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By A M. L Smith, W E. Dubbin, K A. Hudson-Edwards

Jarosites (KFe3(SO4)2(OH)6) are examples of minerals that are highly effective scavengers of toxic elements, and are abundant in acid rock drainage systems, acid sulfate soils, metallurgical wastes and other contaminated sites. The K, Fe and S sites can be filled by toxic elements such as Cd, Cu and Zn, but the mechanisms of this incorporation are not well understood.We have used atomistic simulation methods to model the jarosite (102) surface and its interactions with Cd, Zn and Cu, in order to understand the mechanisms by which these potentially toxic elements are incorporated into the K-jarosite structure. Our results suggest that incorporation via a defect complex consisting of an impurity cation at the K site charge balanced by a K vacancy stabilises the (102) surface in the order Cu>Zn>Cd.

Jan 1, 2008

By Azizan A

The paper presents the results of chlorination of beneficiated rutile and struverite (a tantalum-niobium bearing, rutile type mineral in alluvial tin deposits) by carbon tetrachloride in the range 623¦K to 773¦K. The chlorination of rutile could reach near completion at 773¦K in about an hour. The process was found to follow a modified pore-blocking law, with the basic reaction constant K varying inversely with the particle size, so that the basic process may be a reaction under interface control (chemical control) as modified by the pore blocking effect. The pore blocking factors for the various experimental conditions were evaluated and the predicted curves showed good agreement with the experimental data. In the case of Struverite, a similar kinetic behaviour was observed but the chlorination process was relatively slower than that in rutile. It was also observed that in struverite, niobium got chlorinated faster, followed by tantalum and titanium, indicating a good possibility of separation by chlorination using carbon tetrachloride.

Jan 1, 1996

In presenting the paper, Mr. Davey quoted subsequent work which yielded k, at miscibility gap composition, of about 50.We can confirm the authors' findings for k j 300 for nearly pure tin to k 2 about 50 (average 47) from our own experience and from repeat experiments on materials described by the authors, at 1150°C.During laboratory-scale trials we also found confirmation of the authors' view that it is more difficult to reach equilibrium from the high-iron (in slag) side than from the low-iron (high-tin) side. Working from the high-iron side tends to yield results that point to a high k, leading to optimistic values of iron/tin ratio in final slags. In practice the smelting of a tin concentrate, unless it is exceptionally low in tin and high in iron, must yield initially a tin-rich slag and therefore equilibrium can only be reached from the "tinny" side.

Jan 1, 1967

By W. M. LONIE

Address by the President of the Institute (Mr W M Lonie) in making the presentation of the Certificate of Honorary Membership to Sir Ian McLellan, K.C.G.M, K.B.E. Address by Sir Ian McLellan after accepting the award.

Jan 1, 1979

By Iwu GO, Almond DP, Joasoo _

The gravimetric integral Knudsen effusion method was used to measure cadmium activity values in binary liquid In-Cd alloys in the range 523 to 573 K. The activity measurements together with other studies from the literature indicate that special bonding conditions exist in the melts near a composition corresponding to InCd3. Sound velocities in In-Cd melts were also measured using a precision pulse-echo over- lap method in the range 404 to 953 K. The frac- tional deviation of experimental and ideal isentropic compressibilities at 623K shows a functional dependence on composition with a pronounced maximum near the composition 75 at.%.

