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By P. R. Brito-Parada, G. Bhutani

"The physical processes occurring in flotation columns are very complex as they take place at different scales over a range of sizes and multiple phases. Column design and optimum operating parameters are usually obtained from empirical studies and although progress has been made on its numerical modelling, most column models rely on simplifications that do not fully capture the hydrodynamics. In particular, Computational Fluid Dynamics (CFD) models of the pulp phase in flotation usually assume the bubble population to be monodispersed. While this assumption may be reasonable in some situations, the polydispersed nature of the gas phase can have a significant impact on the predicted flotation rates.Techniques to model size distribution do exist in the literature and have been rigorously analysed in the past two decades for bubble columns, which are very similar to flotation columns from a hydrodynamics point of view. In fact, available CFD models of flotation columns are an extension of bubble column models, sometimes including additional equations for solids treated as passive scalars. This work focuses on the development of an efficient CFD model for flotation columns. The bubble size distribution in the column has been modelled using the Population Balance Equation (PBE), which is solved using the Direct Quadrature Method of Moments (DQMOM). Coupled with the PBE, the multiphase flow equations in the column have been modelled using the standard Eulerian–Eulerian approach. The solution of this coupled system has been made tractable in this work with the implementation of a highly parallelised adaptive-mesh finite element method. This powerful framework has been implemented in the open source CFD code Fluidity and it allows the carrying out of detailed simulations of flotation columns in 2D and 3D, with important implications for industrial column evaluation and design."

Jan 1, 2016

By A. Iizuka

This study was aimed at separating and recovering arsenic, antimony, and tin from refining byproducts generated in a nonferrous smelter. The target byproduct was a silicate slag containing the above elements. The silicate structure of the slag was destroyed by alkali roasting, which then enabled leaching of arsenic, antimony and tin in solution effectively. Arsenic was selectively leached out by hot water after alkali roasting of the slag, while remained antimony and tin in the residue were leached out by a hot hydrochloric acid solution. However, when the solid-liquid ratio in the leaching solution was increased, hydrous gelatinous silica (gel-like silica) was formed during the hydrochloric acid treatment and filtration became difficult. Therefore, high temperature and high pressure leaching was attempted to improve the filterability of the silica leaching residue. In the high temperature and high pressure treatment, the hydrous gel-like silica was transformed into easily filterable aggregated silica, and thus, filtration became easy. By investigating the neutralization and sulfurization treatment for the obtained hydrochloric acid leachate (second leachate), it was possible to separate antimony and tin. INTRODUCTION This study aims to separate arsenic and recover valuable metals such as antimony and tin from refining byproducts generated in a nonferrous smelter. The target smelting byproduct is antimony-containing slag in this study. In many cases, alkali roasting was adopted as pretreatment for extraction and recovering valuable metals from smelting residues and wastes (Rao, 2006). For antimony-containing slag in this study, one effective method for separating arsenic is to convert arsenic to sodium arsenate (Na3AsO4) by roasting with a sodium compound and then to remove arsenic by hot water leaching. In addition, by alkali roasting, the silicate structure of the slag is destroyed, and effectively alkalizing tin and antimony is accomplished. Then, precipitating and recovering tin and antimony leached into the acid solution are considered possible by sulfurization and neutralization treatments. In this research, we conducted basic studies on the following. 1) Destruction of silicate structure in slag by alkali roasting and leachability of arsenic. 2) Conversion of hydrous gelatinous silica to aggregated silica by hydrochloric acid treatment of residues after arsenic leaching under high temperature and high pressure, as well as leachability of antimony and tin. 3) Separation and recovery of antimony and tin by sulfurization and neutralization treatments of hydrochloric acid leachate. These topics of investigation can support to consider the separation and recovery process of arsenic, antimony, and tin from antimony containing slag.

Jan 1, 2019

By M. S. Moats

"The effects of commercial copper electrorefining additives (glue and thiourea) on the electrochemical removal of bismuth are of importance in copper production. It was found that Bi(III) electrodeposition occurs readily from acidic sulfate solution via a diffusion-controlled quasi-reversible reduction. The diffusion coefficient of Bi(III) was measured and found to be less than reported values of copper in similar solutions. The presence of thiourea and/or glue was found to accelerate or de-polarize Bi(III) reduction on stainless steel as compared to the inhibition or polarization of Cu(II) reduction. The additives also inhibited the dissolution of the Bi-Cu co-deposit during cyclic voltammetry. During short term deposition studies, the additives increased the concentration of Bi in co-deposited Cu-Bi products from solutions with low concentrations of Cu (<2 g/L). Bi deposition was significantly suppressed by increasing the Cu(II) concentration in the solution. The formation of a copper layer on the stainless steel electrode appeared to significantly suppress the reduction of Bi(III). This study demonstrates that glue and thiourea depolarize the deposition of bismuth on stainless steel. Therefore, the additives could be used to improve Bi impurity removal during third stage liberation.INTRODUCTIONThe production of high purity copper has been steadily increasing due to the wide application of the metal and its alloys in electrical and electronic products, infrastructure construction, industrial machinery and equipment, general products and transportation (Moskalyk et al., 2003). Most high purity copper is manufactured from copper sulfide mineral concentrates and/or scrap via a pyrometallurgical process followed by electrorefining (Navarro et al., 1999). During the electrorefining process, cast anodes of 99-99.5% purity are electrochemically dissolved into an acidified copper sulfate solution while high purity copper (>99.99%) is plated on stainless steel blanks or copper starter sheets (Davenport et al., 2002). The control of cathode deposit growth (purity and morphology) while maintaining a high current efficiency is of significant importance for copper refining (Ilkhchi et al., 2007). At typically applied current densities for industrial copper electrorefining, mass and charge transfer play important roles in the quality of cathodic products (Hiskey et al., 1998). If the real current density at some surface points is substantially higher owing to uneven current distribution, then rough spots can and will grow faster leading to nodules (Suarez et al., 1992). Nodulated deposits tend to capture solution and anode impurities (slimes) resulting in unacceptable cathode quality (Afifi et al., 1987). Furthermore, these nodules can grow until they eventually contact the anode leading to short circuits and current efficiency reduction (Ilkhchi et al. 2007)."

