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By Katarina Theander, Robert J. Pugh

The generation of froth with a critical degree of stability and height is an important aspect of the froth flotation. In this paper we have studied the synergism and anti-synergism in frothing behaviour in a mixed flotation collector/frother mixture (a model fatty acid; sodium oleate and a model frother; nonionic (polyethyleneoxide alkyl C14E6). Values of the collector / frother molecular interaction parameters (the ß-parameters) were determined from the surface tension data using regular solution theory. The frothing characteristics of the system were evaluated using a glass column equipped with a series of conductivity electrodes, which enabled the water content of the froth to be determined. From these measurements, the dynamic frothability and static froth stability were determined. It was concluded that the synergism/anti-synergism in frothability was depended on the molecular composition of the surfactant system, the diffusion of monomer to the thin film interface and on the breakdown of the mixed nonionic/anionic micelles.

Jan 1, 2003

By Avishan Atrafi

Frothing behavior of surfactants originate from their preferential adsorption at the gas-solution interface. Different surfactants may demonstrate different adsorption behaviors depending on their molecular structure and surface activity. The quantity and rate of adsorption of surfactants at the gas- solution interface in flotation systems will certainly affect kinetics of reaction and fractionation of surfactant between bulk and foam phase and subsequently their frothing characteristics. In this paper, the frothing characteristics of sodium oleate which is the main constituent of fatty acids used in flotation systems is explained. The adsorption behavior of sodium oleate is then compared to a typical non-ionic frother (Methyl Isobutyl Carbinol, MIBC) in terms of different adsorption behavior at the gas-solution interface. Since long chain fatty acids are weak electrolytes, their behavior is a strong function of pH. Also semi soluble salts including apatite contain considerable amounts of ions like calcium in their lattice, so the effect of presence of ions on the frothing behavior of fatty acids requires an investigation. A mass balance on the surfactant transferred to the foam was solved to estimate the bubble surface area flux in foam, which explained how the adsorbed surfactant at gas-solution interface controls the bubble surface area flux at foam. Since sodium oleate adsorption at foam takes place gradually, frother concentration as a function of time was monitored by the total organic carbon measurement (TOC) to compare the surfactant uptake rate at different concentrations, pH and ionic strength. The surfactant concentration adsorbed within foam together with the value of adsorption density from the Gibbs adsorption, leads to the calculation of the surface area flux and prediction of average bubble size in the foam at a specific time frame. This value was compared at different concentrations of sodium oleate. Dynamic surface tension measurements were accompanied to explain the adsorption behavior, though finally equilibrium surface tension turns out to better explain the foamability characteristics. Keywords: flotation collectors, flotation froths, foams, fatty acids, adsorption behavior

