Search Documents

By R. K. Koch

The Bureau of Mines developed a zircon sand molding process for static casting of small titanium or zirconium shapes. Castings with unfinished weights up to 3.5 kg (7.7 lb) were produced in an inductoslag furnace and castings up to 7 kg (15.4 lb) were poured in a consumable electrode skull-casting furnace. Molds and cores were made by ram-molding, foundry-grade zircon sand (AFS gfn 93 to 95) bonded by grade D waterglass and tempered with water. Molds and cores were cured either at 250° C (482° F) or 900° C (1,652° F). Castings from the higher temperature molds broke cleanly from the sand while the lower temperature molds produced castings that had to be cleaned by sand-blasting. However, low-temperature cured molds and cores have a number of advantages as follows: (1) A faster, less energy-consuming curing cycle is used; (2) expended cores are water soluble which greatly facilitates core removal; and (3) enough of the binder in crushed expended molds is reactivated by temper water so that the molding mix can be reused five times without any fresh binder additions and up to twenty times without exceeding a total cumulative binder addition of 52 ml/kg dry sand. Crushed used molds that had been cured at 900° C had no detectable binding strength when mixed only with temper water. A large number of oxide and silicate mold washes were studied for improved casting integrity. The most effective wash found for zirconium or titanium casting was monoclinic zirconia (325 mesh).

Jan 1, 1977

By R. R. Brown

The solubility and the activity of aluminum chloride hexahydrate, A1C13?6H2O, in aqueous solutions were determined as a part of the Bureau of Mines, U.S. Department of the Interior, research to improve mineral processing technology for recovering alumina from low-grade domestic resources. The solubility of A1C13 in pure water was found to be 31.09 and 31.77 wt-pct at 25° and 85° C, respectively, and decreased drastically to 10 and 0.1 wt-pct when the respective amounts of 20.3 and 37 wt-pct hydrochloric acid (HCI) were added in solution. The equilibrium constant for the solubility of hexahydrate, activities, and activity coefficients of A1C13 and H2O were calculated and compared with the results from the available methods of estimation. The results were shown to be useful in leaching nonbauxitic ores for extraction of alumina by changing the solubilities of component salts upon addition of HC1. Simultaneous solubilities of A1C13, FeC13, KC1, and NaC1 in solutions of HC1-H2O were also determined and their effects on the purity of A1C13?6H20 crystallized from mixed salt solutions are briefly discussed.

Jan 1, 1979

By Ronald S. Conti

This U.S. Bureau of Mines report discusses the results of research conducted in the Bureau's experimental mine at Lake Lynn Laboratory on the response of fire sensors to simulated mine fires, which included (1) a slowly developing coal-conveyor belt fire, (2) a rapidly burning liquid fuel-belt fire, and (3) a liquid fuel-belt fire in the presence of diesel exhaust. During these tests, several mine fire sensors were evaluated with respect to sensor placement, spacing, and type. The data indicate that smoke sensors alarm several minutes before CO sensors do; and that, in the presence of diesel exhaust, a prototype diesel-discriminating smoke sensor can successfully function without being sensitive to the diesel contaminants. The vertical placement of sensors in the entry near the fire was also shown to be critical in terms of alarm times. Additional data showed that variations exist in response time and level of response for two brands of electrochemical CO sensor. Results also indicate that early detection of fires will improve the probability of miners' escape, because of reduced smoke concentrations during the incipient stages of the fire.

Jan 1, 2010

By J. E. Tiffany, Z. C. Gaugler

In presenting this list of permissible explosives and blasting devices , the Bureau of Mines desires to call attention to pages 16 and 23 , outlining the conditions in use under which , and only under which , the explosive or blasting device is permissible . In view of publications recounting trade practice favoring the use of a blasting device without stemming , particular emphasis is placed upon condition 4 on page lt and condition 2 on page 23 .. An explosive or a blasting device enumerated in the permissible lists of this Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming .

Dec 1, 1943

By J. L. Eakin

The Bureau of Mines determined agents that are effective in foaming heavy brines and oil from gas wells in severe concentrations of sodium chloride, in severe concentrations of calcium chloride, or in moderate oil-brine mixtures. Dynamic foam tests were designed to select the more effective foaming agents. Numerous foaming agents were tested in concentrated simulated brines, in oilfield brines having varied concentrations of ions, in heavy natural brines, and in a commercial brine generally used as a reservoir pressure-balancing fluid. Several agents were detected that could perform efficiently in the field under the most severe saline conditions. Agents that promote foaming in oil-brine mixtures were also determined.

