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By J. A. Dubinski

One of the greatest threats of mining in hard coal mines are underground fires, which in the past often resulted in the mining disasters. Implementation of scientific principles of fire fighting into practice contributed to a significant reduction of fire hazard in coal mines. However, despite numerous achievements of science in the fight against the underground fires, they still occur creating a potential hazard for the miners and contributing to generate significant costs of fire-fighting operations, the temporary suspension of production or loss of longwalls. This concerns both spontaneous fires and exogenous ones. A significant decrease in the number of spontaneous fires was the result of cooperation between Polish scientists with experts in the field of new methods of fire hazard prediction and selection of new fire prevention and fire hazard monitoring methods. A significant part played here researchers from the Central Mining Institute. The original method of endogenous fire risk assessment based on calorimetric tests of coal and developed mathematical model of the process of coal self-heating allow to predict the risk of spontaneous fires and select proper fire prevention measures adequate to the involved risk. The frequency of exogenous fires is in the last few years is low, but their share in the total number of fires is relatively high and constitutes about 30%. This results from the prevention activities, carried out regularly in mines which are aimed at reducing the fire hazard connected with the use of fire-resistant conveyor belts and other non-metallic materials. Further directions to reduce the hazards connected with underground fires should focus on improving the methods for monitoring hazards together with automation of fire fighting operations.

Aug 1, 2013

By O. Hyvärinen

Outokumpu has developed a new chloride leaching process called HydroCopper®. In this process copper sulfide concentrates are leached at atmospheric pressure in concentrated sodium chloride solution using cupric ions as the oxidant. Copper is recovered from the purified leach solution by precipitating cuprous oxide, which is then reduced to pure copper and further melted and cast directly into copper products. The key reactants: sodium hydroxide, hydrogen and chlorine are generated from the spent sodium chloride using chlor-alkali technology. An important feature in the HydroCopperTM process is that the gold contained in copper concentrates is leached as chloride complexes and recovered from solution by activated carbon. Conditions for the leaching of gold-bearing pyrite can also be achieved in the chloride system by optimizing the redox conditions. This paper deals with the basic factors affecting gold leaching from copper sulfide concentrates. Opportunities for the recovery of refractory gold associated with arsenopyrite and pyrite will also be discussed.

Jan 1, 2005

By J. Satur

In copper mineral processing, pyrite coexisting with copper sulfide minerals like chalcopyrite is separated by flotation as tailings and its oxidation in tailing dams causes the formation of acid mine drainage. This paper proposes carriermicroencapsulation (CME) as a new method for suppressing pyrite flotability, as well as its oxidation. In this method, an organic carrier combined with Ti is used to form a thin Ti02 layer on pyrite, which gives a hydrophilic property and acts as a protective coating against oxidation. To form the coating, a ground pyrite sample was treated with Ti-catechol complex solution under various conditions. Bubble pick-up experiments and flotation experiments showed that the treatment of pyrite with Ticatechol complex changed the hydrophobic nature of pyrite into hydrophilic even in the presence of xanthate as a flotation collector. Oxidation testing of the CME-treated pyrite by 0.02 kmol m-3 HN03 showed that Fe release was suppressed by the CME treatment with respect to the control. This is assumed to be due to the formation of Ti02 coating on the pyrite surface. The effect of CME treatment on chalcopyrite wettability is also discussed.

Jan 1, 2007

By A. J. Harrison

"The introduction of an amendment to the Mines Regulation Act in the Province of British Columbia, passed in July 1974, and similar amendments since enacted by other provinces introduced the Canadian underground mining industry to the use of fire-resistant hydraulic fluids.Few, if any, of the hydraulic circuits in use in underground mining at that time were specifically designed for use with fire-resistant fluids, compared with the increasing number of such circuits conceived and in production today. The technology required in designing equipment for use with fire-resistant fluids may be likened to that associated with conventional mineral oils, but, in many respects, a variety of additional and / or alternative considerations must be taken into account. The fast-increasing use and development of fire-resistant fluids throughout all facets of industry, world wide, during the past 20 years has led to a whole new technology in system construction and component design, whereby acceptable performance can be achieved . However , the transition from conventional mineral hydraulic oils has not been without its problems, particularly when retro-fit of existing units was involved."

