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By Francesco Vegliò, Luigi Toro, Francesca Pagnanelli

Different hydro-metallurgical processes have been studied in order to recover manganese(II) from oxidised minerals such as MnO2. An innovative acid reductive leaching carried out in mild experimental conditions was here considered using agricultural and industrial wastes containing carbohydrates as reducing agents. The leaching process was investigated from a kinetic and equilibrium point of view in order to optimise the experimental conditions, develop a kinetic model and obtain high purity concentrated MnSO4 solutions. To study the leaching kinetic a Shrinking Core Model (SCM) was modified by a variable activation energy term to take into account both the variable reagent concentrations and the reaction rate change with respect to the manganese dioxide conversion. The influence of the particle size in the kinetic model is discussed with the support of SEM analysis before and after leaching. Manganese extraction yield was maximised (170-190 g/L) using appropriate carbohydrates and acid excesses, while impurity concentrations were kept low (Fe<10ppm and Ca<300ppm) pre-treating the ores, using hydro-alcoholic leaching medium and different combinations of down-stream processes. In particular precipitation, solvent extraction and adsorption onto active carbon were tested to eliminate Fe and Ca from MnSO4 solutions.

Jan 1, 2003

By Rodney J. Hundermark, Sharif Jahanshahi, Shouyi Sun

"The major platinum producers in South Africa make use of electric furnaces for the melting of PGM bearing nickel - copper concentrates. To gain better understanding of the furnace operation, research was conducted at CSIRO Minerals in Melbourne, Australia. One aspect of the research project was the investigation of the factors affecting the electrical conductivity of melter type slags.Electrical conduction in slags can occur through two mechanisms: ionic and electronic. There is good understanding of the ionic mechanism. In slags containing high levels of iron, the dominant mechanism is electronic. There is limited understanding of the electronic mechanism and one of the aims of the research was to investigate this mechanism further.Experimental work was carried out on Al2O3.CaO.FeOx.MgO.SiO2 slags similar in composition to the melter slags. Conductivity increased significantly with iron oxide content. Above 20wt% FeOx, electronic conduction was significant and the conductivity varied with the oxidation state of the slag. As the iron oxide content was increased further, the electronic mechanism became more dominant. The conductivity reached a maximum at around pO2 = 10-7 to 10-4 atm., although this value was dependent on the total iron oxide content and basicity of the slag."

Jan 1, 2003

By Brian Hart, Stamen Dimov

"In refractory ores, a substantial part of the gold content may be present as a sub-microscopic component within the mineral matrix of the various carriers. This type of gold may be present as finely disseminated colloidal size gold particles (<0.5µm) or as a solid solution within the sulphide mineral matrix. Such ores are not amenable to gold recovery by direct cyanidation. In order to liberate the sub-microscopic gold, the ore has to be oxidized before being subjected to gold cyanidation and extraction. Autoclave pressure oxidation (AC POX) of the sulphide ore and subsequent cyanidation is a common technology used to liberate the gold in such refractory ores. The additional presence of active carbonaceous matter in such ores (double refractory ores) represents another major obstacle for efficient gold recovery during the process of pressure oxidation and cyanidation. This carbonaceous matter (c-matter) can adversely affect the gold recovery due to its ability to adsorb, or pre-grob gold from the cyanide solution. Advanced micro-beam analytical techniques such as Dynamic Secondary Ion Mass Spectrometry (D-SIMS) and Time-of-Flight Secondary Ion Mass Spectrometry (TOF-SIMS) have become powerful tools for characterization of different forms and carriers of gold for the needs of the mineral processing industry. Major advantages of these techniques are related to their ability to analyze individual mineral particles and provide quantitative analysis with detection limits in the low ppm/ppb concentration range. This paper describes various micro-beam techniques and procedures implemented at Surface Science Western (SSW) for quantification and characterization of the sub-microscopic gold and the preg-robbed surface gold as part of full gold deportment studies in feeds and process stream products."

