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By G. A. Vissac

IN THE preliminary design of a coal washery, the most important factor to evaluate is the ash content of the final product. The ash content permissible may be imposed by market demands, but, in the final analysis, sooner or later - as most consumers today are buying coal on a 'heat value' basis - the coal operator has a certain margin of latitude. and the ash content of the coal to be delivered can be determined on the basis of maximum returns and highest profits. A few years ago, the most desirable separation was selected on the basis of the plus-minus 0.10; that is, the most desirable gravity of the separation was selected at the point showing a minimum amount of near gravities in the raw coal. The reason for this was an expected wide error over these near gravities. Today with the recent development of cry accurate, automatically controlled cleaning apparatus, a much larger latitude is possible, and the most desirable gravity of separation can be selected, almost exclusively, on the basis of the economic factors involved. To illustrate these new methods of investigation we shall give two examples, based on actual coals from the western United States.

Jan 1, 1957

By P. Talonen

Since the last Iron Control in Hydrometallurgy Symposium in Montreal in 1996, the Kokkola zinc plant has increased its capacity from 175,000 t/y to 280,000 t/y by installing an atmospheric concentrate leaching process, which has also affected iron control in the leaching circuit. Major changes have been made at the jarosite residue pond; a subterranean plastic wall reinforced with bentonite and cement has been built around the pond. A new water collecting system that is used for groundwater level control in the pond area was installed. With these two investments in the pond area, it is now possible to prevent any seepage flow from the pond into the surrounding environment. Water pumped from the residue pond is treated in the water treatment plant. This paper describes the behavior of iron in Kokkola's current leaching processes. The treatment of the jarosite, the improvements to the residue pond and the water treatment process are also described.

Jan 1, 2006

By C. M. Anson

This paper describes the progresses used in the manufacture of steel wheel-centres, tyres and axles at the works of the Commonwealth Steel Products Co., Newcastle, N.S.W., Australia. The plant is adjacent to the Northern railway and consists of three main buildings, namely: the foundry, the forging and rolling shop, and the machine shop. The foundry contains a 6-ton Heroult electric furnace, together with all necessary mechanical appliances for moulding. Reheating furnaces, steam hammers and tyre rolling mill are installed in the forging shop. The machine shop contains lathes, boring machines, and hydraulic presses. Until this plant commenced operations all wheels used in Australia were imported, previ.ous to the war, from England and Germany, and latterly from England only. Besides being of great benefit to the country in that there is now a domestic source of supply of these articles, there is also the advantage of retaining the home market; and in addition, a small portion of the population are now engaged in highly technical occupations requiring a great degree of skill. The plant began to operate in October 1919, and by 1921 was in a fair way to meet the domestic demand for those articles of railroad equipment which it manufactures.

Jan 1, 1925

By J. A. Vonhof, R. O. van Everdingen

Since 1949, a total of 59 disposal wells have been installed in Canada to inject liquid wastes from refineries, mining operations and chemical plants into subsurface formations at an ever-increasing rate. Well depths range from around 600 feet to almost 5,500 feet; injection rates range from 0.5 (U.S.) gpm to more than 1,000 gpm for individual wells; wellhead injection pressures range from a slight vacuum to over 500 psi. Apart from strictly technical considerations of well design, the geological, hydrodynamic and hydrochemical conditions at the disposal site have a strong bearing on the safety and success of such operations. Prevailing hydrogeological conditions in large portions of the country do not allow safe subsurface disposal.

Jan 1, 1973

By E. Krause

The oxidation of Fe(II) with S(IV) and oxygen can be used advantageously in leaching systems requiring both Fe(III) and sulfuric acid; e.g., heap leaching of sulfide-containing ores or concentrates. The oxidation of Fe(II) with SO2/air is several orders of magnitude faster than with air alone; rates of up to ?20 g/L'h were observed at 25°C. The reaction proceeds via an intermediate orange-red mixed-valence Fe(II)/Fe(III) sulfite complex, which is present at an essentially constant concentration throughout most of the oxidation process. The oxidation rate of Fe(II) is approximated by the formula -d[Fe(II)]/dt = k [S(IV)] [02]0'3. The concentration of the mixed-valence complex, and thus the iron oxidation rate, decreases with increasing acidity. Certain impurities, such as SCN- and thiourea, negatively affect the rate. The oxidation reaction 2Fe2 + SO2 + 02 4 2Fe3+ + S042- is accompanied by the side reaction H20 + SO2 + 1/202 4 H2SO4. The side reaction becomes particularly important at low temperatures and whenever the oxygen mass transfer is insufficient with respect to the rate of addition of S(IV). Thus, effective oxygen mass transfer is essential for achieving high oxidation rates with minimal acid formation. The activation energy was estimated as 141 kJ/mol over the temperature range 10-35°C.

