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The opening session of the A. I. M. E. was held at the King Edward Hotel, Toronto, on Tuesday, July 25th. Dr. W. G. Miller, on behalf of the Local Committee, opened the proceedings. [ ] President John Hays Hammond, who occupied the chair, introduced Alderman Graham, Chairman of the Reception Committee, and representative of the city, in the absence of His Worship the Mayor. A brief address of welcome was delivered by the Alderman and responded to by President Hammond. The President then requested Dr. James Douglas to present to the honoured Secretary of the Institute, Dr. Rossiter W. Raymond, an oil portrait.

Jan 1, 1907

Prof. Dr. H. Seger and Mr. E. Cramer, Chemisches Laboratorium fur Thonindustrie, Berlin, Prussia (communication to the President)* : We have learned, with much interest, from the pamphlet sent to us, of the work of Messrs. Hofman and Demond, particularly as we observe from their experiments that these gentlemen recognize the usefulness of the Seger cones, and that this method of determining temperatures in the furnaces of the ceramic industry and in the tests of refractory clays is valued, not only in all parts of Germany, but also in other countries. Permit us to say, with reference to the crucibles employed in tests for refractoriness, that we have used of late, besides the magnesia crucibles, also those made of Zettlitz kaolin, with the addition of alumina, previously calcined, with regard to which we beg to refer to our article in the Thonindustrie-Zeitung of December 9, 1893.

Jan 1, 1895

By AIME AIME

INSTITUTE members attending the Annual Meeting in New York who want to see one of the mining engineers' newest aids, photoelastic stress analysis, are due for an interesting afternoon on Thursday, Feb. 15, when open house: will be held at the Columbia University mining laboratory. Information as to the direction and distribution off stresses in mine structures, which has been developed by Professor Bucky, associate professor at the Columbia School of Mines, and David Sinclair, research assistant, is useful in the design of pillars and in the placing of openings relative to working places such as gangways and haulage levels.: This work has been sponsored during the last ten years by the Engineering Foundation.. It is fully reported in T. P. No. 1140.

Jan 1, 1940

By F. E. Calkins

THE following presentation of the more important accumulated facts and probabilities involved in copper ore deposition is based on my experience in examination work and study of the extensive litera-ture of the subject; to make personal mention of all sources of information would require the naming of a small army of able geologists and other investigators who have contributed to, building up the science. I have tried to present the salient features of the subject in logical order and condensed form, and to point out the relative importance of processes involved. Doubt-less many geologists could suggest some changes and many additions. ORIGINAL SOURCE The original source of all copper was in the earth's interior; it has been brought to the outer part of the earth, within reach of man, in three ways: (1) By intrusions and flows of basic igneous rocks containing copper in minute quantities, presumably as silicate or sulfide. No orebodies have been formed by this method. (2) As segregations within intrusive igneous rocks, the copper minerals having solidified at the same time as the rock itself. The few deposits known to have been formed in this manner have been of little or no importance. The oft quoted Sudbury nickel-copper deposits are now known to belong to the class following. (3) By gaseous or liquid aqueous emanations from ,large deep-seated masses of intrusive molten rock. These emanations, or mineral solutions, ascended through zones of connected openings in the earth's crust and dropped their load at points far above their source. Deposits formed in this manner were the primary source of nearly all, if not all, of the world's copper production.

Jan 10, 1923

By J. S. Kirkaldy, R. C. Dorward

The solubilities of copper and gold in silicon and germanium have been determined by equilibration of the solid semiconductors with coexisting liquidus phases. The experimental results were combined with estimated activity coefficients of the liquidus alloys to determine the following partial molar enthalpies and excess entropies of solution for the systems: Solubility measurements were also carried out below the eutectic temperature of the copper-silicon system. The partial molar enthalpy and excess entropy of copper in silicon with respect to Cu3Si were determined to be 40.2 ±0.5 kcal per mole and 9.7 i 0.5 cal per mole — OK, respectively. It has been dentonstrated that nu-cleation and growth of intermediate compounds are retarded in copper-silicon diffusion couples. This points out the dangers of determining equilibrium solubilities by dijjusion methods. THE thermodynamic requirement for equilibrium between contiguous phases at constant pressure and temperature is that the chemical potential of each component be constant throughout the system. Equating expressions for the chemical potential of solute, component 2 say, in two phases, alpha and beta, gives