Jan 1, 2016

By Lawrence Devon Smith

"The concept of risk is well established in the mining industry. It is acknowledged when estimates of reserves are expressed as proven or probable, when mining and metallurgical recoveries are applied to the ore, and when contingencies are added to costs. However, it is difficult to provide a quantitative assessment of risk. The significant sources of risk in a mineral project and how these are addressed in project evaluations are discussed.The discount rate is examined as a fundamental means of reflecting risk in discounted cash flow evaluations. Current industry practice is discussed, and a methodology for the analysis of risk levels is proposed that assesses the constituent components of the discount rate: real interest, mineral project risks, and country risk.IntroductionThis paper examines the components of the discounted cash flow discount rate and proposes a method of estimating project-specific discount rates. The motivation for this work comes from experience of project evaluations in which owners and purchasers had agreed on virtually every aspect of the evaluation except how much the project was worth. Agreement was reached on reserves, grade, recovery, capital costs, operating costs, taxes, and, by combining these components, even on the final cash flow values. The only difference in opinion concerned the discount rate to be used in the calculation of the net present value. Depending on the life of the project, such differences of opinion can cause a variation of more than 50% in the value placed on a project! This is illustrated in Figure I."

Jan 1, 1995

By M. Coleman, M. E. Reed

The control of feed delivery quality to the flash furnace remains an unsolved problem. Many operations around the world still have limited control of feed quality to their flash furnace. Schenck Process and WorleyParsons continue to work towards the ‘holy grail’ of simple quality feed delivering both radial feed distribution and pulseless feed delivery. Ten years ago they joined forces to offer a system based on then Clyde Process RotoFeed system which could deliver ground level installation, online mixing of materials, pulseless feeding direct to the burner, with good radial distribution. Unfortunately, this proved to be too large a step for the Flash Smelting community and met with resistance from the process owners. Since then the community has developed a range of options some of which have been implemented over this period. Despite these improvements there are still areas of concern including safety issues associated with concentrate leaks and spills, uncontrolled variations in feed rate including massive flooding events, intermittent distribution improvement and set up of the burner continues to be trial and error and hard to repeat the success in each burner campaign. These continue to impact flash furnace performance globally on a daily basis. Following the community reticence to pursue the complete solution a number of interim steps are now available to pave the way to the ultimate feed system. The mixing of material has been installed and is delivering line blended materials on a daily basis. This paper will investigate the developments over the last 10 years and discuss the pros and cons of this incremental step process for overall furnace control. INTRODUCTION Schenck Process and WorleyParsons have continued to interact and observe changes in the flash smelting industry and to consider application of the Clyde RotoFeed now incorporated in the Schenck Process ProStreamTM range for delivery of feed directly to the concentrate or matte burner. Schenck Process pneumatic injection from the Clyde Process range, ProStreamTM, utilises two types of volumetric feeders to accurately control the feed of material into an injection pipeline. These are referred to as the RotoFeed and RotoScrew technologies and the choice of feeder type is dependent on the characteristics of the material to be handled. The RotoFeed is generally used for finer, granular and powdered materials which cannot be accurately handled with a screw such as pulverised coal and copper concentrate, whilst the RotoScrew is particularly suited to coarser lump materials, particularly abrasive of cohesive materials like zinc powder, electronic scrap and metal ashes. Both units can operate at high pressures and many systems work at 3 to 10 bar with the occasional system working at 20 or 30bar for carbon to gasifiers. For the Flash furnace the ProStreamTM units can be used to deliver each of the furnace feed materials into a single line, mixing the materials homogeneously and live to the burner.