Jan 1, 2006

By W. Noel O?Brien

Introduction Since 1930 numerous improvements have been made in equipment designed for the mechanical removal of broken ore in underground mining operations. New applications of mechanical equipment, as? well as improvements and adaptations of well established systems, are being made continually. It is the purpose of this paper to discuss present-day equipment for the removal or transfer of broken ore by means of a powered hoist and scraper arrangement. The terms used throughout the paper are those commonly employed in the trade literature and by mining men. The terms slusher hoist, hoist, and scraper hoist are used inter-changeably to mean a machine, powered by compressed air or electricity, with drums for the winding of wire rope. The tail rope, also known as the pull-back rope or return rope, drags the empty scraper toward the tail-sheave, that is, back to the loading point. No attempt is made to cover the entire field of application of scraping methods. Rather it is the? writer's desire to emphasize the fundamental principles of scraping practice and design and to relate them to some modern applications. The available literature on scraping practice has been freely used. together with personal observation and information and advice of practising engineers and representatives of companies manufacturing slushing equipment.

Jan 1, 1951

By D. Yu, T. A. Utigard, M. Barati

"Sulfation roasting of nickel concentrate to generate water-soluble metal sulfates was investigated as an alternative process to smelting for the recovery of valuable metals. The kinetics of dissolution of various species of the calcine in three leachants was studied; hot water, dilute HCl, and concentrated HCl. The results indicated that dissolution of sulfates by hot water at 90 ºC is achieved within 30 minutes. In order to increase the recovery of the valuable metals, acid leaching is necessary due to the existence of ferrite in the calcine.INTRODUCTIONInvestigations on the sulfation roasting of nickeliferous sulfide ores or concentrates were mainly carried out in 1950’s to 1990’s to generate water soluble non-ferrous metal sulfates followed by metal recovery by leaching (Stephens, 1953; Thornhill, 1954, 1961; Fletcher and Shelef, 1964a, 1964b; Fletcher and Hester, 1964; Frankiewicz, 1977; Norrgran, 1983). Commercialization of the sulfation roasting process was only performed by Falconbridge Ltd. (Thornhill, 1961; Boldt, 1967), which employed a sulfation roast process on nickeliferous pyrrhotite at 680 oC where Ni, Cu, and Co were leached and Fe2O3 was produced for the iron industry. In 1965, 118,342 tons of pyrrhotite was processed, however because of the huge SO2 emissions (no acid plant) relative to the nickel production and the poor economics, this plant was shut down.Nickel production from sulfide ores via pyrometallurgical means, especially the electric furnace smelting process, is a major emitter of SO2 to the environment and a big energy consumer (Warner, Diaz, Dalvi, Mackey, Tarasov and Jones, 2007). Nowadays, due to the more stringent environmental regulations as well as the need to reduce energy consumption, metal production by sulfation roasting is gaining more attention as an alternative process to smelting. The main focus of this paper is to investigate the extent and rate of leaching of valuable metals from the sulfation roasted nickel calcine, aiming to maximize the metal recovery and minimize the dissolution of iron species."