Jan 1, 1980

By Bourne R. W, Smith T

This paper presents initial findings of a project examining novel processes for the treatment of refractory sulphidic gold concentrates. Non-oxidative roasting of such concentrates for 12 hours at 750¦C resulted in the finely disseminated gold agglomerating to form discrete grains. The pyrite and arsenopyrite decomposed to form pyrrhotite, whilst the labile sulphur and arsenic driven off was collected on a condenser as a mixture of elemental sulphur, metallic arsenic and various arseneous sulphide compounds. As a result, the cyanide solubility of the gold contained in sulphidic refractory gold concentrate from the Emperor mine in Fiji improved from 54.5 per cent to 98.4 per cent; from the Fimiston mine in WA (65.2 per cent to 96.6 per cent), from the Windarra mine in WA (69.6 per cent to 91.3 per cent), from the Harbor Lights mine in WA (20.4 per cent to 60.7 per cent), and from the Wiluna mine in WA (12.6 per cent to 28.0 per cent). The non-oxidative roasting conditions have not been optimised for each of these minerals. Subjecting the non-oxidatively roasted minerals to mild oxidative acidic iron sulphate pressure leaching (with typical temperature of 100¦C and typical oxygen overpressure of 500 kPa) to remove iron and so further liberate finely disseminated gold, resulted in the cyanide solubility of the gold exceeding 96 per cent for each of these five concentrate types (including those from Harbor Lights and Wiluna). Thiourea leaching of the sulphur-rich residues under acidic conditions resulted in remarkably high gold extractions being achieved. These novel processing options need to be optimised, and their economic viability established.

Jan 1, 1991

By F F. Pitard, K J. Ehrig

The Olympic Dam iron-oxide copper-gold (IOCG) uranium-silver deposit is second in size only to Norilsk, the gigantic metalliferous deposit. Olympic Dam is the largest publicly declared uranium, fifth largest copper and third largest gold resource. The deposit is typified by texturally destructive brecciation and intense iron metasomatism of the Roxby Downs Granite, bedded clastic facies rocks and mafic-ultramafic dykes. The deposit contains over 100 minerals. Copper mineralisation consists of chalcopyrite, bornite and chalcocite. Uraninite, coffinite and brannerite are the dominant uranium-bearing minerals. Gold mineralisation consists of electrum, tellurides and Au-Cu alloys. Hessite is the major silver-bearing mineral. The economic minerals are disseminated throughout the breccia matrix where the average grain sizes of the Cu-sulfide, uranium, gold and silver minerals are ~50, 20, <5, <5 microns, respectively.A significant number of sampling theory-based test programs have been completed since the mid-1990s to establish sampling nomographs, select appropriate sampling (ie split versus chip and interval lengths) and sample preparation protocols, quantify the errors associated with each subsampling stage, determine the practical uncertainty limits of Olympic Dam matrix-matched standards, and identify improvement opportunities related to the ongoing assaying quality assurance / quality control (QA/QC) program. Invaluable knowledge and unexpected insights gained from sampling studies at Olympic Dam have helped to improve our understanding of the distribution of economic and deleterious elements within the Olympic Dam deposit.CITATION:Ehrig, K J and Pitard, F F, 2017. Underground bulk sampling, uniform conditioning and conditional simulation – unrealistic expectations?, in Proceedings Eighth World Conference on Sampling and Blending , pp 21–28 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

Longwalling has reached a high standard both in Germany and Australia and most improvements should be expected in planning, monitoring and control. Double drum shearer have electric drives to 1000 kW and automatic height control is under development. Conveyor pans to 40mm thickness and chains to 2300 kN breaking load are in use with controls for pretension and load compensation under test.Trends in support are towards two leg shields with loads to 3850 kN per leg and electrohydraulic controls. Expert systems have been devised for planning and diagnosis tasks. With increases in technical standards, staff qualification standards at rising too, drawing attention to training requirements for modem personnel.

Jan 1, 1991

By D L. Kennedy

It has always been a challenge to accelerate the underground development progress by increasing the advance rate of each development round. Surveys have shown that most of the development rounds have only been pulled 84 per cent to 94 per cent of the drilled length. Where bare detonators have been used as primers, less advance rate is expected. In order to obtain a good understanding of the influence of priming upon the advance rate in underground development, a series of high energy primer trials has been conducted by Orica Explosives in the goldfields using various types of Orica high energy Anzomex « primers. It has been shown that development face has been pulled an extra 140 mm to 420 mm by priming with Anzomex « K primers compared with conventional primers. From all the trials at different sites, we have seen that the face pulled using K primers was more square than that pulled using conventional primers. Virtually, no butts and toe were left on the face developed using K primers. Computer simulation has been conducted using either a conventional primer, a bare detonator or a K primer as initiator. The study compared the predicted crack patterns developed around the toe of the hole and it was deducted that a detonator-initiated hole would leave a butt some 200 mm longer than that from a conventional primer-initiated hole, and a K primer-initiated blasthole would give rise to stronger initial p-wave, promoting crack development around the toe and increasing the ability to pull close to the full depth.