Jan 1, 2019

By K. Hashiba, Y. Z. Liang, K. Fukui, M. Koizumi

"Efficiency and penetration rate during percussive rock drilling significantly affect the speed of tunneling and excavation. Many researchers and engineers have continuously engaged in the advancement of rock drilling performance. Development and modification of the rock drills based on test data are timeconsuming and costly. Hence it is essential to make effective use of numerical simulation. However, most of the numerical models proposed in previous studies were too simple in comparison with the actual percussive rock drilling in which many factors are involved. The objective of our research project is to construct a new realistic numerical model of continuous percussive drilling, which is based on the previous Okubo-Nishimatsu’s model. In this study, the parts of the previous model involved in stress wave propagation and attenuation were modified. The two models were prepared for HD712 hydraulic rock drill mounted on crawler drills and HD210 hydraulic rock drill mounted on drilling jumbos. Stress wave propagation was computed with the discretized one-dimensional wave equation. The calculated results were compared to the stress waves measured on a rod during percussive drilling. In both models for HD712 and HD210, the measured stress waves can be reproduced with the one-dimensional model of the same acoustic impedance as the actual piston, shank rod and rod combined with the CI+spring model as a rod joint. The calculated results indicate that the spring constant in the model of a rod joint needs to be set appropriately depending on drilling conditions. INTRODUCTIONEfficiency and penetration rate during percussive rock drilling significantly affect the speed of tunneling and excavation. Many researchers and engineers have continuously engaged in the advancement of rock drilling performance. Components related to the percussive drilling are a drill body, a piston, a shank rod, rods, rod joints, a bit and rock. The piston in the drill body is reciprocated by hydraulic pressure and collides with the shank rod a few thousand times per minute. Stress waves generated by the collision propagate and attenuate in the rods and rod joints, and then reach the bit. The bit penetrates and crushes rock. During percussive drilling, the components mutually affect each other and self-induced oscillation occurs. The number of blows and the rate of penetration are determined by the practical drilling conditions such as hydraulic pressure, thrust force, number of rods and mechanical properties of rock. Development and modification of the rock drills based on test data are time-consuming and costly. Hence it is essential to make effective use of numerical simulation. However, most of the numerical models proposed in previous studies were too simple in comparison with the actual percussive rock drilling in which many factors are involved."

Jan 1, 2015

By T. Gerritsen, T. Plikas, K. Ochoa, M. Loveless, R. MacRosty, J. Reichart, R. Pula

Sidewall accretion in a smelting furnace plays an important role in furnace integrity as it provides protection to the sidewall cooling elements and thereby extends the furnace campaign life. The extreme thermal and mechanical stresses in the furnace and changes in the slag chemistry can cause the sidewall accretion to melt or break away decreasing the lining protecting the cooling elements. Thin accretion is highly undesirable as it increases the risk of exposing the cooling elements to the molten bath and in the worst case may lead to a failure. Therefore, monitoring the sidewall accretion on an operating furnace is extremely important to manage furnace integrity and to support safe furnace operation. Operators often generate estimates for sidewall accretion and refractory thickness using either copper cooler temperatures or heat load into the cooling water circuits. Multivariate statistical models, on the other hand, have the capability to consider all the process measurements simultaneously to provide a more reliable estimate. This paper describes the application of multivariate statistical models for sidewall integrity monitoring on a Flash Converting Furnace (FCF) and also discusses the online implementation of these models as the Sidewall Accretion Monitoring System. INTRODUCTION Rio Tinto’s Kennecott Utah Copper (KUC) smelter located near Salt Lake city, Utah operates a Flash Smelting Furnace (FSF) and a Flash Converting Furnace (FCF) to produce high-grade matte and blister copper respectively. Since the commissioning of smelter in 1995, several improvements were made to these furnaces to increase their efficiency and operational safety. At present, Kennecott smelter is known to be among the lowest-emission and highest energy recovery copper smelters in the world. Since the smelter start-up, Kennecott has invested in several advanced furnace monitoring practices to evaluate the integrity of the furnaces and improve their campaign life. An example is their temperature monitoring system installed for the smelting and converting furnaces, which continuously monitors the furnace sidewall temperatures and notifies the operators during temperature excursions. During an investigation on the converting furnace, it was revealed that there were frequent temperature excursions in the settler sidewall area towards the reaction shaft end of the furnace that caused significant furnace downtime. The reason for the sidewall temperature excursions was not clearly known.

Jan 1, 2019

By Bruce C. Fielder

"The concentration of uranium in orebodies discovered in the Athabasca Basin of northern Saskatchewan over the last 20 years has increased by a factor of 100. These high grade uranium orebodies are associated with high concentrations of radionuclides, complex mineralogy and an elemental makeup that includes base metals, arsenic, and molybdenum. Exploiting these high grade ores has required metallurgical advances in milling, tailings disposal and effluent treatment as well as changes in the design of uranium mills.This paper describes the most significant advances, including advances in dealing with the environmental issues which have become more prevalent in recent years. The milling processes of the Cluff Lake Mill, Key Lake Mill, Rabbit Lake Mill, and McClean Lake Mill are compared to illustrate both similarities and differences necessary for milling different orebodies.BackgroundUranium mining in Saskatchewan started in 1953 when the Beaverlodge Mine, owned by Eldorado Nuclear Limited (Eldorado), came into operation at Uranium City. Development in the Athabasca basin started in 1975 when the Rabbit Lake mine came into operation. This was followed by the start-up of the Cluff Lake mine in 1980 and the Key Lake mine in 1983. The McClean Lake mine is forecast to start up in the near future. The McArthur River mine recently received construction approval and the Cigar Lake Project and the Midwest Project are currently in the environmental approval process.The Beaverlodge operation ceased production in June 1982 after nearly 30 years of operation. The Rabbit Lake mill processed Rabbit Lake ore from 1975 until 1985, Collins Bay R-Zone ore from 1985 until 1993, and is currently processing ore from the Eagle Point mine (Bharadwaj, Jarvi and Lam, 1996). The Cluff Lake mill processed ore from the D- Orebody from 1980 until 1984. Since then the Claude orebody has been processed and the OP and DS orebodies are presently being milled (SRK. Senes and Melis, 1987; and Cogema Resources Inc. 1994 ). The Key Lake mill processed ore from the Gaertner ore body from 1983 until 1989 and Deilmann ore has been processed since (Cameco Corporation, 1992b and I 994a). Processing of McArthur River ore in the Key Lake mill is scheduled for 1999. The McClean Lake mill will be processing ore from the JLR, Sue and McClcan orebodies associated with the McClean Lake mine. In future ore from the Cigar Lake and Midwest projects will be processed in the McClean Lake mill. (Minatco Limited. 1991a)."