Jan 1, 2012

By CH. Liu, H. X. Jiang, X. Xiao

"A study has been conducted to characterize the fatigue life in 7050-T7451 thick plate by the comparison between an experimental alloy and commercial alloy. The fracture origins were specified and their sizes were measured by scanning electron microscope (SEM). Additionally, the size, number density and spatial distribution of porosity in the experimental material and commercial material were characterized and compared, using X-ray Computed Tomography(XCT). The results showed that microporosity was the predominant site for crack nucleation and subsequent failure of the experimental alloy. However, as for the commercial alloy, fatigue cracks were found to originate from constituent particles. The presence of microporosity in 7050-T7451 thick plate reduced fatigue life of an order of magnitude or more compared to the commercial alloy. The relationships between size of origin and fatigue life were proposed. It was showed that the fatigue endurance was reduced when the size of porosity increased.INTRODUCTION 7xxx series aluminum alloys, due to their combination of high strength, high resistance to stress corrosion cracking, and good fracture toughness, are widely used in structural engineering applications where high-strength and low-density characteristics are fundamental design requirements (Williams& Starke, 2003). Every designer is striving to find an optimal combination of properties including strength, corrosion resistance and fatigue resistance (Wanget al., 2016). Based on the design principles of aircraft, a higher fatigue resistance of aluminum alloys are required. Thus, many investigations have been carried out on the microstructures and its effect on fatigue properties of the 7xxx series aluminum alloy (Robson, 2004; Schubbe, 2009).Microporosity, which is a common defect in casting materials, can lead to a significant deterioration of mechanical performance and fatigue resistance, especially in the high alloyed 7xxx aluminum alloys. The actual valid loading area decreases due to microporosity, which results in detrimental effect on the mechanical properties. Many experimental studies have been conducted in this research field. Mayer et al.(2003) investigated the fatigue properties of magnesium alloys produced by high-pressure die-casting. The results show that porosity in magnesium alloys greater than0.18mm diameter may be considered as the most important material defect for high cycle fatigue and fully reversed loading conditions. Nadot et al.(2004) found that the near surface defects are much more dangerous than the internal defects. Wang et al.(2001a) used the Weibull statistics method to analysis the influence of the microporosity, oxides and particles on the A356-T6 alloy fatigue life. The results show that, the porosity is more detrimental to fatigue life than oxide films and particles. With regard to fatigue resistance, although the deleterious effect of microporosity has been generally acknowledged, a quantitative understanding between casting microporosity and fatigue life in 7050-T7451 plate is not well established."

Jan 1, 2018

By WM. G. Heeley

This paper will describe the experience gained and explain the deductions made from the phenomenon of the great squeeze which occurred at Brule Mines. The first indication of the commencement of the squeeze was the breaking of posts on the high-side rib of the slope. At first we thought this was due to a lateral pressure only, and we renewed the broken posts with new ones, the result being that the new posts also were soon broken. A noticeable bending and breaking of the collars occurred, with a corresponding reduction in the height of the haulage slope. These symptoms were also evident on the counter above the slope, indicating that the trouble was of an exceptional nature. In the meantime, we had concentrated a large force of repair men, renewing broken timbers and brushing the roof and floor, but in spite of all our efforts we could not overtake the damage being done. Our next problem was to find the cause of this trouble. We were in a new basin of coal (No. 2) which had only been opened a few months, as we had worked the previous four years in another basin (No. 3) where no such trouble as this had ever been encountered. Naturally our first thought concerned the adequacy of the size of the pillars. We had worked in the No. 3 south basin for the previous four years. without any such experience, with 60-feet pillars between slope and counters; whereas we had established 100-foot pillars in the No. 2 south basin between the slopes and counters with an 80-foot pillar between counter and first line of cross-cuts, and 100-foot pillars between the breasts.

