Effect of CaO-SiO2-Al2O3 Slag Systems on the Reduction of Iron Oxide in Carbon Composite Pellet

"In the present study, the reduction behavior of composite pellets comprising of iron oxide, synthetic graphite and slags were investigated in a laboratory-scale horizontal tube furnace. Two different types of slags indicating silicate base and aluminate base slags were chosen to examine the effect of slag chemistry on the reduction behavior of pellets. Slag composition of binding materials has influences on the reactions occurring in composite pellets during direct reduction. In-situ high temperature visualization approach was used to observe the slag / iron / carbon interactions at 1773K (1500°C). The off-gases were measured by means of infrared analyzer to determine the reaction rates of the pellets. Different physical appearances during the in situ reaction inferred a strong correlation between the slag composition and internal reactions. In addition, compression tests were conducted to examine physical strength of the pellets. This investigation was carried out to establish feasibility of physical property control of pellets by selecting optimum slag compositions of binding materials INTRODUCTIONCurrently, most of the iron ore mines have facilities that make an ore more usable for the blast furnace operation by improving its physical properties (e.g. pelletizing and sintering). However, during the process, a large amount of fuel is supplied to indurate materials which consequently deteriorate energy efficiency and produce more CO2 emission. Along with increased interests, direct reduced iron (DRI) making process; simply without coke oven or sintering process, has opened the era of clean and environmental friendly iron making process. While some of the established DRI technologies such as Midrex and HYL were restricted to certain locations where natural gas is abundant, coal based technologies using Rotary Hearth Furnace (RHF) such as FASMET and ITmk3 have been developed with regardless of expensive fuel deposit. In addition to the direct use of pulverized non coking coal and fine iron ore, RHF process also has advantages of utilizing waste materials such as EAF dust, biomass and recycled plastics. Nevertheless, there are still many challenges in the coal utilizing technologies as the unprocessed coal and the waste materials contain huge volatiles and ashes. Although recent investigations on volatiles in a RHF process (Sohn and Fruehan, 2005, 2006) have indicated the benefits of coal in terms of iron oxide reduction and have shown feasibility of multi-layer process, carbon composite pellets still have disadvantages because of its weak mechanical bonding strength. As the mixed system with carbon and oxides generates intermediate gases (e.g. CO and CO2) between solid particles, it is difficult to keep its physical state without the help of binding materials. In this reason, industries have been tried to use various binding materials such as bentonite, kaolinite and Portland cement. However, they are still struggling to find out new materials that provide not only sufficient mechanical strength but also metallurgical properties, such as porosity, reducibility and swelling throughout the reduction reaction. Recently, Canadian researchers (Aota et al, 2006) observed enhanced mechanical strength of pellets by using high alumina cement as a binder and concluded that the method could be used to recycle EAF dust as well, but in depth mechanism of reinforced strength has not been concerned. Most of the ashes coming from binders formulate certain type of slag during the reduction process due to its incombustibility. Thus, observation and regulation of slag property is an essential for the control of carbon composite pellet. Yet, only a little thermodynamic consideration from the perspective of slag chemistry has been adapted in the iron and steel making industries as ash has been easily ignored for its tiny proportion. In this study, effect of CaO-SiO2- Al2O3 slag system on the reduction of iron oxide was investigated in terms of"