Jan 1, 1998

By É. Poulin, J. Bouchard, E. M. Pérez-García

Process control and optimization have always been crucial aspects in the mineral processing industry, and expectations constantly increase to cope with more stringent security, quality, efficiency, and environmental performances. The main challenges to reduce variability of key process variables, and steer profits to higher values while maintaining sustainability indexes within acceptable ranges come from nonlinear responses and circulating loads. The most commonly implemented control strategies rely on simple PID controllers for practical implementation and maintenance considerations. If arguably good performances are accomplished when these are adequately set up, there is also room for further gains by using more advanced methods such as model-based techniques. There is thus a need for more realistic process and equipment models. Based on advances of the past few decades, this paper introduces an autogenous/semi-autogenous mill (AG/SAG) model to be included in a modular comminution circuit simulation toolbox comprising ball/rod mills, material handling, and classification devices. The proposed mill model incorporates a modified version of the classic comminution equation that makes grinding rates proportional to the energy input. It requires the determination of a selection function (fragmentation rates) and a breaking function (fragments distribution). The former is modelled with an S-shaped curve characteristic of AG/SAG processes and the latter is a size-relative distribution of the produced fragments. The power draw is predicted employing the empirical equation of Austin. The paper also develops a case study to illustrate how the proposed simulation framework can capture the behaviour of an actual plant. Model calibration consists in an optimization problem that search the global minimum of the difference between predicted and measured/estimated size distributions, power draw, solid fractions, etc. Results demonstrate that the mill simulator can mimic an actual process in its operation conditions. INTRODUCTION Comminution is a key stage in the mineral processing industry, obviously because the phases of interest must be liberated to be able to recover them. In general terms, the global performance of a plant depends largely on the efficiency of the grinding circuit and on the material properties such as its grindability, density, and mineral grades. The subject has vastly been studied since as early as the 19th century, when Rittinger (1867) and Kick (1883) developed some of the first empirical models to relate grinding and energy input. The great interest in the subject comes from the fact that this operation is costly and, probably most concerning, highly inefficient. Buckingham et al. (2011) estimated that ore comminution can represent up to 60% of the overall plant power draw. Moreover, only a modest fraction of the power draw effectively translates into rock fragmentation. For grinding, estimates range between 1% and 25%, depending on the reference used, while the rest is mainly lost as heath (Fuerstenau & Abouzeid, 2002; Tromans & Meech, 2002; Bouchard et al., 2017).

Jan 1, 2019

By Jiuhua Xu, Yuling Xie, Fenglei Bie, Neng Jiang

"Abstract - The Xiaoqingling Mt. area is one of the most productive gold districts in China. The gold-bearing quartz veins are controlled by a series of east-west shear zones within the Archean Taihua Group, and related to the late Yanshanian (Cretaceous) granite. The major metallic minerals are native gold, electrum, pyrite, galena, chalcopyrite and sphalerite, with gangue minerals dominated by quartz, sericite, ankerite, and calcite. The host rocks are mainly amphibolite, plagioclase gneiss, and migmatites. Principal alteration is sericitization, silicification, pyritization, and carbonization.There are four generations of hydrothermal quartz in altered rocks of gold deposits. The earliest generation of quartz, (Q1), occurs in altered amphibolite gneiss and migmatite, and typically contains fluid inclusions with halite crystals (type A) and two phases, (L+V), of fluid inclusions (type B). The salinities of type A inclusions are 32 wt% to 52 wt%, with dissolution temperatures of halite crystals being from 155°C to 465°C. The second generation of quartz, (Q2), occurs as a fine-grained aggregate associated with sericite, and has small (less than 3 µm) type B inclusions. The third generation of quartz, (Q3), occurs in mylonitic, intensively altered rocks and specially beresite (a type of rock composed of quartz, sericite, and pyrite) near the veins, and contains large amounts of CO2-rich fluid inclusions (type C-fluid inclusions with liquid CO2 and type D-fluid inclusion with high density CO2). The CO2 contents of type C range from 72.6 to 87.4 mol% in gas phases, and 35.7 to 68.3 mol% in liquid phases, based on Laser Raman analysis. The homogenization temperatures of fluid inclusion type A and C are from 215°C to 380°C, and from 210°C to 325°C, respectively. The minimum trapping pressure of fluid inclusions is estimated as 80 MPa to 170 MPa for type A, and from 57 MPa to 190 MPa for type C, which approximate to those of fluid inclusions in vein quartz.The ?18O of quartz are from 10.4‰ to 11.0‰ for Q3 of altered rocks, and from 10.7‰ to 12.8‰ for stage I quartz. The calculated ?18O of fluid inclusions varies from -1.3‰ to 6.0‰. The ?D of fluid inclusions ranges from -67‰ to -59‰ and from -81‰ to -48 ‰, respectively. It is concluded that the water in the hydrothermal fluids both reacting with wallrocks and precipitating orebodies could have been mainly of magmatic and/or metamorphic nature. However, local meteoric water might have been important in late mineralization, because of a distinct oxygen-shift toward the meteoric water. The ?34S values for pyrite of the ores range from -7.1‰ to +7.1‰, with an average of +2.9‰. Those of other sulfides (chalcopyrite, galena, and sphalerite, range from -12.5‰ to 8.3‰. The ratios of lead isotopes for galena of the ores are: 17.06 to 17.31 (206Pb/204Pb), 15.43 to 15.74 (207Pb/204Pb) and 37.58 to 38.45 (208Pb/204Pb). In summary, ore-forming fluids in the Wenyu-Dongchuang gold deposits may have originated from a mantle and/or lower crust source, and ore materials were derived from the Precambrian basement, the Taihua Group."

