk concentrate because of the presence of excess flotation reagents in the slurry and due to locked particles. By replacing the slurry water with clean process water, and by addition of some hydrogen peroxide, entrainment is minimized and excess reagents are removed from the surface, providing a satisfactory separation of copper from nickel. Fine regrinding is required to increase liberation of the locked particles and to obtain 85% copper recovery with minimal nickel contamination of the concentrate.

Jan 1, 2005

By A. Eftimie, M. Stanley

The World Bank Group (WBG) believes that extractive industries can make significant contribution to sustainable development and poverty reduction, providing that environmental, social, and corporate governance issues are properly managed. The WBG recognizes that stakeholders have legitimate concerns about the impact of extractive industries, and management proposals are built around the central theme that investments and policy advice in the extractive industries should lead to poverty reduction. To help governments create appropriate policy and regulatory frameworks, this paper focuses on the linkages between overarching policies and laws and the management / governance of extractive industries at the local communities. It encourages the use of new instruments designed to help ensure that local communities benefit from extractive industries.

Jan 1, 2005

By S. Esmaeili

The yield strength model developed by Esmaeili, Lloyd and Poole [1] has been adapted to model isothermal aging in Cu-containing AA6xxx alloys, with (a) a moderate and (b) a very low Cu content in the solution-treated, as-quenched, condition, Isothermal calorimetry has been used to analyze the kinetics of precipitation in these alloys, While the kinetic parameters for the low Cu alloy has been derived from the present experiments, the previously determined kinetic parameters for the high Cu alloy AA6111 has been used to model the precipitation kinetics in the moderate Cu alloy. The age hardening responses of both alloys have been well predicted by the model.

Jan 1, 2005

By Helen Joyce, Larry Twidwell, Jay McCloskey, Eric Dahlgren, Andy Hadden

The reduction of dissolved selenium oxyanions from mine wastewater utilizing an elemental iron cementation technology on been studied on a laboratory scale at Montana Tech of The University of Montana and on a pilot scale at MSE-Technology Applications as a water treatment process potentially capable of removing dissolved selenium to GO WL. Laboratory and pilot scale studies using elemental iron have demonstrated effective removal of dissolved selenium. Enhanced selenium reduction rates have been demonstrated when galvanically coupled iron/copper and iron/ nickel are utilized. The laboratory and pilot scale results are presented and discussed.

Jan 1, 2005

By J. N. Van der Merwe

In the process of pillar extraction, pillars are seldom if ever extracted completely. The pillar remnants, or snooks, play an important role in the extraction process. At the working face, they need to be stable to provide a measure of support in the immediate area. Further back, they have to fail in a controlled manner to prevent undue load build-up on the pillars that have not yet been extracted. The stability condition at the working area is the result of interaction between the stability of the pillar and that of the roof rock. It is shown that the primary mode of roof layer failure is by bending induced tension. Direct tension can be excluded in most practical conditions, and only in exceptional cases will the first failure be in shear mode. Panel spans required to cause the first goaf to be formed, predicted using analytical considerations, are of the same order as has been observed in practice. Once the first goaf has formed, the horizontal stress is reduced and failure will occur at more frequent intervals. It is shown that bending induced tension is the most likely mode of failure in an unjointed roof layer. In roof layers with a high frequency of weak or uncemented jointing, failure can be expected to occur at spans equal to the joint spacing. In this context, failure will occur at the smallest of the spans required to induce tensile roof failure and the joint spacing. A fundamental procedure to evaluate the likely roof layer failure in a stacked beam system is developed. This can to be used to estimate the loading condition on snooks. It is shown that snooks assist in stabilizing the immediate roof beam. The sizes and positions of the snooks relative to the position of the next pillar to be stooped, control the magnitude of the contribution to stability. The further the snook is from the next pillar, and the larger it is, the greater the contribution to the stability of the immediate roof. Under the condition of loading by the immediate, continuous roof beam, the position and size of a single snook controls the load acting on it. The closer it is to the nearest solid, provided that the roof overhang extends beyond the snook, the greater the load on it. However, once the immediate roof beam fails, the loading conditions change. The snook is then loaded by the tributary area load. A procedure is developed to assess the condition of snooks for different situations. Using the fundamental considerations developed in this paper, snooks can be designed to be stable during the active mining phase in their immediate vicinity, but to fail once the next line of pillars has been extracted.

Jan 1, 2005

By Varadajan Seshadri

Keywords: torpedo car, kinetics, physical modeling A 1:6 torpedo car physical model was built to assess the optimum refining conditions for pig iron desulfurization in the torpedo car considering the industrial parameters used in the steel plant CSBM (Companhia Siderurgica Belgo-Mineira, João Monlevade, MG, Brazil). The refining practice in this plant is through injection of a CaO-CaF2-Mg powder in the pig iron melt. Similarity between the model and prototype were established through Froude and turbulent Reynolds criteria. Mixing times were evaluated by pulse tracer addition and the kinetics of metal/slag interactions were assessed from experiments investigating iodine transfer from kerosene to water. The influence of parameters such as level of metal, gas flow rate, lance penetration, lance orientation were also evaluated.