Jan 1, 1924

By H. Z. Liu, J. M. Zhao, F. C. Wang

"Novel silicate-alginate composite beads containing 2-ethylhexyl phosphonic acid mono-2- ethylhexyl ester (P507) were synthesized and applied for the adsorption of Nd3+ from aqueous solutions. The adsorption amount of Nd3+ has been increased owing to the introduction of P507. The effect of equilibrium pH (pHe), the kinetic and isotherm experiments were investigated. The adsorption reaches equilibrium at 9 h and the maximum uptake capacity is up to 195.4 mg/(g dry adsorbent). The Langmuir isotherm equations are used to describe the adsorption process. Complete desorption can be realized with 0.2 M HCl within 20 min. INTRODUCTIONRare earth elements (REEs) have found various applications in different domains, such as metallurgy industry, ceramic industry, nuclear fuel control, photo-electro-magnetic functional materials owing to their unique properties. Neodymium (Nd), as a representative of all of the most valuable REEs, is widely used as catalysts, laser crystals, capacitors, rubber additives, Nd-Fe-B magnets, hydrogen storage and so on. Thus, the separation and purification of neodymium is significant. Unfortunately, Nd always coexists with other REEs and selective separation of the individual Nd from the REEs mixtures is still extremely difficult owing to their strictly similar atomic structures and chemical properties.Liquid-liquid extraction (LLE) and solid-liquid adsorption (SLA) are the most widely adopted techniques for the separation of REEs in the hydrometallurgical fields. The LLE process is well suited for large-scale continuous operation because of its inherent high capacity and fast kinetics. Nowadays, as a commercial extractant, 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (P507) has been extensively studied for extraction and separation of REEs since it has considerably good extractability and high separation efficiency (Xu et al., 1992). SLA is one of the effective and green separation methods with some prominent advantages, such as easy regeneration of adsorbents, small footprint size, less industrial wastes, higher enrichment factors and column efficiency,rapid solid–liquid separation without emulsion and so on. Hence, the introduction of extractants with excellent performance into adsorbents will integrate the advantages of LLE and SLA (Lee et al., 2009)."

Jan 1, 2012

By E P. Graham

Orebodies occur in an infinite variety of grades, shapes and sizes, and take many millions of years to grow. When extraction starts there is only one possible end -the mine sooner or later will run out of ore and shut down. If the mineral industry is to supply the ever increasing demands of modern civilizations, more and more metals must be found and mined. This will require a never-ending search for ore, and the development of every economic body, large or small. To justify the mining of a small orebody, it first of all must pay its way. If the size of the burden imposed by the capital cost estimates is not carefully worked out, an otherwise promising situation could be killed. The very nature of mining, as a transient industry, re-leases a steady stream of good used equipment, and the trained personnel to install and operate it. All manner of plans and layouts, which can be utilized at a new property, are available. Working these and other economies into the estimates will sometimes make enough difference to give a prospect the green light.

Jan 1, 1964

By Francoi Robert, Andre J. Audet, Alex C. Brown

"The Sigma gold deposit is in a band of deformed metavolcanic rocks that are cut by an irregular mass of porphyritic diorite and by narrow undeformed feldspar porphyry dykes. The gold is in veins consisting mainly of quartz and tourmaline with minor pyrite, carbonate, chlorite, scheelite and free gold. The results presented here concern the structural setting of the ore and are based on a study of the mode of emplacement.Two principal types of veins have been recognized: subvertical and oblique veins. Both types are contemporaneous, mechanically linked and postdate regional deformation. The sub-vertical veins are composed of numerous mineralized lenses that occupy the central part of ductile shear zones of great lateral and vertical extent. Normally, several lenses occur in the same shear zone. The vein material seems to have resulted from incremental filling of openings by repeated vertical movement along rupture planes developed in the central part of the shear zones.The oblique veins are small elliptical lenses of ribboned vein material which formed essentially by progressive vertical opening of oblique fractures. Two types of oblique veins are known: one is restricted to feldspar porphyry dykes, within which they are arranged in an en-echelon fashion; the other is of greater extent and is not restricted to one rock type, but tends, however, to occur in the more competent porphyritic diorite.Vein orientation and mode of formation suggest that both sub-vertical and oblique veins developed during progressive deformation associated with the formation of the ductile shear zones. The latter probably formed in response to a compression that took place late in the tectonic history of the host rocks at Sigma."

Jan 1, 1983

By Francoi Robert, Andre J. Audet, Alex C. Brown

"The Sigma gold deposit is in a band of deformed metavolcanic rocks that are cut by an irregular mass of porphyritic diorite and by narrow undeformed feldspar porphyry dykes. The gold is in veins consisting mainly of quartz and tourmaline with minor pyrite, carbonate, chlorite, scheelite and free gold. The results presented here concern the structural setting of the ore and are based on a study of the mode of emplacement.Two principal types of veins have been recognized: subvertical and oblique veins. Both types are contemporaneous, mechanically linked and postdate regional deformation. The sub-vertical veins are composed of numerous mineralized lenses that occupy the central part of ductile shear zones of great lateral and vertical extent. Normally, several lenses occur in the same shear zone. The vein material seems to have resulted from incremental filling of openings by repeated vertical movement along rupture planes developed in the central part of the shear zones.The oblique veins are small elliptical lenses of ribboned vein material which formed essentially by progressive vertical opening of oblique fractures. Two types of oblique veins are known: one is restricted to feldspar porphyry dykes, within which they are arranged in an en-echelon fashion; the other is of greater extent and is not restricted to one rock type, but tends, however, to occur in the more competent porphyritic diorite.Vein orientation and mode of formation suggest that both sub-vertical and oblique veins developed during progressive deformation associated with the formation of the ductile shear zones. The latter probably formed in response to a compression that took place late in the tectonic history of the host rocks at Sigma."

