FTIR Investigation of Electrochemical Flotation in the Ethyl Xanthate-Pyrrhotite System

The flotation behavior of pyrrhotite was investigated by using ethyl xanthate as a collector. Results showed that pyrrhotite had good floatability from pH 2 to pH 11, and poor floatability when pH was >12. The flotation of pyrrhotite was dependent on pulp potential on various pH values. The potential-pH range for pyrrhotite flotation was established. Cyclic voltammeny and FTIR spectroscopic analysis showed that the major adsorption product of ethyl xanthate on pyrrhotite was dixanthogen. The intensity of FTIR signals of dixanthogen adsorption on pyrrhotite and the anode current of a pyrrhotite electrode and flotation response of pyrrhotite are correlated with pulp potentials.