Jan 1, 1981

By S. Amira

In the last two decades, many new creep-resistant magnesium alloys have been developed for high temperatures applications. Their mechanical performance and corrosion behaviour were reported for various experimental conditions. However, these conditions often led to uneven comparison basis. In the present study the microstructure, mechanical properties and corrosion performance of four of these newly developed creep-resistant magnesium alloys were systematically compared. Specimens were obtained from experimental box-like components that were die-cast and thixocast in comparable conditions. Their mechanical and corrosion properties were compared using similar testing conditions. Results show that the creep resistance, strength and impact resistance of specimens are comparable but systematically lower compared to specimens cast under optimized conditions. The reduced concentration of elements such as Al, Ca, Sr and Ce lead to a decrease of the corrosion resistance of the magnesium alloys in 3.5% NaCI solution.

Jan 1, 2007

By H. H. Claudet

PROBABLY the first flotation mill for treating molybdenite ores was put into operation .in Norway during 1913, when the writer was employed to introduce and apply the Elmore vacuum flotation process at a mine in southern Norway. These operations proved successful and led to other similar installations in that country. It remained, however, for Norwegian engineers themselves to iron out their difficulties and establish the molybdenum industry on a basis which ultimately attained world importance. Just as today, an urgent demand for molybdenum arose during the world war of 1914-18. By 1916, many molybdenite properties were in operation in Canada and several small concentrating mills were under construction. At one of these, in the Ottawa Valley district, the opportunity came for applying the Elmore vacuum flotation process, using a flow-sheet similar to that adopted in Norway. Later, as one of the staff of the General Engineering Company, who had already developed a highly efficient flowsheet for treating molybdenite ores, using the Callow pneumatic flotation process, the writer devoted considerable time to research work and investigations on a number of molybdenite projects and deposits in eastern Canada. The bulk of Canada's production of molybdenite was coming at that time from the Moss mine at Quyon, Que., where concentration of the ore was effected by water-film flotation. It is of interest to note that this process, based on the principle of surface tension, had been developed and introduced by the late Henry E. Wood, of Denver, Colorado- one of the original owners of the Moss mine-at the time he was investigating the Elmore vacuum process in his Denver plant. The process, with certain modifications, was used at several other properties in eastern Canada, and notably in the ore dressing laboratories of the Department of Mines at Ottawa and in a plant at Renfrew, Ont., in both of which ore from deposits in various parts of Canada was treated, with recovery of very appreciable amounts o much needed molybdenite. During the summer of 1917, the water-film flotation mill at the Moss mine was dismantled and the plant was re-modelled by the General Engineering Company to include the Callow system. This installation, using improved flotation methods, was highly successful both as to recovery and grade of concentrate, and proved a decided advance in molybdenite concentration, a recovery of upwards of 90 per cent being obtained, with a concentrate grading over 90 percent MoS2.

Jan 1, 1944

By M. P. Du Plessis

"The paper discusses coal research in relation to the special needs of Western Canada, with its large resources of lignite and subbituminous coals. Research programs are presented under the following headings: Coal Liquefaction, Pyrolysis, Fluidized-Bed Technology, Underground Coal Gasification and Supporting Investigations. Typical processes are presented and their relevance to Canadian coals is described. The longterm plan of the Alberta Research Council for coal research and the steps taken for its implementation are discussed. Finally, some innovative concepts arising from basic research in coal chemistry are discussed.Canada's Coal ResourcesCanada is richly endowed with coal reserves. With estimated ultimate reserves of 600 billion tons in O.76-m (2.5-ft) thick seams under less than 762 m (2500 ft) of overburden, Canada rank s fourth after the USSR, the USA and Chinatu (see Table I) . Canada's reserves are incompletely explored and estimates are constantly being upgraded. Preliminary information from deeper test-hole logs suggest that similar , if not larger, tonnages occur at depths greater than 762 m (2500 ft).The types of Canadian coals and their regional Distribution(2) is shown in Figure 2. Alberta's subbituminous Plains coal represents about 70% of estimated national reserves. A large portion of the coal can be mined at relatively low cost by surface mining techniques, and it is currently being used exclusively for power generation in conventional thermal plants. This coal, however , also represents a large potential .source of liquid fuels which could equal or exceed that of oilsands and heavy oil. Table 3 compares Federal Government estimates for resources and reserves of fossil fuels in Canada and their recoverable oil content or equivalent.A conservation estimate of only the reserves of thermal coal represents an oil equivalent of 27.6 billion barrels , which equals the recoverable reserves of oil-sand bitumen and heavy oil. A more realistic estimate is probably several times this amount. Although coal can be converted to many other end products, such as fuel gas and synthesis gas for hydrogen and ammonia production, liquid fuels remain the most desirable product mainly because they can be transported more cheaply over long distances and their high energy density makes them uniquely suitable as fuels for transport and agriculture."

