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By T Roberts, S Talu

Steel wire weld mesh is a common industry standard surface support used in underground mining, traditionally installed with mining drills during the bolting cycle. As underground mining depth and stress increase, mining methods and their sequences at these depths place challenges on conventional surface support options. These challenges have provided a need for high capacity surface support options that improve development efficiency, reduce the need for secondary ground support installation and is easily installed with current mining equipment. A 5m2 mesh testing machine was built, suspending a 9500kg concrete slab, designed with multiple hold down points to test varying bolting patterns. Mesh load and displacement is accurately measured using a data acquisition system which pushes against the restrained mesh module with an available 200kN load and 1200mm displacement capacity. A testing program comparing conventional surface support, straps and combinations of both were tested for baseline results. New module designs incorporating existing mesh types and new design concepts were manufactured to allow for single pass installation during a bolting cycle. Nine mesh types, mesh/strap combinations and new mesh module designs were compared using the same test method. Based on these results, two high capacity mesh module types are produced. This paper will detail the test program, load and displacement results and underground mesh module performance, describing the two high capacity mesh modules function within the development cycle and manual handling. CITATION:Roberts, T, Talu, S and Wang, Y, 2018. Design and testing of high capacity surface support, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 303–322 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By I Grewal, M Lundt

Dense medium separation (DMS) is one of several preconcentration methods used for early waste rejection from run-of-mine ores at relatively coarse particle sizes prior to additional milling and beneficiation. DMS has been used extensively in the coal, diamonds, mineral sands, base metals and iron ore industries to produce either a final product or as a preconcentration step. Laboratory scale and pilot test work at the Met-Solve laboratory in Canada has demonstrated successful separation and upgrading of other minerals such as lead, zinc, copper and lithium based ores using DMS.This paper reviews historical dense media systems, results from the pilot-scale multi-stage DMS Separator “Condor” system, as well as production plants and associated laboratory heavy liquid separation (HLS) test work on various minerals. The mineral systems tested included a lithium bearing ore and a fluorspar ore. Other minerals were tested but are not reported in this paper.Pilot plant test work on a fluorspar ore showed that 41.6% of the mass could be rejected to the tailings stream while 95.3% of the CaF2 was recoverable to the product stream. On a spodumene sample that was tested, it was possible to reject 55% of the mass to tailings while recovering over 90% of the lithium.In recent market conditions and with the decreasing grades in existing ores, preconcentration should be a consideration to maximise the value of certain operations.CITATION:Lundt, M and Grewal, I, 2017. Dense media separation – a valuable process for preconcentration, in Proceedings MetPlant 2017, pp 122–130 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 11, 2017

By M Barker, H Li

The total number of tailings accidents has reduced from over 50/decade in the 1960s-1980s to less than 30/decade in the 2000s to 2010s. However, the rate of significant tailings dam failures has not been reduced. The significant tailings dam failures the mining industry experienced in the recent history include: Merriespruit, South Africa, 1994; Los Frails, Spain, 1998; Kolontár, Hungry, 2010; Mount Polley, Canada, 2014; and Samarco, Brazil, 2015. The conventional Factor of Safety approach itself may not be enough to further reduce the rate of significant tailings failures due to its limitations such as uncertainty. For example, the same factor of safety could have a vast range of annual probability of failure for different tailings dams, and insufficient consideration of failure consequence. This paper presents a risk based approach for design with the objective being to minimise tailings dam failures, especially those significant tailings failures with high consequence and low probability. This approach includes risk based design and risk management using bowtie tools. In the risk based design, quantitative analysis will be used to estimate the annual probability of failure and the tolerable failure criteria is linked to the consequence category. Bowtie analyses will be used to understand hazards and risks and identify and select independent controls that are effective in preventing and mitigating catastrophic failures. In this paper, examples of risk based design and bowtie analyses are presented and discussed. CITATION:Li, H and Barker, M, 2018. Risk-based approach for minimising tailings dam failures, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 397–414 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Wall J, Platell R, Knight P

