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By Jing Zhan

The fibrous precursor can be obtained by coordination precipitation process, using oxalate, cobalt chloride and ammonia. The composition and morphology of fibrous precursor were characterized by XRD, IR, DTA/TGA and SEM analysis. The results show that XRD pattern and composition of the precursor with fibrous morphology precipitated at pH=9.0 were different from that of ß-CoC2O4?2H2O precipitated at pH=1.0. The mechanism on the thermal decomposition of fibrous precursor was addressed. The influences of various conditions in pyrolysis, including the temperature, time, atmosphere, and the morphology of the precursor, on the morphology, average size and specific surface area of the Co powders were investigated in detailed. At last, the final product, fibrous cobalt powders with diameter about 0.3~0.5µm in size and 40~60 in aspect ratio, were produced by thermal decomposition at 400~500? in the weak reducing atmosphere. The structure of pores in cobalt powders was capillary tube with open ports and the majority was mesoporous.

Jan 1, 2009

By Hebi Yin

A coupled cellular automaton (CA) - finite element (FE) model was developed to calculate the growth of dendrites during the solidification of cubic and hexagonal metals. The model solves the conservation equations of mass, energy and solutes in order to calculate the temperature field, solute concentration and the growth morphology of dendrites, including the grain structure and the dendritic microstructure. Validation of the model was performed by comparing the simulation results with calculation results from previously published works, showing qualitatively good agreement in the dendritic morphology. Application to magnesium alloy AZ91 illustrates the difficulty of modeling dendrite growth in hexagonal systems, observed as deviations in growth direction caused by mesh-induced anisotropy. The model was applied to the simulation of small specimens with single- and multiple- equiaxed grain growths and columnar grain growth in directional solidification. The influence of cooling rate and some kinetics parameters on the grain morphology are also discussed.

Jan 1, 2009

By Hua-qing Li

Electromagnetic stirring process effectively improves the casting quality of metals. In this paper, the physical simulation experiment, in which the molten copper is displaced by mercury, was designed. The factory test parameters were determined according the simulated data. The flow behavior of the mercury to be stirred as well as the relations between the microstructure of plate blanks and the current parameters were analyzed. With an appropriate electromagnetic stirring, the inverse segregation of tin for C51900 alloy plant blank reduces from 15 % ~ 30 % to about 5 %, and the proportion of equiaxed grain rises to larger than 30%.

Jan 1, 2009

By Zhang Qin

Dolomite is main impurity mineral in phosphate ores. In practice of phosphate ores production, the grade of concentrates is only containing P2O5 31-32%.In this study, even the increasing of floatation reagent consumption and decreasing of floatation recovery, economic performance is estimated high according to the decreasing of H2SO4 consumption in subsequent production of phosphate fertilizer and the increasing of products value. In floatation stage, influence factor include the synergism impacts of floatation collector, the stages, time, concentration of ore pulp, which were discussed respectively in this paper. Raw material is characterized by mineralogy, chemical analysis, the grain size analysis and milling test . The results show that the grade of concentration can reach to P2O5 36% by deeply de-magnesium oxide from phosphate ores by floatation , which yield a high added value.

Jan 1, 2009

By De-wen He

The distribution of persistent organic pollutants in the environment is studied using the multimedia environmental fugacity model, and environmental health risk assessment of POPs nearby a copper smelt enterprise is carried out. The result indicates that all are in an agreeable risk level without exception. The annual individual chronic risk index of HCB is 7.50×10-11. The annual individual risk index of 3,3',4,4'-TCB is 1.57×10-9, and the annual individual risk index of 2,3,7,8-TCDD is 6.57×10-9.

Jan 1, 2009

By Daoxin Wu

Originated from(C4H9O)4Ti, nano--rutile TiO2 was synthesized by low temperature hydrolysis process in this paper. After being prepared by decomposing ammonium tungstate and covering on the surface of TiO2, TiO2/WO3 were characterized by means of X-ray diffraction(XRD), UV--vis difuse reflectance(DRS), fluorescence spectrum (FS). Results showed that with the increase of the supported concentration of WO3, the reflectance of DRS and the fluorescence spectrum intensity of TiO2/WO3 decreased accordingly, which indicated the powder?s increase in light absorbance and the decrease in luminescence respectively; with the increase of calcined temperature, the reflectance of DRS increased.

