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By P. A. Davies

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 11pp., 15 refs. Hazards such as vibration, dust emission and fragment projection can result in an area called the Danger Zone being set around a blasting site. Traditionally Danger Zones have been set solely on the basis of consequences (e.g. based on the maximum distance of rock projection or expected ground vibration plus a defined safety margin). Advances in risk assessment and its growing acceptance as a safety management tool have led to the setting of Danger Zones based on both consequences and frequency of occurrence. This allows distances to be optimised on the basis of acceptable risk levels rather than the potential consequences of infrequent events. The setting of a flyrock Danger Zone is used to demonstrate a risk-based approach compared with a traditional consequence approach

Aug 1, 1995

By C. J. A. Mcewan, C. M. Rice

The Rosita Hills contain rich, vein- and breccia pipe-hosted precious metal deposits. Volcanic activity occurred in two cycles - an early, mainly andesitic cone-building phase that terminated in the formation of a caldera and breccia pipes and a later phase characterised by trachytic lavas and dykes, rhyolite domes and lamprophyre dykes. Alteration consists of weak propylitic and argillic and, locally, intense advanced argillic, K-feldspar sericitic and silicic types. Marked trace-element depletions (Rb, Sr, Zn, Mn) are associated with K-feldspar-sericitic alteration and with advanced argillic alterations, whereas enrichments (Pb, Ag) are associated with K-feldspar-sericitic alteration. Gold distribution is highly localised and is controlled by breccia pipes and a caldera ring fault; it is not related to district scale alteration. In general, the geochemical and alteration patterns are complex, but they are clearly influenced by linear structures, the caldera ring fault and breccia pipes. Pipe-hosted Au-Ag and vein-hosted Ag mineralisation are associated, respectively, with early andesitic and late, post-caldera rhyolitic activity. The pipe-hosted and, especially, the vein-hosted mineralisation show affinities with adularia-sericite-type epithermal deposits

Jan 1, 1991

By R. Allington, G. Walton

The approach has been applied with success to the restoration of chalk workings in southern England, and research and trials relating to restoration blasting and the replication of limestone dale landforms have been undertaken. An essential prerequisite for application of the technique is rigorous geomorphological analysis of the locality to ensure that final quarry landforms are consistent with the local geomorphological and landscape setting. It is always important to ensure compatibility of the final landform with the intended after-use, and to achieve this it is also essential that such restoration schemes have a sound geotechnical basis. A disadvantage of the approach is that final slopes tend to be flatter, especially in weaker strata where natural slopes are not steep; the implications for reserves may be unacceptable, particularly in quarry extensions

Aug 1, 1994

By S. G. Tsimas, A. K. Moutsatsou, G. K. Parissakis, M. A. Komiotou

For Greek kaolin producers, a considerable proportion of whose output is from deposits containing more than 4 wt% Fe2O3, the colouring resulting from iron oxide impurity represents a serious problem that necessitates upgrading of the ore to meet commercial specifications. Autoclave leaching with oxalic acid for 1 h at 120 degrees C and 5-6 bar was shown to reduce Fe2O3 by up to 90% without affecting the structure of the kaolin, which maintained its physicochemical properties. The iron oxalate product can either be removed from solution or precipitated as iron hydroxide with recycling of the oxalic acid

Aug 1, 1995

By R. O. Suominen, P. A. Taskinen, K. R. Lilius, A. T. Jokilaakso

Chalcopyrite concentrate was flash-oxidised in a laminar-flow furnace in oxygen-nitrogen atmospheres that ranged in composition from N2 to N2 + 50 vol% O2. Gas pre-heating temperatures were 500-1100 degrees C and four particle-size fractions were studied: 28-38, 38-44, 44-62 and 62-74 micrometres. The effect of the residence time of the particles on sulphur removal was studied in the range 0.1-0.35 s. Scanning-electron microscopy combined with energy-dispersive analysis and back-scattered electron analysis was used to determine the morphology and mineralogy of the reacted particles. Total desulphurisation was achieved under the most oxidising conditions. Particles were observed to undergo fragmentation during oxidation, the violence of this depending on the iron and sulphur contents and the original particle-size fraction. The melting and/or reaction stages of the particles under different conditions were studied in powder samples. Polished sections were examined to follow the development of porosity and the mineralogy of the particles. A model for the fragmentation process is described