Jan 1, 1999

By M Shaffer, D C. Grant, D J. Goudie, P Sylvester, C Voisey

Scanning electron microscope–Mineral Liberation Analyser SEM-MLA can be used to discriminate between hematite/magnetite in iron ores, but achieving backscattered electron (BSE) segmentation between the two minerals is difficult for particles =75 µm using typical preparation and analysis methods for the MLA based on a tungsten filament SEM (Quanta 400) with 25 kV high voltage. Preparing iron ore sample mounts using a slow-speed polishing method, and conducting the experiment on a field emission gun SEM-MLA (Quanta 650) with the high voltage (HV) setting lowered to 15 kV reduces instrument noise and results in very clean BSE images and segmentation. This method requires new X-ray standards to be acquired for each mineral identity at 15 kV because of major changes in the spectra at lower kV. However, once these X-rays are added to the mineral reference list, effective segmentation can be achieved and a proper analysis obtained.CITATION:Grant, D C, Goudie, D J, Voisey, C, Shaffer, M and Sylvester, P, 2017. Discriminating hematite/magnetite via scanning electron microscope–mineral liberation analyser in the - mesh size fraction of iron ores, in Proceedings Iron Ore 2017, pp 541–548 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

Inpit tailings disposal has been undertaken at a number of mining sites within Australia. This paper presents a brief history of the experience of inpit tailings disposal at the Marymia Gold Operation in Western Australia, including geotechnical aspects of the design. Regular monitoring of the inpit tailings disposal into the K1SE Pit at Marymia has allowed the operators of the mine to assess the performance of the tailings storage against its predicted performance during the design phase. Results of this monitoring indicated that the predicted performance was exceeded and the results have been incorporated into the design of another large inpit tailings disposal, the K1 Pit. Monitoring of tailings disposal to both the K1SE Pit and K1 Pit has allowed the mine operator to make substantial savings from inpit tailings storage when compared with above ground tailings storage facilities. The inpit method of tailings disposal at Marymia has proven to be acceptable from an environmental perspective by reducing the water resource requirements of the project, backfilling pits, which would otherwise collapse with time and eliminating the need for disturbing additional areas of mining leases, which usually accompanies construction of above ground tailings storage facilities.

Jan 1, 1999

By B Hu, B Zhang, J Wang, H Ma, D Liu, L Han

Zeolites are potential carriers of slow release fertilisers due to their unique phenomenon for salt occlusion. A comparative study was performed on the capacities of potassium nitrate (KNO3) occlusion in molten KNO3 treated synthetic 4A and 13X zeolite molecular sieves with main channel sizes of 0.41 x 0.41 nm and 0.74 x 0.74 nm respectively. The results show that in a laboratory setting, the treated zeolite 4A contained 13.57 per cent of occluded KNO3 and the treated zeolite 13X did not contain any. This was confirmed by the regular release of K+ and NO3- during washing both treated mixed samples with water and by their IR spectra and TG analysis. There are also changes of the relative intensities of peaks in X-ray diffractograms of both treated zeolite samples. K+ release from molten-KNO3 treated zeolites in deionised water and simulated soil solution shows that release of K+ from KNO3 occluded in zeolite 4A are slow and steady. Proper size fit between the channel size of zeolites pore and the size of K+-NO3- ion pair of KNO3 is the decisive factor for zeolites to occlude KNO3.

