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By J. A. Brierley, C. L. Brierley, K. A. Prisbrey, R. W. Bartlett, J. G. Harrington

Bacterial oxidation of gold-encapsulating sulfide minerals in low-grade refractory ores was investigated over a period of one year. Crushed ore samples were held in wet, bacteria-inoculated, aerated columns. Sulfide mineral oxidation data were correlated with subsequent gold cyanide extractabilities. Experimental results for both sulfide conversion and gold extraction were compared with a biooxidation kinetics model that incorporates rock size, mineral grain size, and heterogeneous pyrite reaction kinetics. Using the model, extrapolations were made over three years for biooxidation of ore in large stockpiles. Ferric ion (oxidant) diffusion in the solution-filled pores of the rock matrix does not control the biooxidation kinetics of ore crushed to -25 mm.

Jan 1, 1993

By Vogwill R. I J

The Boddington Gold Mine, operated by Worsley Alumina Pty Ltd, is located about 100 km south of Perth and is one of the largest-producing gold mines in Australia.Multiple open pits are planned and several extend below the water table, through the deeply weathered lateritic profile and into the underlying Archean bedrock. Groundwater related mining problems, such as poor trafficability, wet floor conditions and slope instability began to occur early in 1990.The mine is located within Archean greenstones which are steeply dipping and faulted. Rock types include mafic to felsic volcanics, pyroclastics and sediments. These rocks have been regionally deformed and metamorphosed and are intruded by quartz micro-diorites and post-mineralisation dolerite dykes. Deep weathering has produced a typical oxide profile consisting of laterite, clay and saprolite zones underlain by weathered to fresh bedrock.

Jan 1, 1993

This paper examines the issues involved in the technical audit and valuation of exploration prospects. Certain methodologies are more appropriate to use depending upon whether the mineral property valuation is of an exploration area, a project under development, or an operating mine. Valuation approaches that are reviewed include the Multiple of Exploration Expenditure, Joint Venture Terms, Rules of Thumb, and particularly the Kilburn Rating Method. The DCF/NPV Financial Simulation Method, even modified by the use of Expected Values, is not considered appropriate for valuing exploration prospects. The choice of the most appropriate methodology and its successful application depends primarily upon the amount of reliable input data available and, more importantly, the experience and judgement of the valuer. It must be remembered that all valuations are time and circumstance specific and will be generally subject to revision as more data becomes available.

Jan 1, 1993

By Malcolm J. McPherson

Within the world of mining health and safety, increasing attention is again being given to underground fires and explosions. This paper reviews the effects of open fires in mine entries on the ventilation system, and outlines current methodologies of attempting to control such a fire. The particular hazards of a fuel-rich fire are discussed. There appear to have been no really significant advances made in methods of extinguishing mine entry fires in the last several decades. The final section of the paper introduces research that is investigating the simultaneous production of an inerting, cooling and quenching atmosphere by means of a dense water fog.

Jan 1, 1993

By Debra C. Man, S. Thomas Freeman, F. Wiley Horne

INTRODUCTION The Metropolitan Water District of Southern California (Metropolitan) is the largest water wholesaler in southern California. Its service area spans the major urbanized portions of Ventura, Los Angeles, Orange, San Bernardino, Riverside and San Diego counties. More than 15 million people are serviced by Metropolitan through its 27 member agencies. The primary sources of Metropolitan's water supply are the Colorado River Aqueduct (CRA) and California's State Water Project (SWP). Currently, planning and design level studies are underway by Metropolitan to expand the water storage and conveyance systems within the service area for the purposes of providing increased efficiency and flexibility to manage limited water supplies, improving water quality, and increasing system reliability. The system reliability issue is particularly significant because the conveyance facilities from both the CRA and the SWP must cross the active San Andreas fault. This fault is considered to be the source fault for the anticipated "Big Earthquake" in southern California. To meet these objectives, Metropolitan's expansion plans involve a major new storage reservoir, new large diameter pipeline and tunnel conveyance facilities, more efficient utilization of existing groundwater basins, and an aggressive public awareness and conservation program. This paper focuses on the planning studies that have been carried out for over 50 miles of tunnels being considered for several of Metropolitan's proposed conveyance systems. These tunnels have ranged in length from a few hundred feet to over 42,000 feet, with depths of cover ranging from a few tens of feet to over 3,000 feet, and finished diameters ranging from 10 to 20 feet.

