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By Atta Ur Rehman, Kwame Awuah‑Offei

This paper examines the effect of bucket geometry (cutting blade profile, floor profile, and blade thickness), speed, motor power output, and muckpile particle sizes on bucket penetration and draft for rubber tire loaders. The work uses a 1:16 scaled model of a load-haul-dump in full factorial experiments to examine the effect of the variables on penetration and maximum draft. The results show that speed and motor output are positively correlated to penetration and draft; muckpile particle size is positively correlated to penetration and negatively correlated to draft (p < 0.0014). The results show that buckets with a semi-spade cutting nose profile yield the highest penetration (mean 118.30 mm) followed by those with the spade (mean 108.88 mm), which also yield higher penetration than those straight blades (mean 95.19 mm). Bucket floor profile and blade thickness had no significant effect on penetration or draft. Also, we determined that increasing the speed and motor power output, simultaneously, can reduce bucket penetration. Thus, operators should not waste energy for no additional gain or even loss in bucket penetration. Also, the work finds speed and motor power output each combine with muckpile particle sizes to affect bucket penetration. This research furthers our understanding of the effectiveness of different bucket geometries in improving penetration and reducing draft for rubber tire loaders.

Oct 29, 2021

By A Nigam, K Biswas, R Sarkar

Because of the problems with 1st and 2nd generations of Advanced High-Strength Steels (AHSS), a 3rd generation of AHSS steels has become prominent and these steels have properties in between the 1st and 2nd generations of AHSS. However, although the 3rd generation of AHSS is a promising candidate as a replacement for its predecessors, there remain some challenges in processing these steels which are essentially medium Mn (Mn content ~ 5–7 wt per cent) and high Al (Al content ~ 1– 3 wt per cent) steels. The use of conventional casting powders based on the CaO-SiO2 system is unsuitable for high and medium Mn/Al steels. This work investigates the development of CaO-Al2O3- based mold fluxes for casting third-generation AHSS steel. Mold fluxes, with otherwise similar compositions but different C/A ratios, are tested and their crystallisation behaviour is examined using differential scanning calorimetry (DSC). A calcium aluminate phase having a composition Ca12Al14O33 was found to be the main crystalline phase in the mold fluxes. A decrease in crystallisation temperature was observed as the CaO/Al2O3 ratio increased from 1.00 to 1.33. The effective crystallisation rate constant exhibited an increase with decreasing crystallisation temperature, indicating a potential influence of nucleation rate on the overall crystallisation rate and suggesting an anti-Arrhenius behaviour in the crystallisation process of these mold fluxes.

Aug 21, 2024

By CHENCHEN SUN, GUOPING LUO, GUOCHENG ZHANG

Preparation of briquettes by adding CaF2 reagent into the Australian iron ore powder. The structure and morphology of iron ore briquettes during various reduction stages (i.e., Fe2O3→Fe3O4, Fe3O4→FeO, and FeO→Fe) were observed via an ore microscope and scanning electron microscopy. The results showed that CaF2 reacted with SiO2 to form CaO and SiF4 gas during the roasting process. The reduction swelling index decreased from 12.36 to 8.83% when the CaF2 content in the briquettes increased due to CaF2-mediated refinement of the hematite grains during the first stage of the reduction process. Lattice distortion resulting from the presence of Ca2+ in the FeO lattice during the second stage of the reduction process, coupled with an increase in the porosity of the iron ore briquettes and the formation of a low-melting-point slag phase, promoted the anisotropic growth of FeO lamellar crystals, which resulted in an increase in the reduction swelling index from 4.27 to 7.36%. During the third stage of the reduction process, the growth of iron whiskers was promoted by wüstite (FeO) lattice distortion caused by a solid solution of Ca2+ in the FeO lattice; the reduction swelling index increased from 15.61 to 24.72%, resulting in the catastrophic swelling of the iron ore briquettes.

May 27, 2021

By CHENCHEN SUN, GUOPING LUO, GUOCHENG ZHANG

In this study, the conditions of raw materials and fuels were simulated for Bayan Obo iron ore concentrate by adding pure calcium fluoride (CaF2) in various concentrations to Australian iron ore. The mechanism by which the fluorine (F) content of the lattice influenced the reduction swelling properties of the iron ore briquettes during various stages of the reduction process was investigated. The results provide insight into the mechanism governing the reduction swelling process in Bayan Obo ore briquettes, which could be used to direct real?world production practices, particularly those related to the rational utilization of Bayan Obo ore resources.