Jan 1, 1969

Alpha Portland Cement Co.'s mining operations at Manheim W. Va., produce 750,000 bbl of limestone yearly, averaging 2200 bbl per working day. Thirteen parallel entries have been driven to date, each almost 30 ft high and about 45 ft wide, extending back 5000 ft to the working faces. Pitch of the seam from the lowest to the highest entries is steep enough to provide excellent year- round natural ventilation, and this, together with the size of the entries and a good bottom, has allowed face crews to drive right up to the working areas in the family car.

Oct 1, 1956

By George H. Hanna

THE importance of the Donets coal field (the Donbas) to the national economy of the Soviet Union is well known. Great as was the significance of this tremendous deposit of coal in prewar days it is destined to become an even greater factor in the economic life of the country now that the tremendous havoc wrought by the Germans is being remedied. Since the war began, new coal fields have been extended; for example output of the Moscow and Karaganda (Kazakhstan) fields has become considerably larger while new mines are producing coal in several parts of Uzbekistan and Kirghizia. The huge West Siberian coal field, the Kuznetsk Basin, is producing more coal than ever before to supply the industries of that region and of the Urals. But so great has been the development of industry to meet war needs, especially in those districts of the Soviet Union that lie to the East of the Urals, that the coal obtained, eked out by such locally-won fuels as peat and wood, is still barely sufficient to meet industrial requirements. The main burden of the coal supply for the restored industries of the West, therefore, will fall on the Donbas.

Jan 1, 1945

By H. N. Lawrie

This study was undertaken on account of the lack of definite knowledge concerning the influence of bismuth on wire-bar copper, and the small elimination of bismuth from copper-matte during the smelting-operations. The early workers who studied the influence of bismuth on copper confined their investigations to malleability and ductility—two physical properties which are related to the others so intimately that their determination is of primary importance. Karsten and Levo1,² using bending- and mealleability-tests, seem to have been the first to take up the subject, and while their results are incomplete, they agree in the main with the later work of Hampe.3 The bending-tests used by the first investigators consisted in bending the specimen until it failed. The malleability-tests were made by beating the material to a knife-edge with a hammer. Hampe not only determined the percentage of bismuth which would cause red-shortness and cold-shortness of the alloy, together with other influences of bismuth on the malleability and ductility of copper, but also took up the influence of the bismuth protoxide, BiO, on copper, and of bismuth sesquioxide, Bi,O,, on the copper protoxide, CuO. Hampe's conclusioris of the influences of these two latter compounds of bismuth on copper are as follows : "If the protoxide of bismnth be alloyed with metallic copper, it is not changed to metallic bismuth, but remains mechanically distributed throughout the copper.

