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By P F. Lauricella, D Hendri

In the Mesel sediment-hosted disseminated gold deposit, the spatial distribution of hydrothermal alteration is controlled by steeply dipping faults and shallowly dipping lithologies. Hydrothermal alteration of carbonate rock is characterised by decalcification, dolomitisation and silicification. Intense argillic alteration occurs in a laccolithic andesite intrusion adjacent to decalcified and silicified carbonate units. Sulphide minerals (pyrite, realgar, orpiment, stibnite and cinnabar) accompany hydrothermal alteration and precious metal mineralisation. The trace elements Ag, As, Sb and Hg are zoned spatially throughout the deposit. Mesel contains a mineable gold reserve of 7.8 million tonnes at 7.3 g/t Au. Gold mineralisation is preferentially localised in carbonate rocks adjacent to and beneath the andesite intrusion. The ore body consists of a central, near-vertical, high grade 'feeder' system flanked by tabular, inward dipping, moderate grade 'ouflow' zones. Mineralisation is controlled predominantly by two steeply dipping faults with high grade (=10 g/t) gold zones centred about structural intersections and fault splays. Gold is submicron size and locked in very fine grained (<10 microns), disseminated and fracture-controlled arsenical pyrite. The Mesel deposit developed where high angle faults guided ascending, sulphidising fluids into reactive carbonate stratigraphy adjacent to and beneath the andesite intrusion and during subsequent migration of the auriferous fluids along 'outflow' channels. Early decalcification and dolomitisation enhanced porosity and permeability prior to silicification and sulphidation. Gold deposition occurred late in the genesis of the deposit.

Jan 1, 1995

By Maria K. Kojo

The interaction between various slags and a nickel concentrate containing pyrite, pentlandite, and violarite were investigated by submerging concentrate pellets in molten slags. The slags were contained in MgO-A12O3 spinel crucibles. The slag oxidizes the iron sulfides in the concentrate, resulting in a nickel matte. The amount of S02 gas formed during reaction was measured to determine the oxidation reactivity of the slags. The experimental variables included temperature, the ferric/ferrous ratio of slag, and other slag properties such as the FeO/SiO2 ratio and the MgO and NiO contents. The reactivity of the slag depended in a complex manner on its oxidizing power, viscosity, and interfacial tension. The slag composition for the greatest reactivity was determined to be Fe3+/Fe2+ = 0.3, Fe/SiO2 = 1.3, and % MgO = 2. This slag, however, caused substantial foaming. Increasing the MgO content to 10% or replacing it by 5% MgO + 8% NiO eliminated at a slight decrease in reactivity. The implications of the findings from this work in the bath smelting of nickel sulfide concentrates are discussed.

Jan 1, 1995

By Benjamin Vidales

Copper in concentrations above 0.5 weight percent in iron and steel causes hot shortness. This tendency is intensified in the presence of dissolved tin above 0.05 weight percent in the alloy. The understanding of the mechanism of removal of copper from molten iron and steel is of industrial importance. In this investigation, we present the experimental results of the removal of copper from molten iron using sulphide flux in the temperature range 1000°-1500°C. The solution thermodynamic properties of binary sulphide melts have been estimated by using the relevant phase diagrams and the behaviour of copper sulphide in these melts is discussed. The kinetics and thermodynamics of the removal reaction are also explained and, the experimental results are also reported showing the equilibrium distribution of copper and sulphur in molten iron.

Jan 1, 1995

By F. -U. Schneider, F. Wellenkamp

Based on previous investigations of ultrafine comminution in planetary ball mills, a new centrifugal mill has been developed which permits similar high stress conditions. Because this new type of mill is equipped with an immobile chamber, devices for measuring energy, for cooling the milling vessel, as well as, in continuous operation, for material feed and discharge can be more easily attached than to planetary ball mills. Observations of particle behaviour have shown that, in the case of dry grinding, most of the material is found on the mill walls even after short grinding times. Due to the fact that energy dissipation takes place mainly in the zone near the wall, a grinding system which reduces the amount of ball filling required is at an advantage.