Jan 1, 1965

By Peter H. Toepfer

This report presents the factual data obtained by the Bureau of Mines during diamond-drilling investigation of the Sunset copper deposit in the Index mining district, Snohomish County, Wash. The Sunset mine, first produced copper ore in 1902, but its main period of activity was from 1923 through 1930, The mine has produced 263,500 tons of ore, from which 1,500 ounces of gold, 156,000 ounces of silver, and 12,912,000 bounds of copper-were recovered. The mine has, been idle since 1946

Jan 1, 1953

By C. L. Karr

U.S. Bureau of Mines (USBM) research has shown that fuzzy logic and genetic algorithms (GA's) have great potential for industrial process control. A technique has been developed by the USBM in which GA's are used to substantially reduce the time needed to design fuzzy logic controllers (FLC's).This technique shows promise as an efficient, robust approach to developing control systems. The research described in this report is twofold. First, the basic approach to developing an FLC using GA's is presented. The GA-designed FLC is developed for a specific physical system, a pH titration system. Second, empirical results are presented in which variations in the FLC implementation are compared. Specifically, the effects of altering five aspects of the pH FLC are considered: (1) membership function form, (2) number of fuzzy classes, (3) the center-of-area method, (4) implication operator, and (5) fuzzy rule form. Results indicate that (1) the technique in which GA's are used to design FLC's is effective, and (2) when this technique is used, variations in FLC implementation have little effect on FLC performance in a chosen control problem.

Jan 1, 2010

By Juel H. Stears

Research was done to determine if a hydraulically operated penetrometer developed by the Bureau of Mines could be used to estimate the roof-bolt anchorage capacity of mine roof rock. Tests were conducted both in the laboratory using cement cylinders and underground in shale rock. Hardness readings were measured by the penetrometer around the periphery of the bolt holes at the anchorage horizon. Roof bolts Nere then installed and subjected to an anchorage test. The results showed that the penetrometer readings could be used to determine the optimum stratum for roof-bolt anchorage but could not be used to make an accurate estimate of the anchorage capacity.

Jan 1, 1965

By T. E. Green, E. F. Spano, W. J. Campbell

A combined ion exchange X- ray spectrographic method was evaluated for the determination of 11 metallic elements in high - purity tungsten : Aluminum , calcium , chromium , cobalt , copper , iron , magnesium , manganese , nickel , titanium , and zinc . Copper , nickel , and manganese in the 5- to 100 - microgram range ( 1 to 20 parts per million based on 5 - gram samples of tungsten ) , calcium in the 10- to 100 - microgram range , and cobalt in the 5- to 20 - microgram range can be determined within an accuracy of ± 10 percent of the amount present . Limits of detection of these elements are 0.05 to 0.14 microgram . The overall method was unsatisfactory for the determination of aluminum , chromium , iron , magnesium , titanium and zinc in tungsten .

Jan 1, 1964

By Will H. Coghill

Recent work on beneficiation of the .Alabama red iron ores and ferruginous sandstones has brought out interesting new facts on particle-size reduction that axe a valuable supplement to what is already known.4/ The work was done by the Southern Experiment Station of the Bureau of Mines in cooperation with the University of Alabama, University, Ala., on two samples from the Birmingham district. One was an oolitic red iron ore containing about 35 percent iron; the other was a ferruginous sandstone containing about 25 percent iron, particularly attractive because of its low phosphorus content. In both samples rounded quartz (sand) grains were embedded in an oolitie, "onion skin" matrix of hematite. The hematite carries varying amounts of clay,-which limits the grade of concentrate that can be made. The clayey hematite is soft, so that the rock crumbles readily under pressure. The sand grains shell out like corn,, and without much exaggeration the mill used for differential grinding might be called a "sheller,"

Jan 1, 1940

By H. R. Shell, Robert C. Johnson, Wilbur H. Warwick

Alpha silicon nitride fibers , Si3N4 , were successfully grown in graphite crucibles by a new method utilizing silicates and silicon ( S in equations below) as sources of silicon and using carbon , aluminum , and silicon as reducing agents (R in equations below ) . The basic reaction mechanism is believed to be generally as follows : 1,300 - 1,500 ° C S + R + N₂ SiO + RO + N₂ › 3Si0 + R + 2N₂ _1,300 - 1,500° C 3RO + Si¸N • ( 1 ) ( 2 ) A build - up of coatings on the solid raw- material particles hindered the evolution of silicon or silicon monoxide vapor and thereby slowed down further formation of silicon nitride fibers . Free oxygen in the crucible caused the formation of amorphous silicon dioxide ( SiO2 ) fibers . This problem was solved by passing , entering , and exiting gases through layers of lump graphite inside the reaction vessel . The silicon nitride fibers grew best around 1,400 ° C. Nitrogen flow rates from 4 to 6 liters per minute were adequate . The fiber widths were generally only a few microns whereas their lengths sometimes reached one - quarter inch or more . Chemical and X- ray analyses indicated that bulk fiber samples were usually 80 to 90 percent Si3N4 . The fibers had good oxidation resistance to about 1,260 ° C. Thermal shock resistance was excellent . Electrical resistance was determined .