The Argyle diamond mine is located in the East Kimberley area of Western Australia, some 100 km south of the town of Kununurra. The diamondiferous Argyle olivine-lamproite diatreme was discovered in August 1979. Production began in December 1985 at a planned throughput of 3 Mtpa to recover 25 million carats of diamonds. Presently, Argyle is the world's largest producer of natural diamonds and produced over 40 million carats in 1993 from seven million tonnes of lamproite ore treated. Two phases of evaluation have been carried out. The first in 1981-82 was designed to prove around 60 million tonnes of ore to justify the establishment of a mine with a minimum life of 20 years. The second phase, in 1989-90 involved drilling the orebody to greater depths to provide data on which to plan the final pit design. The final pit contained 120 million tonnes of ore at 5.3 carats per tonne (ct/t) grade. Mining of the planned pit will extend the mine life to around the year 2004, following which it is possible that a further cut-back could be mined. There is also the potential for future underground mining. A substantial amount of geotechnical work has been undertaken due to the fact that the pit will be nearly 500 m deep and is located in a mobile zone causing abnormally high residual stresses to occur in the pit walls. The occurrence of low strength rocks at depth in the pit walls further complicated the situation. Hydrogeological investigations were done to determine pit dewatering requirements and to assess the effect of dewatering on pit wall stability.

Jan 1, 1994

By P Gnnther, A M. van Niekerk

Coal mining operations in the Upper Olifants River Catchment in the Mpumalanga Province of South Africa are challenged with the increasing production of excess mine water that cannot be fully managed by existing practices of pollution control at source, recycling, and reuse on mining sites, storage and limited release to the natural water course. In contrast to this, the Olifants River Catchment is experiencing water stress and insufficient water is available to satisfy all water quantity and quality requirements for future industrial and municipal growth. It is estimated that the catchment has a deficit of 192 million m3 per annum if the reserve water requirements are taken into account. The future increased water requirements can be met by water transferred to the Olifants River Catchment from adjacent catchments. The cost of transferred water is likely to be substantially higher than the current cost of water supplied to local municipalities, commerce and industry. BHP Billiton and Anglo Coal Corporation are working together to jointly implement water management strategies that will contribute to the achievement of in-stream and dam water quality and aquatic objectives for the catchment. Consideration is now being given to the treatment and beneficial use of excess mine water. This will inaugurate a new era for the coal mining industry in South Africa, in which a pollution threat to the water resources in the Upper Olifants River Catchment is converted into a water source for beneficial use. Three potential mine water reclamation and reuse schemes have been identified and this paper details the technical, institutional, legal and financial considerations in the implementation of these schemes.

Jan 1, 2006

By E Werner, B R. Leavitt

The chemistry of acidic mine drainage discharging from flooded coal mines is commonly reported to improve with time after flooding. This investigation describes a 18-year dataset of post-flooding water chemistry for a below-drainage underground coal mine within the northern Pittsburgh coal basin (Pennsylvania, USA). The Montour mine is a 5650-hectare below-drainage coal mine of maximum 260 metres depth. Montour was closed in 1980 and flooded to within 38 metres of land surface within 4.8 years. Pumping averaging 210 L/s was then employed to maintain water levels at this elevation. The flooded proportion of the mine (by volume) at full flooding was 56 per cent. The shaft where water was pumped from Montour for water control is located about 70 per cent of the distance between the mine water table and the back of the mine ù that is, it is close to the back of the mine. The residence time (total water volume at flooding divided by pumping rate for control) is estimated at 5.6 years. Time series of chemical analyses show three phases of chemical behavior in post-flooding discharge. In Phase I (zero to two years after flooding), iron concentrations were high and reached their maximum (1100 mg/L). In Phase II (two to four years after flooding), a transition was begun to alkaline conditions, with decline in iron and other solutes. In Phase III (>4 years), net alkaline conditions began, with iron concentrations declining exponentially to 50 per cent of mined volume. This attainment of net alkalinity in this case may have also depended on abundant calcite in overburden extended up to 30 m above the mine floor.

Jan 1, 2003

Mining of copper ore is still the most important business in Chile. In order to mine ore with a copper content of less than one percent at Minera Los Pelambres in an economical way, opencast mining is mandatory. Due to the prevalence of avalanches at the mine, the concentrator was located in a stable area, some distance from the mine. As a consequence, the material has to be transported between mine and concentrator by conveyor. A downhill conveyor system has been implemented for more than ten years as the most suitable and most economical ore transport alternative. Due to the length (12.6 km) and inclination (1300 m drop) of the conveyor system, the stresses in the steel cord belt are the dominant design criterion, resulting in a belt quality of ST 7800. Additional dynamic belt stresses during transient operating conditions are avoided by the installation of high capacity adjustable frequency drives. The rating of a single drive unit is 2500 kW. During ten years of operation, several capacity increases have been implemented, from an initial 5800 t/h up to the current capacity of 9900 t/h. This presentation describes the engineering challenges of the implementation of the world's strongest belt conveyor system. Capacity increase measures like the development of new control and breaking strategy, proved by dynamic simulation of belt forces and belt speed scenarios are explained. During this long-term partnership of RWE Power International, the former Rheinbraun Engineering, with Minera Los Pelambres, RWE has been engaged continuously for development work, safety checks, expert opinions and maintenance audits, and giving new impulse to conveyor technology.