Jan 1, 2009

By Elli Miettinen

In Copper Flash Smelting operation disturbances may lead into dust build-up in the gas train and off-gas handling system causing reduced heat recovery efficiency and process availability. Flue dust of a Copper Flash Smelting process heat recovery boiler has been characterized and its thermal conductivity and diffusivity have been determined. Dust accretions consist of several layers possessing varying particle sizes, densities, and thermal properties, with the binding phase usually being sulphate. All the dusts can be regarded as effective thermal insulators with thermal conductivity values of less than 2 W/mK and thermal diffusivity values of less than 0.005 cm2/s. Porosity can be regarded as a fairly good indicator of the thermal transport efficiency of these types of materials, but the material microstructure must also be considered. The results can be used in the dimensioning of metallurgical heat recovery boilers and they also provide accurate input data for process models.

Jan 1, 2009

By Thomas Niehoff, Dave Stoffel

"Energy in the form of natural gas, oil and electricity is expensive and will continue to be a rare resource in the future. Recycling of metals, instead of primary production, is a logical and crucial step towards energy conservation. Energy consumption can be impacted by using advanced combustion systems for metals recycling. Air-fuel combustion has been the conventional method to melt and recycle metals. Global competitive pressures, “greenhouse” gas emissions, and high energy prices force melt shop operations to optimize energy usage and reduce overall operating costs. Oxy-fuel combustion and process technology can be applied to metal recycling operations to meet these objectives. Linde has converted several hundred furnaces from air-fuel to oxy-fuel technology and has extensive experience in optimizing the use of oxygen in furnaces. Additionally, Linde has the process knowledge necessary to avoid costly start-up issues that can accompany the transition to oxy-fuel technology. This paper will describe the benefits and potential issues for conversion to oxy-fuel.IntroductionThe furnace combustion system is the heart of a fossil fuel fired melting process and must be properly matched to the furnace to work as one cohesive unit. Furnaces vary widely in size, shape and features. Rotary furnaces are barrel-shaped and can be designed for tilting or nontilting operation. In a rotary furnace, the products of combustion create a single or double pass through the furnace prior to exiting. Reverberatory furnaces are box-shaped and can also be designed for tilting or non-tilting operation. Reverberatory furnaces are constructed of single or multiple chambers, with or without metal bath movement, and designed for continuous or batch processing. Different furnaces are used for different feedstock materials and products.Furnace combustion systems also vary in many ways. Combustion systems can be of air-fuel or oxy-fuel based technologies, or a combination of the two, resulting in an air-oxy-fuel system. Each of these types of systems has different combustion characteristics which can produce very different results. Here we will describe specific differences in melting processes and their associated energy requirements."

Jan 1, 2009

By P Christen, D R. Ashley, G R. Power

The Ernest Henry Mine is currently a copper-gold open pit operation situated in north-west Queensland, Australia. It is owned and operated by Xstrata Copper with a current throughput of 11 million tonnes per annum; however, open pit operations are scheduled to cease in late 2011. The deposit dips at approximately 45¦ and extends for at least another 400 vertical metres below the final 530 m deep pit design. Resource drilling from 2002 until mid 2008 has enabled an Indicated Mineral Resource to be established to 1000 m below surface. Scoping and prefeasibility studies (PFS) have been completed toward determining if this resource is suitable for underground mining and a feasibility study is currently progressing with a sublevel caving (SLC) concept. This paper briefly describes the process by which the SLC method was selected, conclusions regarding the non-selected methods, and then discusses the optimisation process used to derive the mining plan. The key optimisation parameters include the production drive spacing, level spacing, draw strategy, cut-off grade and production rate. Key risks will then be assessed and economic sensitivities studied. Final sensitivities will use Monte Carlo simulations to improve the transparency of the projectÆs risk profile. The feasibility study (FS) began in March 2008 and this paper describes the main optimisation steps at the time of writing and outlines the plan for study completion through to March 2009.