Jan 1, 1995

By R. J. Matetic, D. Elsworth

The objective of this U.S. Bureau of Mines hydrologic-subsidence investigation was to evaluate the effects of longwall mining on the local ground water regime through field monitoring and numerical modeling. Field data were obtained from multiple-position borehole extensometers (MPBX's) that were used to measure subsurface displacements. Survey monuments were installed to measure mining-induced surface deformations. Numerous drawdown and recovery tests were performed to characterize hydrologic properties of the overburden strata. Coreholes were drilled above the study area to determine lithologic and strength characteristics of the overburden strata using the rock samples collected. Electronic recorders were installed on all monitoring wells to continuously monitor ground water levels in coordination with mining of the longwall panels. A combined finite element model of the deformation of overlying strata, and it's influence on ground water flow was used to define the change in local and regional water budgets. The predicted effects of the postmining ground water system determined by the model correlated well with field data collected from the field site. Without an infiltration rate added to the model, a static decrease of 3.0 m (10 ft) in water level would occur due to mining of both longwall panels and if an infiltration rate was inputted in the model, no predicted long-term effects would occur to the ground water system.

Jan 1, 1995

By Eggins SM, Crawford AJ, Maillet P

The Fiji Islands are remnants of a once continuous Solomon-Vanuatu-Fiji-Tonga volcanic arc (the Vitiaz arc), located at the boundary between the Indian-Australian and Pacific plates. They record a history of (i) arc volcanism the late Eocene to late Miocene, (ii) an extensive magmatic response to arc rifting (5.5-3.OMa) during which volcanism was dominated by shoshonitic to tholeiitic basalts, and as rifting continued, (iii) a transition from arc to intraplate volcanism. The Hunter Ridge-Hunter Fracture Zone separates the inactive South Fiji Basin from the actively spreading North Fiji Basin, and has been considered to be a transform zone, almost parallel to the motion vector of the Australian plate. However rocks dredged during the 1993 `Alize' cruise, from along the northern part of the Hunter Ridge are typical arc tholeiites, and therefore demand that subduction has occurred beneath the Hunter Ridge sometime during the last û 5Ma.

Jan 1, 1995

The Yabulu refinery of Queensland Nickel Pty Ltd located near Townsville now imports more than three million wet tonnes per year of nickel laterite ore from New Caledonia and Indonesia, making it the largest importer of any commodity in Australia. The project has illustrated that importing untreated bulk ore and re-exporting high value products makes good economic sense for the company and the nation. The economics of this exercise have been considerably enhanced in the past year by changing the project's principal product from nickel oxide sinter to refined high purity nickel metal. It is one of the few operations in the world where nickel ore is transformed to nickel metal at a single site. Several novel technological processes were developed at Yabulu and incorporated into the refinery to allow this product transition to occur. By utilising internally developed technology the new processes were installed at a capital cost of less than $10 million. It is unique for a large nickel producer to completely change the quality of its entire product range many years after the plant was constructed and considerable attention to marketing the new products has been required.

Jan 1, 1995

By George Pittman, Dan McCutchen

When an explosive manufacturer in the USA wants to put a new explosive formula or detonator design in the toughest proving ground in North American, it is Florida. Florida conditions have baffled many creditable blasting experts. This paper deals with some of the methods used to overcome these problems.

Jan 1, 1995

By N. Kanarin

A thermodynamic study is reported on the chlorination of Fe(1-x.)O, Fe2O3, Cr2O3, MgO, Mg2SiO4 with chlorine in the presence or the absence of reducing atmospheres. The reactivities of these compounds as well as that of Mg3Si2O5(OH)4 using Cl2+N2, Cl2+air, and Cl2+CO gas mixtures were studied by non isothermal thermogravimetric analysis between 20 and 1000 °C. The same solids were chlorinated in a horizontal experimental set, during two hours between 350 and 1000 °C, in reducing and oxidizing atmospheres: The chlorination products were examined by XRD and SEM, and possible reaction paths were examined. Results indicate that the carbochlorination of these solids was better than their chlorination; Furthermore, the carbochlorination was performed at lower temperatures than those of the chlorination. Finally, the reaction extent was higher in the case of carbo-chlorination of these compounds. Based on these results, a process was suggested for the selective recovery of chromium compounds from the chromite concentrate.

