Spokane Paper - The Influence of Bismuth on Wire-Bar Copper

This study was undertaken on account of the lack of definite knowledge concerning the influence of bismuth on wire-bar copper, and the small elimination of bismuth from copper-matte during the smelting-operations. The early workers who studied the influence of bismuth on copper confined their investigations to malleability and ductility—two physical properties which are related to the others so intimately that their determination is of primary importance. Karsten and Levo1,² using bending- and mealleability-tests, seem to have been the first to take up the subject, and while their results are incomplete, they agree in the main with the later work of Hampe.3 The bending-tests used by the first investigators consisted in bending the specimen until it failed. The malleability-tests were made by beating the material to a knife-edge with a hammer. Hampe not only determined the percentage of bismuth which would cause red-shortness and cold-shortness of the alloy, together with other influences of bismuth on the malleability and ductility of copper, but also took up the influence of the bismuth protoxide, BiO, on copper, and of bismuth sesquioxide, Bi,O,, on the copper protoxide, CuO. Hampe's conclusioris of the influences of these two latter compounds of bismuth on copper are as follows : "If the protoxide of bismnth be alloyed with metallic copper, it is not changed to metallic bismuth, but remains mechanically distributed throughout the copper.