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By Adrien Antenen, Didier Villette

CITRON has developed a new process for the recycling of hydroxide sludge, household batteries, catalysts, automobile shredding residues, grinding sludge and other metal containing organic and inorganic waste. A pilot plant with a capacity of 1,000 tons per year has started operations in April 1998. In August 1999, an industrial plant became operational with an initial treatment capacity of 23,000 tons.

Jan 1, 2000

By Hiroshi Nakajima, Kotobu Nagai, Toshihiro Hanamura

"Low carbon ferritic steel bars with ultra-fine grain structure was developed through a warm rolling for the first time by the present authors. They show better low temperature toughness than conventionally hot-rolled plates. Hence, the brittle fracture surfaces in Charpy tests were examined in terms of the effective grain size of fracture, compared with those of conventional QT steels. The ductile-to-brittle transition temperatures were in good accordance with those for the QT steels if referred to the effective grain size of fracture: · However, the size was a few times that of the ferrite grain. This means the grain refining is not yet fully utilized from the viewpoint of low temperature toughness. The anisotropy of· the impact properties and the annealing effect of highly dislocated structure on the toughness are also discussed in the present paper.IntroductionFor structural materials, both high strength and good toughness are required. Well-known approaches for obtaining better toughness for steels are as follows:1) Grain refining2) Addition of Ni3) Thin plate effect by cracking parallel to the rolling direction prior to crack propagation4) Contribution of metastable austenite.Among them, only the grain refining can raise the strength and improve the toughness. And it is well known that the finer the ferrite grain size, the lower the ductile-to-brittle transition temperature. For example, in the case of 0.11 carbon steel, the transition temperature decreases linearly to in d 1/2 [1 ]. However, these have been told in the regime of coarse grain size that is larger than 10 µm in diameter. There ~as .been no study dealing with the low temperature toughness in the regime of ultra-fine grain size with a diameter in the order of 1 µm."

Jan 1, 2000

By Charlie Brumbaugh

Antarctica with its diverse conditions such as severe cold, high winds, rock and ice structure and limited explosives available posed many obstacles. This paper will give an overall view of the methods used to overcome these obstacles on a daily basis on the highest, driest, coldest continent on earth.

Jan 1, 2000

By T. R. Ellis

The author attempted to concurrently apply the US Uniform Standards of Professional Appraisal Practice and the Australian VALMIN Code to a complex mineral property appraisal assignment. This led the author into many severe difficulties. These difficulties included the high standards needed in the work of others, and information and statements needed from the client. The exercise also highlighted many positive features of both documents. Some conflicts were found between the two documents. Implications and thoughts regarding the development of a set of US minerals appraisal standards are discussed.

Jan 1, 2000

By B. Mishra

The major waste product of the alkaline extraction of alumina from bauxite [Bayer Process] is known as red-mud. Approximately, a ton of red-mud is produced for every two tons of bauxite that is mined. The red-mud produced from Jamaican bauxite is rich in hematite, alumina and titanium oxide. It has been shown that over 90 wt. pct. alumina can be recovered from red-mud by soda-ash sintering and caustic leaching. Hematite can be carbothermically reduced with a degree of metallization of over 94 pct. At this stage, the product could be charged through the tuyeres in an iron blast furnace or smelted to produce pig iron. The mineralogical characteristics of the reduced product are not amenable to magnetic separation for iron recovery. The problems associated with the use of reduced red-mud as an alternative to direct-reduced iron [DRI] has also been discussed. Special attention has been paid to lower the alkali content of the reduced material. If smelted, the concentration of titanium oxide in the slag will be significantly high justifying its recovery by an acid-leach process. This paper describes the successful efforts of iron and alumina recovery.

Jan 1, 2000

The acoustic signals emitted from a laboratory-scale ball mill were used for the estimation of the comminution of two complex sulphide ores, viz. Merensky and UG2 ores from the Bushveld Igneous Complex in South Africa. The digital acoustic signals were transformed to power spectral densities that could be related to particle size distributions (-75 µm to 4000 µm) in the mill by use of continuum regression. This approach is more general than principal component regression methods or Kalman filtering used previously and resulted in significantly more accurate calibration in the case of the Merensky ore, where approximately 93.4% of the variance in the particle size distributions could be explained. With fewer data available, the variance in the particle size distributions in the UG2ore could be explained less accurately (82.4%), but still satisfactorily. In addition, smaller particle sizes (less than 300 µm) could be modelled more accurately in the case of the UG2 ore.