Jan 1, 2014

By Leena Vesa, Antti Remes

Design of thickeners is based on laboratory test work, characterizing the material and determining the optimal reagents, dosages and settling regimes. Several methods for dimensioning plant scale equipment exist. Kynch and Talmage-Fitch design procedures has been applied widely for a long time. Nowadays, besides them, a dynamic laboratory test work is applied for design of high rate thickeners. In that the laboratory unit is operated with known solids load per area, feed and flocculation conditions and with raking of the underflow. All these test methods afford useful data for setting up and calibrating a dynamic simulation model of a plant scale thickener. This paper presents a flocculation kinetics based dynamic thickener simulation model and a procedure to calibrate the model parameters. With the model, the underflow stream composition can be simulated over time as a function of the thickener operating parameters, which are: the feed rate and composition, underflow pumping rate, flocculant dosage and dilution of the feed. In addition, the model incorporates calculation of the slurry bed level, the cone pressure, the yield stress and the rake torque. Such a dynamic modeling scheme enables setting up simulation aided operator trainings and developing and testing of advanced control strategies, for example. The unit model can be integrated as a part of concentrator-wide flow sheet simulation model as well. Here, calibration of the kinetic flocculation model based on a laboratory test case data and further the operation of a simulated plant scale thickener are presented.

Jan 1, 2014

By F. B. Waanders

Coal, as energy resource, possesses numerous characteristics and properties which all have an influence on its gasification behaviour. The two properties considered as critically important when evaluating a coal source for gasification is its mineral content and slagging behaviour. Research has indicated that slagging formation can be inhibited or even prevented by the addition of a fluxing agent. It is thus of great importance to understand the mineral interaction during gasification in order to select a suitable fluxing agent for the prevention of slagging and clinker formation in the gasifier. The aim of the present project is to evaluate the effect of iron as a fluxing agent and study the transformation of the mineral and added iron during gasification. A pre-determined amount of pure elemental iron (between 2wt% and 20wt%) was added to a base case coal sample in order to study the effect of the addition of iron to the coal. The transformation of the iron in conjunction with the possible iron containing minerals present in the coal was studied by means of Mössbauer analyses. Typical characterisation techniques included proximate analyses, ultimate analyses and ash composition analyses. The ash fusion temperature analyses (AFT) were used to study and predict the slagging behaviour of the iron-spiked coal samples. Even though AFT analyses only provide an average flow property, it gives a good indication of the changes that the iron addition induces on coal properties. FactSage modelling was carried out in conjunction with the Mössbauer and AFT analyses. From the proximate, ultimate and ash composition analyses it was clear that the coal used con-formed to the average characteristics measured over an extended time period. From the AFT values it was seen that an increase in the flow temperature occurred with the addition of pure elemental iron to the coal, which can be of importance for operational purposes as to raise the gasifier temperature and not to have slagging problems to occur in the gasifier. The Mössbauer data show that he-matite is the main Fe-component that forms from the pyrite originally present and from the added iron to the coal, consistent with FactSage modelling, which shows that the partial oxygen pressure determines which mineral species will form. This study opens up new possibilities when considering operational problems experienced in in-dustrial gasifiers. Successful completion of this study and a study to look at reducing conditions in the gasifier will also add to the knowledge that already exists regarding fluxing agents.

Jan 1, 2014

By Montaser S. EL Salmawy, Takahide Wakamatsu, Eishi Kusaka

"The effect of ethoxylation of long chain alcohols on the quartz and feldspar flotation behaviors was investigated for surfactants of the octylphenol polyoxyethylene family. The tests were carried out with an average of 7.5 (Triton X 114), 9.5 (Triton X 100), 30 (Triton X305), 40 (Triton X 405) and 70 (TritonX 705) oxyethylene units. Electrokinetic and flotation studies on quartz have shown that at low pH values, quartz could be floated with polyoxyethylene octytlphenols. The possible mode of adsorption of these nonionic surfactants may be suggested to be due to hydrogen bonding between the oxygen of ether and hydrogen in the free hydroxyl groups on quartz surface. It was anticipated that the selectivity between quartz and microcline would decrease as oxyethylenic chain length increases.Electrokinetic methods were used to elucidate the mechanism of surfactants adsorption and to correlate these findings with the optimum flotation conditions. The polymeric surfactants would reduce the negative values of zeta potential of quartz while the reverse is true for feldspar. After treatment of microcline with HCl, its electrokinetic behavior in the presence of Tritons X surfactants became similar to that of quartz.The obtained results would suggest that separation of quartz from feldspar using nonionic surfactants of octylphenoletoxylated alcohols having shorter oxyethylenic chain length at low pH could be achieved"