Jan 1, 1910

By A. Mitchell

An approximate phase diagram has been developed for the CaF2-CaC2 system, indicating a eutectic point at 1240°C, Ncac2 = 0.13, and no detectable solid solution in either phase. The liquidus line is shown to correspond to a simple c22- ion in solution. A thermo-chemical study of&apos; the reaction between carbon-saturated Ni-Ca alloys and CaC2-CaF2 liquids indicates that lhe Raoullian activity coefficient of CaC2 in dilute solution in Cap2 al 1500°C lies between 8 and 10. Some effects of the stabilily of Cap2-CaC2 solutions at high temperatures on electroslag remelting praclice are outlined. THE alkaline earth acetylides. MIIC2, have a reasonably high thermochemical stability at high temperature in the solid state,&apos; with the exception of magnesium, which forms an unstable acetylide at low temperatures (-500°C) and a carbide, Mg2C3, in the range 700&apos; to 1000°C. The acetylides of calcium and barium have been shown to have limited solubility in their respective chlorides,&apos; and further these solutions contain the acetylide as a C: ion.&apos; The equivalent magnesium solutions have not been studied. Although calcium "carbide" is used as a desulfuriz-ing reagent in steelmaking. and is possibly present as an acetylide-oxide phase in very basic electric arc practice slags, the acetylide ion appears to be substantially unstable in a silicate slag.* As a conse- *This instability arises from equilibria in the reaction: CaC2 + CO = (Ca0) + 3C where the low intrinsic solubility of CaC2 in silicate lattice, and the low activity of CaO in a silicate solution where CaO/Si02 < 1, combine to give a very small equilibrium concentration of CaC2 in solution in such silicate slags at temperatures in the region of I 500°c, even under carbon-saturated conditions. Under highly basic conditions, a liquid CaO-CaC2 phase may separate from the silicate system quence of this, the possibility that reactions involving CaC2 in silicate solutions are of importance to general steelmaking practice is remote. However, in operations involving a slag primarily based on a halide, or alkaline earth oxide, we must take into account the possibility that CaC2 will appear in quantities sufficient to significantly affect both the chemical and physical properties of the slag. The work outlined below presents a study of the CaF2-CaC2 system intended to provide sufficient data to allow an estimate of the importance of this system to electroslag remelting and welding practice. However, we should indicate at this point that there will be other processes, e.g., heat treatment, flux cleaning of castings, fused salt electrolysis, and so forth, where alkaline-earth halide fluxes are in contact with carbon, graphite, or carbides, and where halide-acetylide solutions must be taken into account. EXPERIMENTAL 1) Structural Studies. In view of the difficulty ex-perienced in handling CaC2 prepared from calcium turnings and propane gas at 700°C, it was decided to use solutions prepared directly in the equilibration apparatus, Fig. 1. The starting materials were: a) Ni-Ca-C alloy, prepared by adding calcium to liquid nickel held under calcium fluoride in an induction-heated graphite crucible; b) calcium fluoride, prepared by fusing calcium fluoride powder (British Drug House "EXTRA PURE") calcium fluoride in an induction-heated graphite crucible, in air, followed by electrolysis between graphite electrodes at 1 amp cm-2 density, for 10&apos; coulombs per g CaF2. This procedure decomposes the CaO produced by hydrolysis during the fusion step, replacing it by CaC2; Ca2+ + 2e-Ca*(l) Ca*(l) + 2C(gr)-(CaC2)caF2 O2- -2e-O*(g) O*(g) +C(gr)-CO(g) This results in a composition of between 2 and 5 wt pct CaC2 in CaF2. Fifty grams (in lumps) of this material were placed in a graphite crucible, together with Ni-Ca-C alloy (averaging 20 wt pct Ca), and the equilibration apparatus assembled. The alloy reacted with the crucible at high temperature to give CaC2, which dissolved in the calcium fluoride solution to give the desired composition. Cooling curves were plotted manually for these liquids, with rapid stirring and CaF2 seeding to minimize supercooling, and using a Pt/Pt 13 Rh thermocouple calibrated on the freezing points of nickel and copper. This gave a reproducibility of ±0.l°C. and an absolute accuracy of the thermocouple of ±l°C. An example curve is shown in Fig. 2, with the CaF2 end of the binary system in Fig. 3. The CaF2-CaC2 ingots were crushed, under dry nitrogen, and sampled for chemical analysis and X-ray examination. Analytical details are given in the Appendix. Powder diffraction data indicated that the only phases present in all samples examined were calcium fluoride and tetragonal (Types I and 111) calcium acetylide,4 with no evidence of solid solutions or compound formation. 2) Thermochemical Studies. The apparatus used to obtain activity data on CaC2 in these systems is shown in Fig. 4. It consists of an arrangement whereby the graphite crucible and its contents (CaF2-CaC2. Ni-Ca-C) can be rapidly cooled without exposure to air. Trial experiments to determine an equilibration time by ap-

