Search Documents

In many base metal sulphide concentrators reagents such as collector and cyanide are often added to the grinding mill as well as to the flotation circuit. Whilst good reasons can be cited for splitting the reagent addition in this way, the benefits of such are rarely quantified and the complex reagent-mineral-media interactions occurring during milling are often poorly understood in terms of pulp chemistry. A new laboratory batch grinding mill designed by Magotteaux allows the user to measure, monitor, and control the pulp chemical conditions during grinding when testing different ores and media. Some of these parameters include pulp pH, pulp Eh, temperature, gaseous atmosphere, and dissolved oxygen concentration. In a recent development, the mill has been coupled with a simple on-line reagent monitoring system, designed by CSIRO, which allows the levels of species such as xanthate and cyanide in the grinding pulp to also be measured continuously during milling using a robust UV detection system. In this way the uptake of collector during grinding and the rate and ex-tent of cyanide interaction with the minerals and media can be determined as a function of grinding time. A series of grinding tests using an Australian nickel sulphide ore was conducted with the coupled system in which the cyanide dose, xanthate dose, and media type were systematically varied. The xanthate and cyanide levels were monitored as a function of grinding time and the data collected are discussed in terms of the pulp chemistry of the system and implications for plant reagent dosing strategies.

Jan 1, 2014

By J. Z. Yuan

The purity of rectorite is only about 70% after preliminary mineral processing, which has limited its application. In this research, different pulp densities, different dispersants, different dispersing methods and purification flow sheets were used to purify rectorite. The results show that it is possible to obtain high pure rectorite clay with the purity above 90% and concentrate yield between 24.9% and 29.4% by the purification process with composite dispersants, stirred mill grinding dispersion and so on. The obtained high pure rectorite can be further used in rectorite nanocomposites.

Jan 1, 2014

Rotor speed is one of the key hydrodynamic parameters in froth-flotation and it plays an important role in bubble-particle attachment. Laboratory scale studies for optimizing the rotor speed to achieve maximum flotation rate constant (K) of quartz, ground by ball mill, are. Purity of quartz was 99.4 percent and d80 of ball mill product was 230 µm. Each size fraction was separately subjected to flotation at three different rotor speeds, namely, 1200, 1000 and 800 rpm, and the flotation rate constant was calculated. The results showed that the flotation rate constant was high at the rotor speed of 1200 rpm. The flotation rate constants achieved at 1200 rpm were 8.676, 8.232, 7.818, 7.248, 7.068 and 6.984 min-1forthesize fractions of +300, -300+250, -250+212, -180+150, -150+125 and -125+106 µm, respectively. Keywords: froth flotation, rotor speed, flotation rate constant, ball mill, quartz

Sep 1, 2012

By I. Nishkov, I. Grigorova, N. Valkanov, M. Ranchev

The processing of sulphide ores with variable and complex mineral composition and physical properties, such as those processed by two-stage selective flotation scheme in “Erma reka” concentrator, Minstroy Holding JSC, requires excellent selectivity in order to achieve acceptable concentrate grades. The lead-zinc ores from the hydrothermal lead-zinc deposits mainly contain galena (PbS), sphalerite (ZnS), pyrite (FeS) and chalcopyrite (CuFeS2), as well as non-metal minerals such as quartz, carbonates and clinopyroxenes skarns. One of the main impurities present in sphalerite is iron, which is known to be detrimental to the rate of sphalerite flotation and its recovery. The results from the conducted laboratory and industrial tests, presented in the previous study, showed that it is possible to depress the iron rich sphalerite by adding MINFIT® (modified sulfur-oxy depressant) at the pH of approximately 9.5 in rougher lead flotation circuit, leading to reduction of zinc sulphate consumption and complete elimination of cyanides from the flotation process. Furthermore, the consumption of copper sulphate, which reactivates the surface of the zinc minerals, was significantly reduced. Consequently, the optimisation of the reagent regime in the Erma reka concentrator, led to notably improved qualitative (grade, recovery) properties of the final lead and zinc concentrates. Moreover, when comparing the reagents consumption for 2014 and 2016 – when the processing plant have been applying the new optimized reagents regime, comprises the use of MINFIT as the primary depressant, the following results have been achieved: ZnSO4 decreased by 30%; CuSO4 consumption decreased four times and full rejection of cyanides from the process. Finally, this paper provides a state-of-the-art review of the obtained results during the period of application of the new flotation reagents regime in the Erma reka concentrator, Minstroy Holding JSC.