Jul 1, 1991

By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

By J. S. Duval

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The compilation of the National Uranium Resource Evaluation aerial gamma-ray data to produce maps of the apparent surface concentrations of potassium, uranium and thorium for the conterminous USA has resulted in a reasonably accurate representation of the distribution of these elements in the surface rocks and soils. This claim is supported by the general agreement between the mapped geology and the patterns seen in the data

Jul 1, 1991

By N. Krauland, A. Nystrom, M. Board, S. Sandstrom

Several deep Swedish cut-and-fill mines experience severe ground control problems, including roof collapse and wall sloughing, as a result of variable rock quality and high in situ stresses. A project to examine the problem included two main areas. The first was prediction of mining conditions at depth and the adaptation of cut-and-fill mining to such conditions; the second was the assessment and improvement of support methods at present and future depths. Simple, elastic, mine-scale numerical models were used to optimise stope sequencing and more detailed, stope-scale models to simulate the failure processes around a stope and the interaction of rock mass and support. Kristineberg was chosen for testing and calibration of the predictive methods because of its long history of severe ground conditions and the large base of observational and monitoring data available for comparison. Horizontal cut and fill was found technically suitable to depths beyond 1 000 m and economically viable if ore value covers support costs. Stability can be achieved with the present support technology down to 1 000 m but the 7-strand 15.2 mm cables have poor deformation properties (5% failure strain) compared with rebar rock bolts (17%). Reducing the intervals between levels from 100 m to 50 m will cut support costs and improve production reliability and capacity. Simulation of sill-pillar mining indicated that conditions would be most severe when pillar height was reduced to 15-20 m; mining of a sill pillar has been carried out successfully to the last 3 m, whose extraction is planned for the near future

Dec 1, 1995

By D. C. Goldring

Many high-grade iron ores are considered to result from the supergene enrichment of banded iron formations. The secondary processes may be related to either present-day or ancient erosion cycles and may reach a considerable depth. Other high-grade ores hosted by banded iron formations are regarded as either sedimentary or metamorphic in origin although often also subjected to the secondary processes. The evidence for this multiplicity of origins is reviewed with descriptions of selected deposits: Kedia d'Idjil and M'Haoudat in Mauritania, Bomi Hills and the Nimba Range in Liberia, the Itabira district in Minas Gerais, Brazil, and El Pao in eastern Venezuela. Emphasis is placed on the recognition of textures that show that some ores are tectonites, the precursor materials having undergone pervasive deformation accompanied by metamorphism. The question whether such ores are pre- or syntectonic is difficult to resolve, the evidence being inconclusive, but a diagenetic/early deformation origin is preferred. The possible range of origins has to be taken into account in exploration, particularly as regards the depth of drilling, and in the characterisation of ores for metallurgical use

Jul 1, 1991

By P. H. Davenport, L. W. Nolan

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Geochemical mapping provides a direct approach to delineating areas of epigenetic mineralisation and for relating the regional distribution of this mineralisation to an overall tectonostratigraphic and structural framework, as well as to extensive areas of hydrothermal alteration. Organic lake sediment is a widely available and effective sampling medium for regional geochemical mapping in Newfoundland, that has proved to be valuable in Au, Sb and W exploration

Jul 1, 1991

By M. Gallego, R. Oyarzun, L. Ortega

Evidence of metallogenic activity in an area dominated by Upper Precambrian and Palaeozoic metasediments was partially explained in the 1980s when drilling and a geophysical survey detected hidden intrusions, but questions remained to be answered about the nature of the fluids. Sb mineralisation at El Juncalon vein-type deposit was selected for geological, geochemical and fluid inclusion studies as a model with a relatively simple quartz-stibnite-pyrite paragenesis. Many of the characteristics were those of Chinese-type vein Sb deposits, which can be regarded as atypical of the epithermal type as they are hosted by clastic rocks