Jan 1, 1969

By John L. Burns

The object of this chapter is to present data concerning the effect of the introduction of relatively slight amounts of carbon and nitrogen into supersaturated solution in iron. The study is confined to the alpha temperature range of both the Fe-C and Fe-N systems. The age-hardening characteristics of these two systems are considered. These data are compared to those of other age-hardening alloy systems and a "classification" is essayed. A.—Relation of Lattice Parameter and Electrical Conductivity to Changes in Physical Properties Due to Aging of Fe-C Alloys Since Whiteleyl in 1927 showed that some of the iron carbide that is normally present in slowly cooled low carbon-iron alloys disappears on rapid cooling from just below the A, point, interest has been manifested in the possibilities of age-hardening in these alloys. Masing and Koch,~ and at the same time and independently, W. Koster,~ proved these alloys to be age-hardenable. A. A. Bates4 a little later also published an interesting paper on changes in physical properties due to the aging of low-carbon steels. Many other papers have appeared showing changes in physical properties in specific instances due to this same phenomenon.

Jan 1, 1934

By W. C. MENDENHALL

THE problem of maintaining the mining industry is two-fold; finding new supplies in the face of increasing difficulties, and making such advances in the arts of extraction and preparation as to use supplies of lower grade. Progress in mining and reduction methods and in transportation makes ore today of that which was waste yesterday. These are the fields of the metallurgists and the transportation engineers. The geologists and mining engineers must work together on the problem of ore finding. As the old prospector fades from the scene, men with equal hardihood and patience and equal power to meet the physical obstacles which confront the seeker after ore, must take his place, armed with all that has been learned from human experience about the causes, the controlling conditions, the indications, and hiding places of the metals. Such a seeker is dealing with some of the most complex and obscure of natural phenomena. In nature&apos;s laboratory, tremendous forces are at work. Tempera-

Jan 1, 1926

By M. L. Fuller

OWING to the nature of the die-casting process, freshly cast alloys are undoubtedly not at equilibrium from the standpoint of alloy phase relationships. After casting, therefore, they tend to undergo phase changes, with the ultimate effect of reaching a state of equilibrium at the aging temperature, beyond which no further change takes place. This phase alteration undoubtedly is one of the primary causes of the changes in dimensions and physical properties that zinc-alloy die castings undergo during aging. It is planned to report on this problem in a series of papers of which this is the first. The writers have made a study of commercial zinc die-casting alloys over a period of several years, utilizing the X-ray diffraction technic of determining the phase composition changes in the alloys. Up to the present, two principal phase changes have been observed which are capable of causing dimensional changes: (1) the segregation of secondary constituents from the zinc-base solid solution and (2) the beta aluminum-zinc decomposition. The latter is the subject of the present paper and studies on the former will be reported upon at a future time.

Jan 1, 1934

By Alan T. Gorton, T. L. Joseph, Gust Bitsianes

High-temperature X-ray diffraction techniques were used to determine thermal expansion coefficients of iron and its oxides. Lattice parameters of a and iron, wiistite, magnetite, hematite, and goethite were determined and plotted as a function of temperature. From these results, the true and mean linear thermal expansion coefficients were calculated. In the case of noncubic crystals, the expansion coefficients were determined along each of the crystallographic axes. The effect of the magnetic transformation on lattice parameter was measured for a iron and magnetite at their respective curie temperatures. COEFFICIENTS of expansion for iron and its oxides were determined from the temperature dependence of their lattice parameters. From these data, the true linear coefficients were derived by means of the formula: at =[(l/ao )(dao/dt)] [1] where at is the true linear coefficient of expansion, a, is the lattice parameter in angstrom units, and all variables are referred to the temperature, t, in OC. Thus the true expansion coefficient represents the instantaneous change in lattice parameter on a unit basis and at a particular temperature. A second expansion coefficient is also often used. It is termed the mean linear coefficient and is defined in the following way: am = [ao(t) - ao(O)]/ao(0) l [21 This coefficient represents the average change in lattice parameter on a unit basis but at a specified parameter length, ao at O°C, and over a specified temperature range,1 to 0°C. Generally the true co-