Jan 1, 2018

In this paper, various methods, such as XPS, XRD, SEM and zeta potential measurement are applied to investigate the action mechanism of sodium sulfide in flotation of lead and zinc oxysalt minerals. The experimental results show that the mechanisms of sodium sulfide in flotation of lead oxysalt minerals and zinc oxysalt minerals are different: on the surface of cerusite, there is lead sulfide phase formed under the reaction of sodium sulfide, resulting that the cerusite surface shows the form of galena, which is advantageous to the adsorption of anion collector and improves the floatability of cerusite as a result. On the surface of zinc oxysalt minerals, there is no zinc sulfide phase formed, but the sodium sulfide increases its surface electronegativity, and enhances the adsorption of cation collector lauryl amine, so the floatability of zinc oxysalt minerals is improved. The difference of action mechanisms of sodium sulfide on lead and zinc oxysalt minerals exactly explains the reason why different collectors are selected in the flotation of cerusite and smithsonite, which are both carbonate minerals although.

Jan 1, 2014

By Jianjun Tian, Changjiu Zhang, Chunmin Wang

Two lines of single stage autogenous milling circuits have been installed and commissioned as the primary grinding process for the Sino Iron project where magnetite ore is treated to produce iron concentrate via magnetic separation. Various challenges were encountered during the commissioning and ramp up stages which are discussed in the paper and include treating a highly competent ore in a closed circuit AG mill, operating the largest mills in the world and dealing with a number of engineering issues related to plant operability. Details of how these challenges were overcome are described as well as the observed operating characteristics of the mills and their optimisation through rigorous study, simulation and successful solution implementation. Further potential improvement opportunities are also discussed as part of the ongoing technical program at site.

Jan 1, 2014

By H. Q. Peng

The study of synergistic reagents combination of mineral floatation is more and more important with the decreasing of bonanzas now. In order to determine the chemical reaction mechanism, here we present the synergistic reagents combination: amyl-xanthate, butyl-dithiophosphate and N,N-diethyldithiocarbamate ester, which dissolved by different organic solvents. The reagents were applied by an Anhui mine to float low-grade covellite as a substitute for ethyl-xanthate. One reaction products Na2HPSO3?5H2O (disodium hydrogen-thiophosphate pentahydrate) which was re-crystalized and measured by X-ray diffraction analysis. In its crystal structure, the two crystallo-graphically different Na ions are six-coordinated and are bridged by two covalent bonds with the O atoms of water molecules to give a basket unit. However, we can?t get Na2HPSO3?5 H2O by combining butyl-dithiophosphate and N,N-diethyldithiocarbamate ester under the same condition. This discovery may provides a intuitionistic evidence that in the process of reaction, the three com-pounds would cooperate with each other, but the decisive reaction may be the hydrolyzation of amyl-xanthate.

Jan 1, 2014

By M. Illikainen

Limestone is used for neutralization of acid leachates in a number of hydrometallurgical processes. The aim of this study was to clarify how limestone ground to different particle sizes can neutralize sulfuric acid. The laboratory scale ball mill was used in grinding experiments carried out using ball sizes of 20, 30 and 40 mm and volumetric slurry densities of 30, 40 and 50 percents. Varied grinding times were used in order to produce limestone samples with different particle size classes on which the neutralization potential and rate were determined. The results of the study showed that the neutralization potential of limestone is not dependent on its particle size between 5 and 120 µm. However, the particle size strongly affected the neutralization rate of sulfuric acid: The smaller the particle size, the higher the rate of neutralization. Thus, when optimizing the cost efficiency of the process, the optimal degree of grinding should be considered taking in account the required residence time in neutralization phase.

Sep 1, 2012

By A. M. Ozbayoglu

Gross calorific value (GCV) of coals was estimated using artificial neural networks, linear and non-linear regression techniques. Proximate and ultimate analysis results were collected for 187 different coal samples. Different input data sets were compared, such as both proximate and ultimate analysis data, and only proximate analysis data and only ultimate analysis data. It was observed that the best results were obtained when both proximate analysis and ultimate analysis results were used for estimating the gross calorific value. When the performance of artificial neural networks and regression analysis techniques were compared, it was observed that both artificial neural networks and regression techniques were promisingly accurate in estimating gross calorific values. In general, most of the models estimated the gross calorific value within ±3% of the expected value.