Jan 1, 1995

By David R. Zuchelli, Elio L. . Checca

Two case studies of methane gas explosions and their effect on the operation of underground coal mines are presented. The studies detail the recovery operations and investigations at each mine site. These include the circumstances prior to the explosions and the effects on the surface and underground ventilation control systems. Various ignition sources such as surface and underground electrical power systems, degasification sites, ventilation shafts, test well casings, and lightning activity were investigated. In each case, a lightning report from the National Lightning Detection Network1 was used in conjunction with the physical evidence and eyewitness accounts to confirm lightning strikes as the ignition source for the explosions.

Jan 1, 1995

By Williams D. J

The boundary element method is one of a number of tools that have found wide application in geomechanics for mine design and stress analysis. Two examples are presented in this paper, illustrating the use of the boundary element method to find potential problem regions in large-scale excavations. These examples are from a Papua New Guinea open cut mine and an Australian sub-level caving operation. Because of the scale of the mines and the complexity of the excavations, the boundary element method is the only practical numerical modelling technique to account for the major influences. Although the boundary element method uses only linear elastic models of the rock mass, the paper illustrates techniques for dealing with non-homogenous and anisotropic rock masses, as well as clasto-plastic effects associated with an excavation.

Jan 1, 1995

A vital ingredient in ensuring that metals exploration companies, working in the developing countries of thePacific Rim, support the development of national geologists is making such a learning program cost-effective. There is a wide spectrum of learning needed in the development of these explorationists: the technical and conceptual skills to carry out exploration efficiently, the professional and managerial skills to apply the exploration in the work situation, the personal attributes required to manage their exploration effectively, and a company organisation that allows them to learn and use these skills and attributes.

Jan 1, 1995

By A. M. Marabini, G. Belardi, V. Alesse, M. Acosta

Sotiel mine is situated in the Iberian Pyrite Belt in southern Spain, some 40 km north of the port of Huelva. Although mining operations at the site date back to Roman times, the present mine came into production in 1983 and 5.6 million tonnes of ore had been extracted by 1993. The orebody is volcano-sedimentary and consists of fine grained copper, lead and zinc minerals in massive pyrite surrounded by slates and volcanics. Prior laboratory research had resulted in the synthesis of a new collector, belonging to the MercaptoBenzoOxazole (MBO) class that acts selectively towards Cu and Zn minerals after activation with CuS04. The MethylMercaptoBenzoOxazole (MMBO) version of this collector had been used for the laboratory flotation of Cu minerals and sphalerite activated by CuS04. This resulted in identification of the optimal physicochemical conditions for laboratory-cell flotation of the two minerals from samples of complex sulphide ores, and subsequently the reagent has been tested in the Sotiel plant (Spain). The plant has three flotation sections. With conventional re-agents, the first section yields a Cu concentrate grading 21% with a total recovery of 29%, and the second one yields a 40% Pb concentrate with total recovery of 34% and a 47% Zn concentrate with total recovery of 78%. Application of the new synthetic reagent in the copper and zinc circuits produces a more selective process with a decrease in re- agent concentration grade and recovery are increased by 2 and 9 points respectively in the case of Cu and by 1 and 3 points where Zn is concerned. Moreover, the penalty elements in the Cu concentrate are halved.

Jan 1, 1995

By Qingxia Liu, Chen Tingzhong, Chen Jin, Yang Xiaosheng

It is common problem (Huan Xinsheng, etc.,l992)for most iron ore concentrators in China that the concentration of thickened tailings is lower than the need for economical transportation. To solve the problem, two methods of improving the properties of the existing thickeners and using separate thickening technique have been applied in three iron ore concentrators. However, in the case of the Daye iron concentrator a new technique of cyclone-flocculated sedimentation was developed by present authors and verified by experiments. The new technique employs efficient hydrocydone designed by authors in conjunction with a low cost flocculant named KLP.

Jan 1, 1995

By Godresse M, Turczynski G. P J, Driver I. J, Low G, Ozawa N

Geological evaluations of coal deposits have been traditionally undertaken in a somewhat manual manner. Information is collected downhole by chip sampling, coring and using downhole geophysical logging. This information is then interpreted by an experienced geologist to define the coal and noncoal lithological units. Coal units were subsequently correlated to provide data for structural modelling. In recent years a number of advancements in interpretation techniques have been made based on Artificial Intelligence. This paper describes an integrated geological interpretation system based on maximised use of Al techniques. The first part describes the lithological interpretation which uses a number of boreholes with both logged lithology and downhole geophysical logs. This information provides a learning set of data to the neural network. The second part concentrates on the correlation of both coal and noncoal units from borehole to borehole. Problems in this area, in a manual sense, are interpretation of correlation across weathering zones and other geological anomolies. The technique is based on pattern recognition and dynamic programming techniques where a correlation matrix is developed relating all holes with their maximum correlations.