Jan 1, 1998

By William Petruk, Donald Leroux, Michael Cooper

"Brunswick's primary flotation circuit (CuPb) produces a low grade concentrate containing considerable amounts of undesirable sphalerite and pyrite. To determine the cause of the poor selectivity, a series of Quantitative Mineralogical Analyses (QMA) were performed on several CuPb circuit streams. It was observed that significant fractions of sphalerite and pyrite reporting to the concentrate was liberated, meaning that their depression was not complete. The study highlighted the need for some R&D efforts to be spent in sulphide flotation fundamentals.IntroductionThe viability of many mining projects strongly depends on the performance of their concentrators. More than ever, competitive grade concentrate and high metal recoveries are criteria of paramount economic importance. The selectivity of solid/solid separation processes used in concentrators must be maintained at high levels or continuously improved.Flotation is the solid/solid separation process used by most base metal producers. In spite of its low operating cost, flotation remains a very complex process. To make it selective, precise reagent dosages and electrochemical conditions must be maintained. The difficulty in controlling flotation lies in the numerous heterogeneous reactions that can take place between the different solid, liquid and gaseous phases involved. This complex chemistry makes flotation selectivity difficult to understand and, therefore, to improve from a theoretical point of view.Brunswick Mining and Smelting, near Bathurst N.B., operates a 10500 tpd concentrator which produces four concentrates through five stages of sequential flotation (Figure I). Various reagents are added at key process stages while the ore undergoes different electrochemical conditions. Although the selectivity is important at all stages, the performance of the very first separation, the CuPb circuit, is the most critical. It is here where mineral misplacement to the wrong stream has the greatest economic consequences."

Jan 1, 1996

By Nicolas Gatelier, Sophie Laurent, Thierry You

Hard-rock caverns for hydrocarbon storage are a very particular type of underground facility controlled not only by local administrative and regulatory constraints that can be very specific, but also by the possible risks of geotechnical or geomechanical failure. Each such facility throughout the world is a prototype that needs to be adapted to very different site conditions. The straight forward application of design methodologies from relatively similar fields (mines, tunnels) can be very useful, but risks holding back the scientific and technical improvements needed by an engineering industry in full development. Here we look at various case histories and at problems that have been raised where recent attempts at standardization would appear to have been ill adapted, and where storage designers, through experience and judgment, may still provide innovative engineering solutions.

Jan 1, 2015

By T. Crivits, I. Bellemans, K. Verbeken

In the metallurgical industry, furnace cooling is often employed to enhance furnace lifetime. Hence, the pyrometallurgical phase comes in close contact with a non-air coolant. The proximity of the pyrometallurgical phases to the coolants may lead to dangerous situations. In case of a breach of the cooling circuit, the contact between a hot and a cold liquid may cause a vapour explosion. The outcome of this vapour explosion includes a pressure wave which could result in damage to the furnace, bodily injuries or even casualties. To prevent such dramatic events, the origin of vapour explosions is currently being studied in more detail. For this purpose, OpenFOAM was used to perform Computational Fluid Dynamics (CFD) simulations. In a first step, simulations were run to get a better idea of the influence of the compressibility on the simulations. The obtained results help in getting a better insight on the need of computational power, and possible numerical errors using compressible or incompressible solvers in future simulations. In a second step, systems without vapour explosions were simulated and compared to experimental results with mercury and aluminum. INTRODUCTION Humanity started using metals for tools around the Chalcolitic (~7400 cal BC), when copper was melted in small furnaces (Radivojevic, Rehren, Farid, Pernicka, & Camurcouglu, 2017). Nowadays, metallurgy has grown into a major industry and it has become impossible to imagine society without metals. In the pyrometallurgical industry, coolants (low temperature liquids, for example water) and pyrometallurgical phases (high temperature liquids, such as slags, mattes and alloys) are typically present in close proximity of each other. The interaction between these two phases can have catastrophic consequences (Tveit et al., 2008; Ferguson & Zsamboky, 2017). A vapour explosion may occur as the consequence of the rapid evaporation and expansion of the coolant. Whereas the volume of a gas increases linearly with the temperature (approximately a factor four by heating from 100°C to 1300°C), a simple calculation of the ratio of the two specific volumes shows that evaporation causes the volume of water to increase by a factor of 1700 at 100°C and ambient pressure (Table 1 and equation (1)), a number that was also found in literature (George, Nexhip, George-Kennedy, Foster, & Walton, 2006). The volume change occurs so fast that it resembles an explosion, hence the name vapour explosion. Such an explosion at industrial scale can cause economical losses, bodily injuries or even fatalities.