Sep 1, 2012

By Shiou-Chuan Sun

THIS paper presents the design and operation of a frothmeter capable of measuring the frothing characteristics of pine oils and other frothing reagents. The experimental data show that the frothability of pine oil is governed by: 1-rate of aeration, 2-time of aeration, 3-height of liquid column, 4-chemical composition of pine oil, 5-pH value of solution, 6-temperature of, solution, and 7-concentration of pine oil in solution. The effect of mineral particles on the behavior of froth also was studied, and the results can be found in a separate paper.1 The results also show that the relative frothabilities of pine oils in the frothmeter generally correlate with those in actual flotation, provided that other factors are kept constant. In addition to pine oils, the other well-established flotation frothers were tested, and the results are included. In this paper, compressed air frothing is the frothing process performed by means of purified compressed air, whereas sucked air frothing is the frothing process accomplished by purified air sucked into the glass cylinder by a vacuum system. The term vacuum frothing denotes that froth was formed by degassing of the air-saturated liquid under a closed vacuum system. Apparatus The frothmeter, shown in Fig. 1, is capable of reproducibly measuring the volume and persistence of froth as well as the volume of air bubbles entrapped in the liquid and is capable of being used for compressed air frothing, sucked air frothing, and vacuum frothing. Fig. la shows that for compressed air frothing, the apparatus consists of an airflow regulating system, 1-3; a purifying and drying system, 4-8; a standardized flowmeter to measure the rate of airflow from zero to 500 cc per sec, 9; and a graduated glass cylinder, 13; equipped with an air regulating stopcock, 10; an air chamber, 11; and a fritted glass disk to produce froth, 12. The fritted glass disk, 5 cm in diam and 0.3 cm thick, has an average pore diameter of 85 to 145 microns. The pyrex glass cylinder has a uniform ID of 5.588 cm and an effective height of 63 cm. The inside cross-sectional area of the glass cylinder was calculated to be 24.53 sq cm, or 3.8 sq in. For sucked air frothing, Fig. lb shows that the apparatus for compressed air frothing is used again, with the following modifications: 1-compressed air and its regulating system, 1-3, are eliminated; and 2-a vacuum system, 16, equipped with a vapor trap, 15, and a vacuum manometer, 17, is added. The vacuum system can be .either a water aspirator or a laboratory vacuum pump. Any desired rate of airflow can be drawn into the glass cylinder, 13, by adjusting the opening of the air regulating stopcock, 10. The sucked air stream is cleaned by the purifing and drying system, 4-8, before entering the glass cylinder, 13. When this setup is used for vacuum frothing, the air regulating stopcock is closed. The frothmeter has been used for almost 3 years and has proved to give reproducible results, as illustrated in Table I. With a magnifying glass and suitable illumination, the frothmeter also can be used to study the attachment of air bubbles to coarse mineral particles.2 Experimental Procedures Except where otherwise stated, the data presented were established by means of the compressed air method. The volume and persistence of froth were recorded respectively at the end of 4 and 6 min of aeration at a constant rate of airflow of 29.3 cc per sec which is equivalent to 71.6 cc per sq cm per min, or 462.6 cc per sq in. per min. The aqueous solution for each test, containing 1000 cc of distilled water and 19.2 ± 0.5 mg frothing reagent, was adjusted to a pH of 6.9 ± 0.2. The volume of froth is expressed as cubic centimeter per square centimeter and is equivalent to the height of the froth column (the distance between the bottom and the meniscus of the froth). The volume of froth was obtained by multiplying the height of froth by the cross-sectional area of the glass cylinder, 24.53 sq cm. Before each test, the glass cylinder, 13, was cleaned thoroughly with jets of tap water, ethyl alcohol, tap water, cleaning solution, tap water, and finally distilled water. The cylinder with stopcock,

Jan 1, 1952

Frothing in Seawater Flotation Systems

Sep 13, 2010

By James A. Finch, Xiang Zhou, Yue Hua Tan

Methods to determine frother functions, control of bubble size and froth properties, are now widely used. Some collectors also exhibit frother functions which are less understood. Using a water-air system in a mini-mechanical flotation cell setup, this paper determines bubble size and water overflow rate for three amine collectors: one primary amine (dodecylamine, DDA) and two commercial ether amines (Flotigam® EDA and Flotigam® 2835-2L) and their combination with two common frothers, MIBC (methyl isobutyl carbinol) and PPG 425 (polypropylene glycol, molecule weight 425). Compared to the frothers, the amines were less effective in reducing bubble size, giving larger minimum size and the two commercial amines showed evidence of coalescence at low concentration. In blends, at fixed frother dosage, frother eliminated the coalescence but as amine concentration increased the amines dominated bubble size. Water overflow was a strong function of reagent type. For fixed 1-cm froth depth, PPG 425, Flotigam® 2835-2L and to a lesser extent DDA produced overflow while MIBC and Flotigam® EDA did not. In blends with frother overflow increased except with Flotigam® EDA. Mechanisms are briefly explored. The principal benefit of blending identified is the elimination of coalescence if residual concentration of the two commercial amines is below ca. 10 ppm.