Jan 1, 2003

By Stefaan J. R. Simons, Michael T. Spyridopoulos

In this paper the effect of humic substances (natural surfactants), electrolytes and solid particles on bubble coalescence, and as a consequence on froth stability, has been investigated. We formed two bubbles of equal size and forced them to collide using a novel experimental apparatus. The interactions were recorded by a high-speed camera, the images of which helped to determine the coalescence frequency and the coalescence time, as well as the mechanisms of the interactions. Two types of humic substances were used, along with three different electrolytes. Humic substances appeared to have a considerable effect on bubble coalescence, while the effect of electrolytes was minimal. Moderate and high hydrophobic glass spheres were used between two bubbles. Very hydrophobic spheres promoted fast bubble coalescence, while moderate hydrophobic spheres had no effect. We present data of coalescence frequency and time, as well as images of the coalescence events.

Jan 1, 2003

By R. L. Pascual, W. J. Whiten

"The froth flotation process is not well understood. Both flotation models, and the parameters used to describe the stream flows are not well defined. They in fact vary considerably in different applications. This creates difficulties is designing a simulation program suitable for use by plant personnel, consultants, and researchers. In addition to simulation, an effective simulation program can be expected to provide a range of other services.This paper shows how a process circuit simulator can be designed with sufficient flexibility to satisfy these needs, and discusses some of the additional services."

Jan 1, 2003

By Sanja Miskovic, Manjunath Basavarajappa

Numerical investigation of fluid flow characteristics and mixing efficiency of different impeller designs, based on the mixing characteristics of a passive scalar/tracer, is conducted using CFD for lab scale flotation cells of diameter D and height H equal to 300 mm. Fine computational mesh containing close to 1.6 million cells is used to obtain fully resolved steady state flow field close to the impeller. Unsteady scalar mixing simulations are performed on a relative coarse grid consisting of approximately 450,000 cells. Based on detailed numerical simulations, flows are fully characterized for four impeller designs at two off-bottom clearances C of 50 and 25 mm (D/6 and D/12). Passive scalar is injected from the cell bottom and the time required to attain uniform concentration distribution inside the cell volume is taken as the mixing time by monitoring scalar concentration at four discrete locations. The effect of varying agitation speed and off-bottom clearance on mean flow characteristics is also investigated. The scalar mixing results reveal regions of low mixing efficiency and are used to understand mixing process in greater detail. Through the previous research work, it was found that the main flow pattern undergoes transition from double-loop to single-loop configuration with decrease in off-bottom clearance below a certain critical height for stirred tanks using flotation impellers in the absence of stator. The inclusion of stator is found to alter the mean flow behaviour by preventing the jet from transitioning to axial type flow for lower clearance. Power numbers for different impeller designs are calculated based on the torque generated on impeller blades, and also from the total turbulent kinetic energy dissipation in the overall fluid volume. Power number is found to exhibit a significant dependence on off-bottom clearance based on the CFD results.

Jan 1, 2014

By E. Burdukova

This paper explores the relationship between the rheological behaviour and mineralogical nature of three different natural ore types. Rheological measurements performed here on Platreef, Kimber-lite and Norseman-Wiluna ores are correlated with the variation of phylosilicate mineral content in these ores and the corresponding physical properties of selected phylosilicate mineral groups. Preliminary results show that the clay mineral group (talc) has the least effect on both Bingham yield stress and viscosity of the three ore slurries tested, whereas the serpentine mineral group has a dramatic increasing effect on the Bingham yield stress especially at very low solid volume fractions. The Bingham viscosity of the mineral slurry appears to be the most influenced by the presence of the swelling clay mineral group (smectite). Significant increases in either Bingham yield stress or viscosity due to elevated contents of these problematic phylosilicate mineral groups are likely to cause negative effects on the processing and manageability of mineral slurries but it is unclear which is likely to have a more detrimental effect.