Jan 1, 1965

By V. Annamalai, J. B. Hiskey, L. E. Murr

The kinetics of copper cementation on rotating disks of body and tear-top beverage can aluminum alloys were studied as a function of temperature and copper ion concentration. Both alloys followed the two-step kinetic regions, an initially slow rate followed by an enhanced rate. Experimental activation energy determinations (9.04 to 19.62 kJ/mol) indicated that ionic diffusion controlled the reaction mechanism between 20° and 60°C. At low temperatures (< 20°C), the system appeared to be controlled by the presence of an aluminum oxide surface film. The results of this study showed that cementation kinetics for the beverage can aluminum alloys are similar to those for pure aluminum. It was also found that the chemical removal of the oxide layer is less important for the alloys than /or the pure aluminum system. The characteristics of the resultant copper deposits were studied under a scanning electron microscope, and the reaction kinetics seemed to depend strongly on the nature and morphology of the deposits. In addition, maximum rates occurred when the deposit structures were fine feathery dendrites.

Jan 1, 1980

By K. H. Nimerick

A recent study has attempted to identify properties of hard-to-float coal that make them responsive to froth conditioning. Froth conditioning is the process of chemically enhancing the hydrophobic surface character of fine coal particles to improve their recovery by froth flotation. Since its introduction, froth conditioning has enabled recovery of an additional 1.9 Mt (2.1 million st) of coal. This study correlates field results to chemical, physical, and petrographic properties. The most direct correlation relates the coal&apos;s oxygen content to its response to froth conditioning. The higher the oxygen content, the greater the benefits of froth conditioning.

Jan 1, 1985

Jan 1, 1957

By R. A. Wood, R. I. Jaffee, H. R. Ogden, D. N. Williams

Dispersion-containing titanium-copper alloys were prepared having mean free paths varying from 1.0 to 9.7 P. Tensile studies at room temperature and at 1000°F showed that little or no strengthening occurred when the mean free path exceeded 3 p. However, at lower values of mean free path appreczable strengthening was observed. A considerable amount of strengthening also resulted from copper in solid solution. DURING the past several years, an increasing amount of study has been devoted to dispersion hardening, an alloying process in which increased strength is obtained through the addition of a ran-

Jan 1, 1961

By AIME AIME

NATURE was in a smiling mood on December 18, 1883. On that day, Chester Alan Fulton, the sixty-first President of the American Institute of Mining and Metallurgical Engineers, was born, and she endowed him with every good quality within her reach - looks, physique, intelligence, and character. Brought up in the valley of the Hudson River, with the mighty Palisades which make it the "Rhine of America," he has lived up to his early promise - as a man, as an engineer and as a friend.

Jan 1, 1943

By M. E. Wadsworth

The region about the south shore of Lake Superior is to geologists one of the most interesting districts of the United States, embracing as it does, in a limited area, old crystalline rocks, together with forms that are almost in their original condition of a beach sand and mud. In this region was first established the base of the geological column, the Azoic (" without life") System of Foster and Whitney, or the Archæan (" the beginning ") of Dana. Overlying this system are found the sandstones and limestones of the Paleozoic (" ancient life "), and their associated lava-flows (Algonkian ?). These systems possess a strong economic interest, owing to the stores of iron in the Azoic and of copper in the Paleozoic or Eozoic of this district, which forms one of the most important mining regions in America. The geology of this section is so difficult and complicated that, in its general discussion, perhaps no proposition can be stated concerning any portion of it to which exceptions cannot be taken. Indeed, out of the general discussion of different points comes in time the truth, and various geologists, even now, are working over this region in the endeavor to arrive at some consensus, or at least to determine upon what points they can agree, and upon what points difference of opinion will have to exist between them at present, until further evidence can be obtained. The writer will endeavor to give in a brief form that which appears to him at present to be the most correct statement of the geological structure of the region, admitting that from time to time, as more complete evidence shall be obtained, he expects to change his views in the future, as he has done in the past, if that evidence shall cause him to believe that he has been mistaken.

Jan 1, 1898

Jan 1, 1985