Jan 1, 1964

By E. J. Kloos

This publication lists devices approved jointly by the Secretary of Interior and the Secretary of Health, Education, and Welfare, as of May 24, 1972, under provisions of Section 11.2, Part 11, Subchapter B of Chapter 1, Title 30, Code of Federal Regulations (37 F.R. 6244, March 25, 1972), for use in mines as respiratory protection in oxygen-deficient atmospheres, and in gases, vapors, dusts, fumes, and mists. Included are self-contained breathing apparatus, gas masks, and supplied-air, dust, fume, mist, and chemical-cartridge respirators. Names and addresses of manufacturers appear in the appendix.

Jan 1, 1972

By Richard L. Rains

In 1984 and 1985, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied part of the 162,887-acre Mormon Mountains Wilderness Study Area (NV-050-161) in order to evaluate its identified mineral resources. The study area is located in Lincoln County, NV, about 60 miles northeast of Las Vegas. The study area had no mines or mining claims in 1985, and no mineral resources were identified within the study area, or at the Whitmore mine or Iron Blossom prospect near the study area. The alluvial fans around the southern boundary are staked with about 450 placer claims. Chemical analyses of samples indicate that some limestone in the study area is suitable for manufacturing cement or for agricultural purposes but the limestone is distant from markets and therefore not economic in the foreseeable future. The study area is blanketed with oil and gas leases, but no known productive horizons were identified.

Jan 1, 1986

By Robert L. Grayson, Syd S. Peng

"An airborne dust study was undertaken at a Southwestern Pennsylvania underground bituminous coal mine by the Pennsylvania Department of Mines and Mineral Industries in 1964 for the purpose of making recommendations and requirements regarding compliance with health and safety aspects of The Bituminous Coal Mining Laws of Pennsylvania, approved by the legislature on July 17, 1961. The study was designed to accurately represent the airborne dust conditions of the subject mine. Sampling by midget impinger of specific worker locations throughout the mine was accomplished. Sample analyses yielded dust concentrations to mppcf, particle size determinations in cumulative per cent less than specified cut-off diameters, and determinations of free silica percentages in total dust samples. The data from this study is further analyzed, and the results are presented.INTRODUCTIONThe Bituminous Coal Mining Laws of Pennsylvania, enacted in 1961, prompted a study of respirable coal mine dust by the Department of Mines and Minerals Industry in 1964. In recognition of their obligation for ensuring the health and safety of bituminous coal miners, the department set out to characterize the airborne dust of mines throughout the commonwealth. The purpose of the studies was to make recommendations and requirements for compliance with the law and for control of airborne coal mine dust in Pennsylvania mines.One such study was undertaken at an underground bituminous coal mine operating in the Pittsburgh Seam in Southwestern Pennsylvania. The study was desig11ed to sample specific worker locations throughout the mine site and characterize the respirable dust relative to each of them. A midget impinger was used to gather respirable range dust samples during an 8-hour shift. Continuous miner operator, roof bolter, stoper bolter, loading machine operator, shuttle car operator, gathering motorman, mainline motorman, and rotary dumper jobs were sampled underground. In addition, barge mover, coal sampler, fine coal operator, heavy media operator, and boiler room attendant occupations were sampled on the surface. The surface sampling was over a 71-hour shift because of UMWA contract provisions."

Jan 1, 1988

By Will H. Coghill

Recent work on beneficiation of the .Alabama red iron ores and ferruginous sandstones has brought out interesting new facts on particle-size reduction that axe a valuable supplement to what is already known.4/ The work was done by the Southern Experiment Station of the Bureau of Mines in cooperation with-the University of Alabama, University, Ala., on two samples from the Birmingham district. One was an oolitic red iron ore containing about 35 percent iron; the other was a ferruginous sandstone containing about 25 percent iron, particularly attractive because of its low phosphorus content. In both samples rounded quartz (sand) grains were embedded in an oolitic, "onion skin" matrix of hematite. The hematite carries varying amounts of clay, which limits the grade of concentrate that can be made. The clayey hematite is soft, so that the rock crumbles readily under pressure. The sand grains shell out like corn,, and without much exaggeration the mill used for differential grinding might be called a "sheller,"