Jan 1, 2019

By Mariam Melashvili, Chris Fleming, Rene Jackman

"A study was undertaken to develop a flowsheet for treating a high grade silver/gold ore body by cyanidation, CCD and Merrill Crowe precipitation, with tailings detoxification to meet stringent limits for cyanide and thiocyanate concentrations in the final discharge. In one of the flowsheets examined, free cyanide in the final leach liquor was recycled to the mill where it was hoped that it might react beneficially with fresh ore to reduce the cyanide makeup by an equivalent amount. However, laboratory results suggested that most of the cyanide recycled to the mill reacted with iron forming a soluble ferrocyanide complex. This would have had a negative impact on cost, not only because the cyanide recycled to the mill could not be claimed as a credit, but also because the presence of ferrocyanide in the final tailings meant copper sulphate had to be added to the SO2/air cyanide detoxification process to precipitate the iron cyanide. In an alternative flowsheet that was examined, recycling of cyanide to the mill was abandoned, and this allowed the milled slurry to be pre-aerated in a single mixing tank before cyanidation. During alkaline pre-aeration, any ferrous ions that are generated in the mill are oxidized to ferric ions, which, unlike ferrous ions, are inert in cyanide solution. This significantly reduced cyanide consumption and lowered costs in the detoxification of the tailings. In this paper, the cost implication of these two circuits is compared.INTRODUCTIONMost of the gold that is produced by hydrometallurgical processes is recovered by cyanide leaching. The reason for that lies in the superior thermodynamic stability of the gold cyanide complex and the favorable economics this confers on the process (Fleming, 2014). However, the gold in most of the gold-bearing ores processed is a very minor component, and therefore, the leaching response is often dominated by that of the host minerals.Many gold ores treated by the cyanidation process contain iron minerals. Cyanide reacts readily with some iron minerals forming ferrocyanide as one of the compounds. Ferrocyanide is stable when solutions are exposed to air and does not retard the dissolution of gold. In fact, it has been claimed that potassium ferrocyanide in the presence of oxygen is a weak solvent for gold (Hedley & Tabachnick, 1958). The main problem with the formation of this compound is the consumption of cyanide. Ferrocyanide contains six molecules of cyanide for each atom of iron {Fe(CN)64-} so the wasteful consumption of cyanide is greatly increased by its presence. Thiocyanate is also often produced during the reaction of certain iron sulphide minerals with cyanide, and contributes to the wasteful consumption of cyanide. In addition, environmental regulations in certain countries demand that thiocyanate be removed from the tailings, and this adds significantly to the cost of tailings treatment."

Jan 1, 2016

By H. Deveci, E. Y. Yazici, A. D. Bas

The leach solutions of waste of printed circuit boards (WPCB) may contain a wide range of base and precious metals with different concentrations due to heterogeneity of these wastes in composition. Therefore, selection of a suitable metal recovery method is of practical importance for downstream processing of pregnant leach solutions of WPCB. Sulphuric acid leaching of WPCB in the presence of a suitable oxidant is capable of dissolving base metals as well as precious metals such as silver. In this study, cementation of silver from sulphuric acid leach solutions of WPCB using metallic copper, aluminum and zinc was studied. The WPCB sample was assayed to have a silver content of 694 g/t. A synthetic leach solution containing 20 mg/L Ag in sulphuric acid solution (0.51 M H2SO4) was prepared based on the silver concentration in pregnant leach solutions of oxidative sulphuric acid leaching tests. Total sulphate concentration ([SO4 2-]T) was kept constant using sodium sulphate at 1 M. Metallic powders of copper (-850 +600 µm), aluminum (-425 +45 µm) and zinc (-45 µm) were used in the cementation tests. The effects of metal type (Cu, Al or Zn), dosage of metal powders (above the stoichiometric ratio by up to 2000-fold) and temperature (20-80°C) on the rate and extent of silver extraction from the solution was investigated. The effect of presence of copper on the cementation performance was also tested. Under suitable conditions high silver recoveries (>90%) was achieved using metallic copper and zinc while aluminum yielded the lowest silver recovery (i.e. 40% Ag). The kinetics of cementation by zinc was comparatively higher than that of other metals. Increasing the temperature was observed to significantly enhance both the rate and extent of silver cementation. SEM-EDS studies were performed to characterise the metallic powders after cementation.

