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By M. H. H. Mahmoud, T. A. El-Barbary, E. A. Abdel Aal, I. A. Ibrahim, A. K. Ismail

Fertilizer-grade phosphoric acid with a P2O5 concentration of 50% should contain less than 1.5% Fe2O3, otherwise, the P2O5 water solubility of the fertilizers prepared from high-iron acids will be low. High-iron Egyptian phosphate concentrates fromAbu-Tartur and Sebaiya- West were leached with sulfuric acid and recycled phosphoric acid to produce 50%-P2O5 phosphoric acids containing 4.0% and 2.7% Fe2O3, respectively. The high iron contents were reduced to the industrially accepted limit of 1.5% Fe2O3 by precipitation with potassium sulfate. The factors affecting the effi¬ciency of the precipitation process, e.g., temperature, time and K2O/Fe2O3 ratio, were systematically studied, and the optimum conditions were achieved. The clarification of the prepared phosphoric acid from iron-containing sludges was also investigated by varying the time and temperature. The utilization of the separated sludges as fertilizer and recovery of P205 by pulping in water were also evaluated.

Jan 1, 2000

By J Player

Big Bell Mine started experiencing relatively large mining related seismic events, and accompanying rockbursts, from February 1999. Twelve rockbursts damaged access development from February 1999 to June 2000, with severe damage extending for up to 100 m along footwall drives. Five seismic events associated with the rockbursts were recorded by the AGSO, measuring 1.9, 2.2, 1.7, 2.4 and 2.2 on the Richter scale. These events affected 485 and 460 footwall drives in August and November 1999 and 535 footwall drive in June 2000 (drive level nomenclature is equivalent to the depth below surface and RL). After the third event (July 1999) it was apparent that the seismicity was not a once-off phenomenon. This (sudden) onset of seismicity required management to implement a series of precautionary measures:to ensure the safety of the workforce, to maintain continuity of production, and to reduce rockburst damage rehabilitation. The measures included extended re-entry periods and exclusion zones in high-risk areas, improved rockburst resistant support systems in areas prone to damaging seismic activity and improved support systems in areas prone to shakedown damage. A full-scale minewide ISS seismic system was ordered in October 1999 and commissioned in February 2000. A portable eight-channel CSIR-Miningtek system was installed at short notice as an interim measure in August 1999. This CSIR system covered the northern producing stopes, where the majority of the rockbursts had occurred. The objective of the seismic monitoring was to monitor relative activity and to determine trends with regards to time and location. MAP3D numerical modelling was used to investigate the relationship between seismicity and various combinations of stress components to assess the relative seismic risk in both current and proposed working areas. This information is used to determine where and at what stage in the mining cycle the rockburst resistant support is required. Analysis of the seismicity has determined two distinct modes of seismicity û small-scale localised, high frequency events in high stress areas and larger events related to shear along previously intact foliation surfaces. This paper includes a summary of the seismic history, seismic data analysis, support system design, mine design adjustments and management action to minimise the effects of seismic activity at Big Bell Mine.

Jan 1, 2000

By Lewis Gordon, Alan Morrow, Aundra Nix

At the ASARCO Mission Mill, a multivariable, predictive controller was used to optimize parallel grinding circuits, improving throughput and product size. Using a dynamic model of the grinding circuit developed from on-line testing the software manipulates 4 variables to control 14 quality and constraint variables in each circuit. Traditionally, model-based control in grinding is difficult due to ore changes. This is addressed via a novel method to predict mill overload and automatic model switching.

Jan 1, 2000

By Paul Morrison

The paper describes the design process, trial testing and contract pile installation of 772 pre­cast concrete piles at a site in Surrey, South East England. Recommendations on how to improve the design, construction trials and main contract piling phases of the project are made. The building layout is shown in Figure 1 and is comprised of a central circulation area with five office wings radiating out from its southern side (only three of these wings were constructed in Phase 1 of the project). Approximately 60% of the circulation area and one office wing were built with a single level basement. The basement was constructed "bottom-up" in open cut with the void between the basement walls and the cut slope being back-filled with compacted site won soil above a perimeter drainage system at basement slab level. The building has up to 3 stories above basement level and is a reinforced concrete structure. The client for the project is Pfizer Ltd. Pfizer Ltd was represented on site by Laing Project Management (Laing). The consulting engineer was Ove Arup and Partners (Arup) while the piling contractor was Roger Bullivant Ltd (RBL).