Sep 1, 2012

By E. T. Tuzcu

In this manuscript, a new approach for modeling the rate of grinding process is explained. A review about grinding rate definitions so far is given and the possible ultimate way for grinding modeling is given as modeling the rate based on energy spectra. The traditional/phenomenological approaches for modeling size distribution of grinding mills give their place to a new generation modeling technique. Developments in the computational methods and necessity to model product size distribution of large mills, larger than ball mill size, paved the way for this novel technique. The traditional grinding rate models are mostly based on the back calculated breakage parameters from the experimental data. However, direct modeling of breakage parameters and hence the prediction of size distribution of the grinding mills may become possible with this approach. The material breakage data and discrete element method (DEM) energy spectra are the main components of this approach. Albeit the focus in this study is on modeling of breakage rate under impact mode of breakage, the abrasion mode of breakage was also tested by carrying out abrasion tests. Impact mode of breakage was analyzed using ultra-fast load cell device (UFLC) and drop weight tester. Dry tumbling test was carried out for abrasion experiments. Obtained material breakage versus energy data are combined with the collision energy spectra to obtain the breakage rate function. In addition, the material breakage versus energy information from the tests is converted into breakage distribution function. The model was verified in a lab scale mill (90 cm diameter-15 cm length). 10 to 15 kg of limestone was ground using 50 mm steel ball at varying conditions, i.e., rpm, volume loading. It is shown that the proposed model predicts all (1, 2, 4 min.) grinding intervals for all experiments highly accurate.

Sep 1, 2012

Copper nickel separation is performed by mineral processing techniques both pre and post smelting in Copper Cliff at Vale Canada?s Operations. The separation at Clarabelle Mill takes advantage of the ore mineralogy to affect a separation on the rougher concentrate where chalcopyrite and pentlandite exhibit high liberation and high recoveries thus their separation is simple although incomplete. The copper concentrate comprises only 50% of the copper in ore with the remaining copper being separated post smelting in the Matte Separation plant where the slow cooled Bessemer Matte is again treated by mineral processing operations using flotation to separate the chalcocite and heazlewoodite and magnetic separators to remove a metallic nickel alloy. This paper discusses the mineralogy, separation processes and work currently underway to improve the separation of copper from nickel in these plants.

Sep 1, 2012

By J. Menuge, G. Barker

"Liberation (QEM-SCAN) and surface chemical (time of flight secondary ion mass spectrometry -ToF-SIMS) analyses have been undertaken on plant Pb circuit flotation samples with the aim of defining the factors resulting in sub-optimal recovery. Lead flotation circuit feed, cleaner concentrate and tails samples were examined on a size-by-size basis using QEM-SCAN. Sulfide minerals accounted for approximately one third of the flotation feed with pyrite making up 16 wt.%, followed by sphalerite (13 wt.%) and galena (3 wt.%). Non-sulfide gangue minerals comprised calcium carbonates calcite (26 wt.%), dolomite (14 wt.%) with quartz, feldspars and barite all contributing > 5 wt.%. QEM-SCAN analysis indicated that liberation was not the primary cause of the poor flotation response. Principal component analysis was applied to the ToF-SIMS data derived from five samples (as for QEM-SCAN plus rougher concentrate and tails) to enable identification of correlated surface chemical components. Although a significant range of correlations were observed we focus here on those that show a discernible pattern throughout the float circuit. It was found that for the flotation feed the surface of galena were largely obscured but where Pb was observed there was a strong correlation to surface Fe. For the rougher and cleaner concentrates the galena surfaces were relatively clean with no correlation to Fe for the rougher concentrate and minor correlation in the cleaner concentrate. However, in the rougher and cleaner tails the clear correlation of galena with Fe was again apparent. These results suggest, in combination with prior studies of pyrite morphology, that the principal factor effecting grade is the rapid oxidation of the framboidal pyrite resulting in the contamination of the galena surface with a high loading of hydrophilic oxidised Fe species, thus depressing flotation."

Jan 1, 2014

By Harshad Bhagwat

The objective of this work is to investigate the inadequacies of current CFD based methodologies of model development for predicting combustion behavior of pulverized coal in furnaces. In the present paper, a steady state CFD model was used for in-depth analysis of pulverized coal combustion. The model accounts for turbulence, coal combustion, convective and radiative heat transfer and motion of coal particles. It also uses coal combustion models to account for important processes such as devolatilization, combustion of char and the evolution of fuel nitrogen during coal combustion. The model predicts fluid flow, heat transfer, progress of combustion and pollutant formation (NOx, etc.). The model uses several parameters, which need to be tuned with experimental data, which is not only limited in quantity but also insufficient in detail. Various existing methodologies like part calibration method for tuning of the parameters are discussed. In the present work, the parameters associated with coal combustion models were tuned and validated with published data obtained from an experimental furnace using one such part calibration methodology. The results clearly show that the model predictions differed with the experimental data not only quantitatively but also qualitatively. These discrepancies were attributed to part calibration methodology. A detailed parametric study was carried out to demonstrate the importance of parameters from various classes, namely, combustion kinetics, heat transfer, process and geometry parameters, and CFD model parameters. This investigation clearly indicates that parameters from different classes have significant effect on combustion behavior. The discrepancies in current methodology are discussed and a need for comprehensive methodology is highlighted. Keywords: pulverized coal combustion, computational fluid dynamics (CFD), pollutant formation (NOx), mathematical modeling