Jan 1, 2000

By R. J. Pruett

The Georgia kaolin district is the world’s largest producer of kaolin. Georgia production tripled from 2.87 Mt (3.17 million st) in 1968 to8.35 Mt (9.2 million st) in 1998. Development of the Georgia kaolin industry can be traced to the identification of the mineral resource, the adoption of innovative process technologies and the creation of markets for kaolin. Georgia kaolin is an abundant and high-quality resource that shows a range of advantageous properties. Technical developments in wet processing, delamination and calcination allowed production of high-value products. The use of kaolin pigments in the paper industry provided a market that absorbed the rapid growth in kaolin production.

Jan 1, 2000

By Jun Sugiyama, Hiroyuki Sano, Toshiharu Fujisawa, Hideki Takeuchi, Chikabiuni Yamauchi

"The solid .state electrotransport (SSE) is one of the most promising methods for the elimination of gaseous impurities from chemically active metals, such as rare earth metals. . In the present work, the SSE process was applied for the oxygen removal from praseodymium. The SSE factors, such as effective valence, were measured under the various temperatures, electric field intensities and initial oxygen contents, and the effects of those conditions on the SSE process were discussed. Furthermore, the solubility of oxygen in .solid praseodyillium was also measured·, by using the SSE method and metal-oxide equilibrium method.IntroductionWhen a direct current is passed through a solid alloy, not only electrons but also solute atoms are transported as charge carriers toward the anode or cathode. This phenomenon is referred to as an electrotransport or electromigration. The solid state electrotransport (SSE) is the application technique, based on this principle, to the pUrification of the solid metallic materials.Rare earth metals are used for various functional materials, such as magnetic, optical or electronic materials, therefore their high purity metals are required [l ,2]. However, rare earth metals are chemically active and have a strong affinity with gaseous elements (e.g. oxygen, nitrogen, hydrogen and carbon). In many cases, eliminating operations of gaseous elements have not been always made commercially, because these impurity elements could not be eliminated by usual treatments applied to the purification of ·common metals. As an alternative method, authors have proposed the· application of the SSE process to the elimination of gaseous impurities from rare earth metals. Investigations have been carried out on the yttrium-oxygen and neodymium-oxygen systems and the results were already reported[3,4]."

Jan 1, 2000

By D. Maurice, W. D. Riley, J. A. Hawk

"The increased penetration of wrought aluminum into the automotive market is stimulating a need to separate wrought aluminum from cast aluminum because of: a) the additional value of scrap wrought alloys and b) the increase in the total amount of aluminum automotive scrap will outstrip the demands of secondary aluminum foundry industry. The availability of clean fractions of wrought and cast aluminum and incidentally, a clean cast magnesium fraction will allow increased recycling of aluminum used in the automotive industry.Hot crushing has been tested previously and proposed as a means to separate cast from wrought alunrinum product. The underlying concept is that when a mixture of cast and wrought aluminum is thermally processed and then subjected to crushing action, differences in toughness between wrought and cast aluminum alloys will become more pronounced. Hence, it should be possible for conditions can be established such that the cast material fragments, while the wrought material, having lost much less of its toughness, merely deforms. The two types of product could then be separated by simple sizing methods.In this paper we report on the testing of this concept. We were unable to replicate the results which originally demonstrated proof of concept. Possible reasons for this are discussed, as well as the possibility that the original results may not be as desirable as the current results for subsequent sorting."

Jan 1, 2000

By M Revell

The paste fill system at BHP CanningtonÆs underground silver-lead-zinc mine is described. The first of its type in Australia, the paste fill system has been operational since December 1997. Key technical and operational learnings since the first underground stope was filled are presented. Issues addressed include plant performance, pipe wear and failure, automatic control, rheology and in situ performance.

Jan 1, 2000

By J. Moskowitz

Construction of the new JFK International Airport Light Rail System (LRS) began in 1998 with a pre-construction load test program. This $1.2 billion design-build project consists of approximately 13 kilometers of elevated twin rail. The elevated rail system is supported on nearly 500 piers requiring deep foundations. The presence of underlying compressible and liquefiable soils as well as space constraints precluded the use of large spread footings. In the 1980's the Port Authority undertook extensive testing to evaluate various piles and drilled shafts types. The LRS piling sub-contractor and the Geotechnical Engineer conducted additional tests for this project to identify the most cost effective deep foundation type. Candidate piles types included: Monotube®, Tapertube®, and closed ended pipe piles. The tapered pile types were found to be the most cost effective and the project utilized both the Monotube® and Tapertube® piles. This paper presents the results of the load test program and the issues related to pile driving induced vibrations and ground movement.