Jan 1, 2000

Magnetic separation using particle rotation in a continuously rotating magnetic field offers very low to insignificant non-magnetic particle entrapment, and precise magnetic fractions. The precision of rotating magnetic field separations makes the method ideal for dry laboratory magnetic analysis work, where conventional laboratory magnetic separators can give misleading or uncertain data. The very low entrapment characteristics make the method ideal for entrapment-critical separations within the diamond exploration industry or in gold recovery. A single wet rotating magnetic field (RMF) unit is able to achieve a cleaner separation (at similar or better recovery rates) than a three-stage separation using conventional wet drum separators. The RMF separator is able to work effectively at particle sizes below 50 ¦m, and RMF separation could, at least in theory, be used down to single domain particle sizes. Rotating magnetic field (RMF) separation is carried out by magnetically spinning the particles at frequencies up to 300 Hz. The particle rotation itself may be used to roll the particles out of the separator. At angular velocities of 100 Hz, magnetic flocs are unable to form, and any entrapped particles are energetically expelled. In an RMF separator, the outer drum can be stationary while the inner magnet rotor rotates, allowing, for example, the injection of cleaning water underneath the separating magnetics to help remove small suspended non-magnetic particles.

Jan 1, 2000

By Kazuyoshi Sato, Keizo Uematsu, Nozomu Uchida

"Confocal fluorescence scanning laser microscope was applied to characterize the surface flaw of ceramics in great detail. A high potential -of the characterization technique is presented first. Then the technique was applied to clarify the relationship between the flexural strength of ceramics and the surface flaw. This kind of direct information of surface flaw should be essential for the fundamental study in this area, but has been lacking. The examination revealed that large defects are present on the machined surface of ceramics. Their size is consistent to the flexural strength measured on the material. The characterization tool was also applied to examine the formation of surface flaw in machining of ceramics.IntroductionClarification of fracture origin should be the starting point in the study on strength in ceramics. However, this task has been extremely difficult in some ceramics, such as an alumina ceramics. It may break from both internal and surface flaws. The former should reflect the quality of production process and the latter the machining. Examination of surface flaws should be very important for developing a better machining method for ceramics. The knowledge may valuable for establishing a better production process also.ExperimentAlumina Referceram (JFCC) was used as samples. They are cut to size of 3x4x40mm, and the surfaces were ground to meet the requirements of testing method for flexural strength of fine ceramics, JIS R 1601. They were soaked in an aqueous solution of fluorescence dye and evacuated with an aspirator for an hour to allow the solution penetrate into surface flaws. After excessive solution remained on the surface was removed by gentle washing, the specimens were dried at 120°C for 48 hours. The 4 point bending mode was applied to measure the fracture strength."

Jan 1, 2000

By lchiro Aoi, Hideo Nakae, Makoto Yoshida, Makoto Ishino

"The influence 6f gravity on the microstructure of unidirectionally solidified Cu-Pb monotectic, Ag-Si and Fe-C eutectic alloys is studied. In order to examine the influence of gravity in a lg environment, both the upward (opposite to direction of gravity) and downward (direction of gravity) unidirectional solidifications are carried out. The results are as follows: (1) For the upward solidified Ag-Si eutectic alloy, the eutectic Si continuously grows. On the other hand, in the downward solidified Ag-Si alloy, the Si grows discontinuously and disperses into the ex-Ag matrix. (2) No morphological difference in the eutectic growth is observed between the upward and downward solidified Fe-C eutectic alloys. (3) In the case of the upward solidified Cu-Pb monotectic alloy, a banded structure, which consists of Pb-rich layers and Cu-rich layers, is observed. However, such a banded structure -is not observed in the downward specimen. (4) The banded structure is not found in the upward solidified Cu-Pb-0.05 mass % Al and Cu-Pb-0.1 mass % Al alloys. In the Cu-Pb-0.05 mass% Al alloy, a fibrous -L 2 phase grows continuously parallel to the growth direction at low growth rate. Only 500 mass ppm addition of aluminum induces the morphological change of the monotectic L2 phase.IntroductionThe influence of gravity on the solidification of eutectic and monotectic alloys has been investigated in microgravity environments [l-9]. The purpose of these studies was to obtain a homogeneous microstructure of eutectic or monotectic alloys, most of which alloys tend to solidify with macro-segregation under gravity. However, in most of the previous experiments, e.g., in free fall systems, in aircraft or in space laboratories, the growth rate was too high to realize a planar solid/liquid interface. This would be due to the limited time for solidification. Thus, it was difficult to examine the influence of gravity on the planar coupled growth of the eutectic or monotectic alloy. In this study, both the downward U.D.S. (unidirectional solidification by gravity) and upward U.D.S. (opposite direction to gravity) are carried out in order to examine the influence of gravity on the coupled growth in a lg environment [l0, 11]. In the case of the downward U.D.S. using the current Bridgman method, the molten alloy must be confined between the crucible and the solid."