Jan 1, 2005

By Jonguk Kim

Hydrothermal sulfides were recovered from the16°50?S triple junction area in the North Fiji Basin, at a water depth of ca. 1900 m. The chimney samples can be divided into three groups according to their major metal contents: 1) type 1 (Fe-Cu-rich), 2) type 2 (Fe-Cu-rich with minor Zn), and 3) type 3 (Zn-rich) chimneys. Type 1 chimneys are mainly composed of chalcopyrite and pyrite, and are enriched in elements commonly precipitated under high temperature conditions (> 300°C), such as Cu, Co, Mo, and Se. Type 3 chimneys consist dominantly of sphalerite and marcasite with traces of pyrite and chalcopyrite, and are enriched in elements commonly associated with low temperature (150 to 250°C), such as Zn, Cd, Pb, As, and Ga. Type 2 chimneys show mineralogy similar to that of type 1 chimneys but their metal contents range between type 1 and type 3 samples. Trace element compositions of basaltic rocks indicate that magma generation in the triple junction area was influenced by two different sources: N-MORB and E-MORB. Sulfur and lead isotope patterns of the hydrothermal chimneys show distinct differences between the type 1 and type 3 chimneys. For example, type 1 sulfides are depleted in 34S and have lower Pb isotope ratios compared to type 2 and 3 chimneys. The d34S values (0.4 to 5.6?) of chimney sulfides are typical range of sulfur isotope composition of sediment free mid-ocean ridge hydrothermal system. Type 2 and 3 sulfides show slightly higher d34S values than type 1 sulfides, which can be explained by subsurface boiling of hydrothermal fluids followed by mixing of saline solutions with ambient seawater. Lead isotope compositions of the chimneys indicate that the Pb in type 1 and type 3 chimneys originates from hydrothermal leaching of N-MORB and E-MORB volcanic rocks, respectively. Considering that both these chimneys are located in the same area, our model suggests that type 1 chimneys formed by hydrothermal circulation controlled by an intrusion of N-MORB magma; the fluids were not influenced by boiling during the formation of type 1 chimneys. In contrast, type 3 chimneys are younger and were formed by hydrothermal circulation closely related to E-MORB magma intrusion at shallower depth. The necessary conditions for phase separation of the hydrothermal fluids that formed the type 3 chimneys might result from changed P-T conditions in a shallower high-temperature reaction zone beneath the hydrothermal venting site. Under these conditions the fluid may cross the two-phase boundary for seawater, ensuring subcritical phase separation. The mineralogical and geochemical properties of these chimneys suggest that type 1 and type 3 chimneys were probably black smoker and white smoker, respectively. Type 2 chimneys might be product of low-temperature replacement of type 1 chimneys, which is related to formation of type 3 chimneys.

Jan 1, 2005

By David Smith

Construction of a new transportation link frequently requires crossing under an existing highway or railroad. Although traffic diversions may permit a cut and cover structure to be built, ‘zero impact’ tunnel solutions are becoming increasingly popular. The vertical clearance between the new tunnel structure and the existing highway or tracks may be very low; sometimes less than two meters. This leaves little room for error since any ground loss can rapidly translate into surface settlement. Problems can be avoided by maintaining the stability of the tunnel face and by minimizing ground movement around the tunnel lining. This paper examines construction methods that have been used to construct short tunnels with shallow cover, and highlights factors to be considered for future projects.

Jan 1, 2005

By H. J. McQueen

Large-scale industrial production of pipe began with longitudinal hot pressure welding of wrought iron by passage of skelp (narrow strip with beveled edges) through a die or bell that curled it about a longitudinal axis until the edges were forced together. Such small to medium tubes could be reduced by rolling or drawing; with threaded connections, they were excellent for distribution of clean water and of illuminating gas for street, home and industrial lighting. Although steel lacks the fluxing slag for pressure welding it has hot strength similar to iron; hot-pressure bell welding was advantageously transferred to steel in long coiled strip with 50% higher cold strength. For pipe without weld-line defects, hot cupping followed by Pilger mill rolling produced tubing that revolutionized bicycle quality and high-pressure service for boilers and chemical processing. Mannesman hot rotary piercing produced long thick walled tube that permitted reduction or expansion by rolling to provide pipe sections up to 60 cm diameter and 12 m long. During 1910 - 1940, oil and gas pipeline technologies, notably welding evolved markedly as they proliferated in the United States, in response to far-flung petroleum fields, expanding industry consumption and the automobile revolution. In the Second World War combat pipelines were laid rapidly, such as: the Canol line through the Yukon to Alaska, and fuel supply lines across the channel and through liberated France. Perfection of welding techniques for both longitudinal and spiral weld large diameter pipe in combination with controlled-rolling of micro-alloyed steels made possible reliable Arctic pipelines. The development of pipe production and utilization in Canada is recounted. The fabrication techniques and metallurgical controls are explained.