Jan 1, 2014

By Caroline Olsen

The objective of this study was to achieve Zn activation control in an industrial Cu flotation circuit treating a complex Cu-Pb-Zn-Au-Ag sulphide ore at the LaRonde Division of Agnico-Eagle Mines Limited (Québec, Canada). In order to provide process relevant results, a laboratory testing methodology was developed to duplicate plant operational parameters. The action mechanisms of ZnSO4, TETA (triethylenetetramine) and NaHSO3used as depressants in order to limit ZnS activation were examined. Laboratory flotation tests with and without Cu2+ions (the ions responsible for ZnSactivation)were performed. All depressants showed equal or better flotation performance relative to baseline tests. For example, in the presence of Cu2+, the Zn recovery reduced from 32.2% to 17.5% in the copper rougher concentrate after adding ZnSO4(with a dosage of 50 g/t). TOF-SIMS analyses confirmed the relative decrease in surface Cu in the samples treated with ZnSO4and TETA. For the case with TETA, this indirectlyindicates the formation of a copper TETA complex in solution, thereby reducing available Cu for transfer. The TOF-SIMS and XPS data indicate that the addition of ZnSO4and NaHSO3resulted in an increase in surface metal hydroxides and SO3 on ZnS grains inhibiting both Cu and collector attachment.ZnSO4 was subsequently tested with success in the LaRonde concentrator. The addition of 40 g/t ZnSO4 at the conditioning (or cleaning) stage led to a 2% reduction in Zn content in the Cu and PM concentrate. Recently, improvements towards the control of copper sulfate addition in the downstream Zn flotation circuit resulted in the reduction of Cu2+ in process water. As this ?cleaner? water is recycled for Cu and PM flotation, the addition of ZnSO4 is now used only as required.

Sep 1, 2012

By D. Pirouzan

It is customary to use more than one stage of flotation to obtain an acceptable level of separation of valuables. Flotation circuit design is usually accomplished by applying empirical rules which usually results in operations not working at their optimum conditions. Given the capabilities of genetic algorithms (GA) in finding an optimum solution in a very disturbed search spaces, they can be used to obtain the desired flotation circuit configuration. In flotation circuit configuration and optimization problem, a combination of metallurgical parameters such as yield and concentrate ash content could be used as the fitness function for the genetic algorithm. The multi-objective nature of the problem justified to use Pareto method to arrive at a set of solutions. The appropriate configuration based on technical or economical considerations could then be chosen. To obtain the fitness function for any given configuration, it is necessary to model every flotation stage. The proposed method was used to find the optimum circuit configuration for a coal washing plant. The objective was to arrive at the highest yield while producing a concentrate with a certain ash content (< 11%). The feed to the flotation circuit was characterized based on the size fractions and their flotation rate constants. Results showed that with a 95% confidence, the absolute difference between the modeled and measured values were 2.9-5.5% for yield and 0.4-1.1% for concentrate ash content. When the proposed GA-based circuit configuration was implemented in the plant, the yield increased from the original value of 57.6% to 65.7% while producing concentrate ash content (10.9%) within acceptable limits. By adding one stage to the current three-stage circuit, it was predicted that the yield could further increase by 3.8% while keeping the quality of the concentrate within the appropriate level. Keywords: modeling, optimizing, flotation circuit configuration, genetic algorithms

Sep 1, 2012

Goethite ore are the third most abundant source of iron. The overwhelming part of these ore is represented by low-grade varieties which cannot be used in iron and steel industry without preliminary beneficiation. Biomass is a renewable solid fuel, which is feasible for the substitution of coke and coal in the manufacturing due to its lower contents of harmful elements and abundant raw material sources. Utilization of biomass in iron ore sintering process as heating agent and reducing agent contributes to energy conservation and emission reduction. The biomass was mixed together with goethite ore for roasting process to investigate the effects of reduction roasting. The results show that the goethite ore is dramatically reduced and magnetized into maghemite by biomass with the biomass dosage less than 20% and the roasting temperature below 650 oC. When the goethite ore roasted with biomass, the magnetization values could be enhanced more than two orders of magnitude, meets the standard of magnetic separation, which could significantly reduce the iron beneficiation cost. Keywords: biomass, goethite, reduction, magnetization, roasting

