A Comparative Study on Potassium Nitrate Occlusion in 4A and 13X Zeolite Molecular Sieves

Zeolites are potential carriers of slow release fertilisers due to their unique phenomenon for salt occlusion. A comparative study was performed on the capacities of potassium nitrate (KNO3) occlusion in molten KNO3 treated synthetic 4A and 13X zeolite molecular sieves with main channel sizes of 0.41 x 0.41 nm and 0.74 x 0.74 nm respectively. The results show that in a laboratory setting, the treated zeolite 4A contained 13.57 per cent of occluded KNO3 and the treated zeolite 13X did not contain any. This was confirmed by the regular release of K+ and NO3- during washing both treated mixed samples with water and by their IR spectra and TG analysis. There are also changes of the relative intensities of peaks in X-ray diffractograms of both treated zeolite samples. K+ release from molten-KNO3 treated zeolites in deionised water and simulated soil solution shows that release of K+ from KNO3 occluded in zeolite 4A are slow and steady. Proper size fit between the channel size of zeolites pore and the size of K+-NO3- ion pair of KNO3 is the decisive factor for zeolites to occlude KNO3.