Jan 1, 2016

By E. Ghali, A. D. Bas

"Treatment of oxide, e.g. roasted gold ores has received relatively less attention than sulphidic ones and recently, handling of oxide gold ores is becoming essential. In this study, the influence of roasted gold ore (RGO) slurry (at 35% solid ratio) on the electrochemical dissolution of gold has been examined using pure gold and iron oxide minerals (hematite, maghemite, and magnetite) as disc electrodes by zeroresistance ammeter mode either in one or two separate containers. The presence of slurry decreased galvanic currents, i.e. corrosion rates due to the release and increase in the amount of soluble and/or insoluble species that could retard further the anodic behaviour of gold. Higher galvanic currents were observed in two separate containers than that in one container indicating the primary importance of galvanic interactions. SEM-EDS results observed iron hydro/oxide coatings on gold surface in case of magnetite test. However, in case of RGO electrode it is not a perfect passivation, although somewhat decreasing trend was observed on gold dissolution. These findings have revealed that passivation is not only a laboratory phenomenon, but also it could be responsible for the slowdown of gold dissolution in industrial practice.INTRODUCTIONThe cyanidation of gold is an electrochemical corrosion process thus; the dissolution of gold can readily be studied by electrochemical techniques. The outcome/summary of previous electrochemical studies of gold leaching can partially be summarized as follows: Filmer (1982) and Lorenzen and van Deventer (1992) reported the negative effect of pyrite and pyrrhotite on gold leaching due to the galvanic interactions; Aghamirian and Yen (2005) studied gold galvanic corrosion in presence of sulphide mineral electrodes only in one cell using zero-resistance ammeter (ZRA) mode; Dai and Jeffrey (2006) discussed, individually, the anodic and cathodic behaviours between gold and sulphide minerals, and Azizi et al. (2010, 2011) used a bed reactor to examine the influence of sulphide minerals on gold dissolution in one and two separate cells. Accordingly, a slowdown in gold leaching has generally been attributed to the passivation phenomenon, although the indication of this phenomenon is still an undergoing debate. For instance, Mrkusic and Paynter (1970) identified the passivation as the film formation of dissolved species from calcine, Crundwell (2014) explained passivation, in the case of corrosion of metals, as the formation of a layer which is composed of a new chemical species on the mineral surface and this layer inhibits or blocks further reactions. He suggested that passivation is related to the oxidation of the metal, and the formation of a passive layer that retards the rate of dissolution by several orders of magnitude. Consequently, galvanic interactions, passivation phenomena, or combinations of them are considered significant electrochemical factors affecting gold dissolution (van Deventer, Reuter, Lorenzen, & Hoff, 1990; Azizi, Petre, & Larachi, 2012). It is important to note that generalizing the influence of a mineral/metal on gold dissolution may not be correct in all cases, since contrary behaviours/results (for pyrite) have been observed (Aghamirian & Yen, 2005). Therefore, electrochemical study of gold is still a subject of research and need to be examined further in detail."

Jan 1, 2016

By R. Lapcevic, P. Lokin

"Among other components, ore body „T“ was discovered in the Bor pit copper mine at a depth of app. 500m. The ore body is relatively small: 60-65m long, 40-45m wide and up to 50m high, but with an extremely high content of copper and accompanying metals. The rock mass containing the ore body is composed of altered andesite of relatively poor physical-mechanical characteristics. The exploitation of this ore body by way of conventional mining methods was associated with high risk, cost, and potential losses of the rich ore. Due to everything specified hereinbefore, the adopted solution involved ore exploitation with complete ensuring of excavation stability, thus forming an extremely large underground opening. The excavation and supporting were performed according to the NATM principles along with applying shotcrete, 9-25 m long cables, and horizontal and vertical lattice girders. The excavation of the ore body was completed in app. 2.5 years, all the while ensuring complete stability and security of people and equipment; construction works were constantly monitored. The proposed solution for ore excavation enabled more than 95% exploitation of ore as requested by the Investor, while depletion due to waste-rock excavation was less than the allowed 5%. INTRODUCTIONThe Bor copper deposit is located in Eastern Serbia. Copper exploitation in Bor commenced as far back as 1902. A total of 26 ore bodies varying in size and valuable mineral content have been excavated so far. One of the most recent excavated ore bodies is ore body „T“, which is one of the smallest bodies by volume, but also a body with one of the largest content of copper and accompanying metals. An important fact regarding its exploitation is that it is located at a depth of app. 500 m; that its shape is irregular: 60-65 m long; 40-45 m wide and app. 50 m high; and that it lays within a rock mass of relatively poor physical-mechanical characteristics. In addition, above it, in its immediate vicinity, ore body „F“ was previously excavated and its room was refilled with backfill and water. Excavation methods common in mining practice (excavation with caving, excavation with backfilling, excavation with protective pillars) were inadequate in this case for various reasons:• The immediate vicinity of the previous ore body „F“ room could cause expansion of the caving zone also to that room, along with penetration of groundwater and flotation sludge;• Possibility of deformation expansion caused by caving as far up as the surface of the terrain, including the urban area;• Difficulties in maintaining the stability of excavation sidewalls having steep slopes and great height;• Significant loss of ore mass with a relatively high content of metals etc."