By W. L. Freyberger, R. B. Booth

Froth flotation is a chemically induced method for beneficiating or up- grading an ore, which utilizes a layer or column of froth as a separating medium to segregate and remove the valuable minerals from the worthless gangue components of a finely ground ore suspended in water. The object of this chapter is to discuss the theoretical aspects of froth formation, the various frothing agents employed in flotation, and the effect of chemical structure on froth formation, and to correlate these factors with flotation technology. The flotation method of separation is conducted in three main steps: 1) selective chemical modification of the surface of specific mineral particles to effect floatability or nonfloatability; 2) contact between air bubbles and mineral particles, the selective adherence of floatable minerals to these bubbles, and the rejection of nonfloatable minerals; and 3) separation of the floatable minerals from the nonfloatable minerals. As indicated above, these three operations are achieved by the use of chemicals. Frothers play their most important role in the second and third steps by influencing particle- bubble contact and by affecting the degree of separation obtained in the froth column. Frothers, as defined by flotation operators, are compounds that are used specifically for the purpose of creating a froth in a flotation separation. How- ever, some collectors produce froths that are adequate for some flotation operations. Although this chapter is chiefly concerned with the specific frothers used in flotation, some discussion of frothing collectors is included. Otherwise, collectors (or promoters) and modifiersare not discussed at length; for information on these types of flotation chemicals, the reader is referred to other sections of this book or to other sources.l HISTORICAL DEVELOPMENT OF FROTHING AGENTS Historically, there are two distinct phases in the development of frothing agents and other flotation chemicals: 1) 1860 to 1920-oil flotation, and 1921 to date-chemical flotati0n.2~3 Early in the first period, large quantities of fatty and oily materials, up to 10 to 20% of the weight of the ore, were used as a means of separating the sulfide and oxide components from the gangue minerals in ore pulps. Later, various gases replaced these large quantities of oil as a buoyant and separating medium, decreasing oil requirements to less than 1% of the weight of the ore. With this reduction in oil

Jan 1, 1962

By K. Rushdi, B. E. Abulnaga

The conventional Froude number is blind to the presence of solids, their density and their concentration in a stream of slurry mixture such as tailings flowing in an open channel. This often leads to rough approximations of subcritical, critical and supercritical regimes, based on one phase flow Froude number, limiting subcritical to a value smaller than 0.8 and supercritical to values above 1.4, as proposed in the past by Green, Abulnaga and other authors. While acceptable for small flows, such approximations can be uneconomical for the larger flows encountered in some modern plants that treat up to half a million t/day. A review of concepts of a densimetric Froude number sheds some light on the effect of solids on stratification prior and subsequent to a hydraulic jump. While the approach is heavily borrowed from modern sedimentology, it provides a useful tool to designers of large launders or open channel tailings systems. These concepts are reviewed with some practical examples.

Jan 1, 2013

By Daniel Cluff

Frozen backfill for mining operations in permafrost must be delivered in such a state so as not to thermally impose on the host rock surrounding the filled stope. The placement process, the material strength demand, and the freezing time delay are the parameters that control the applicability of the method. A two-year research program was carried out in the field and using a laboratory-scale apparatus, designed to simulate a pour of frozen backfill, to study the mixing, thermal properties and segregation. The frozen rock and tailings must be at a below zero temperature and get fully wetted so the surfaces cause adherence of the particles to one another and enhance the solidification of the poured backfill. The results provided a recipe and a process for mix design for open stoping operations in cold regions. The testing evaluated the sensitivity of the test parameters that included the amount of water added in the mix, the temperare of water, the rockfill/tailings ratio, and the temperature of solid constituents.The paper presents the result of this environmentally friendly, innovative technology. The distribution of the materials and the mixing process are instrumental in achieving the properties required for open stoping applications.