Jan 1, 2008

By F Sahlström, E M. Jolis, V R Troll, E Jonsson, K Högdahl, C Harris

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Bastnäs-type magnetite-skarn-hosted rare earth element (REE) mineralisations are located in the Palaeoproterozoic Bergslagen ore province, central Sweden, and occur along a ca 100 km long belt of 1.90–1.87 Ga metavolcanosedimentary rocks. Ten different Bastnäs-type deposits have been sampled in order to assess the origin of ore-forming fluids in these systems. Magnetite and quartz have d18O values ranging from -2.3 to +1.1‰ and +7.2 to +8.3‰ respectively. Mineralised carbonates have d18O values between +5.8 and +7.2‰ and d13C values between -5.4 and -3.3‰. Temperature calculations based on the O-isotope composition of mineral pairs, combined with available fluid inclusion data, suggest primary mineralisation at ca 650–400°C. For these temperatures, calculated equilibrium fluids have d18O values that range from those typical of magmatic fluids (+6 to +8‰) to lower values (down to +3‰). Variation in carbonate O and C isotope data are consistent with interaction between local Palaeoproterozoic carbonate rocks (d18O = +12.5 to +19.6‰ and d13C = -1.8 to +1.7‰) and fluids of a magmatic origin. It is suggested that the Bastnäs-type REE-magnetite mineralisations formed as a result of reactions between local carbonate units and high-temperature, magmatic-dominated hydrothermal fluids during 1.90–1.87 Ga (Svecofennian) syn-volcanic activity.CITATION:Sahlström, F, Jonsson, E, Högdahl, K, Harris, C, Troll, V R and Jolis, E M, 2015. O and C isotope study of Bastnäs-type rare earth element mineralisation, Bergslagen, Sweden, in Proceedings PACRIM 2015 Congress, pp 439–444 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By G R. Ballantyne, M S. Powell

A comprehensive Australia-wide survey of comminution energy consumption at copper and gold mines was presented by the authors at the 11th AusIMM Mill Operators’ Conference 2012. The database has been extended to include major overseas mines and used to benchmark comminution energy consumption across the industry. The mines included in this study now represent 15 and 24 per cent of the total global gold and copper production respectively, and almost all Australian production. The comminution energy intensity per unit of saleable metal has been presented in a graphical form similar to a cost curve used in economics. The graphical method has been developed to assess the competitive advantage that can be achieved by reducing comminution energy intensity.This benchmarking tool has been applied to three published case studies to assess its applicability. The first case study indicated that a large reduction in size-specific energy (kWh/t -75 µm) was achievable by converting standard semi-autogenous and ball mill circuits to include high pressure grinding roll and stirred mills. The second case study investigated the metal-specific energy reduction historically achieved by Bougainville with the addition of a preconcentration screening plant. The final case study was conducted by Barrick Gold Corporation and involved incremental efficiency upgrades at three of its gold mines: Cortez, Cowal and Mara North. The application of the benchmarking tool to each of these case studies successfully demonstrated the scale and competitive advantage that was achieved by reducing energy intensity.CITATION:Ballantyne, G R and Powell, M S, 2014. Benchmarking comminution energy consumption for improved efficiency, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 95–100 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

EnergyAustralia is a state-owned corporation in the state of New South Wales, whose responsibility includes ownership and management of an electricity distribution network. Expansion of the high voltage distribution network in the Sydney central business district (CBD) includes the requirement to run an additional five 132 kV feeders over 1.7 km from south of the CBD to a new 132 kV substation in the northern section of the CBD. A driven tunnel is currently being excavated in Sydney sandstone beneath Darling Harbour to contain the new 132 kV feeders. Tunnel construction methods involve both roadheader and tunnel boring machine (TBM) excavation. This paper describes the design development of the cable tunnel, discusses the use of a geotechnical baseline report as an integral part of the contract documentation and provides an update of the current construction works.  

Jan 1, 2008

By Agrawal R. D, Kapoor M. L

Activity of FeO in the ternary system MgO-FeO-CaO in contact with metallic iron has been measured at 1000 K employing the cell.PtIFe, (Mg, Fe, Ca)OIZr02 - CaOIFe, FeOlPt. Measured data are used to study the phase stability relations in the system MgO-FeO-CaO and an isothermal section at 1000 K through this system is drawn.