By H. Sato, R. J. Lipp, I. Iwasaki, K. A. Smith

Selective desliming holds much promise for upgrading low-grade, finely disseminated iron ores that are not readily amenable to conventional flotation. The process is extremely sensitive to the presence of calcium and magnesium ions that are in process water or are released by constituent minerals. The effects of these two alkaline earth ions on quartz were compared through streaming potential measurements, flocculation and cationic flotation tests, abstraction tests and scanning electron microscope studies. Calcium ion, adsorbed as CaOH+, and magnesium ion, attached by heterocoagulation as Mg(OH)2 precipitate, were responsible for the flocculation of quartz suspension and for the depression in cationic flotation of silica in alkaline pulp solutions. Magnesium hydroxide coating could be removed, similarly to adsorbed calcium ion, by complexation with EDTA and polyphosphates.

Jan 1, 1980

By Donald E. Freshcorn

The minimum sulphur level which can be attained during fluid bed roasting of zinc sulfide concentrates is largely determined by the residual sulfates of calcium, magnesium, and zinc. The fractional conversion of these elements to their respective sulfates is derived from semi- empirical relationships, and multiple regression analysis is used to fit the relationships to experimental data from a commercial fluidized bed roaster. The resulting equation shows that the calcine leaving the roaster contains almost no zinc sulfate, nearly all of the calcium is present as calcium sulfate, and the amount of magnesium sulfate formed is primarily dependent upon the roaster temperatures.

Jan 1, 1976

By S Hapugoda, H Han, L Lu

Charcoal produced from Syzygium Zeylanicum trees was widely used in ancient Sri Lankan iron smelting practices. Charcoal made from Syzygium Zeylanicum tree trunks, branches and leaves were analysed by optical mineralogy and SEM and found to contain unusually high concentrations of calcium oxalate (CaC2O4.H2O – CaOx) crystals in plant cells. Partial and full reduction tests of a high-P Brockman ore were conducted at several temperatures with coke and coke doped with CaOx and CaCO3. It was observed that CaOx promoted reduction and generated comparatively more metallic iron in reduced samples. Furthermore, CaOx encouraged phosphorous partition into slag phases than into the metallic iron, suggesting CaOx can a potential alternative fluxing material to calcium carbonate for treating high-P iron ores in ironmaking processes.

Sep 18, 2023

By Lixin Qian, Tiejun Chun, Yifan Wang, Huan Wang, Hongming Long, Zhengwei Yu

To solve the problem that the sintered liquid phase fluidity characteristic of low silica (w(SiO2) < 3 wt%) and high silica (w(SiO2) > 7 wt%)) iron ores were different from actual sintering production with using the common method based on w(CaO)/w(SiO2), a new improved method based on n(Fe2O3)/n(CaO) was proposed. The differences between two methods for iron ore fluidity detection were studied. The results show that when the common method is used to detect the liquid phase fluidity, as the content of SiO2 increased from 2.12 to 11.68 wt%, the amount of CaO addition augmented from 7.88 to 32.65 wt% and the corresponding fluidity index changed from 0 to 5.68. The fluidity index has a linearly positive correlation with the content of SiO2. The improved method could significantly reduce the effect of the change of CaO addition on the fluidity characteristic of iron ore which caused by the difference of SiO2.

Mar 1, 2018

By Dong-Wei Li, Tao Zhang, Diao Jiang, Zhou Wang

The feasibility of simultaneous vanadium extraction and phosphorus removal from vanadium-containing hot metal was demonstrated with laboratory experimental investigation.The effect of CaO addition on the distribution behavior of vanadium, phosphorus between basic vanadium slag and semi-steel as well as the influence of basicity on the leaching behavior of vanadium, phosphorus was particularly studied. Results show that vanadium oxidation ratio slightly decreases with the increase of basicity, but phosphorus oxidation ratio rapidly increases with the increase of basicity. The leaching of roasted vanadium slag with various CaO contents indicated that the optimal slag basicity for extracting vanadium was 1.5. The maximum leaching efficiency of vanadium could reach 84.02% and the sequence of vanadium leaching efficiency by using different leaching reagents was: 160 g/L Na2CO3 > 100 g/L NaHCO3 > 400 g/L (NH4)2CO3 > 5% H2SO4.