Sep 1, 2012

By F. N. Shi

Ore breakage characterization plays an essential role in the design and optimization of comminution circuits. Recently, the JKMRC comminution research team has developed a Rotary Breakage Tester (JKRBT). The JKRBT uses a rotor-stator impacting system, in which particles gain a con-trolled kinetic energy and are impacted against the stator, causing particle breakage. The first unit of industrialised JKRBT was installed at the Anglo Research in South Africa in March 2007, and five more JKRBTs are currently being fabricated for some of the world?s major mining companies. In addition to the JKRBT, an improved breakage model has been developed at the JKMRC, which more accurately describes the effect of specific energy, particle size and incremental breakage caused by repetitive impacts. The validation outcomes show that the JKRBT, together with the new breakage model, generate statistically similar breakage parameters to the traditional drop weight tester (DWT), but with significant advantages over its predecessor. The limitations of the DWT, specifically its lack of precision of the energy input, the lengthy time required to run individual tests and the challenges en-countered in testing small particles, have all been overcome by the JKRBT. The recent developments in the JKRBT and the new breakage model offer several prospective applications. These developments have the potential to revolutionize the ore breakage characterization in the years to come.

Jan 1, 2014

By M. Rehor

The importance of brown coal as a raw material is currently given by growing energy needs of Czech Republic. More than 70% of mined brown coal comes from North Bohemian Basin these days. Mining of brown coal is run in four mining locations. They are geologically different and the parameters of mining coal are quite different too. This requires a little bit different methodology of both extraction and reclamation. Methods of reclamation works in the region are given mainly by the characteristics of overburden rocks appearing in the upper horizon of recuperated localities. The difficulties of the North Bohemian mine dumps reclamation works are caused by extremely unfavourable properties of rocks poured down to the majority of mine dumps. These are mainly rocks of the overlaying strata and the rocks strata of brown coal bed. Main materials poured down to the mine dumps are sands, clayey sands and kaolin ? illitic clays. Admixtures in filled rocks consist of organic (coal) mass, siderite and pyrite. These rocks are mechanically instable with respect to the wind and water erosion and during weathering they are getting unfavourable, acid (phytotoxic) nature, due to the influence of SO3 and Al ions. External and internal dumps of open pit mines are significant part of the North ? Bohemian landscape sustained by excavation. Their as fast as possible preparation and gradual integration into ecosystem of the area is interest of both citizens of region and mining companies. The paper briefly summarizes the methodology of restoration of the largest dumps of the North Bohemian Brown Coal Basin and the results of analyses and evaluation of samples taken on restored localities Rado-vesice dump, Strimice dump, Ru?odol dum pand internal dump of Bilina mine. An example of modern non-tradicional restoration methods is the restoration of internal dump of Bilina mine (application of power plant stabilizer). According to observations and results of sample analyses the methods of restoration were selected to limit the erosion influence, adjust the chemical and physical composition of surface of Radovesice and Strimice dumps. The application of marlites and bentonite prevent the unfavourable weathering processes on dump surface. Compensation of Quaternary sediments was artifically formed here. The need of marlite ploughing in, application of organical substrates and vegetation preparation was proved on Radovesice dump. The conception of landscape reclamation of the largest dumps after finishing of mining, methodology of technical reclamation and well considered using of fertilizable soils are main results presented in this article.