Jan 1, 1987

Precious metal mineralization at the North Arm goldfield in SE Queensland occurs in the Triassic North Arm Volcanics, a sequence of andesite to rhyolite, pyroclastic and epi- clastic rocks deposited in a continental envir- onment. This unit displays a well-defined fracture system on Landsat imagery, including several arcuate structures which may represent former calderas. Two of the latter are associ- ated with zones of hydrothermal alteration, breccias and anomalous precious and volatile metal values. At the North Arm prospect, alter- ation is zoned from outer propylitic into exten- sive sericitic, although K-feldspar alteration is prevalent in the rhyolite. A zone of advanced argillic alteration is also present at Mt. Ninderry, SSE of North Arm. Alteration involves depletion of Na, Ca and Sr, and vari- able enrichment of S, As, Au, Ag, Hg and Mo. K and Rb are strongly enriched in K-feldspar altered zones. Precious metal mineralization occurs in veins, stockworks and hydrothermal breccia zones, and pervasive low grade Au-Ag dispersion is found throughout the sericitic and K-feldspar altered rocks. Veins and brec- cia interstices contain abundant quartz (common- ly banded), minor pyrite, calcite and sericite, with traces of silver grading to electrum, frei- bergite, naumannite, allargentum, marcasite, chalcopyrite and sphalerite. Mineralogical and geochemical characteristics are consistent with that found at volcanic-hosted epithermal precious metal deposits, particularly with the low-sulphur/adularia-sericite type.

Jan 1, 1987

By Lloyd F, Bayley F. J

The new South Mine in the Western Deep Levels complex is destined to become an ultra deep project extending to depths of 4 200 m below surface and where rock temperatures are likely to exceed 65 ¦C. Initial estimates put refrigeration requirements at 133 000 kWR. A surface refrigeration plant with an initial capacity of 42 000 kWR has been commissioned and will be used for mining the upper levels.

Jan 1, 1988

By Basillo CI

The adsorption mechanisms of various thiol collectors can be subdivided into four classes: chemisorption, EC-mechanism, catalytic oxidation and metathetical substitution. The chemisorption mechanism occurs at potentials below the thermodynamic potentials for the metal-thiol compound formation and is reversible. The EC-mechanism occurs when the mineral is sufficiently oxidised to liberate metal ions to form metal-xanthates; therefore, it is observed with more easily oxidisable minerals and/or with collectors having large pK values. Thionocarbamates adsorb on sulphide minerals via the EC-mechanism due to their large pK values. Although the adsorption occurs at very low potentials as compared to xanthates, it is irreversible with large overpotentials. On the other hand, the adsorption of modified thiophosphates and thiophosphinates occurs near the thermodynamic potentials because of the low pK values. The metathetical substitution is believed to occur only when a mineral is highly oxidised. These classifications are useful for studying the effects of electrochemical potentials and the molecular structure on the collector adsorption Mechanisms.

Jan 1, 1993

By K Lownie, R Sani, A Sianturi

Part of the PT Freeport Indonesia (PTFI) mine production is in the process of transitioning from the deep ore zone (DOZ) mine to the deep mill level zone (DMLZ) mine. The DMLZ mine is the next lift in the caving series and lies 500 m below the current DOZ footprint.In order to reduce the need for a very expensive additional ventilation system for the DMLZ mine, it was decided to reconfigure some infrastructure and upgrade the performance of the three existing DOZ mixed flow ventilation fans in situ, reducing the new fans required to two. This was far less costly than providing complete new installations.These fans are installed in individual underground chambers in DOZ mine exhaust drifts and connected to the DMLZ mine exhaust drifts system in 7 m × 7 m airways size, through sets of 6 m diameter by 500 m high raises.The upgrade process involved replacement of motors, fan shafts and bearings. The existing 1600 kW DOZ mixed flow fans are 3500 mm diameter and operate at a speed of 595 rev/min and were originally designed to deliver 390 m3/s at 3.3 kPa. Efficiency optimisation may be required at a later date.The upgraded DMLZ fans are required to deliver 425 m3/s at 3.7 kPa and it was necessary to increase in motor size and speed to 2200 kW at 710 rev/min. This paper will discuss the fan upgrade project and in particular the integration of an unusual ventilation system, which is based on the semi parallel operation of multiple large fans.CITATION:Sani, R, Sianturi, A and Lownie, K, 2017. Operation of deep mill level zone mixed flow fans after the first fan upgrade – a parallel fans case study, in Proceedings Australian Mine Vent Conference 2017, pp 285–292 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017