Sep 1, 2012

By Xianjun Lyu, Junxiang Wang, Peng Wu, Minjie Lian

"In recent years, the efficient cementation of mine tailings is a new way to manage mine solid wastes. The traditional cement materials have a slow setting time, large dosage and poor cementation strength for fine aggregate such as mine tailings. Therefore, the preparation of new type cementitious materials for the cementation of fine tailings has great potential in the treatment of mine waste solids. The paper mainly focuses on exploring the critical factors affecting the cementing performance of granulated blast furnace slag and its performance in the cementation of fine aggregate. Results indicate that the fineness of slag has a significant effect on its cementitious activity and Portland cement clinker has a better stimulation effect on the cementitious properties of slag than lime. And, anhydrite has a better early stimulation effect on the cementitious properties of alkali-activated slag compared to semi-hydrated gypsum and dihydrate gypsum. According to a series of tests on the cementation of fine iron tailings, the optimal ratio of slag, Portland cement clinker and anhydrite is determined as 60:30:10. Compared with P.O 42.5 ordinary Portland cement, the new slag based cementitious material shows much better cementing performance on fine tailings sample. Under the dosage of 12%, the compressive strength of fine tailings mortar using slag-based cementitious material in 3 curing days is increased to 168% that of using P.O 42.5 ordinary Portland cement, while the compressive strength in 28 days curing period is increased to 194%."

Jan 1, 2018

By Héctor X. Toro, José Francisco Cabello, Douglas Batista, Álvaro Videla, Claudio Luiz Schneider

The Minas-Rio Project, located in the state of Minas Gerais, Brazil, is currently under construction. The new plant will have a regrinding circuit that uses VertimillTM. The objective is to process itabirite iron ores and it is expected that the consumption of media will represent a large part of the plant operating cost. Many studies in the literature indicate that the size of the grinding media directly influences the grinding efficiency. The size distribution of the charge media is related to the surface area of the charge. In this study, a sample of itabirite iron ore was tested with respect to grindability in a laboratory scale ball mill. The test mill was equipped with a torque device to accurately measure power consumption, as required for the determination of energy specific kinetic parameters. Five tests were carried out with different sizes of steel balls and with SICAM (sub-inch Cast Media). The size distributions of the feed and product of the several grinding tests were used to calibrate population balance model parameters for each condition. The results confirmed that the ball charge with smaller diameter is the most efficient among the different media charge tested.

Jan 1, 2014

By B. Tora

The new method of evaluation of grindability of hard coal and its blend is shown. Standard Hardgrove test is used as a base to work out this method. The essence of this method consists of simulation of milling process in close circuit (mill-classifier) and determination of energy consumption and quantity of product under the constant feed flow. The research equipment designed specially for this project is described New method of grindability measuring completes standard Hardgrove method withdrawing its faults: ? bigger (c.a. 10 times) and more representative sample is used; ? the milling process is carried out in close circuit (similarly to the industrial condition); ? energy consumption of the milling process is determined for three samples, which differs in grain size. The new method of evaluation of grindability of hard coal and its blend is shown. Standard Hardgrove test is used as a base to work out this method. This method allows us to determine energy consumption of the milling process. The essence of this method consist of simulation of milling process in close circuit (mill-classifier) and determination of energy consumption and quantity of product under the constant feed flow. Our results will complete the Hardgrove method and will help us to better characterise coal. At the same time investigations in industrial scale are carried out. These investigations will verify this new method. Also a new mathematical model of the milling process is being elaborated. It will be used to predict behaviour of coals in industrial conditions.