Jan 1, 1981

By F. Flores

With the World Summit for Sustainable Development planned for 2002 in mind, nine of the world's largest mining companies decided to initiate a project to examine the role of the minerals sector in contributing to sustainable development, and how that contribution could be increased ? the Mining, Minerals and Sustainable Development Project (MMSD). This project assumed from the start that sustainable development could provide a useful framework to guide the minerals sector which main goal was integrating economic activity with environmental integrity, social concerns, and effective governance systems. The broad steps of MMSD project strategy can be grouped into four major categories: increase understanding of sustainable development; create organizational-level policies and management systems for implementing the principles of sustainable development; collaborate with others with common interests to take joint steps towards sustainable development, and; increase our ability to work towards sustainable development at the local, national, and global levels. In opinion of the article's author, to go ahead with the MMSD strategy and achieving the sustainable development objectives, it is necessary to consider the concept of self-organization, fundamental of the emergent new scientific paradigm, and the consequent epistemology and values that conform a supporting culture for sustainable development.

Jan 1, 2007

By N. Melnyk

IN the past, the Cadomin Coal Company has opened four mines, all in the same coal seam or its folds. Three of these were opened from river level by horizontal entries or rock tunnels, and the fourth, the present working mine, by vertical shafts. This paper deals largely with some operating phases of this fourth mine, with which the writer has been associated. The seam worked here is a thick, steep, bituminous seam, and the writer feels there is a paucity of published data on the mining of such seams. Possible reasons for this are that such seams do not !end themselves to intensive development or mining, there is little chance to mechanize because of the extreme pitch, and operations are fraught with many problems. In addition, the present operations in this particular seam are being carried on at a level below the former workings, introducing new problems, not en-countered on the upper level. Coal will, without question, long continue to be an important factor in the national economy, and some of the best coal is to be found in thick, steep seams. But with the exhaustion of the easily-mined coal near the outcrops, future coal will have to come more and more from lower levels. At Cadomin there is still considerable coal on the second level, below the old river-workings, and there is a possibility that, in the future, still lower levels will be worked. It is the purpose of this paper to indicate some phases of such lower-level operations and to invite discussion.

Jan 1, 1942

By M. D. Gerst

The degree to which copper will continue to be in an integral part of the world economy in the future will depend largely on the dynamics of global economic development, the primary and secondary copper resource stock, technological change, and potential environmental constraints. We have characterized the copper cycle of 1994 for all of Earth's regions and for the planet itself (T. Graedel et al., Environmental Science & Technology, 38, 1242-1252, 2004) and recently updated that cycle to year 2000. In this paper, we compare various features of the 1994 and 2000 cycles. The three largest-using regions, Asia, Europe, and North America, all increased their absolute rate of copper use between 1994 and 2000, and all increased the per-capita rate of copper use as well. Globally, the use of copper increased by about 32%, from 11.7 to 15.3 million metric tons, while population increased by only 8%. Various changes are seen in scrap trade, finished products trade, and other parameters of the cycle. We conclude by considering how the rates of technological change and growth in demand, especially in Asia, may influence the copper cycle in the years ahead.