Oct 1, 2010

By Jacques H. Nantel, James F. Archibald

"Frozen tailings material may be required, in the future, to perform the support functions of underground backfill in mines located in zones of permafrost, notably in the high Arctic. To date, no knowledge of physical support parameters of such materials has been obtained in Canada due to the limited mining activity in permafrost regions. It is therefore judged essential that the important physical and mechanical properties relating to frozen tailings material be assessed.Innovative mining methods will be required to cope with the harsh environmental conditions that exist at mining sites in the Canadian Arctic. A preliminary laboratory study, in the absence of field trials at limited Arctic mining sites, has been completed in which the physical and mechanical properties of several types of representative mill tailings mixtures have been investigated. A variety of tests, to determine frozen slurry and pelletized tailings strength properties, moduli of compression, optimum water contents, deformation characteristics and the like, have been conducted.The results of this study will be used to establish guidelines for the suitability of tailings use in such northern mining environments. IntroductionFrozen tailings material has never been used to backfill underground openings in Canadian mines. At present only one Canadian mine, the Polaris Mine situated on Little Cornwallis Island, is investigating the use of frozen backfill. However, the Canadian North covers a large territory and potentially contains a large number of mineral deposits. The understanding of concepts related to mining activities in sub-zero frozen ground is therefore important.The implications of using frozen tailings as underground backfill material are far reaching both from the point of view of mine stability and disposal of tailings in the arctic regions.The strength of frozen materials (soil, backfill, etc.) may take on different meaning depending on the engineering situation. Both the concepts of rupture and excessive deformation need to be considered.The functions usually required to be performed by the backfill material in underground mines may be summarized asfollows:a) working floors; such as in cut-and-fill stopesb) stope wall support; for cut-and-fill and delayed fill stope~c) self-support when backfill is exposed on one face; during pillar recovery phases.For fill functions such as working floors, the short-term response of the frozen fill is the dominant concern. For the other fill functions, the long-term deformation response of the frozen fill, or creep, is of interest."

Jan 1, 1986

By Derek J. Cyr

Climate has an immense impact on the properties of Athabasca oil sands and the ease or difficulty with which it is excavated and extracted. During the winter months, exposed oil sands surfaces freeze. When hydraulic and electric shovels used in the various operations in the Fort McMurray area excavate the benches, large frozen lumps are created. These lumps are either destined for a lump dump where increased costs are incurred due to rehandle, or they are sent to the primary crushers where they can cause significant downtimes by jamming the crusher. The crusher down time can sometimes be in the order of hours of lost production. Studies on data from two consecutive winters at Syncrude Canada?s North Mine show a high correlation between climate and the generation of frozen oil sands lumps. Temperature, ground cover, traffic, bench exposure time, oil sands grade and moisture content all contribute to this problem. A 1D frost penetration model was used to predict the depth of frost expected in oil sands and the corresponding likelihood of frozen oil sands lumps. To combat the challenge of frozen lump generation, a number of proactive and reactive measures can be taken: artificial snow, shallow ponds, scheduling, blasting or ripping.

May 1, 2004

By David Goodman

The typical operating conditions in Solvent Extraction plants are presented. The various materials of construction used for solvent extraction equipment are reviewed and the history of their use presented. The properties of the materials in common use today, stainless steel, thermoplastics and fiber reinforced plastics, are compared together with cost data. The manufacturing and construction aspects of these materials are discussed.

Jan 1, 2003

By L. Ozdemir, B. Asbury, T. G. Rozgonyi

A new type of bit, that has been developed and is being evaluated, shows great potential in expanding the range of rock strength that can be cut by continuous miners and roadheaders. This new style of bit is called the frustum. The tools tested in this program were developed, manufactured and patented by Briese Industrial Technologies, Inc. The frustum derives its name from the unique geometric shape of the cutter, or cutting insert. The frustum shape cutting tool has previously been proven as an effective cutting tool for machining metals, metal matrix composites and polymers. The frustum rock bit has a very dense carbide frustum shape tip mounted on the end of a steel body similar to the conical bits typically used on continuous miners and roadheaders. In between the carbide frustum cutting tip and the steel body there can be a bearing that allows the frustum to rotate around the bit axis. When the bit is forced into the rock at a skewed angle, the frustum tip rotates as it travels. This rotation greatly reduces the cutting forces acting on the bit when compared to the current state of the art conical drag bits. This cutting force reduction, derived from the frustum’s cutting action, allows for much harder and more abrasive rock to be cut without quickly wearing out the bit. Full scale laboratory cutting tests have been performed with the frustum bit in direct comparison to the current state of the art conical bits. Field trials of the frustum bit are currently being planned. Test procedures, results and findings are presented.