Jan 1, 1995

By James P. Bennett

The U.S. Bureau of Mines, Tuscaloosa Research Center, is conducting a review of the usage of different types of refractories, the current industrial practices to recycle/dispose of spent refractories, and the concerns associated with these practices. This information will serve as the technical basis for initiating a research program to recycle or find alternate uses for spent refractory materials. Approximately 1.6 million metric tons of clay based and 1.2 million metric tons of non-clay based refractory materials were manufactured in the United States in 1992 alone, representing a value of almost 2 billion dollars. Landfill has been and remains the disposal means of choice. Issues such as environmental regulations, concerns over landfill disposal, future liability, and product stewardship programs have brought about increased emphasis for recycling or alternate material use. Information on refractory consumption and the issues associated with recycling or disposing of used materials will be discussed, including current recycling practices.

Jan 1, 1995

By Robert B. Hopler

First, a definition: “an explosive is called a permissible explosive when it is similar in all respects to the sample that passed certain tests by the national Bureau of Mines, and when it is used in accordance with the conditions prescribed by that bureau. * This was the definition as stated in Miners’ Circular No. 2,” published by the United States Bureau of Mines in 1911, and it is still applicable today. Of course there have been changes over the years, with the name “MSHA Permitted Explosive” now the legal terminology since January 1989, but the old 1911 circular still tells us what the material is. Note that the definition doesn’t even specifically state “coal mining.” A permissible can be required in guy underground operation that is deemed to have a gas or dust hazard, although in 1911 it was certainly meant to refer only to coal.

Jan 1, 1995

By S. K. Sharma, D. A. Stanley

The US Bureau of Mines is investigating the fundamentals of the flocculation process. The objective of this study was to determine the effects of various physico-chemical parameters, namely, shear rate, polymer dosage, and polymer concentration, on floc growth and to determine the applicability of a model for predicting polymer flocculation behavior. A rapid in-line particle size analyzer was used to follow the progress of both the floc growth and the breakage as a function of time. A genetic algorithm (GA) was used to determine the unknown parameters in the model and to fit a curve to the experimental data. The results showed that the model reproduces the experimental data with only reasonable accuracy and that it was relatively insensitive to the parameters. Results of the flocculation study showed that increases in the polymer dosage had a greater effect on the time required to reach the maximum floc size than on the floc size itself: It was also determined that, given all the above parameters, the degree of slurry mixing during the flocculation process had the greatest bearing on floc growth.

Jan 1, 1995

By Hugh W. Rimmer

The design of comminution circuits and the evaluation of alternatives should be based on state-of-the-art equipment and appropriate design criteria - considerations that are often neglected by today's designers. This paper critically reviews common circuit designs, evaluates various alternatives for difficult-to-treat ores, and discusses the factors that should be considered when developing new plant designs or auditing existing plant performance. Data obtained from laboratory, pilot and plant-scale test work on a wide range of ores and circuits are used to justify the author's conclusions.

Jan 1, 1995

By Nobuo Takahashi

Effective solvent extraction media have been investigated for purification of rare earths. At first, a quaternary ammonium compound was studied. The counter anions of rare earths and organic dielectric substances were tested to improve separation factors,. And second, crown ethers were selected for extractant. Several diluents of crown-adducts were tested to improve solubility and distribution coefficient as well as the counter anions of rare earths. Especially, in the presence of strong reducing agents, highly selective extraction of europium from other rare earths was observed. The third extactnts were ß -diketones. Presence of organic dielectric substances was very effective to improve separation factors. Though those. three groups of extractants were suitable for mutual separation of light rare earths, alkyl esters of alkyl-phosphonic acids were suitable for mutual separation of heavy rare earths because of their high separation factors. To keep proper pH value was necessary for acidic extractants, so control method of the solution pH was studied with high molecule insoluble amines or salts of those.

Jan 1, 1995