Jan 1, 1993

By Jan K. Wolski

Detection of the air recirculation branches within a large ventilation network may be difficult, therefore a PC computer routine has been developed to perform this task in an efficient and reliable manner. This paper describes the method illustrated using a network with complex multi-recirculation circuits. The fact that only the air flow directions and not the flow rates are used in calculations is of some interest. The air recirculation during a real mine fire is demonstrated using the PCVENT program, whose version 4.0 includes current information about any recirculation branches during network calculations or during a fire simulation. This paper also discusses some transient problems related to air recirculation, and gives examples.

Jan 1, 1993

Gold heap leach operations often process low grade ores with little margin for cost increases. The advantage of heap leach operations is the considerable savings in both capital and operating costs. This paper looks at an alternative pH modifier to lime in the heap leach process, namely bauxite waste mud or red mud. The red mud can contain trace amounts of gold and was found to be an excellent source of slow release sodium hydroxide for long-term pH modification. Column cyanide leaches showed that 25 kgt-1 of red mud provided a higher pH and longer pH modification than 0.25 kgt-1 of lime. Contaminants leached from the red mud hampered the adsorption of the aurocyanide complex onto activated carbon.

Jan 1, 1993

By K. L. Wiley

In-situ leaching, initiated in 1986 at San manual, was economically developed in 1989. The primary reason for this lag time between startup and viable production was the time required for technical development. The technical development pursued comprised detailed design, development, and implementation of in-situ well construction methods, formulation of suitable well pattern arrays, and the development of extensive hydrogeologic and geochemical knowledge of the mineral deposit. Since 1989, the in-situ leaching program has become a viable and cost effective method to extract copper from the supergene mineralized zone of the San Manuel deposit. The in-situ leaching methods that are currently utilized have been progressively expanded and continually developed and will became the cornerstone of copper production from the San Manuel oxide mineral deposit. This paper presents an overview of the supergene hydrogeology, current design techniques, drilling methods and well completion, pump determination and setting, solution management, and future plans for the increased extraction of copper by in-situ leaching methods at the San Manuel mine.

Jan 1, 1993

By Seth L. Pearlman

A major excavation support case history for the Eastern approach to the Third Harbor Tunnel (THT) in Boston, MA is described, which uses an anchored Soil Mixed Wall (SMW). Both general and project specific information is provided regarding the design and construction of SMW walls. In addition, conclusions are presented that discuss the suitability of this particular application and other possible variations.

Jan 1, 1993

By Brij M. Moudgil, Shoulian Zhu, J. L. Pinault

A new technique, prompt neutron activation probe (PNAP), for analyzing phosphate rock slurry in-situ was evaluated both in the laboratory and at the plant. The technique yielded a high precision in the analysis of Ca, Si and H using 252Cf source. Low accuracy of the direct measurement of P using 241Am/Be in the laboratory tests was attributed to the interference of rare earth elements present in the samples, particularly Gadolinium. No significant effect of variables such as solids loading, particle size distribution, and flotation reagents was observed on the probe performance. The probe can detect the compositional changes of the feed, tailings and the concentrate streams in the plant.

Jan 1, 1993

By M. S. Celik, G. Onal, S. Atak, A. A. Abramov

An oolitic phosphate ore composed of phosphate (mainly francolite) and carbonates as gangue has been tested for the suitability of the reverse flotation process. The samples were first ground autogeneously followed by the reverse flotation process. While the carbonates were floated by sodium oleate the phosphate was depressed by phosphoric acid. The effect of particle size, reagents type and concentration on flotation recoveries have been investigated to determine the optimum conditions. By this process, a run-of-mine ore containing 16.72 % P205 was upgraded to 28.00% P205 with a recovery of 77.0% The mechanism of optimum flotation with phosphoric acid observed at pH 6.3 is explained based on a relationship involving surface potentials and the ratio of required collector concentrations for the respective minerals.