Jan 1, 2007

By Roger C. Parsons

"The problems presented by ice formation and interference with processes, structures and mechanical operations in the mining industry can be expected to increase sharply as more of our mineraI needs are supplied from the far north. A process of rapid ice destruction is presented which lends itself to the effective removal or penetration of ice. Suggestions are offered for applying the system to problems related to mining activity in cold environments. The system can be readily adapted to large-scale operation, the reactant components being transported in crystalline form and volatilized on site.IntroductionThe number of operational mines in northern environments, relative to the number of mines in the temperate zone, will increase in the years ahead. This is not surprising, because:(a) in the past, those mines closest to centres of commerce had minimum transport charges and hence were more economic to develop;(b) great centres of commerce were far removed from northern environments;(c) the exhaustion of ores and lowering of grades in temperate zones now offset to some degree the extra transport costs applied to northern ores;(d) the abundance of excess energy in the north in the form of oil, gas and hydropower attracts mining as a means to justify its development; (e) assuming that the frequency of mineral occurrence north of the 52° N latitude is no different than south of it, there are many deposits waiting to be developed.As a result of current and projected activity in northern environments, we are faced today, and will be increasingly so in the future, with mining problems rarely encountered before-problems related to below-freezing temperatures. Engineering activity in permafrost regions will increase as new mining ventures are developed north of the 52° N latitude, roughly coinciding with the -1.1 ° C isotherm in Labrador, the upper temperature boundary for permafrost."

Jan 1, 1982

By Hans D. Gougar

To meet an increasing demand for minerals, mining operations are moving to ever more remote regions. The lack of a local energy supply and infrastructure, coupled with social and regulatory demands for lowered environmental impact of mining operations, presents an opportunity for a seemingly unlikely competitor ? a nuclear power plant. The Modular Pebble Bed Reactor concept, currently in various stages of research and development around the world, offers a high degree of reliability and safety with minimal consequences for the local or global environment. The passive safety features of this design eliminate the need for the extensive active safety systems that add significantly to the cost of current water-cooled reactors. With the MPBR, as with all nuclear plants, there are no appreciable quantities of waste products released to the environment during normal operations. In contrast with conventional reactor designs, the MPBR would also remain radiologically safe even under the most severe abnormal circumstances. The key to the design is the fuel element. Enriched uranium microspheres are coated with various layers of pyrolytic carbons and silicon carbide to form a highly-temperature resistant particle that effectively retains all fission products. These particles are mixed with graphite and formed into 6 cm pebbles. A randomly packed vessel of such pebbles forms the reactor core through which helium is circulated as a coolant. Computer models and tests performed on actual pebble bed reactors confirm that fuel failure temperatures are not reached even during the most severe conceivable loss of coolant accident. The reactor drives a gas turbine cycle with resulting efficiencies as high as 48%, comparable to natural gas-fired units. The low price of uranium fuel and low maintenance requirements translates into competitive operating costs. However, high capital costs prevent the MPBR from competing with natural gas in most markets. In remote applications where no fossil supplies are readily available, the playing field is more level. This paper summarizes the features of two of the more promising candidates for remote applications and discusses the strengths of the MPBR from the perspectives of fuel supply and environmental impact.

May 1, 2002

By I. Stefanou, J. Sulem

"In the last thirty years, the study of earthquake mechanisms has emphasized the major role of rock friction. Earthquakes appear to be the result of a frictional instability and occur by sudden slippage along a pre-existing fault or a plate interface. Multiphysics couplings play a major role in earthquake nucleation and seismic slip. The effect of shear heating and thermal pressurization may be of prime importance in the control of the stability of shear deformation inside the slipping zone. Other mechanisms in relation with thermal decomposition of minerals affect the pore pressure and the temperature evolution of the system, and can play a significant role in the extreme strain localization observed in field. The actual width of the localized zone is a key parameter for understanding fault weakening mechanisms. On the basis of field observations, laboratory experiments and recent advanced modeling, these phenomena are analyzed and discussed in order to bring some new insights in the understanding of earthquakes nucleation.INTRODUCTIONIn the last thirty years, the study of earthquake mechanisms has emphasized the major role of rock friction. Earthquakes appear to be the result of a frictional instability and occur by sudden slippage along a pre-existing fault or a plate interface (Scholz, 1998; Sykes, 1978). The conceptual model of spring slider system is commonly used to represent the interaction between an elastic crustal block and a fault zone. Stick-slip instability is possible if the softening rate of the shear resistance of the fault zone is high enough as compared to the stiffness of the crustal block. Therefore, weakening mechanisms that can explain how the frictional resistance of a fault decreases with slip and/or slip rate is of prime importance to understand how an earthquake nucleates. In recent years, several drilling programs in active faults (e.g. the Nojima fault in Japan, Boullier, 2011; the Aigion Fault in Greece, Cornet et al. 2004, the Chelungpu fault in Taiwan, Ma et al. 2006, and the San Andreas fault in the U.S.A. Ellsworth et al. 2000) as well as high velocity friction experiments (e.g. Tanikawa et al 2012a; Tanikawa et al. 2012b) have highlighted the physico-chemical processes involved in the nucleation of seismic slip (see for the example the review paper of Niemeijer et al. 2012)."