May 1, 2010

By M A. Noppé

"Mining is an inherently risky business: from the technical, environmental, social and economic uncertainties associated with advancing an exploration concept to a viable project; to the risks associated with the operating, market, and safety risks and uncertainties attached to a developed mine; and the final mine closure process.Investors and other stakeholders assessing the risk, opportunity and relative value associated with a resource project need to appreciate the project in its correct context. Errors, omissions, biased reporting or conflicting information in reporting may result in a misinterpretation of technical and financial results, leading to biased estimates or assumptions on project value (Noppé, 2016).Simplistically, a project can be assessed on three key areas for positioning the project in its correct relative context, namely: the project development stage the confidence in the estimated quantities and qualities of the resource, reserve and/or product the level of accuracy, precision and confidence in the technical and economic studies supporting the project.In the latter case, the ‘technical and economic’ information includes assessing the necessary social, environmental and commercial/legal/governmental approvals for the project.Responsible management of a resource project through its full life cycle relies on competent and dependable control and direction being effectively provided by the technical, business and board leadership of the organisation. In turn, the project information must be effectively communicated between various disciplines, these disciplines and the company, and the company and its stakeholders.CITATION:Noppé, M A, 2016. Responsible management and transparent reporting across the project life cycle, in Proceedings Life-of-Mine 2016 Conference, pp 5–7 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 28, 2016

By O Dominguez

Significant value can be added to ore supplied from the mine to the mill by measuring its quality in real time and performing grade control additional to that within the mine. Responsibility for ore quality between the mine and mill stockpiles is not always clear due to operational siloes so geologists and mining engineers need to be involved collaboratively with metallurgists to optimise ore value prior to processing. Sensors, such as the GEOSCAN-M which utilises high specification Prompt Gamma Neutron Activation Analysis (PGNAA), that measure conveyed ore flow representatively (continuous and fully penetrative) and in real time have been used in the minerals sector since 2003 and have been successfully applied in multiple commodities. Quality can be measured within the mine where material is conveyed underground or in-pit. Bulk ore sorting is used to divert increments of waste from the ore stream to upgrade material sent to the crushed ore stockpile (COS) as well as to create run-of-mine (ROM) stockpiles of different qualities to maximise blending opportunities and accommodate processing priorities, eg blending out deleterious content. The real time composition measurement can be combined with moisture and fragmentation analysis data for improved ore type characterisation, to control ore blending, for feedback to the mining schedule and block model reconciliation, and feed forward control for grinding and processing operations. The paper discusses various parameters measured and derived in existing operations that are used to maximise coarse waste rejection and metal recovery, optimise plant feed quality consistency, and reduce consumables; power, grinding media, water, reagents, and minimise fine tailings generation. Innovative geometallurgy applications are also discussed.

Mar 22, 2022

By Moyes A. J

The Intec Copper Process uses a strong chloride electrolyte at atmospheric pressure and 80 - 85¦C to produce high purity, 99.99 per cent copper granules and elemental sulphur. A recent, exhaustive study by an independent, major Australian corporation has shown the capital cost of an Inter plant to be approximately half that of a copper smelter at the 200 000 tpa capacity level and approximately half the operating and capital cost at the 50 000 tpa level. The Inter process costs were also shown to be greatly superior to the best available leach/SX/electrowin technology. The process utilises a multi-stage counter current leach at 80 - 85¦C with the addition of air at atmospheric pressure to precipitate iron as a goethite type compound, followed by a two-stage purification process separating impurities in metallic- and other forms. Purified cuprous chloride/sodium chloride solution is fed to an electrolytic diaphragm cell where high purity copper granules are produced at current densities of 1000 - 1500 A/m2 withoutthe need for conventional electrode stripping. Power consumption is approximately half that of the cupric route. The product is suitable for the direct powder metallurgical conversion of the granules to products such as wire or strip. All the steps in the 'furnace free' conversion of copper mineral to product have been demonstrated The process can treat low grade and contaminated concentrates without penalty, thereby offering greater returns to the miner. Lead, zinc and silver may be recovered as metals, with the high oxidation potential of the electrolyte allowing extraction of gold at high efficiency. The gold is selectively precipitated on activated carbon with negligible copper and silver contamination.