Jan 1, 2000

The primary objective of designing, constructing, commissioning and operating a technically and economically viable processing plant cannot be achieved without a rigorous scientific understanding of the chemical principles underlying every facet of the total flowsheet, from feed preparation through to a final product. Having developed a thorough understanding of the chemistry involved, the next challenge is to match the innovative advances with the necessary engineering skills. In simple terms, there is little point in proposing a new processing route if it is not possible or practical to design, construct, commission and operate it. Thus to achieve our objective, it is necessary that processing facilities that are both smarter and cheaper be developed. This presentation highlights a number of the more significant research and development activities that are designed to facilitate the conversion of a smart idea into a real process. Following a brief discussion of several examples, the presentation concludes with the observation that a pro-active team approach is almost mandatory in order to achieve an acceptable outcome.

Jan 1, 2000

By Keizo Uematsu, Satoshi Tanaka, Nozomu Uchida, Yutaka Saito

"Effect of moisture content must be fully understood for controlling the granule compaction of ceramics. It changes the mechanical behavior of spray-dried granules applied for compaction process, and governs the structure and properties of .ceramics. To understand the time-dependent change in processing, the kinetics was examined for change of moisture content for granules placed in a die and the pressed compacts also. The results were explained in terms of apparent moisture diffusion coefficients. They varied non-linearly with the PVA content in the granules. The results were explained through the non-uniform PVA distribution in the granules.IntroductionMoisture must be controlled in compaction process to produce the green compacts having uniform structure. It affects glass transition temperature of binder and thus the deformation behavior of powder granules under an applied stress. Several studies [1-7] have clarified the effect of moisture content on the compaction behavior of granules and the structure of resultant compacts for both die pressing and cold isostatic pressing (CIP) of pre-formed compacts. In these studies, the moisture contents in the system were equilibrated with the humidity in the atmosphere before compaction. In practice, however, the moisture content in the system may vary with time if the relative humidity of surrounding atmosphere is different from what the granules were equilibrated previously. This is very likely case in real production processes. However, the kinetics of moisture change in the granules as well as in the pre-formed powder compacts have not been well studied. For controlling the microstructure in a system, it is necessary to fully understand the kinetics of moisture change and its relevance to packing structure of powders."

Jan 1, 2000

By Erik A. Munroe, Nelia W. Dunbar, Virginia T. McLemore

In New Mexico, there are at least 100,000 abandoned mine waste rock piles with widely ranging geochemical and mineralogical compositions. A geochemical and mineralogical study was implemented for five waste rock piles, some which contained sulfides, in the Hillsborn Mining District. Chemical and physical characteristics of mineral grains and their secondary mineral oxidation rinds were examined with the electron microprobe. Pyrite and chalcopyrite appear to be the most reactive to oxidizing conditions. Clays, iron oxide, iron hydroxide, iron sulfate, and primary texture rinds exist in the waste rock piles analyzed.

Jan 1, 2000

By K. Ohmori, K. Takeya, S. Yoshizawa, A. Kawamoto, T. Ishikawa

"High performance Sm2Fe17N3 magnet powder is developed nitriding Sm2Fe17 alloy that 'is made using a reduction and diffusion method. Typical remanence, coercivity and maximum energy product of the fine powder are 1.40 T, 1.13 T and 323 kJ/m3, respectively. Decreasing samarium content, oxygen content and the amount of a-Fe are found to be the important factors to realize high-energy product.High performance injection molded Sm2Fe17N3 anisotropic magnet is also developed using the powder and an original binder system developed in order to mold at low temperature. Typical remanence, coercivity and maximum energy product obtained are 0.77 T, 0.78 T and 103 kJ/m3, respectively in the density of 4.77 Mg/m3The temperature coefficient of remanence is -0.07 %/K and that of coercivity is -0.54.%/K. The initial irreversible flux loss of the magnet that has a permeance of two is -5 % at 100 °C and the irreversible .flux loss of it is -4.4 % exposing it at 80 °C for 1000h.IntroductionSm2Fe17N3 alloy powder is expected to be very useful for a bonded magnet. The reasons are as follows. The magnetization is as large as the Nd2Fe14B alloy. Curie temperature is even higher than the alloy. The uni-axial anisotropy is comparatively higher than the alloy. Consequently it is possible to obtain high coercivity after just milling the powder and therefore possible to obtain high-energy product in a bonded magnet as it is realized in the SmCo5 bonded magnet. On the other hand, sintering is difficult because it will be decomposed into samarium nitride and a-Fe when heating it up to 500°C:"