Aug 1, 1995

By A. R. Biggart

Twenty-sixth Sir Julius Wernher memorial lecture, presented at the Tunnelling '94 symposium held in London, 5-7 July 1994. In describing 18 projects with which he has been involved over a period of 36 years, the author aims to illustrate how technological change and an increase in scientific knowledge have influenced tunnelling practice, which he nevertheless maintains does continue to be an art. Tunnels discussed are: the Silver Street, Blackfriars, Whitechapel, St. Paul's and Waterloo Post Office tunnels, 1958-1969; metro tunnels on the Victoria Line, London, 1962-1970; the introduction of tunnel boring machines (TBMs), 1971-1978, in the Empingham reservoir diversion tunnels in Rutland, the bentonite tunnelling machine experiment at New Cross, the Southern tunnel water main section of the London Ring Main and the Warrington sewer in Cheshire; tunnels in rock 1975-1981, for the Lune Wyre and Megget Manor aquaducts, Weymouth sea outfall and Bristol interceptor sewer; Priestley TBM tunnels 1969-1982; the Greater Cairo wastewater project 1983-1987; Anacostia River crossing, Washington DC 1985-1987; the Channel Tunnel 1987-1992; and the Storebaelt eastern tunnel in Denmark, 1992-1994.

Dec 1, 1994

By E. Niehuis, J. Y. Kim, H. G. Cramer, S. L. Chryssoulis, K. G. Stowe, C. Bendel

TOF-SIMS was used to detect, identify from parent molecular ions and determine the relative concentrations of collectors sorbed on the surface of mineral particles in concentrate and tailings samples from three Canadian concentrators. In the Kidd Creek Zn circuit, sphalerite lost to tailings carried on average a quarter of the amount of isobutyl xanthate present on that recovered to Zn concentrate; amyl xanthate, which is not reported as added to the circuit, was also detected on floated sphalerite and pyrite. At Brunswick, sphalerite particles lost to the scavenger tailings had ten times less amyl xanthate and isobutyl xanthate than those recovered to the Zn final concentrate, while both xanthates were detected on sphalerite floated to the Cu-Pb cleaner circuit. At Matagami, significantly more isopropyl xanthate and isopropyl dithiophosphate were detected on sphalerite recovered to the final Zn concentrate than on that lost to the Zn rougher tailings

Dec 1, 1995

By W. P. C. Duyvesteyn, B. J. Sabacky

Reprinted with revisions from Extractive metallurgy of copper, nickel and cobalt, volume I: Fundamental aspects. ed. Reddy R.G., Weizenbach R.N. Warrendale, Pennsylvania: The Minerals, Metals and Materials Society, 1993. Development work on the Escondida process, concluding with the successful operation of an integrated leach-SX-EW pilot plant and a pilot flotation plant for the upgrading of leach residues, demonstrated that all major process objectives could be achieved. Extraction of 40% of copper in concentrates containing monovalent copper was achieved with essentially no oxidation of sulphide sulphur. The Cu contents of leach residues from four different types of concentrate were successfully upgraded to the original feed grades, giving a product that has potential as a high-quality concentrate for the smelter market. A compact solvent extraction section effectively recovered the ammonia lixiviant for recycling to leaching and selectively transferred Cu into a conventional acid sulphate electrowinning system. High-quality "six-nines" copper cathode was produced on commercial-scale stainless steel blanks, demonstrating that the process will be able to compete effectively in the premium cathode market

Dec 1, 1995

By Xiao Min You, D. R. Swonbourne

Smelting of Cu anode slimes involves the use of a slag to hold the oxidised Cu, but some Ag is also inevitably oxidised to the slag. The solubility of Ag in sodium silicate slags at 1 100 and 1 150 degrees C has now been determined over a very wide range of oxygen partial pressures. Silver was found to be present in the slags both as neutral atoms and as AgO(0.5). The activity coefficient for atomic Ag was a very strong function of slag composition and temperature, whereas that for AgO(0.5) was much less affected by slag composition and was almost independent of temperature over the limited range examined. The results reveal that the dissolved Ag cannot be fully recovered by reduction of the slag with very reducing gases