Sep 1, 2001

By Abolfazl Eslami, Masoud Zare, Ali Asadi, Ali Abrang

"Physical small scale models for study of deep foundations can be performed in simple chambers (1g), calibration chambers (CC), and centrifuge apparatus (ng) which involve some limitations and difficulties. In recent years, Frustum confining vessels (FCV) have been developed for physical modeling of deep foundations. This device is frustum of a cone shape that applies a steady pressure on its bottom and creates a linear stress distribution along its vertical central line. A new FCV which has been built in AUT is introduced. This device has a height of 1200 mm, top and bottom diameters of 300 and 1300 mm, respectively. Through the application of bottom pressure up to 300 kPa, the insitu overburden stress conditions equivalent up to 40 m soil deposits consistent to the embedment depth of commonly used piles. Observation indicated that there is approximately a linear trend of stress distribution, and this device can create realistic overburden stress in the desired control volume along the central line. Moreover, a couple of compressive and tensile load tests were performed on steel tubular open end model piles driven in sand with length of 750 mm and different diameters and L/D ratio between 8-15. Comparison of load capacity between tested and full scale piles demonstrate a suitable conformity for similar confinement conditions. Therefore, the FCV can be realized as an appropriate apparatus for investigation of piling geotechnical behavior and examination of construction effects.IntroductionDeep foundations are designed as foundation system for supporting heavy loads, high rise and important structures. Different theoretical, numerical and experimental approaches have been developed to study the geotechnical behavior of deep foundations. Experimental methods are employed to clarify directly pile-soil interaction and because of repeatability, analogy, rapid measurement and cost efficiency, physical modeling can be realized as an intermediate technique compared to element testing and full scale load tests."

Jan 1, 2015

The FSPE Award for Services to the Engineering Profession was awarded to Or Francis George Hill at a ceremony held in January of this year by the Federation of Societies of Professional Engineers. The following is an abridged version of the citation made by Professor A.N. Brown, President of FSPE, and of Or Hill?s reply. Achievements. It is indeed fitting that such a distinguished group of people have gathered on this special occasion to honour and pay tribute to Or Pinkey Hill

Jan 1, 1988

By C. A. Young

Previous experimental results have shown that an increase in temperature and/or oxygen concentration leads to an increase in the hydrophobicity of fluorite (CaF2) with adsorbed oleate. Subsequently, ex-situ Fourier transform infrared (FT-IR) transmission studies suggested that this increase in hydrophobicity was the result of double-bond reactions between adjacent oleate species adsorbed at the fluorite surface. Now an in-situ FT-IR study on single crystals of fluorite has been used to monitor this phenomenon using internal reflection spectroscopy (IRS) with the crystals serving as reactive internal reflection elements. The double-bond reaction has been correlated with in-situ adsorption density measurements. These results demonstrate that only the first chemisorbed oleate layer undergoes the double-bond reaction at an appreciable rate. However, multilayers of precipitated calcium oleate in the case of fluorite appear to react minimally even for oxygen saturated solutions at elevated temperatures.

Jan 1, 1991

By E. Suoninen, K. Laajalehto, L. Kartio

Efficient separation of pyrite from other sulfides is of great importance for the metallurgical performance of flotation processes. In this work Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Photoelectron Spectroscopy (XPS) were used to study the surface chemistry of pyrite in depression, activation and xanthate adsorption under conditions of controlled potential. Modifications of pyrite surfaces after treatment with depressants (lime, sulfur dioxide, sodium cyanide) and after activation with metal ions (Cu, Pb) were studied. The principal adsorption product identified on pyrite was dixanthogen whose formation started at about +0.15 V and +0.25 V (vs, SHE) in ethyl and amyl xanthate solutions, respectively. Copper xanthate was formed on copper(II) activated pyrite. Activation mechanism of pyrite by copper(II) salts is likely to be electrochemical where copper occurs as copper(I) on the surface of pyrite. Effective depression is achieved by sulfur dioxide and sodium cyanide. Depression at high pH is due to formation of iron(III) hydroxides. Calcium ions do not affect the electrochemistry but adsorb on pyrite and reduce the surface sites for dixanthogen adsorption.