Jan 1, 2015

By G. Szilvay, P. Kinnunen, J. Salminen, V. Miettinen, O. Salmi, J. Mäkinen

This paper demonstrates experimental studies on bioprocessing of different waste streams. In Part I of this paper three tailings from mining industry were bioleached with mixed acidophilic culture in order to solubilize valuable metals, like copper, nickel, zinc and manganese to leaching liquor. Bioleaching resulted in > 70 %, > 85 %, 100 % and > 70 % leaching yields for Cu, Ni, Zn and Mn, respectively. However, contaminants like arsenic and chromium were not leached efficiently and they will cause challenges in residual solids and sometimes also in metal recovery from leaching liquor. Bioleaching resulted in 99 % leaching yield for copper. Part II demonstrates mine water treatment and also gold recovery from process liquids with biosorption method. The novelty of biosorption was finding that certain fungal species were able to be cultivated to self-immobilized systems, which are easier to operate than traditional suspended biomass methods. Biosorption resulted in more than 90 % removal for all contaminants, but was also seen to be gold selective.

Jan 1, 2014

In the leaching and recovery of gold from copper containing gold ores using cyanidation, some copper minerals also dissolve which can have a detrimental effect on the process efficiency and economics. There are also environmental concerns with current operations discharging cyanide and copper cyanide species into tailings dams, and strict regulations prohibit this for greenfield plants. Cyanide destruction however is not an economic option for new plants treating copper-gold ores. This paper evaluates a potential recovery process to overcome the copper cyanide problem. Despite gold dissolution occurring in copper cyanide solutions having no free cyanide, gold recovery from ores is lower compared to free cyanide. Thus, cyanide addition has to be optimised to maximise the gold recovery whilst endeavouring to eliminate free cyanide at the completion of leaching (CN:Cu less than 3:1). Subsequently, copper cyanide can be recovered using activated carbon. The loaded copper cyanide is easily recovered from the carbon with a cyanide soak and distilled water wash such that the eluted CN :Cu ratio is less than 4:1. The copper could be recovered efficiently by electrowinning, by decreasing the pH of the eluant to 5. The remaining cyanide solution, after electrowinning, is then neutralised to form NaCN and recycled.

Jan 1, 2005

By Michael E. Charles, Jaroslav J. Vocadlo

"The hydraulic transport of solids through pipelines can have many advantages over other modes of transport. Numerous successful applications both within plants and over longer distances have demonstrated the technical and economic feasibility of slurry pipelining. Solids successfully transported include kaolin, coal, iron ore, gilsonite and limestone, and others, such as sulphur and potash, are likely to be transported in Canada in the near future. However, though the technology of solids pipelining is quite advanced the underlying principles have not yet been formulated past the semi-empirical stage. The main objective of this paper is to present a discussion of the important technical and economic considerations in the design of so lids pipeline systems by reference to typical data. The Worthington slurry pumps and pilot facilities are briefly described."

Jan 1, 1972

By D. Hamilton

The electrode of a PEM fuel cell consists of two distinct sections - the catalyst layer and the porous transport layer (PTL). There are several kinds of PTL material, although all use carbon fibres as the solid fraction. The fibres can be matted to form a paper, woven into a cloth, or chopped to form a felt. Despite the different morphologies of the media, they are all anisotropic in structure, that is the majority of continuous fibres lie perpendicular to the direction of bulk transport. Currently, no models account for anisotropy and all transport coefficients are calculated as volume weighted averages or from empirical correlations (not developed for fibrous porous media). The present work presents a new methodology for determining anisotropic transport coefficients in fibrous porous media. A numerical experimentation process is employed wherein random samples of the PTL are generated and used to solve a diffusion transport equation. Effective transport coefficients are determined by integration of flux across the domain boundaries once a steady state solution has been reached. Multiple random samples at each porosity are generated in order to predict statistical variance. The results are correlated for ease of implementation in full PEM models.