Jan 1, 2005

By Carl Johnson, D. R. Todd

The Blue Ridge Low Level Outlet (LLO) was a design/build contract to provide a secondary means of discharging water from the Blue Ridge Reservoir. The project involved driving a 3.25 m (11 ft) modified horseshoe tunnel by 293.5 m (963 ft) long utilizing conventional drill and blast methodology. The intake shaft and structure were constructed inside of a sheet pile cofferdam surrounded by a maximum of 20.1 m (66 ft) of water. The shaft was excavated 4.87 m(16 ft) diameter to a depth of 12.8 m (42 ft) below the tremie slab elevation. Steel lining, including a transition from 3.66 m to 2.74 m (12 to 9 ft) diameter and a90 degree elbow were installed in the inlet shaft and then backfilled with concrete. This paper will describe the RFP phase, the design phase, challenges of the underground construction and contractual challenges.

Jan 1, 2005

In order to avoid impurity problem and enhance absorption/desorption kinetics of Mg-based compounds, nanostructured Mg-based compounds were synthesized from Mg, Ni and other elemental nanoparticles produced by hydrogen plasma-metal reaction. XRD and TEM results demonstrate that homogeneous nanostructured Mg-based compounds with less impurity were successfully synthesized by this method. DSC in hydrogen atmosphere, pressure-composition isotherm and the kinetics of hydrogen adsorption/desorption were investigated at different temperatures. The results show that the nanostructured Mg-based compounds can absorb hydrogen in a high speed at a low temperature.

Jan 1, 2005

By W J. Botha

The Palaeoproterozoic Transvaal Supergroup in the northern Cape Province of South Africa hosts high grade (>60 per cent Fe) hematitic and specularitic iron and manganese mineralisation. The mineralisation is primarily exposed along the western margin or in the central part of a major interference fold structure known as the Maremane dome. The bulk of South AfricaÆs iron ore production is currently provided by two active mines, Kumba Resources megaton Sishen iron ore mine on the northern end of the dome, and the smaller Assmang Beeshoek mine on the southern closure. The undeveloped Sishen South deposit, which contains ~400 Mt of high-grade hematite ore, is located approximately 9 km towards the southwest of Postmasburg. It forms a linear extension of the Beeshoek mine and as such contains comparable laminated, breccia and conglomeratic iron mineralisation. The Transvaal Supergroup sediments were deposited in two distinct fault-controlled basins on the Archean Kaapvaal craton. Basement rocks in the western Griqualand West basin are formed by a carbonate platform sequence (Campbellrand Subgroup), which is overlain by a thick sequence of banded iron formation of the Asbesheuwels Subgroup. A major unconformity separates these rocks from the red-bed Gamagara Formation, which is correlated with the base of the Olifantshoek Supergroup. Diamictites and lavas of the Postmasburg Group have been thrust over these units from the west. The mineralisation process is related to regional scale supergene iron enrichment of Kuruman banded iron formations along the unconformity. During regional tectonism associated with the Kheis orogeny (2400 - 1700 Ma) the Maremane dome was uplifted, and the basal dolomite units thus exposed to erosion and karstification. The overlying banded iron formations collapsed into karst sinkhole structures where leaching of silica and enrichment of hematite occurred. Although the exact mechanism of the mineralising process remains unclear, karstification preserved components of the original concordant laminated and massive ores. These ores were subsequently eroded and deposited as conglomeratic and gritty ores down-dip of the Maremane dome in alluvial fan systems. A thin veneer of recent calcrete or Tertiary Kalahari clay beds masks the subsurface geology and most of the orebodies, thus ground geophysical gravity surveys proved excellent exploration tools to penetrate the surficial cover. These surveys were used extensively for delineation drilling and to deduce the subsurface geology and structural development of the area. Finally Sishen South orebodies were modelled with ModelVision software in an attempt to obtain an exploration template for the surrounding area.

Jan 1, 2005

By J. Stephen Slottee, Jerold Johnson

The use of a thickener, without filtration, to produce a non-settling paste (also called thickened tailings) with non-Newtonian rheology has been practiced in Australia for many years for the disposal of red mud. The application of paste thickening technology outside of alumina is relatively new. Interest and installations in paste thickening are rapidly growing. Water shortages and environmental pressures make consideration of thickening tailings to solids concentrations within the paste range necessary in most new tailings projects. The paste thickeners at the DeBeers CTP plant in Kimberley, South Africa are the latest example of paste tailings disposal on the surface, also called “stacking”. Houman (2003) The use of a paste thickener as an alternative to filtration for mine paste backfill is a more recently developed application. This paper describes the principles of design and general operating characteristics of a paste thickener compared to the conventional and high-rate thickener. The application and operating performance of paste thickeners in mine backfill is discussed as an example. An integrated approach to process design is described that matches the performance of the thickener, pumping system, and application on a common rheological basis to ensure that none of these steps prevents achieving process performance targets.

Jan 1, 2005