Jan 1, 1995

By Gu Guohua, Hu Yuehua, Zhang Qin

The flotation behavior of pyrrhotite was investigated by using ethyl xanthate as a collector. Results showed that pyrrhotite had good floatability from pH 2 to pH 11, and poor floatability when pH was >12. The flotation of pyrrhotite was dependent on pulp potential on various pH values. The potential-pH range for pyrrhotite flotation was established. Cyclic voltammeny and FTIR spectroscopic analysis showed that the major adsorption product of ethyl xanthate on pyrrhotite was dixanthogen. The intensity of FTIR signals of dixanthogen adsorption on pyrrhotite and the anode current of a pyrrhotite electrode and flotation response of pyrrhotite are correlated with pulp potentials.

Jan 1, 2005

By S. Subramanian, K. A. Natarajan, D. N. Sathyanarayana

FTIR spectroscopy is used to study the ad¬sorption of an oxidized starch on hematite, corundum, and quart: substrates. The difference spectrum of the adsorbed starch on hematite indicates surface reactions involving -CH2OH and -COH groups and shows striking similarities with that of the ferric-starch system, suggesting chemical interaction between the iron of hematite and the starch adsorbate. The IR spectra of starch adsorbed on corundum and quart: show no evidence of chemical interaction, although hydrogen bonding is apparent. The extent of adsorption of starch on hematite. corundum, and quartz decreases along the series. The evidence for chemical interaction of starch with hematite is further obtained by the X-ray photoelectron spectra of starch adsorbed on hematite, showing noticeable decrease in peak positions of O(Is) and C(Is) of free starch. The Mössbauer spectrum of hematite with stanch adsorbed on it complements these findings.

Jan 1, 1990

The influence of fuel additives on automobile exhaust emissions was studied using engines currently found in the U.S. vehicle population. The fuel additives used in the experiment were four multifunctional additives and one lead antiknock additive. Experimental work was done to determine both the direct effect of the additive per se on exhaust emissions and the influence of Long-term additive effects on emissions with mileage accumulation. Results showed no significant direct or intermediate effect on exhaust emissions for any additives tested. In subsequent experimental work concerned with the long-term or indirect effects of additives, the detergent-dispersant additives were found to have little influence on emissions when used in conjunction with high-quality oil and motor fuel. The lead (tetraethyl) antiknock additive increased exhaust hydrocarbons approximately 12 to 17 percent during a 4,000-mile accumulation period using a base fuel containing 2 ml of tetraethyl lead per gallon. An unleaded fuel was used during a similar accumulation period with no significant increase in exhaust hydrocarbons with mileage.

Jan 1, 1971

The National Institute of Occupational Safety and Health has classified diesel exhaust as a potential human carcinogen. Though standards for diesel particulate matter (DPM) in the work place have not been established, concern for the health of miners is prompting mine operators to consider methods for reducing worker exposure to diesel exhaust. Approach One of many methods for reducing DPM being investigated by the Bureau of Mines is the use of additives in diesel fuel to improve combustion. Research Results Three fuel additives have been tested in Caterpillar and Deutz diesel engines which are similar to types used in underground mines. One iron-based additive containing ferrous picrate had no effect on emissions. A second iron-based additive containing ferrocene reduced DPM between 5 and 45 pet depending on engine operating conditions. The 37-pct reduction for an 8-minute duty cycle, which includes a wide range of transient loads and speeds, is considered to represent in-mine performance.

Jan 1, 1990