Jan 1, 2005

By M. J. Gagnon

The agglomeration of particulate materials is used in many mineral processes to enhance the settling of the fine particles, Depending upon many physical and chemical parameters, the aggregates demonstrate specific density-size distributions, In this study, a fractal model of the agglomeration process is introduced, Based on reliable experimental data and on physical calculation, the model presented helps to envisage the initial formation of the micro-flocs, and to interpret the subsequent interactions between the aggregates in terms of either coagulation or flocculation, Data from different sources, materials and different agglomeration processes are analysed and compared in the light of the proposed model.

Jan 1, 2005

By D. Ibarra, J. Jacob, A. G. Guezennec, P. d’Hugues, A. Archane

The lack of adequate gas mass transfer is a rate limiting step in many bacterial leaching processes. Oxygen often becomes a limiting factor because of its low solubility compared to the high demand induced by sulfide oxidation. One way of increasing the solubility of oxygen in water or in media solution is by increasing the driving force, i.e. raising the oxygen partial pressure in the gas stream supplied to the leach pulp. The use of oxygen is a well-known practice in high-temperature bioleaching reactors (above 70°C) whereas air is usually preferred in medium and low-temperature operations in order to avoid too high dissolved oxygen concentrations which could impact negatively the bacterial activity. The purpose of this study was to investigate the use of oxygen-enriched gas in bioleaching reactors at 40°C in order to improve the gas transfer in the system when operating at high solid load (20% and more). Bioleaching experiments were performed on a sulfide-rich tailing waste (pyrite 60%, copper 0.8%, cobalt 0.06 %, gold 1 g/t) using the “BRGM-KCC” bacterial consortia. The reactor used for the tests was designed on the basis of a new bioleaching reactor concept developed by Air Liquide, Milton Roy Mixing and the BRGM which uses floating agitators to inject gases and to mix and to suspend solids in the bioleaching solution. Two types of tests were carried out: with air injection and with oxygen enriched gas mix injection. The aim of this work was to confirm the capacity of bacteria to grow and to dissolve pyrite in this type of bioreactors in oxygenrich atmosphere, and to compare sulfides dissolution rates during both types of bioleaching tests. The results obtained show that the use of oxygen enriched gas mix does not decrease bioleaching performances compared to air injection. High metal extraction yields were achieved (above 80%). No deleterious effect due to oxygen use was observed on the bacteria despite the high level of dissolved oxygen reached in oxygen tests (up to 14 mg.L-1).

Jan 1, 2016

By D. Saramak, Z. Naziemiec

"Chalcedonite is an unique rock due to the relatively small area of its occurrence. It also possesses multi-raw-material features therefore it should be given a special protection aiming at its complete and optimal utilization. It is the natural sedimentary rock and the only mine in Poland, located in Inowlodz, where the opencast mining from “Teofilow” deposit is carried out.Chalcedonite mainly consists of cryptocrystalline and microcrystalline chalcedony together with small amounts of autogenous and detrital quartz. The chalcedony itself is a fairy common mineral and many forms of its occurrence is known, some of them are semi-precious minerals. Among the most popular ones following can be found: agate, bloodstone, onyx, carnelian, chrysoprase. Many countries own chalcedony deposits: Australia, Brazil, India, Canada, Namibia Russia, South Africa. However chalcedony in its pure form does not occur in the mentioned chalcedonite rock. The pores, which take usually from 5% to 25% of volume and have sizes smaller than 0.5 mm, are the characteristic feature of all chalcedonite forms. The paper presents some crucial problems of its processing together with most significant directions of its applications. New method of chalcedonite enrichment based on densimetric separation (patented in Poland) is presented. Results of investigation show that the obtained products can increase quality of concrete and filter grits."

Jan 1, 2016