Jan 1, 1992

By Paton T. P

In the technical sense, as well as in the professional sense, the word 'model' can have many meanings. More than 23 000 references were uncovered by a simple literature search on keywords ' MO D EL#. and. (META LLURG#. or. M I NERAL#)' . For the purpose of this paper, 'models' will be considered to be mathematical formulations which attempt to represent or approximate a process. The model may be purely, or a combination of: ò fundamental models, based on the laws of physics, chemistry and thermodynamics; ò semi-empirical or phenomenological models, where an intuitive concept of the process is formulated and found by testwork to fit observed behaviour; and ò empirical or 'black-box' models (including neural networks), where a mathematically convenient form is proposed and fitted. Even under this more restricted definition, which eliminates heuristic and statistical 'models', it is clear that the efforts expended in devising and using models have exploded during the years since the first APCOM Conference in 1961, benefiting from the dramatic decrease in the cost of computer power. This paper reviews the areas of usage of computer modelling in the metallurgical and mineral processing industries, from plant design, through off-line support, to on-line modelling and automatic control. In each area, frontiers of new development of the technology are mentioned. It is noted that, while modelling is now standard practice in design, it is not yet the norm in operating and controlling plants. The reasons for this partial acceptance are, it is argued, less related to the limitations of the technology than to the human and organisational factors involved in transferring technology to implementation.

Jan 1, 1995

A process was developed based on the thermal hydrolysis and precipitation of iron from solutions resulting from the leaching of zinc plant residue. A study was made of the hydrolysis of iron, at temperatures in the range 140-220°C, in both pure solutions of ferrie sulphate and in leach solutions derived from plant spent electrolyte.At 200°C hydrolysis of pure ferric sulphate solutions results in the precipitation of ferric oxide, Fe2O3, at low acid. concentrations, and a basic salt, Fe2O3.2S03.H20, at hIgher acid concentrations. At 180°C ferric oxide is precipitated at low acid concentrations, but at higher acidities. carphosiderite, 3Fe203.4SO.3.9H20, is the stable phase. Frequently a mIxture of ferric oxide and carphosldente IS produced at 180°C, the ratio of phases being dependent on the non-equilibrium experimental conditions.With solutions derived from plant spent electrolyte hydrolysIS at elevated temperatures results in the precipitation of jarosite compounds of the type NaFe3(S04)2(OH)6 The precipitation of natrojarosite jarosite, and ammonio-jarosite was studied in detail. Temperature, free acidity, and the concentration of sodium potassium, and ammonium ions are critical factors which affect the extent of precipitation.A process based on ammonio-jarosite precipitation was tested in a pilot plant.An alternative method of iron removal based on the addition of zinc oxide calcine, to neutralize excess acidity, and the precipitation of ferric oxide was also tested in the pilot plant. Both processes appear economically favourable...

Jan 1, 1967

By M A. Gontalves, A F. D C Varajpo, S A. Stachissini

Clays from the Santa Elena Peninsula, south-east of the Ecuador coast, were investigated with a view to identifying their main mineralogical, physical, chemical and textural characteristics as well as their potential for industrial use as adsorbents. Identified as calcic bentonites, two representative samples from the Tosagua Formation (Oligocene to Lower Miocene) were selected for acid activation trials. The selection criterion was based on the greatest amount of clay fraction (<2 ¦m fraction) associated with the greatest content of montmorillonite. For the activation treatments, HCl and H2SO4 solutions of 4, 6 and 8 N were used in a stirred glass reaction vessel with the clay sample under reflux during four hours at temperatures of 70¦C for HCl and 85¦C for H2SO4. Mineralogical analysis by X-ray diffraction (XRD), chemical analysis by X-ray fluorescence (XRF), differential and gravimetric thermal analysis and measures of density, surface area and porosity indicated the changes occurred in the crystal structure of the montmorillonite. The acid treated clays were utilised in trials of purification and decolourisation of soybean vegetable oil in a ratio of 2:100 (clay/oil) at 90¦C for 30 min, under constant stirring. After centrifugation of the suspension, the wavelength of the bleached oil was measured by UV-visible spectrophotometer and the bleaching capacity of the clays was determined. The best bleaching capacity of the samples was obtained with 6 N H2SO4 acid-activated clays. The bleaching capacity was compared to Tonsil, a commercial acid-activated clay and similar results between them evidenced the potential industrial application of the Ecuadorian clays to bleaching of vegetable oil.