Jan 1, 1983

By McNeely DuBose

INTRODUCTORY PROSPECTING for aluminum has always been, and still is, a peculiar combination of the technical with the physical approach, and 1 want to explain my conception of the term 'prospecting' when applied to aluminum, which differs in some respects from the ordinarily accepted idea of prospecting. In the early days of gold mining, prospecting was a search in the hills and the river beds for the metal, not for its chemical combinations. And so it was in the early days of aluminum, with the difference that the search for the metal was carried on, not in the hills and dales, but in chemical laboratories. Aluminum is never found in the elemental state and at that time the metal bad never been seen, but scientists of that day bad forecast that such a metal must exist and in 1807 Sir Humphrey Davy went so far as to give this unseen metal a name, aluminum, from the Greek word alumen. This word applies to our alum, and it was from alum that Davy sought to produce the metal. It is strange to think that, in laboratories throughout England and on the continent, prospecting for aluminum was busily under way by men who had never seen the metal they were searching for. Their situation was something like that of the fisherman and the 'big one' that got away. They could describe the metal, give its exact weight, and even name it, but they could not produce visual evidence of its existence. Eventually, however, the efforts of the scientist 'prospectors' were rewarded and in 1826 the metal was actually produced, possibly first by Wohler, though Oerstedt, a Danish chemist, is usually credited with the achievement.

Jan 1, 1951

By K. S. Raja, B. Pesic, S. Kshetri

"We investigated the electrochemical corrosion behavior of commercial permanent magnetic material (NdFeB alloy) in 0.1 M NaH2PO4 solution (pH:4.75) containing 0 – 1000 ppm of chloride at room temperature (298 K). The material was evaluated in magnetized and demagnetized condition with different surface preparations such as: Ni-Cu-Ni coated, uncoated (bare), and anodized (in fluoride containing ethylene glycol at 60 V for 15 minutes to form a thick nanoporous oxide surface). The nickel coated magnetic sample showed reasonable pitting corrosion resistance up to 100 ppm chloride addition. The uncoated samples showed passivity in chloride free phosphate solution. Chloride additions caused pitting and the pitting protection potential was equal to the corrosion potential with 100 ppm chloride addition. Demagnetization did not alter the electrochemical polarization. However, the passive film formed on the magnetic sample showed higher charge carrier density than the film formed on the demagnetized sample. INTRODUCTIONSintered NdFeB permanent magnets exhibit excellent magnetic properties such as large energy product [(BH)max > 450 kJ/m3], high saturation magnetization (1.6 Tesla), and high coercivity (1.2 – 2.08 x 106 A/m) (Sugimoto, 2011). However, the NdFeB magnets are prone to corrosion attack because of the presence of Nd-rich intermetallic phases, such as Nd4Fe (Jurczyk & Jakubowicz, 2000). Nd-rich and B-rich intermetallic phases are distributed in a matrix of Nd2Fe14B tetragonal ferromagnetic compound in a permanent magnet. Generally, several types of Nd-rich phases are present in the magnet with Fe:Nd ratios ranging from 1:1.2 to 1:7. The volume fractions of Nd-rich and B-rich (Nd1+xFe4B4 type) phases are about 10% and 7% respectively (Li, Ma, Li, & Wang, 2011) . Among these intermetallic phases, Nd-rich phase has the most active electrochemical potential. Therefore, dissolution of this phase occurs in preference to other phases by galvanic corrosion when exposed to moisture. Since Nd-rich phases are present at the grain boundaries of the Nd2Fe14B matrix, corrosion leads to disintegration of the magnet."