Jan 1, 2014

By Mohsen Hashemzadehfini

Nowadays heap leaching has become established as a mineral processing technology for treatment of some low grade minerals such as copper, gold, and zinc, etc. Heap height, particle size, leach reagent consumption, and metal recovery are four important metallurgical parameters in a hydrometallurgical process like heap leaching. This paper investigated the effects of heap height and particle size on copper recovery as well as acid consumption. Three heap heights of 2, 4 and 6 meters and two particle size fractions of less than 25.4 mm and 50.8 mm were selected as variables in the experiments. The research results showed the inverse relation between heap height and copper recovery as well as acid consumption. Under given conditions, the copper recoveries of minus 25.4 mm ore are 78.63%, 66.27% and 52.88% higher than that of minus 50.8 mm samples for the heap heights of 2, 4, and 6 m, respectively. Both copper recovery and acid consumption increase with decreasing particle size. Keywords: heap leaching, heap height, particle size, acid consumption

Sep 1, 2012

By G. Y. Zhou

During Zijinshan copper heap bioleaching, pyrite was leached in plenty resulting in high ferric concentration in solution. It has affected bioleaching and extraction processing greatly. It results much acid and iron in solution and bad effect to extraction processing. The paper studied the influence factors in the course of pyrite leaching and ferric ion chemical oxidation, especially studied the redox potential for copper bioleaching so as to find key factors affecting the dissolution difference between chalcocite and pyrite. The results show that the redox potential is important factor. Copper and pyrite leaching rates are 95% and 11% respectively and there is great dissolution difference between them at redox potential 700 mV (SHE). During pyrite bioleaching, the indirect action of bacteria gives priority to bioleaching cooperating with the direct attack of microbial cells attached to the mineral surface. Redox potential is determined by ratio of ferric and ferrous, ferric in solution was supplied by the way of oxidation of T. f bacteria, sufficient bacteria concentration and active character were two vial factors of controlling redox potential. It is indicated that copper can be selectively bioleached during copper bioleaching by controlling redox potential of bioleaching. The conclusion will provide theoretic foundation on balance of acid and iron during bioleaching for copper of higher S/Cu ratio. The experinment proved that bacteria activation was decreased on condition of both low pH value and intermittent aeratation during bioleaching. It resulted that the oxidation velocity of ferrous ion was decreased and redox potential was controlled. The dissolution of pyrite was depressed. It would be possible to actualize selective leaching of secondary sulfide copper ore during bioleaching process.

Jan 1, 2014

By F. L. Mentg

The utilization of acid leaching tailings was studied. It is obvious that the Fe in acid leaching tailings can be leached into solutions as Fe2+. In this paper, the influence of conditions, including the concentration of ferrous sulfate, pH, temperature and velocity of air flow was investigated. The optimum conditions for preparing seed crystal are as follows: the concentration of ferrous sulfate is 20 g/L; pH is 9.5~10; reaction temperature is 10~20?; velocity of air flow is 0.4m3/h. The optimum conditions for preparing iron oxide red are as follows: the concentration of ferrous sulfate is 5 g/L; reaction temperature is 80~85?; velocity of air flow is 0.13m3/h. At last, the product of iron oxide red could be prepared by ammonia method.

Jan 1, 2014

By R. B. Shu

A moderate thermophilic microorganisms, has been isolated (45?) from a typical sulphide mine in the region of Mo Jiang located in the southwest of China. The culture has been used to extract copper from chalcopyrite concentrates obtained from De Xing copper mine. The majority of experiments were carried out in 300mL Erlenmeyer flasks containing 150mL volumes of mineral suspension. Effects of some variable parameters such as solids concentration, pH and the concentrations of inorganic nutrients on the bioleaching of chalcopyrite obtained from De Xing copper mine were investigated. For a given concentrate the most important factor affecting the fractional copper extraction was the size of the mineral particles. The overall rate of leaching was found to be limited by the area of mineral surface. The attack started in cracks and genetic defects and finally reached the whole chalcopyrite surface. As a consequence of this, the ore showed strongly cracks. The additive of ferrous sulfate increases the bacteria activity, but did not improve chalcopyrite bioleaching. The results indicate that the nature and relative proportions of the various minerals present have been shown to be important factors.

Jan 1, 2014