Mar 1, 2017

By H. Henao, E. Kohnenkamp, L. Rojas

The slags generated in the copper conversion process are mainly composed of Cu2O-Fe2O3-SiO2 with the compounds CaO and Al2O3 in concentrations up to 10 wt%. The present work contributes to the knowledge of the conversion process, generating experimental data for the diagrams of phases Cu2O-Fe2O3- SiO2-Al2O3 and Cu2O-Fe2O3-SiO2-CaO. The experiments were carried out in a tubular furnace at temperatures of 1150°C and 1200°C under a condition of saturation with tridymite. Once the equilibrium was reached, the samples were fast quenched in water. The phases in the samples were observed in a Scanning Electron Microscope (SEM) and the elemental composition of the phases analyzed by means of Energy-dispersive X-ray spectroscopy (EDS) detectors. The addition of Al2O3 and CaO into the Cu2O-Fe2O3- SiO2 system resulted in an appreciable displacement of the liquidus lines, corresponding to an expansion of the liquid in the tridymite primary phase field. INTRODUCTION The conversion process of copper consists of oxidizing Fe and S present in mattes with 60 to 65wt% Cu (up to 16wt% Fe). This process is separated into two stages: 1- Slag blowing: Fe is oxidized, the addition of a flux such as SiO2 (silica) forms a second liquid phase called slag, this phase is removed from the furnace; 2-Copper blowing: in this stage, the matte with low concentration of Fe (<1% w/w) is again oxidized to remove S as SO2 in the exhaust gases. The product of these two processes is the formation of Copper Blister (> 98wt% Cu) (Schlesinger et al., 2011). Unlike the aforementioned conventional processes, in most Chilean smelters, conversion Peirce- Smith Furnaces are loaded with high copper matte (70–75wt% Cu) (Henao & Moyano, 2016). Due to the low concentration of iron in these matte (up to 5wt%), it is considered that separating the conversion process in two stages is neither operational nor environmentally convenient. Therefore, the process is carried out in a single stage (Pradena et al., 2006), generating a slag phase with a high percentage of Cu2O (wt%Cu>40).

Jan 1, 2019

By Peter Hayes, Evgueni Jak, Taufiq Hidayat, David Grimsey, Denis Shishin

"An integrated nickel flash smelter is operated with Peirce-Smith converters at the Kalgoorlie Nickel Smelter. To improve the partitioning of arsenic between slag waste and matte product, an option to modify the slag–matte chemistry by addition of CaO was analysed. A combination of plant sample analysis, high-temperature laboratory experiments and thermodynamic modeling was carried out to evaluate the process options. The high-temperature experiments involved the re-equilibration of industrial matte-slag samples at 1225 °C and P(SO2) = 0.12 atm, rapid quenching in water, and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LAICPMS). A private thermodynamic database for nickel sulfide smelting and converting was used together with the FactSage thermochemical software package to assist in the analysis of the distribution of elements between slag and matte as a function of CaO addition. The thermodynamic predictions combined with experimental data obtained in this study can be used to characterise the effect of CaO fluxing on the slag–matte thermochemistry during the nickel sulfide converting.INTRODUCTION At the Kalgoorlie Nickel Smelter (KNS), nickel sulfide concentrate is processed in an Outotec-type flash furnace to produce nickel matte containing +47 wt% Ni. Separation of nickel matte and waste slag from the flash smelting is enhanced through settling in the electric arc -heated zone attached to the flash furnace. The flash furnace matte is further processed in a Peirce-Smith converter to produce Ni-rich matte containing +66 wt% Ni (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011). Iron silicate-based slag is used in the converting process at KNS. Most of the arsenic is contained in the final matte and very little of the arsenic partitions into the slag. Previous work by Font et al (Font, Hino, & Itagaki, 2003) shows that the distribution ratio of arsenic between calcium ferrite slag and nickel-matte (LAsslag/matte) is significantly higher than that between iron silicate slag and nickel-matte, where LAsslag/matte = (wt pct As in slag)/{wt pct As in matte} (1)"