Jan 1, 2012

By L. Voisin, G. Damm

"In order to develop a new pyrometallurgical process for eliminating detrimental arsenic and antimony from the impurity-rich matte produced from copper concentrate, and for treating the occasionally generated speiss in nonferrous smelting processes, the phase relations in the Fe-Cu-S-As-Sb system saturated with carbon at 1473 K were investigated. The distribution of elements between the condensed phases at the miscibility gap, where three equilibrated phases of iron-rich alloy, copper-rich alloy, and matte coexist, were also studied. The investigation was carried out by performing a series of laboratory scale experiments in an electrical furnace at 1473 K, followed by a quenching method on the final stage. The samples obtained from the experiments were analyzed by using Inductively Couple Plasma (ICP), Atomic Absorption Spectroscopy (AAS) and Carbon Infrared Spectrometry (CIS) techniques.The results were compared with previous investigations for the Fe-Cu-S-As-C and Fe-Cu-S-Sb-C systems and discussed on the basis of the molar fraction distribution for both arsenic and antimony in the matte phase at five different matte grades. It is expected that by using this phase separation technique it might be feasible both, the cleaning of a complex copper matte and the elimination of arsenic and iron together with an acceptable amount of antimony into the iron-rich alloy phase, which can be discarded as a harmless and smaller deposit."

Jan 1, 2014

By W. W. Bake

INTRODUCTION IN IN JUNE, 1943, the main pillars of the Beattie Mine glory hole failed, allowing over a million yards of wet clay and debris to flow into the mine, completely filling all workings to within seventy feet of the 3rd level. The resulting Job of clearing these workings and rehabilitating the mine represents a unique and hazardous operation, seldom, if ever, previously encountered in Canadian mining. The purpose of this paper is to describe one phase of this operation -that of cleaning and rehabilitating the mine from the 6th to the 9th level -to outline briefly the events which led up to this work and to describe the techniques and costs involved. It will be noted that such costs, methods, and performance figures as are dealt with in this paper refer only to work in the internal shaft and adjoining workings from the 6th to the 9th level, previous work having been done under other supervision and management. The Beattie mine is in Duparquet township, northwestern Quebec, twenty miles northwest of the town of Noranda and twenty-three miles southeast of the town of La Sarre. The mine and the town of Duparquet, which it?supports, are accessible by highway from Noranda throughout the year. Production at the Beattie mine began in May, 1933, and up to June, 1943, twenty-one million dollars in gold and silver had been recovered from five and a half million tons of ore.

Jan 1, 1951

By A. O. Dufresne

WITHOUT transportation, mining would be quite impossible. Any person familiar with the operation of a mine knows full well that from the minute ore is blasted, it is kept moving until it reaches the treatment plant. In the mill, by means of conveyors and elevators, the ore is brought from receiving bins to one machine after another until finally its valuable mineral is separated from the gangue. The finished product must then be shipped -either by boat, rail, or motor trucks to industrial centres, where it undergoes further treatment and transformation into finished commercial goods. Everybody appreciates that the winning of an or-e includes, amongst various operations, the moving of large quantities of material of generally low value. Transportation, therefore, must be considered One of the most important factors in the economics of mining. My assignment, this afternoon, is not to treat of that phase of transportation as it directly affects mining operations, but rather to consider some of the aspects of overland transportation and its influence in bringing about the development of mining camps in Canada. I shall take the liberty of rapidly surveying conditions facing prospectors, mine developers and operators from the time a region is still in a pre-pioneering stage until such time as a mine starts shipping its concentrates.

Jan 1, 1956

By S. Esmaeili

The yield strength model developed by Esmaeili, Lloyd and Poole [1] has been adapted to model isothermal aging in Cu-containing AA6xxx alloys, with (a) a moderate and (b) a very low Cu content in the solution-treated, as-quenched, condition, Isothermal calorimetry has been used to analyze the kinetics of precipitation in these alloys, While the kinetic parameters for the low Cu alloy has been derived from the present experiments, the previously determined kinetic parameters for the high Cu alloy AA6111 has been used to model the precipitation kinetics in the moderate Cu alloy. The age hardening responses of both alloys have been well predicted by the model.

Jan 1, 2005

By Rob Assabgui

Presentation Overview ? Stobie Mine Sublevel Cave Background ? Elevated Silica Levels ? Silica Control ? Challenges and Issues ? Conclusions

Oct 1, 2010