Jan 1, 2008

Coal slurry pumping was introduced into the U.K. in 1973. Gateside packs were prepared in areas of containment using R.O.M. coal and a special fast setting cement. The packs restricted roadway convergence and moderated spontaneous combustion risks, but costs were high and alternptives were sought. A similar system using OPC and an accelerator had limited success. Much more successful was the Aquapack process which used dilute slurries of a special OPC based cement and an accelerator based on sodium carbonate and bentonite pumped simultaneously into la fabric packbag. The Tekpak system using HAC and a much modified calcium sulphate mixture superceded Aquapack on the grounds of improved cement pumping life lower alkalinity and lower costs. A further modification of this system gave a cement with a 24 hour pumping life thus obviating flushing out pipe ranges except at the week-ends, improved packbags also increased the efficiency of the process. The hazard of spontaneous combustion can be inhibited if air supply channels across the waste can be located and plugged. Using gas samples from pack pipes to locate the heating and injecting a special grout, formulated from bentonite, sodium silicate and thixotroping agents. into the waste on the intake road has proved a successful method of controlling heatings. Mine' roadway and face cavities are being safely and successfully filled with cementitious foams produced in a novel placer machine. The foams are based on fast setting cements with specialised foaming agents. Up to 13 cu. metres per hour of fast setting thixotropic foams can be produced and their use is now widespread throughout U.K. coal mines.

Jan 1, 1986

By C Smith, D Lilly

The Lafarge Marblehead Plant in Marblehead, Ohio, USA produces 4.2 million tonnes of sized aggregate yearly. In 1997, a program was instituted to maximise primary crusher productivity through the optimisation of blasting variables and procedures. A proprietary blasting shot report database and the Lafarge production database was statistically analysed to provide guidance in the program. Blasting powder factor (kg/m3) was the main control variable utilised to increase crusher throughput. In 2005, the program was refined to increase the production of certain high margin aggregate sizes and the reduction of fines. The principal blasting component affecting the percentage of high margin size production appears to be pattern area (burden and spacing area). This can be coupled with powder factor to optimise the production rate of high margin aggregate sizes. The size optimisation program incorporates the blasting shot report database, Lafarge production database, statistical analysis and aggregate sampling. A preliminary indication is that the production of high margin sizes (12.7 mm X 4.8 mm, 24.4 mm X 12.7 mm, and 50 mm X 25.4 mm) has been increased seven to 12 per cent utilising these techniques. As an added benefit, blasting costs have been reduced linearly as burden û spacing pattern areas have increased and powder factors have decreased. The program is ongoing and will investigate other blasting procedures and variables including electronic blasting caps to further increase the production of high margin products. The statistical methods involved in the analysis are described in this article for use in other mines and situations. The methods described can be used to optimise crusher throughput, digging rates and product size.

Jan 1, 2007

By C E. J de Ronde, J G. Scott

Economic gold mineralisation was discovered at Round Hill by Homestake NZ Limited in 1984 and was subsequently put into production by Macraes Mining Company Limited (MMCL) in 1990. The total mineral resource in 1990 was estimated at 41.4 Mt @ 1.42 glt at a 0.7g/t cut off, for 1.8 Moz of gold. Since project start up the mill has been upgraded twice to increase throughput and reached its current capacity of 3.2 Mtpa. At 31 December 1996, a total of 16.2 Mt of ore at average grade of 1.73 g/t has been excavated, yielding 655,000 oz of gold. MMCL began exploration along the Hyde Macraes Shear Zone in 1994. Since 1994, exploration has been successful with the discovery of over 3.5 Moz of gold. The resource now stands at 110 Mt @ 1.46 g/t gold for 5.1 Moz. This success has led to a planned expansion of the processing capacity to 9 Mtpa with the building of a new 6 Mtpa processing plant.