Jan 1, 2015

By D. A. Garland, A. D. Jackson

"Alanx ceramic/metal composites are proprietary products developed by Lanxide Corporation who joined with Alcan to form Alanx Products L.P. in 1988. Alanx ceramic/metal composites are composed of silicon carbide in a combined alumina and metallic aluminum matrix. In laboratory slurry wear tests conducted by Alanx ceramic/metal composites have shown to perform well against other wear resistant materials. At the Kidd Creek Concentrator Alanx CG896 ceramic/metal composite was tested in two pumping applications, the primary cyclone feed pumps and the filter feed pumps. In both instances the wear rates of the parts made of Alanx CG896 were far less than the gum rubber parts traditionally used. As of year to date September 1992 the unit cost to repair primary cyclone pump parts has dropped 58% from 1991 figures. For the filter feed pumps the unit cost to maintain the pumps has dropped by 33% as compared to 1990 figures. The total savings represented by implementation of Alanx wear parts, based on projected year end unit costs for 1992, as compared to 1991 costs for primary cyclone feed pumps and 1990 figures for filter feed pumps, is $166,753. INTRODUCTIONAt the Kidd Creek Concentrator the cost to maintain the primary cyclone feed pumps and the filter feed pumps was a constant concern. Rubber wear part consumption was quite high and the manpower required was considerable. For 1991 the total cost to maintain five primary cyclone pumps was $244,062. The cost to maintain the filter feed pumps in 1990 was $72,076. A wear material was needed that would increase the time between repairs and that would increase the reliability of these pumps between scheduled shut downs."

Jan 1, 1993

By J. P. Jylhä, A. Jokilaakso

The Outotec Flash Smelting process is widely used in primary copper production. A layer of slag on top of matte (copper–iron sulphide melt) creates a barrier through which matte droplets descend. Droplets of different sizes settle through the layer at different rates, which increases possibility of copper losses as smaller matte droplets may be removed with the slag. In this work CFD-DEM (computational fluid dynamics – discrete element method) coupling was used to simulate matte droplets settling through the slag during slag tapping. Discrete droplets and slag flow were simulated with DEM and CFD, respectively. This new approach enables tracking and solving movement and interactions of individual droplets. User-defined models were created to take coalescence and reaction kinetics into account. Coalescence created larger droplets, while the reactions decreased droplet size and increased its density. Drag caused funnelling effect, which pulled droplets towards the centre line of the descending cluster. This research is the only study known by the present authors in modelling liquid-liquid systems with the CFD-DEM coupling. Simulating coalescence and chemical reactions for discrete droplets enables more realistic simulations. However, CFD- DEM simulations are computationally resource intensive already without additional models, so a full scale industrial settler modelling still waits for further increase in computer performance. INTRODUCTION Flash smelting is a method used in copper and nickel production. In the flash smelting process, oxidation of sulphides in a concentrate is used to release energy needed to smelt the feed. In the process, copper matte is formed. Matte has copper content in the range of 55 – 70% (Sridhar, Toguri, & Simeonov, 1997), the rest is mainly sulphur and iron but has still many other impurities (Taskinen, Seppälä, Laulumaa, & Poijärvi, 2001). Oxidized iron forms iron-silicate slag while SO2 is collected for acid production (Davenport & Partelpoeg, 2015). The Outotec flash smelting furnace (FSF) can be divided in four major component: concentrate burner, reaction shaft, settler and uptake. Concentrate, flux and oxygen enriched air are injected into the reactor through the concentrate burner. The mixture then reacts in the reaction shaft forming matte and slag, which are collected in the settler, while off-gases flow out of the reactor through uptake for heat and dust recovery, and SO2 collection for H2SO4 production. The matte and slag form separate layers due to immiscibility and density difference. Raw material feed is continuous, but the matte and the slag are tapped periodically. A flash smelting furnace is depicted in Figure 1.

Jan 1, 2019

By N. Katsikaros, N. S. ‘ Yap, B. Adaszynski

"Cyanide is a well proven, effective lixiviant that has been utilised for centuries in gold extraction processes. Despite being used in close to 90% of gold processing plants, cyanide leaching is still being scrutinised due to its toxic nature. With governments tightening the regulations on cyanide management, and recently erected sites situated closer to community and environment, leach waste and tailings treatment has become increasingly important. Gekko Systems has worked with engineering companies and directly with gold producers to provide technical services and supply complete modular cyanide destruction (detox) systems for plants leaching both run-of-mine ore and high sulphide gravity and flotation concentrates. Although similar in principle, the different materials presented unique challenges in design and implementation. Similar to designing any section of a processing plant, the development of the cyanide destruction plant design began with laboratory test work to simulate the full scale operation. This paper focusses on the laboratory test work and how other critical factors such as geographical location, logistics, and local community play a role in the process design and construction. Two design and supply cases are discussed in this paper; one treating intensive cyanidation concentrate leach tails and one treating whole ore CIL tails. Although these plants both use the SO2/O2 process, each presented different challenges in laboratory testing and plant design, resulting in variations in final implementation including reagent choice, oxygen supply, and process control.INTRODUCTIONSince 1887, cyanide has played a large part in the beneficiation of gold from gold bearing ores. Cyanide is used to solubilise gold into solution, and is typically added in excess to maintain the leaching process. Some or all the excess cyanide can often be recovered and reused in the process however chemical destruction of cyanide is often necessary to manage cyanide levels in the tailings storage facility (TSF)."

Jan 1, 2016