Jan 1, 2014

By Zhong Hong

A novel ilmenite collector, tert-butyl benzoic hydroxamic acid (TBHA), was investigated in this paper. The flotation performance and adsorption mechanism of TBHA to ilmenite were evaluated through pure mineral flotation tests, ?-potential measurement and IR spectrum analysis. The experiment results indicated that TBHA exhibited strong collecting capability to ilmenite under pH 6.0-8.5. At pH 7.0-10.0, TBHA existed in the form of anionic species in aqueous solution, and the ?-potential measurement results showed the surface of ilmenite maintained negative and more negative after the adsorption TBHA on it, which inferred that TBHA might adsorb on the surface of ilmenite through chemical interaction. The IR spectrum analysis further confirmed the chemical interaction between TBHA and ilmenite surface. Keywords: Tert-butyl benzoic hydroxamic acid, Ilmenite, Flotation, Chemical adsorption mechanism

Sep 1, 2012

Over the last four years, a major collaboration between CSIRO-MIS, UCT and JKMRC has produced two significant advances in the modelling of comminution. The Universal Comminution Model (UCM) uses parametric SPH/DEM studies of comminution and separation devices to calibrate mathematical models which are suitable for industrial use. The Virtual Comminution Machine (VCM) uses the same computationally intensive techniques based on discrete element modelling (DEM) and smoothed particle hydrodynamics (SPH) to directly model any comminution device by combining a CAD file describing the machine design, sophisticated ore characterisation methods and advanced particle scale flow and breakage simulation. The UCM should be useful for process analysis and optimisation of existing equipment and circuits while the VCM should make a major contribution to the evaluation and development of new machines. Progress to date is encouraging with several processes now well described using DEM. This paper also reports on progress towards combining DEM for particles with a realistic slurry model based on SPH for different types of comminution devices. In due course, this combination should allow accurate modelling of particle transport in wet mills to be combined with DEM models.

Jan 1, 2014

By S. N. Shahcheraghi

Bioleaching method makes use of bacteria in solving metallic sulphides, so that these bacteria tend to convert insoluble metal sulphides into soluble sulphates. Since the kinetics description of this process is inevitable for better interpretation of relation between metabolism and growth of live organisms, as well as optimization of metals extraction processes, in this paper, this description is represented and designed in mathematic (kinetics) model for copper sulphide minerals based on Monod kinetics model. According to this model, special growth rate of bacteria (?) is a hyperbola function of restrictive substrate concentration (S). By Solving and developing of Monod kinetics model, a comprehensive kinetics model for bioleaching of copper sulphide minerals results. The designed is also applicable for other metal sulphides.

Sep 1, 2012

By Liu Xiaodong, Jiang Meifen, Kou Xiaoyan, Lu Xianjun

"Two low grade calcium bentonite (Ca-bentonite) from Hejia (HJ) and Boteng (BT), Shandong, China, mainly contain montmorillonite and quartz, and slightly feldspar, calcite, and montmorillonite content are 32.37% and 55.90%, respectively. In order to examine the feasibility to produce activated clay to meet the standard of Chinese chemical industry (HG/T2569-2007), three types of industrial production process are proposed according to the screen test. The first process is grinding the raw bentonite to -200 mesh and then activating. The second is to activate the raw bentonite directly, and then classify the production to -200 mesh. The last one is to activate the raw bentonite after purification. Three parameters, which are sulphuric acid strength, ratio of liquid to solid and treatment time, are optimized via orthogonal test for every process. The preliminary test indicates that it is feasible to produce acid bentonite of difference quality. For the sample of HJ, milling the raw to -200 mesh first and activating afterwards, the parameter is at 9% acid strength, the ratio of liquid to solid 2, the time 4 hours, temperature 90°C, the products can meet the qualified grade for animal and vegetable oils refining. For the sample of BT, milling the raw to -200 mesh first and activating afterwards, the parameter is at 15% acid strength, the ratio of liquid to solid 2.5, the time 2 hours, temperature 90°C, the products can meet the qualified grade of high decolorization for petroleum products refining. For the sample of BT, adopting purification to -325 mesh by stirring and rubbing at first, and then activating at 9% acidity, under the conditions that the ratio of liquid to solid is 2, the time is 2 hours and the temperature is 90°C, the products can meet the first grade of high activation degree for petroleum products refining."

Jan 1, 2014

By Kyoungkeun Yoo

A citric acid leaching test after heavy medium separation process was performed to remove the heavy metal contaminat such as Pb, Cu, and Zn from contaminated soil. The lead component was removed from soil by heavy medium separation whereas zinc component shows 0 % - 37.9 % removal ratio with particle size. The citric acid leaching was conducted to remove the remained zinc component. The removal ratio of Zn reached to more than 95 % under the conditions; 10 % in pulp density, 200 rpm in agitation speed, 50 °C, 2 mol/L in citric acid concentration at 2 hrs in leaching time. These results suggest that the heavy medium separation method followed by citric acid leaching is effective for treatment of soil contaminated with various chemical forms of heavy metal. Keywords: metal contaminated soil, citrate, heavy medium separation, zinc

Sep 1, 2012