Jan 1, 1993

By A. Probst, J. A. Finch

"Solids concentration (% solids) profiles and the clear liquid/slurry interface level (mudline) were determined from conductivity measurements in thickeners at Falconbridge' s Strathcona mill (Ni concentrate and non-mag thickeners) and Kidd Creek Division (Cu, Zn concentrates and final tails in the concentrator and thickeners in the Zn plant).The conductivity measurement system consisted of a probe 1.5 m in length with 24 electrode cells, a 24-channel relay, a conductivity meter and a computer. A conductivity profile is collected which locates the mud-line by the sharp change in conductivity. The conductivity measurements are readily converted to solids concentration profiles without need for calibration.The results from the conductivity measurements were compared with those from pressure profiles and direct measurements on local samples obtained using a modified Noranda sampler.It is concluded that the conductivity technique is applicable to locate the mud-line and to estimate the solids concentration profiles in thickeners. This on-line information could improve the operational efficiency of industrial thickeners.INTRODUCTIONAn automated, on-line technique for detecting the clear liquid/slurry interface (or mudline) and the variation in solids concentration with depth would enhance thickener operation and control. In some processes such enhanced control offers significant benefits. For example, in hydrometallurgical operations solid/liquid separation is often the process limiting step. Water treatment plants are increasingly expected to operate remotely and reliable sensing is vital.Current attempts to detect the mud-line include reflection of some signal (e.g. sonar), floats (Dahlstrom, 1985) and measurement of pressure (Rosenblum, 1991), and in one case, natural radioactivity of the solids (Johnston and Simic, 1991). A recent commercial development uses reflection from a vertical array of optical transmitters/sensors, which also gives local solids concentration (BTG Inc., 1991)."

Jan 1, 1993

By George P. Demopoulos, Vladimiros G. Papangelakis, Dimitrios Filippou, A. J. Monhemius, G. W. Warren, E. Peters

A new method developed for the estimation of the activity of Ht in mixed sulfate solutions is described and examples of application of this method to the system H2SO4-ZnSO4-FeSO4-Fe2(SO4)3 from 298 to 473 K are offered. The method makes use of an "extended Debye-Hiickel" type of equation that was originally put forth by Das for pure H2SO4 solutions at ambient temperature. The treatment of mixed sulfate solutions was made possible by combining that equation of Das with a speciation algorithm which calculates the abundance of all species formed. The developed method, which also takes into account ionic strength and temperature effects, was used to generate hydrogen ion activity and speciation data for all possible acid/metal sulfate pairs of the system H2SO4-ZnSO4-FeSO4-Fe2(SO4)3. Finally, under the light of the reported data, specific examples of hydrometallurgical reaction systems are analyzed in terms of thermodynamics or kinetics. In particular, the systems discussed are: hydrometallurgical precipitation of hematite, solvent extraction of Fe(III), acid leaching of zinc ferrite, and oxidation of Fe(II) to Fe(III) by O2(aq).

Jan 1, 1993

By A. S. Malicsi, Vathsala Rajagopal, I. Iwasaki

Corrosion and abrasion properties of a series of chromium-containing, cast-iron balls, with Cr contents ranging from 0% to 29%, were evaluated and compared with austenitic stainless-steel and mild-steel balls. Marked ball wear tests were performed on artificial ore samples consisting of 95% quartzite, with either 5% pyrrhotite or 5% chalcopyrite, under a nitrogen or oxygen atmosphere. The electrochemical mechanism was investigated by correlating the corrosive wear with the corrosion currents obtained from potentiodynantic polarization curves under abrasion. Flotation recoveries were determined on a 95% quartzite + 5% pyrrhotite sample ground with various cast-iron ball materials under an oxygen or nitrogen atmosphere. Electrochemical results are found to be in good agreement with flotation results and with corrosive wear data obtained from marked ball wear tests.

Jan 1, 1993

By J. Hanna, R. Kalathur

Over the years, Alabama's coal industry has generated, during mining and cleaning operations, about 150 million st of fine waste coal, with this total increasing at a rate of 2 million stpy. Reclamation of the fine-size wastes (containing 20% - 60% clean coal by weight) provides, free of charge, mined and crushed feed stocks for coal recovery. Also, the removal or recovery of pyrite from the tailings should eliminate a major source of acid-water pollution. Tests were made on the impounded wastes and current plant discharges to recover the coal fraction by sizing, gravity and flotation techniques. Gravity separation of the +100-mesh material produced commercial-grade coal averaging 7.6% ash, 0.8% sulfur and 13,471 Btu/lb. However, the coal yield, at about 31 % - 56%, was relatively low. Froth flotation, using mechanical and froth column methods, gave similar coal products at much higher coal recovery rates of 87% - 93%. This coal analyzed 10% ash and 1.1% sulfur.