Jan 1, 2017

By H Park, V Sahajwalla

"Due to the increasing amount of gangues in iron ores, a beneficiation process is required more as a preliminary step for ironmaking process. However, mechanical grinding and washing of iron ore needs tremendous effort that increases operating cost. Therefore, there is a necessity of a novel approach to ironmaking which can tolerate considerable amounts of silica or alumina. In the present study, a high alumina-carbon composite pellet was examined for an ironmaking process. The effect of compositional changes in the CaO-FexOy-Al2O3-SiO2 oxide system on the reduction of carbon composite pellets was investigated in a purpose built thermo-gravimetric analyser (TGA) at 1473K (1200¦C). As a result, alumina increased the reaction rate of carbon composite pellets by increasing surface area, while silica decreased the reaction rate by lowering surface area of samples. Infrared gas analysis assisted with the reaction kinetics of carbon composite pellets through measurement of CO and CO2 in off-gases. This study will assist with establishing the new pelletising method which differs from the conventional fluxed pellets.CITATION:Park, H and Sahajwalla, V, 2013. Effect of CaO-FexOy-Al2O3-SiO2 oxide system on the reduction of carbon composite pellets, in Proceedings Iron Ore 2013, pp 467-472 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 12, 2013

"In the present study, the reduction behavior of composite pellets comprising of iron oxide, synthetic graphite and slags were investigated in a laboratory-scale horizontal tube furnace. Two different types of slags indicating silicate base and aluminate base slags were chosen to examine the effect of slag chemistry on the reduction behavior of pellets. Slag composition of binding materials has influences on the reactions occurring in composite pellets during direct reduction. In-situ high temperature visualization approach was used to observe the slag / iron / carbon interactions at 1773K (1500°C). The off-gases were measured by means of infrared analyzer to determine the reaction rates of the pellets. Different physical appearances during the in situ reaction inferred a strong correlation between the slag composition and internal reactions. In addition, compression tests were conducted to examine physical strength of the pellets. This investigation was carried out to establish feasibility of physical property control of pellets by selecting optimum slag compositions of binding materials INTRODUCTIONCurrently, most of the iron ore mines have facilities that make an ore more usable for the blast furnace operation by improving its physical properties (e.g. pelletizing and sintering). However, during the process, a large amount of fuel is supplied to indurate materials which consequently deteriorate energy efficiency and produce more CO2 emission. Along with increased interests, direct reduced iron (DRI) making process; simply without coke oven or sintering process, has opened the era of clean and environmental friendly iron making process. While some of the established DRI technologies such as Midrex and HYL were restricted to certain locations where natural gas is abundant, coal based technologies using Rotary Hearth Furnace (RHF) such as FASMET and ITmk3 have been developed with regardless of expensive fuel deposit. In addition to the direct use of pulverized non coking coal and fine iron ore, RHF process also has advantages of utilizing waste materials such as EAF dust, biomass and recycled plastics. Nevertheless, there are still many challenges in the coal utilizing technologies as the unprocessed coal and the waste materials contain huge volatiles and ashes. Although recent investigations on volatiles in a RHF process (Sohn and Fruehan, 2005, 2006) have indicated the benefits of coal in terms of iron oxide reduction and have shown feasibility of multi-layer process, carbon composite pellets still have disadvantages because of its weak mechanical bonding strength. As the mixed system with carbon and oxides generates intermediate gases (e.g. CO and CO2) between solid particles, it is difficult to keep its physical state without the help of binding materials. In this reason, industries have been tried to use various binding materials such as bentonite, kaolinite and Portland cement. However, they are still struggling to find out new materials that provide not only sufficient mechanical strength but also metallurgical properties, such as porosity, reducibility and swelling throughout the reduction reaction. Recently, Canadian researchers (Aota et al, 2006) observed enhanced mechanical strength of pellets by using high alumina cement as a binder and concluded that the method could be used to recycle EAF dust as well, but in depth mechanism of reinforced strength has not been concerned. Most of the ashes coming from binders formulate certain type of slag during the reduction process due to its incombustibility. Thus, observation and regulation of slag property is an essential for the control of carbon composite pellet. Yet, only a little thermodynamic consideration from the perspective of slag chemistry has been adapted in the iron and steel making industries as ash has been easily ignored for its tiny proportion. In this study, effect of CaO-SiO2- Al2O3 slag system on the reduction of iron oxide was investigated in terms of"