Jan 1, 2009

By H Benzer, N A. Aydogan

It is well known that the high pressure grinding rolls (HPGR) can only be operated efficiently under choke feeding conditions in which a material bed is built up between the rollers to ensure interparticle breakage. By increasing the fines amount in the material bed up to a specific level with the recycling load, a uniform material bed is created and higher pressure gradient along the roller width is obtained which results in compact flakes including more fines. Extensive test work has been carried out with an industrial HPGR unit grinding cement clinker in a cement plant in Turkey. During the test work the recycling load of the circuit was changed to achieve different ratios to the fresh feed rate in order to identify the effect of the recycling load on the circuit performance. Six different tests were performed with the circuit at steady state. For each test, samples were collected from HPGR fresh feed and discharge, and total feed, then the particle size distributions of the samples were determined and mass balances around the circuit were calculated. The conclusion was that the reduction ratio of the HPGR increased with increase in recycling load. The flake densities showed the same trend with more compacted flakes being produced for higher recycling loads.

Jan 1, 2009

Jan 1, 2009

By J. Doucet, C. Price

In an industrial setting, operational changes are continually introduced, driven by new technologies or changing economics. Because of day-to-day variability, quantifying the impact of these changes based on metallurgical performance requires long trial periods to achieve statistically significant results. Tools and techniques developed by the mineral processing group at McGill University have allowed for direct measurement of process variables (e.g., bubble size, gas and solid holdup). Two case studies are described where direct measurement techniques were used to evaluate: a) a new rotor stator mechanism; and b ), the introduction of a new frother type. Application of these methods has accelerated the evaluation of process changes and improved confidence in results.

Jan 1, 2009

By J. C. Squire, E. W. Baker, G. A. Sullivan, G. W. Flathers

A mine collapse severs communication with trapped miners. Landlines are crushed and commercially available radios cannot penetrate hundreds of feet of dense, conductive earth without the use of regenerative repeaters that may also be crushed. This paper describes a proof-of-concept device that uses seismic P-waves, instead of radio waves, to allow communication of a code that represents prearranged messages, including the safe haven location identifier, number of people and air quality, from trapped miners to aboveground rescue units. The transmitter designed is about 0.03 m3 (1 ft3) in size and can broadcast for four hours from its 27-kg (60-lb) battery pack. The receiver consists of a geophone and a 2.5-kg (5.5- lb) signal conditioning unit attached to a laptop computer, which displays the communication signal in real time. Testing in a bituminous coal mine with an MSHA representative revealed the device was able to transmit through 271 m (890 ft) of overburden, at 0° and 12° from vertical, using 500 W of power.

Jan 1, 2009

By L. Patts, J. Rohrbaugh

The Mine Safety and Health Administration (MSHA) has received several reports of filters igniting when high-temperature disposable filters were used on non-cooled diesel exhaust systems in underground coal mines. Based on laboratory testing (to determine the ignition temperature of these filters, which were loaded in the field with diesel particulate matter, or DPM), MSHA determined a maximum safe operating temperature for high-temperature disposable filters. When the results of the laboratory filter ignition testing were reported to the Coal Diesel Partnership (comprised of members of the Coal Industry, Labor, NIOSH and MSHA) the Partnership charged NIOSH with investigating the safe use of high-temperature disposable filters. This paper reports on the design, fabrication and testing of a unique exhaust gas cooling device and the ability of this device to successfully lower filter inlet temperatures and thus reduce the potential for fires.