Jan 1, 2000

By Kensuke Sassa, Shigeo Asai, Norihisa Waki

"A new method for separating inclusions from a molten metal using a high magnetic field has been proposed. The principle of this method based on the magnetization force has been confirmed in experiments of separating intermetallic compounds imitating inclusions from molten Al-Si-Mn-Fe and Al-Si alloys. In order to measure a magnetic susceptibility, the Gouy's method has been so modified by using a super-conducting magnetic as to work in a high temperature up to 1473K. A theoretical expression for the magnetization force, which is indispensable to evaluate the magnetic susceptibility, has been derived. The magnetization forces acting on intermetallic compounds which were used in the magnetic separation were measured over the range of liquidous to solidous temperatures and the magnetic susceptibilities of the intermetallic compounds were obtained from measured magnetization forces by use of the theoretical expression.I. IntroductionRecent developments in the technology of super-conducting magnets have given rise to the circumstance that a high magnetic field over a relatively large space is readily available without liquid helium. Then, it has been found that a high magnetic field provides magnetic effects to nonmagnetic substances and various interesting phenomena have been reported in the broad science fields of physics, chemistry and biology1). ""A science related to a high magnetic field"" in which many fields are transversally viewed from the standpoint of a high magnetic field2 ) is going to be established. In particular, new phenomena and functions brought by the science related to a high magnetic field are also useful for Material Science and Engineering so that the creation of Materials Science and Engineering related to a high magnetic field"" has been conceived 3).Now, when a substance regardless of being magnetic or nonmagnetic is put in a magnetic field, it feels a magnetization force, which is familiar to such a force that a magnet attracts iron. The force is in proportion to the product of magnetic field strength, its gradient and susceptibility so that a precipitated substance can be separated from a molten metal based on the difference between susceptibilities of a substance and a melt. This is a basic principle of the magnetic separation. So far the application of the magnetic separation has been limited to the separation of ferromagnetic substances from a nonmagnetic medium. A high magnetic field, however, has enabled to separate nonmagnetic substances from a nonmagnetic medium.In this study, a new method to separate inclusions from a molten metal using a high magnetic field has been proposed. The principle of the method was verified by experimental works and the feasibility on the elimination of inclusions in steelmaking processes has been studied"

Jan 1, 2000

By D. A. Horne, V. R. Daiga

Certain steel mill wastes contain significant amounts of zinc oxide due to the use of galvanized scrap during the steel making process. Typically electric arc furnace (EAF), and basic oxygen process (BOP) flue dusts contain 20 to 30% zinc oxide and 40 to 50% iron oxides, along with smaller quantities of lead and cadmium. These materials can be recovered from the flue dusts by using a proven rotary hearth furnace (RHF) process. By-products of the recycling operation include a crude zinc oxide fume, which is captured in a baghouse filtering system, and sponge iron that may be recycled into the steel making operation. Crude zinc oxide properties plus the operating experience from two commercial RHF installations utilizing MR&E's DRyIron™ Process will be presented.

Jan 1, 2000

By Robert Lee, Jay Rodgers, Kirk Whitaker

The time domain during which an explosive detonates and causes rock to fragment and displace is on the order of tens of milliseconds. Because of this, the dynamic processes that occur during this time frame often become a source of confusion when trying to analyze the performance of explosive products in decked blast designs. As an illustration, the authors have experimentally examined explosives malfunction in decked blasts through state-of-the-art measurement techniques. The interaction of explosive products and blast geometry was examined in detail using the analysis of a series of decked blastholes. Explosive and initiator malfunction in decked blasts is often considered to be entirely the result of insufficient inert decking material, however, it is shown that rock properties and dynamic burden conditions may have a significant impact on decking performance. The successful application of deck-blasting technique for control of ground vibration amplitude relies on an understanding of the true dynamic performance of the blasthole.

Jan 1, 2000

By Normand Tassé

Reactive barriers, which consume oxygen, are prospective though unconventional alternatives to physical barriers for Acid Mine Drainage prevention. However, a reactive barrier implies a problem of duration. Pore gases were analysed in several wood waste piles in order to understand the factors which control wood degradation and help to determine the effective life span of such a cover. Long term efficiency seems to strongly depend on the degree of water saturation at the bottom of the pile, likely because the development of a microbial biomass in such an environment helps to keep the amounts of nutriments and readily metabolizable organic substrates at a high level, which in turn promotes oxygen consumption.