Jan 1, 2012

By Pan Gu, Zhen Zhang, Jiang Diao, Bing Xie, Hongyi Li

Viscosities of FeO-SiO2-V2O3-CaO-P2O5 slags have been measured at the temperature range of 1673 K to 1773 K (1400°C to 1500°C). This investigated system represents the major components of basic vanadium slag that is an important intermediate product of a novel vanadium extracting process, in which removal of phosphorus and extraction of vanadium can be achieved from the vanadium-containing hot metal simultaneously. It was found that higher CaO/SiO2 ratio resulted in lower viscosity in the composition range of interest. Also, the viscosities increase with the increasing P2O5 concentration. The varying viscosities can be attributed to the modification in complexity and polymerization of the slag network. The variation of apparent activation energies are in tune with the viscosity measurements. The results of this work revealed the effect of CaO/SiO2 and P2O5 on the viscous properties of FeO-SiO2- V2O3-CaO-P2O5 slags and therefore provide the theoretical foundation for the control of the coupling de-P and V-extraction process.

Jan 1, 2016

By Z. Q. Chen, M. H. Loretto, Y. G. Li

"As-cast, As-forged, as-solution-treated, and solution treated and aged microstructures of Ti-15Mo (IMI205) with and without carbon were examined using optical microscopy, scanning electron microscopy .and transmission electron microscopy. Tensile testing was carried out at room temperature. It was found that carbon acts primarily as a titanium carbide former: Titanium carbides increase slightly the tensile strength, but decrease the ductility of IMI205. These observations are interpreted in terms of the titanium carbide morphology observed using SEM and TEM and the phase diagrams of Ti-Mo, Ti-C, and Mo-C.IntroductionIn a recent study on the development of a burn-resistant 13-Ti alloy, carbon was introduced· into the Ti-V-Cr system in order to optimise the mechanical properties. Research results[1, 2] demonstrate that carbon addition can refine the 13 grain size and improve the stability of the 13 phase in Ti-V-Cr alloys. The most attractive result is that carbon addition produced a marked improvement in the ductility of alloys when the carbon content is over 0.1 wt.% in this alloy system. Even after long exposure, the alloy with carbon addition maintains good ductility. One of the main reasons for the ductilising of the alloy is that titanium carbides can getter the oxygen from the 13 matrix.In view of the success of carbon addition in improving the properties and the stability of the Ti-V-Cr alloy, it is of interest to investigate the behaviour of carbon addition in other beta Ti-base alloys. The objective of the present work was, therefore, to assess the microstructures and mechanical properties of IMI 205, a metastable beta titanium alloy, with and without carbon addition using optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), wavelength dispersive X-ray (WDX) analysis, room temperature tensile testing."

Jan 1, 2000

By García B., Wolff E.

The pellet qualities primarily depend upon the thermal profile and gaseous environment during induration. During the induration of the pellet, it undergoes physical as well as chemical changes. Physical changes are mostly due to sintering and chemical changes are due to carbon burning inside the pellet. The effect of carbon on sintering is investigated on a single pellet scale using an optical dilatometer. Sintering is a complex process that involves transportation through various mechanisms. Sintering is quantified in terms of sintering ratio and the kinetic parameter, exponent ‘n’, under isothermal conditions is deduced using the power law equation. The value of n can be used to estimate the sintering mechanism at different isothermal temperatures. Also, the activation energy is calculated using the empirical Arrhenius equation. The activation energy of 0 per cent coke and 1 per cent coke-containing pellets are 531.0 kJ/mole and 552.6 kJ/mole respectively. The order of magnitude of activation energy suggests the same mechanism in both cases. Although the mechanism of sintering is the same, 1 per cent coke-containing pellet sinters more at any isothermal temperature.