Jan 1, 2009

By M. R. Hieb, J. R. Britt, S. P. Harteis, M. J. Sapko, E. S. Weiss, R. K. Zipf

The design requirements for mine ventilation seals have undergone a radical transformation in recent years, and these revisions have greatly increased the cost of the seal designs and their construction. For example, in the past two years, new federal regulations have increased the minimum design requirement to withstand explosion pressures from 138 kPa (20 psig) to 345 kPa (50 psig) or 827 kPa (120 psig), depending on whether the sealed mine volume is monitored continuously or not. Moreover, there is still a possibility that under certain conditions (such as detonations), even higher pressure requirements may be necessary. The ability of a monolithic, stand-alone mine seal to reliably withstand the full range of possible explosion pressures is becoming increasingly difficult and expensive. In an effort to develop a practical alternative, the West Virginia Office of Miners’ Health Safety and Training (WVOMHST) and the National Institute for Occupational Safety and Health (NIOSH) have collaborated in a research effort to develop a practical, economic and safe mine sealing technique that can enable mine seals to meet the full range of new explosion pressure design requirements. The basic idea is to use a barrier of common mine gob and rubble, in combination with a conventional mine seal, so that the pressure resulting from a gas explosion is reflected, absorbed and attenuated, and the pressure on the ventilation seal is reduced. This paper discusses some concepts and preliminary test results for a “passive mine blast attenuator” (PMBA) that can provide a useful alternative to increasingly larger and stronger stand-alone mine seals. Numerical models and full-scale experiments conducted at the NIOSH Lake Lynn Laboratory Experimental Mine (LLEM) show that the use of a PMBA can signficantly reduce the blast pressure and impulse on conventional ventilation seals.

Jan 1, 2009

By C. V. Deutsch, O. Babak

A longstanding problem in geostatistics is that kriging usually assigns significantly greater weights to end samples in strings of data than it does to central samples. These weights are theoretically valid, but suboptimal estimates may result when there are geological trends in the variable near contacts, that is, large weights may be applied to samples that are systematically lower or higher than average. A number of ad-hoc corrections exist, each with pros and cons; none are fully automatic with a well-defined measure of optimality. A new method for estimation in a finite domain is proposed. This method is referred to as finite domain kriging. The method is based on kriging with a successively larger number of data. The total number of relevant data (n) is established, and then n kriging matrices are solved. The first matrix has the closest single data value (n-1 weights are set to zero); the second has the two closest data (n-2 weights are set to zero) and so on. The final matrix has all n data. The kriging weights used for estimation are the average of the weights from the n successive kriging runs. Each kriging run is optimal, yet with different smoothing and a different treatment of data at the end of the strings. The result is a set of weights that does not give undue influence to data values at the end of strings. The methodology is developed with examples. Cross validation shows that finite domain kriging outperforms conventional kriging.

Jan 1, 2009

By J. Brune, P. J. Coleman, L. Martini

Research in the field of mining safety and health in the United States plays an important part in protecting the lives of miners. The National Institute for Occupational Safety and Health (NIOSH) Mining Program conducts surveillance, studies and developmental work aimed at improving the safety and health of miners. With recent reviews of the Mining Program by the National Academy of Sciences and the Mining Program response (NIOSH, 2008), the importance of setting goals, conducting high quality engineering and scientific research and evaluating the outputs, outcomes, relevance and impacts of these projects has been reemphasized. Surveillance of reported injuries is a first step in deciding on research directions and in designing specific projects. Groups of injuries often share features and attributes that suggest common causes and may respond to similar preventive efforts. Identifying groups of injuries also serves to prioritize intervention efforts. The Mine Safety and Health Administration (MSHA) Accident and Injury database (MSHA, 2008) provides individual case reports of mining injuries, illnesses and certain no-injury accidents (events such as roof falls that stop mine production or miners’ activities for more than one hour). This database is an indispensable resource for researchers and stakeholders needing information on the statistics of these events. From an epidemiological perspective, research projects target groups of miners at risk due to specific patterns of work, equipment, mine settings and the management of safety and health in their mines. Incidence rates are provided by the MSHA data for selected variables, such as surface/underground location, standard industrial classification and state. While incidence rates are the preferred measure for all variables, denominators are not typically available; for example, to more clearly understand the data about injury by occupational type, it would be necessary to conduct demographic surveys. A current survey of the demographics of the mining industry should be complete by 2010, which will allow incidence rates to be developed for a number of variables such as age, occupation and experience. This survey will provide the first update of its kind since the first survey was conducted in 1985. This report describes an alternative method of analyzing and presenting MSHA data for the purpose of identifying high-cost, high-severity injuries and illnesses. Researchers at the NIOSH Spokane Research Laboratory (SRL) developed programs to find the top five most frequent accident classes, natures of injury, types of accidents and other selected variables from the MSHA database. Studying these variables gives a cross-sectional snapshot of the most frequent groups of injuries within a commodity, regional group or time period, and allows researchers to quickly understand developing patterns for new research projects. The primary benefit of this approach is to