Jan 1, 2000

By A. Hammel

This paper summarizes indigenous mining methods used to collectmetal ores in pre-colonial southern Africa, south of 15°S. These methods, for the purposes of discussion, are divided into sections inorder of increasing organizational complexity, from scavenging,which only required basic equipment and a relatively minimal division of labour, to underground mines, which necessitated complex planning to overcome obstacles such as the need for illumination and ventilation. Examples concerning the pre-colonial exploitation of iron, copper, tin, and gold have been taken from the archaeological literature. This review paper provides an introduction to the technology that was available to and used by miners in the past, illuminates some of the factors limiting their operations, and supports the claim to the indigenous nature of this activity

Jan 1, 2000

By E. J. Peuraniemi

Oxidation of chalcopyrite concentrate and two low-iron copper mattes were studied using a laboratory scale laminar-flow furnace simulating the phenomena taking place in different zones of the reaction shaft of a flash smelting furnace. In the experiments, screened fractions were fed into the furnace and sampled after short reaction time intervals by quenching them into a water film. Experimental conditions included temperatures of 1100 and 1300°C with reaction gas oxygen contents from 21 to 75 vol.%. Samples were analysed chemically for Cu, Fe and S to define removal rate of sulphur. Optical and scanning electron microscopy with EDS-analyser were used to examine the samples. In this paper, oxidation kinetics as well as ignition of particles are discussed. Changes in particle morphology, size, and composition are viewed to closely define the proceeding of the oxidation, and, consequently, to compose a detailed model of dust formation and reaction mechanisms. Data obtained in the experiments broadens the knowledge of physical and chemical phenomena in flash reactions and serves as reference for computer simulations.

Jan 1, 2000

By R. Haecker, S. Gupta, P. Somasundaran

Rock disintegration processes are usually inefficient and costly operations in mineral beneficiation, mine development and oil well preparations. Thus, there is a strong need for improving the energy efficiency of unit operations such as drilling and comminution. The effects of selected cations and anions on drilling efficiency in a hard rock formation (Dakota Sandstone) were studied. The zeta potentials and the tensile strengths of the drilled samples were measured under similar chemical conditions. The chemicals tested included MgCl2, Na2CO3, AlCl3, NaCl and Dodecylammonium chloride. The results indicated that drilling rates can be enhanced or retarded depending on chemical conditions such as the solution pH and the type and concentration of reagents. Drilling data are correlated with mechanical (tensile strength) and interfacial (zeta potential) properties of the rock formation. The mechanisms involved are discussed in light of Rehbinder's and Westwood's theories.

Jan 1, 2000

The purpose of this paper is to look at the costs of tailings disposal, and in particular the comparative costs of different disposal methods in different situations. Costs are often the hidden design parameter. We know that they are important but sometimes feel that it is not very respectable to talk about them in public. It is better from a public relations point of view for it to appear that the decision-making process is driven by environmental factors or best practice rather than looking for the cheapest option. But this presumes that the two are mutually exclusive and this need not be so. These issues are discussed later in the paper. It is also commonplace for the scale of the mining operation to change with time, typically involving increased throughput rates and total tonnage. New ideas in tailings disposal make their appearance. The regulatory attitude can change. Having made a decision about the disposal method at the time of original feasibility study and design it is easy to suppose that the mine is æstuck with itÆ. But that also need not necessarily be so. Careful costing of options may reveal that a switch in method could be cheaper in the long run. The designer will often tend to think in terms of initial earthworks and site development costs. Aspects of power consumption, labour, and periodic campaigns to move tailings pipelines and carry out embankment raises are either overlooked or not given the same emphasis. This can distort the evaluation process. It is productive to think in terms of dollars or cents per tonne as a basis of comparison, not just the total sums. Tailings disposal can cost from as little as 10 - 20 ó/t to over $1.00/t which is a big range. There may be good and unavoidable reasons for the high figure but there would need to be to justify being so far over the industry average. At the same time, mining and processing costs, at least for gold, are around $15 - 20/t. Viewed from this perspective tailings disposal will always be a relatively small component of the annual budget.

Jan 1, 2000

AustraliaÆs strong position as an aluminium producer and potential magnesium producer combined with rapid market growth in the automotive industry, proximity to Asia and other natural advantages points to considerable opportunity for downstream processing and manufacture with light metals in this country. Development of a vertically integrated light metals industry in Australia needs to be pursued with vigour, as does the continued development of global strategic alliances through the value adding chain.

Jan 1, 2000