Jan 1, 1940

By D. E. Shanks

As part of its program to lessen dependence on foreign bauxite as the Nation's primary source of cell-grade alumina, the Bureau of Mines is investigating sulfuric acid (H2S04) leaching procedures for the recovery of alumina from domestic aluminous materials. The successful application of a H2S04 leaching process depends on the recovery of the aluminum values in an easily washed and filtered form, containing a minimum of water to be driven off in the subsequent calcination step. This goal was met by the high-temperature hydrolysis of simulated aluminum sulfate [A12(S04)3] leach liquor. Crystalline, insoluble aluminum hydroxy sulfate [A1(OH)S04], which had a water-to-alumina mole ratio of 1:1, was produced. Eighty-six percent of a solution containing 127 g of A12(S04)3 per liter and 76 pct of a solution containing 336 g of A12(S04)3 per liter were hydrolyzed to insoluble aluminum hydroxy sulfate by autoclaving for 1 hr at 320° C and rapidly quenching to room temperature. Higher operating temperatures were precluded by corrosion of the autoclave. The yield of aluminum in the hydrolysis product increased with increasing hydrolysis temperature and decreasing A12(S04)3 concentration.

Jan 1, 1981

By Farrel W. Lytle

Instrumental analysis has become an indispensable tool in research and production of the rare-earth elements. This development can be attributed mainly to a combination of two factors--the marked chemical similarity of the rare-earth elements, which excludes classical methods of analysis, and the speed and accuracy of instrumental-analysis techniques. With continued improvements in methods of producing high-purity rare-earth elements, keeping pace instrumentally is becoming much more difficult. Accordingly, greater emphasis is being placed on improving instrumental limits of detection and accuracy. The methods employed most frequently for determining impurities in rare-earth elements involve use of the optical-emission spectrograph (3, 4)4/ and the spectrophotometer (9). Although numerous X-ray-emission spectrographic methods (6-8) have been developed for analyzing rare earths, these techniques have not included detection of low-level impurities. This investigation was conducted to find the precision and accuracy of X-ray fluorescence in deter-mining impurities in rare-earth oxides in the 0.01-to 1.0-percent-concentration range.

Jan 1, 1959

By G. V. Sullivan

The Bureau of Mines conducted preliminary beneficiation studies of a gold-bearing graphitic schist from Blue Hill, Tallapoosa County, Ala. The average analysis of the material was 0.08 oz/ton gold. Tabling of minus 35-mesh material recovered 83 to 94 percent of the gold at grades of 6.925 to 2.165 oz/ton, respectively. A combination of jigging and tabling resulted in a concentrate assaying 24.3 oz/ton gold and contained 87 percent of the total gold. Treatment of the material by jigging, tabling, and amalgamation recovered 86.5 percent of the gold.

Jan 1, 1969

By R. V. Ramani, R. Bhaskar

"The results .of an experimental and theoretical research study into the spatial and .temporal behavior of dust in mine airways is summarized in the paper. Experiments were performed in mine airways under both controlled and .normal operating conditions. The controlled experiments included the documentation of the concentration and deposition patterns for two types of dust under three different velocities. Real-time dust concentration data were obtained using Real-time Aerosol Monitors (RAM-1) to determine the dispersion coefficient in a mine airway. On the theoretical front, a convection diffusion model of the dust flow phenomenon in mine airways was developed considering dominant mechanisms affecting dust transport and deposition in mine airways. Mechanisms modeled include turbulent and gravitational deposition, coagulation, and dispersion.In this paper, comparative analyses of results of the controlled experiments with the predictions of the mathematical model are presented. In addition to the overall validity, the adequacy of the individual components of the model, such as deposition in the total and respirable range, and dispersion are examined in light of the experimental observations.The experimental data from controlled experiments compared more favorably with model predicted results for similar conditions as opposed to the ·comparative analysis results for in-mine experiments. Specifically, the model· predictions for an 800-meter stretch of a mine airway reveal some significant differences from the behavior noticed in the mine. The deposition was lower than that predicted by the model. Consequently, concentrations were higher than those predicted by the model. The implications of these and other findings for further investigations are discussed in the paper."

Aug 31, 1989

By L. P. Kleinmann

To control the formation of acid drainage at its source, the Bureau of Mines has investigated the role of iron-oxidizing bacteria in the oxidation of pyrite. In laboratory tests, it was determined that Thio-bacillus ferrooxidans could be controlled in coal refuse using anionic surfactants, with an associated decrease in acid production of about 75 pet. Based on these results, large-scale tests were conducted at an 8-acre active coal refuse area in northern West Virginia and an 11-acre inactive refuse pile in southern West Virginia. Acid production was decreased 60 to 95 pet for 4 to 5 months after application of 55 gal/ acre of 30-pct sodium lauryl sulfate solution. To date, effluent surfactant concentrations have been extremely low. Either a hydroseeder or a road-watering truck can be used to apply the surfactant. Since the surfactant solution must reach the pyritic material to be effective, sites that have been reclaimed are generally not amenable to these procedures. A simple laboratory test is described that provides an estimate of adsorption potential; this can be used to calculate a safe application rate.

Jan 1, 1983