Jan 1, 2009

By F. Varley, J. Whyatt

A variety of dynamic failure cases with regional impact were described at a bump symposium held in 1958. These types of events, while rare, are of particular interest because their ability to impact a large area has disaster potential. These cases can be grouped into two broad classes of events by mechanism. These are (1) a slip along steeply dipping faults and (2) the fracturing of strong strata above or below the coal seam. Both failure modes produce dynamic or “shock” loads on the perimeter (roof, rib and floor) of mine openings. Special consideration should be given to these failure modes in the planning of deep coal mines, since their occurrence is not within the professional experience of many contemporary workers. In addition, their potential is not evaluated by many of the analysis tools commonly used to evaluate hazards in coal mine plans.

Jan 1, 2009

By J. Paraszczak

Metal mining at great depths presents a number of serious challenges for mine operators. Among them is the high demand for fresh air required to cool down mine openings, evacuate noxious gases and contaminants and provide sufficient amounts of oxygen for miners. At the same time, modern mechanized mines extensively use diesel-powered load-haul-dump (LHD) machines, trucks and other mobile equipment. These vehicles not only emit exhaust gases and diesel particulate matter (DPM), but constitute an additional source of heat. As mine regulations get steadily more stringent with regard to air quality, the use of diesel engines has an additional adverse impact on ventilation costs. In this context, the present paper examines possible alternatives for diesel power trains, both those commercially available and those in development. They are reviewed with regard to their principles, required infrastructure, stage of technology development and progress. The questions of their flexibility, practicality and economic viability are also addressed. Finally, their possible benefits and potential for implementation in the conditions of deep metal mines are discussed. The paper concludes with short- to medium-term predictions concerning promising drive alternatives for vehicles destined to operate in deep metal mines.

Jan 1, 2009

By A. G. Mayton, D. H. Ambrose, C. C. Jobes, N. K. Kittusamy

In a systematic study, the National Institute for Occupational Safety and Health (NIOSH) evaluated seat designs in low- and mid-seam shuttle cars during production operations at two underground coal mines in southern West Virginia. The purpose was to support, with additional data, earlier findings that NIOSH ergonomic seat designs (featuring viscoelastic foam padding and lower-back support) may help reduce health risks to operators of coal mine shuttle cars. Eight shuttle car operators evaluated seven seat designs (one already in use in each vehicle and five NIOSH designs) relative to perceived and measured whole-body vibration (WBV) exposure (including vehicle jarring/jolting) and discomfort. Operators’ perceptions using a visual analog scale (VAS) and questionnaire ratings were compared with International Standards Organization (ISO) 2631-1:1985 fatigue-decreased proficiency (FDP) limits and measured WBV levels on low- and mid-seam shuttle cars. Objective and subjective data results indicated that NIOSH seat designs (with added adjustability, lower-back support and improved seat padding) performed better to reduce vehicle jarring/jolting levels and that shuttle car operators favored them over existing seat designs. The NIOSH low- and mid-seam shuttle car seats showed 45 to 77 percent better performance in FDP and 9 to 60 percent better performance overall in operators’ ratings. Considering the VAS results for low- and mid-seam shuttle cars under no-load conditions, operators rated the level of jarring/jolting 18 to 89 percent lower with the NIOSH seats. Reductions in measured vehicle jarring/jolting were 19 to 46 percent for the three-directional vector sum accelerations relative to the existing seats on the low- and mid-seam shuttle cars. Questionnaire responses indicated that operators for both shuttle car models rated NIOSH seat designs as more comfortable overall. Vehicle operators most frequently suggested adding armrests to improve the seats on the mid-seam shuttle car. A suggested improvement for the low-seam shuttle car was to make the seat a better fit for the operator compartment, which would enhance clearance between the operator and vehicle controls and allow for better seat adjustment and operator visibility.

Jan 1, 2009