Jun 21, 1905

By D. C. Kaliampakos, A. K. Moutsatsou, J. K. Skotaras

The wastes from marble extraction in the Thasos- Kavalla-Drama region of northeastern Greece could be utilised as a new source of high-quality white carbonate fillers for the European market. Large deposits, satisfactory properties, acceptable processing costs and environmental benefits are among the factors that would have a positive bearing on a proposal for their use in this way. DTH, the waste arising from dolomitic marble quarrying operations on the island of Thasos, appears to be the more suitable material than DA waste from Nikissiani on the mainland because of the lower cost of primary grinding and the higher production rate of ultrafines with a mean particle size of 5 micrometres (the optimum size for filler properties in the case of both DTH and DA), its superior whiteness, the benefits that such use would bring to a very severe and complex environmental problem and the lower transport cost

Jun 18, 1905

By H. K. Taylor

Ore reserves are inadequately defined. Geological reconnaissance and pre-feasibility mining work generate a broad range of valid tonnage estimates, many published for the benefit of various interests, who may view all figures as reserves. This work reviews the regular estimation of tonnages, grades and relevant factors for single deposits. A consistent framework of definition is suggested which, by conforming to the known structures of feasibility studies and long-range plans, avoids the pitfalls of over-categorisation and of unrealistic promises. Applications are based on North American experience but are intended for general use

Sep 1, 1991

By D Macdougall, J Otto

The financing of large mining projects in developing countries is often achieved, at least in part, by limited-recourse financing methods. Financing agreements are affected by the basic accord that is struck between the host government and the sponsors of the project. It is concluded that governments and project sponsors should take into account the requirements of lenders when structuring such mineral development agreements to maximise the potential for attracting project financing. Lenders are likely to be most interested in aspects such as fiscal arrangements, calculation of taxable income and general accounting rules, royalties, transferability of payments/dividends overseas, corporate structure and control, staged development, financing, loan support and state guarantees/approvals, political risk, provisions for default, product marketing, settlement of disputes and environmental issues

Aug 1, 1994

By C. McCall, J. T. Knight, J. R. Ridley

Gold mineralisation in the gabbro sills is mainly stratabound to quartz- and Fe-rich, granophyric-textured units and is sited in undeformed, brittle quartz vein sets, which form pipe-like orebodies. Hydrothermal wallrock alteration consists of hornblende-plagioclase-calcite-quartz with minor biotite, garnet and chlorite and with arsenopyrite and pyrrhotite as the dominant sulphides. Geothermobarometric data suggest that gold was deposited at around 520 degrees C at 2.8-3.8 bar. Mineralisation is thought to have occurred during amphibolite-facies metamorphism. Fluid inclusion and isotope data indicate that gold mineralisation was the result of deposition from a low-salinity H2O-CO2-CH4 fluid of either metamorphic or magmatic origin. Although the Three Mile Hill deposit differs from others in the area in its wallrock-alteration assemblages, peak-metamorphic timing of gold deposition and distinct geochemical associations it forms a brittle stratabound ore body which suggests structural and gold-depositional mechanisms in common with those of the other gabbro-hosted gold deposits

Jun 18, 1905

By G. Zhan, P. Mousset-Jones, G. Danko, J. J. K. Daemen, C. Mezei

Paper presented at the conference Risk assessment in the extractive industries, held in Exeter, 23-24 March 1994, and first published London: IMM, 1994, preprint volume. 18pp., 12 refs. (Originally entitled: Tunnel roof diagnosis using a robotic sensor test bed.) An integral roof diagnosis method is proposed to assist in assessment of risk regarding the stability of an excavation. A Robotic Sensor Test Bed (RSTB) is being developed for the characterisation of roof stability. The sensor test bed consists of a sonic/ultrasonic wave response sensor, a laser surface profiler and a surface temperature sensor. These sensors are mounted on an articulated robot manipulator for performing remote-controlled or fully automated diagnoses. A number of laboratory and field sonic/ultrasonic tests were conducted. A high-energy ultrasonic transducer and an impact device were used to resonate rock slabs. The fracture depths of the slabs were found to be inversely related to the measured resonance frequencies. The agreement between identified and actual dimensions was acceptable. Field tests also showed that loose rock on the surface can be clearly distinguished from solid formation by comparing their wave responses. The robotic laser profiler part of the RSTB was used to measure surface geometry. Different scanning methods are being developed to achieve the fastest and most precise measurements and to provide pertinent information about rock joints and major fractures

Dec 1, 1994