Jan 1, 1993

By Thomas J. Feeley

The US Department of Energy (DOE) is supporting the engineering development of three advanced physical coal cleaning technologies: selective agglomeration, advanced flotation and advanced cycloning. Each is capable of significantly reducing the pyritic-sulfur content of US coals. The objective is to provide the coal and electric-utility industries with a cost-effective option for addressing the SO, emission reductions required by the 1990 Clean Air Act Amendments (CAA). A secondary objective is to evaluate the potential of advanced coal cleaning for removing trace elements that are precursors to the formation of hazardous air pollutants (HAS). The proposed National Energy Strategy (NEE) and the 1990 CAA lay a foundation for a more efficient and environmentally sustainable energy future (1991). The need to use energy resources in an environmentally sound manner presents critical challenges and opportunities for coal preparation during the next decade, particularly regarding the control of SOS and HAY emissions. The principal challenge is the development of cost-effective coal preparation approaches for sulfur and HAY precursor removal.

Jan 1, 1993

By M. J. Richards, T. X. Ren

Determination of the state of an underground fire plays an important role in fire fighting, rescue and reopening operations. This is normally achieved by the analysis and interpretation of fire gases taken from the fire zone. However, drawing conclusions from gas analysis is not an easy task and needs specialist skills, expertise and experience that are usually beyond the knowledge of the officials in a mine. The complexities of a mine fire and the uncertainties of available information often make effective fire fighting decisions difficult if not impossible. This paper describes a knowledge based expert system that can aid in the diagnosis of sealed coal mine fires. Using a commercially available shell, the expert system has been designed to accommodate a series of diagnostic rules replicating the reasoning logic that would be used by human experts. The system allows the diagnosis of explosibility of the fire zone and trends of various fire ratios to be easily visualised for decision making. By continuously analysing the incoming information, the system is able to provide a rapid assessment of the situation of a sealed mine fire prevailing under specific mining and geological conditions. In addition, short term trends in fire behaviour can be predicted and possible fire control actions recommended. An example is given and shows how this system can be used as an analytical tool in various ways to assist the combating of coal mine fires. Further development of the system is discussed.

Jan 1, 1993

By Roy S. Nutter

The automation of coal mining must occur in a manner that is economically beneficial to the industry and that enhances the safety of the underground and surface workplaces. The work at WVU over the last five years in applying expert systems and neural network controlled autonomous robotics provides the mining industry with tools that when properly applied should clearly lead to mine-wide management and operational improvements and should also contribute to a higher awareness of safety issues by all work crews. This work includes the development of MMSS (Mine Management Support System) and the detailed development of autonomous robotics utilizing neural networks for mining systems.

Jan 1, 1993

By C. A. Hesse

The Quartz Hill Molybdenum Project, In Southeast Alaska, was the first mining project to attempt the permitting of a submarine tailings disposal system in the United States, since the passage of the National Environmental Policy Act of 1969 and the Clean Water Act of 1977. Over $20 million was spent by the project developer in baseline data gathering and In funding the preparation of the four Environmental Impact Statements and other environmental documents required at various stages of the project between 1977 and 1988. Because of the timing and a unique set of environmental, legal and regulatory requirements which applied to this project, innovative approaches were developed. This report describes those requirements and the developments, and gives a full historical account of the campaign for permitting submarine tailings disposal at Quartz Hill, until denial of the NPDES permit application by EPA in September 1 990. The extensive studies done for Quartz Hill suggested that under certain conditions the selection of submarine tailings disposal can be the overall environmentally preferred alternative for a mining project. The Quartz Hill story illustrates the complexity of the existing permitting structure and paints out the desirability of rationalization to achieve a more effective system.

Jan 1, 1993

By George A. Morgan

The 53 countries that constituted Africa in 1991 accounted for a significant portion of total world output of a number of mineral commodities. However, total output for the continent declined for many major mineral commodities produced compared with that of 1990. Also, Africa's share of total world output of these commodities generally declined. (See tables 1 and 2.) The most conspicuous declines were for cobalt and copper owing to mining and metal processing difficulties experienced by the world's two largest cobalt producers, Zaire and Zambia. Phosphate rock output declined primarily owing to a sharp fall in production from Morocco, also a leading world producer. Morocco's state corporation for phosphate production experienced marketing problems, leading to the decline.

Jan 1, 1993