Jan 1, 1997

During the intial two years (1972 - 1974) of exploration at Telfer, water require- ments were limited to supporting a 50 man camp and diamond drilling to verify thickness and grade of the stratabound ore deposit. Water bores were drilled to intersect the Middle Vale Reef down dip from its outcrop about 70 metres below surface. The MVR reef is an oxidized pyritic horizon which contains 30% - 65% sulphide below the zone of oxidation and forms a highly porous leached gossanous zone to a depth of 100 metres. Surface run-off water from the low hills associated with the Main Dome structure have led to annual re- charge of this extensive aquifer which MAP AREA Lake Waukarlyearly Permian rocks Precambrian basement - - ~;; rocks Sand d.n.s pò. _ « Drainage sg 1 qo~ (`-~.~ ? ò;+ Palaeochannel and 1 d {- subsurface drainage % GLENN BOREFIELD PASSMORE FAULT ;òTsI1. G-OId MIns BOUNDARY oChr~st as t .` Pool 4, 1 j`` Lake Dora òt ~daN 22' 0, 50 Niter KILOMETRES Fig 1. Telfer district map, Great Sandy Desert, Western Australia.

Jan 1, 1988

A drive, 3,500 ft long, was planned to explore mineralization exposed by diamond drilling. A rate of advance of 150 ft per fortnight, approximately double previous Broken Hill rates, was required. Subsequent to the completion of this drive its extension for a further 6,200 ft was planned to provide a main haulage way along which ore could be transported from a newly acquired lease back to the main hoisting shaft, a total distance of 13,500 ft.This paper describes the working conditions, relationships, manning and costs, and gives details of the cycle and equipment used to achieve rates up to 170 ft per fortnight.OBJECTIVEDiamond drilling from the 1,000 ft level at the Delprat Shaft section had indicated that the zone of mineralization, about 150 ft wide, which had been explored on the 1,000 ft level for a length of 2,600 ft, continued downwards with a westerly dip. The drilling results showed that within this wide zone there were arrower lenses of mineralization of possibly payable grade (see composite plan, Fig. 1).Diamond drill holes of 2,000 ft and over, particularly through heavily sheared areas of sericite schist, had been found to be costly, slow, and inadequate in testing the potential and trends of these smaller concentrations of mineralization.It was therefore decided that an exploratory drive should be advanced from the northern limit of the 1,480 ft level into the western mineralization, and that from this drive diamond drill holes should be drilled at dose intervals to outline the ore.The 1,480 ft level was chosen for the following reasons.1. It had the greatest northerly reach of the accessible levels at No. 7 Shaft section below the 1,000 ft horizon and therefore would enable the test to be made most quickly.

Jan 1, 1965

By Z Chang, S A. Mrozek, S Windle

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. It is important to understand skarn-porphyry transitions in order to use exposed skarns to look for associated and potentially larger porphyries. For such purposes, a good start is to understand the transition between porphyry and skarn in known deposits. In this contribution, we report the transition at Antamina, Peru, where skarns occur in and around a Miocene complex comprised of more than seven porphyritic intrusions. There are three types of skarn-porphyry relationships. The earliest intrusive phase, P1A, contains both endoskarn and porphyry-style quartz veins with secondary biotite halos. The porphyry quartz veins and endoskarns formed at the same time. Locally, the intrusion contains only endoskarn without porphyry quartz veins and is surrounded by exoskarns in carbonate wall rocks. In the third scenario, later porphyry (P2) intruding into P1A porphyry and skarns related to P1A contains abundant granular quartz veins and secondary biotite alteration but does not have significant endoskarn. The granular quartz veins also extend into earlier P1A skarns. The scarcity of endoskarn associated with P2 is related to the supply of Ca. The earliest P1A intrusion intruded into carbonates that supplied abundant Ca, therefore both endoskarns and exoskarns formed. In contrast, where the wall rocks of the later P2 intrusion are P1A or skarn related to P1A, there was little free Ca, therefore only porphyry-style quartz veins formed.CITATION:Chang, Z, Mrozek, S A, Meinert, L D and Windle, S, 2015. Skarn-porphyry transition – an example from the Antamina skarn, Peru, in Proceedings PACRIM 2015 Congress, pp 409–414 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By E Christodoulou, L Zoumpoulakis

The kinetics of the thermal decomposition of MgCO3 was investigated using isothermal experiments performed in a thermogravimetric analyzer under a nitrogen atmosphere at 380¦, 400¦, 450¦ and 480¦C. The weight loss data as a function of time were modified to give the fraction that reacted (ß) and the rate of reaction (dß/dt) vs. time (t). Kinetic analysis of the experimental results, using three different methods, showed that diffusion predominates the MgCO3 decomposition over the investigated temperature range, with the data being best fitted by JanderÆs equation ([1−(1−ß)1/3]2=kt). The activation energy was estimated by Arrhenius plots using both the initial reaction rates and rate constants from fitting the above equation. The values estimated were 27.1 and 171.4 kJ/mol respectively.

Jan 1, 2001