Jun 17, 2024

By Sheikh Abdul Rezan, M. N. Ahmad Fauzi, Yong Jing Hui, NORLIA BAHARUN, Noor Izah Shoparwe, Srimala Sreekantan

In this paper, the effect of carbon reductant on carbothermal reduction and nitridation of copper-doped titanium oxide (Cu–TiO ) was investigated.

Mar 1, 2017

By S Lakemond, L I. Ku, J Vaughan

Conventional processing of poly-metallic gold containing flotation concentrates are challenging for a number of reasons. One reason is that substantial copper and zinc in the cyanide leach solution compete with gold and silver for carbon adsorption sites. In this study, metal-cyanide adsorption kinetics and equilibrium are measured on three samples of coconut derived activated carbon and one sample of synthetic carbon. Loading selectivity was confirmed to be in the order gold&gt;silver&gt;copper&gt;zinc for all carbon samples. The synthetic carbon tested showed promising results in terms of loading kinetics and capacity for precious metals.CITATION:Lakemond, S, Ku, L I and Vaughan, J, 2013. Effect of carbon type on adsorption of Cu, Zn, Ag and Au from mixed cyanide solution, in Proceedings World Gold 2013 , pp 411-418 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By H. Tan

?Preg-robbing? is the active adsorption of gold from cyanide solution by the ore components. The role of carbonaceous coatings on chalcopyrite surfaces in the preg-robbing of chalcopyrite has been investigated by using pure chalcopyrite and a copper concentrate. Activated carbon and graphite were chosen as representative carbonaceous contaminants. It was found that the carbonaceous coatings enhanced the preg-robbing of chalcopyrite. Activated carbon coating increased gold adsorption onto chalcopyrite to a lager extent, in comparison with graphite coating. In the preg-robbing of the copper concentrate, gold adsorption was increased to larger extent at finer particle sizes and at higher contents of activated carbon or graphite. The preg-robbing of chalcopyrite was reduced or eliminated, depending on the concentrations of free cyanide. However, the gold adsorption on the carbon and graphite coated chalcopyrite could not be avoided even at higher cyanide concentrations, and this adsorption was solely attributed to the carbonaceous coatings. Zeta potential studies indicated that the carbonaceous coatings reduced the negativity of the chalcopyrite surface charge. As shown by SEM analysis, gold not only accumulated at the edges and defect sites, but was also spotted on the smooth surfaces of chalcopyrite with carbon or graphite present. XPS results revealed that gold was strongly reduced on chalcopyrite surfaces, with the sulfide ions of the chalcopyrite being oxidized to elemental sulfur. Diagnostic elution indicated three mechanisms contributing to gold take-up by chalcopyrite, i.e. gold reduction, physical adsorption and chemical adsorption.

Jan 1, 2003

By Peter Zhang, Daniel Su, Bo Hyun Kim

Shale gas wells drilled in longwall chain pillars are influenced by longwall mining. Longwall mining on each side of the chain pillars can create overburden movements and induce deformations in gas well casings. If the deformations result in a casing breach, intrusive shale gas could leak into the longwall mine with serious safety consequences. This study concerns five shale gas wells in the chain pillars between two adjacent longwall panels in the Pittsburgh coal seam under a cover depth of 670 ft and a mining height of 7 ft. The gas wells were constructed with typical casing design, but a casing cementing alternative with uncemented production casings was practiced. Four production casings were uncemented, and one production casing was unintentionally cemented with good quality cement to a 535-ft depth and low-quality cement stringers from a 444- to 535-ft depth. The longwall faces passed by the shale gas wells as each adjacent longwall panel retreated. Production casings were surveyed by a multi-finger caliper after each panel was mined. No deformation was detected in the four uncemented production casings, but small deformations were detected in the partially cemented production casing. The maximum measured deformation in the cemented production casing was 0.05 in. after first panel mining and 0.06 in. after second panel mining. The casing deformations were also predicted by the FLAC3D model set up on site-specific overburden geology. The predicted deformations were in good agreement with the measurements in terms of deformation locations and magnitudes. All five shale gas wells resumed normal production after being temporarily plugged during the period of mine-by. This study provides a successful demonstration of the effectiveness of a casing cementing alternative for decoupling production and intermediate casing, and thus minimizing the influence of longwall mining in the shale gas wells drilled through longwall chain pillars.

Jul 1, 2023