Jan 1, 2000

By J. B. Vander Sande, I. G. Solórzano, B. S. You, P. M. Jardim, W. W. Park

"Alloys with six different compositions in the system Mg-Ca-Zn were produced by melt spinning. The aging behavior of alloys was investigated by measuring the changes in microhardness after isochronal aging and the microstructure was analyzed by means of transmission electron microscopy (TEM), energy dispersive X-ray spectrometry (EDS), scanning transmission electron microscopy (STEM) and scanning electron microscopy (SEM). All six compositions in the as-solidified condition show a difference in microstructure between the wheel contact side (zone A) and the free surface side (zone B) as a result of the differences in the solidification rate across the ribbons. One of the alloys (Mg-l.5wt%Ca-6wt%Zn) was chosen to be more deeply investigated in this work as it exhibited grain boundary films and an age hardening behavior was produced in that alloy.IntroductionMagnesium is the lightest of all the commonly used metals, and very attractive for applications in transportation. It also has a number of other desirable features, including good ductility, better damping characteristics than aluminum, and excellent castability. However, there are some negative features, such as high reactivity in the molten state, inferior fatigue and creep resistance as compared to aluminum, poor corrosion resistance and high production cost.In recent years there has been a significant increase in magnesium use as a structural material. These structural applications include aerospace, automotive and nuclear industries as well as appliances and sporting goods (1 ). According to reports on Mg-Zn alloys, the addition of Zn (2) in magnesium increased strength. Also, since the maximum solubility of Zn in magnesium is 6.2wt%, a considerable amount of Zn can be retained in solid solution in magnesium alloys by rapid solidification. In addition, Ca is known (3) to be one of the most potent alloying elements for refining the microstructure and precipitates in magnesium alloys, and also to improve mechanical strength and corrosion resistance."

Jan 1, 2000

Milling circuits are known to be difficult to control. In order to address these difficulties, it was decided to develop and test a model predictive controller (MPC) for a milling circuit. A milling simulator was written using Microsoft Visual C++ and used to design and test the MPC controller. Due to the large number of tuning parameters in a controller of this type, an optimizing algorithm was written that automatically tunes the controller. Good, robust control was obtained when the controller was tuned using this algorithm. Control was further improved by combining feedback and feed forward control and by using quadratic programming in the MPC algorithm. The movement of the manipulated variables was reduced by using a novel technique that allows the controlled variable to vary within a specified region around the set point. An optimiser controller was also successfully implemented to control the circuit at its maximum throughput.

Jan 1, 2000

By S. Finsterle, R. C. Trautz

We performed numerical modeling studies to investigate water seepage into underground openings excavated in unsaturated fractured rock. Water seepage is a key factor affecting the performance of a nuclear waste repository such as the one proposed at Yucca Mountain, Nevada. The amount of water dripping into an underground opening depends on the connectivity and permeability of the fracture network as well as on the capillarity of individual fractures intersecting the opening. We developed a high-resolution numerical model of an unsaturated fracture network and examined the appropriateness of seepage predictions using a fracture-continuum model. Model calibrations to liquid-release tests performed at Yucca Mountain are also discussed.

Jan 1, 2000

The current methodology to design stope support systems in South African gold and platinum mines is based upon the tributary area concept. The discontinuous nature of the hangingwall rock is not adequately addressed, and mechanisms leading to rock mass failures between adjacent support units are poorly understood. The work reported here aims to formulate a basis for quantifying support mechanisms and gain insights into the influence of rock discontinuities on stable hangingwall spans. Numerical models are used to qualitatively investigate the stress transfer from the support units to the discontinuous hangingwall. Stable hangingwall spans are quantified by considering two failure mechanisms, namely (i) beam buckling, and (ii) shear failure due to slip at the abutments. The output of the proposed design methodology is appropriate site specific support spacing, based on discontinuity spacing and orientation. The method is particularly suited to mines at intermediate and great depth, where typically the hangingwall is highly discontinuous due to face parallel mining induced fractures. Results of parametric studies show that with increasing in situ compressive hangingwall stress, beam thickness and friction angle, hangingwall stability is increased, leading to wider stable hangingwall spans between adjacent support units.

Jan 1, 2000

By Nicholas Kyriazi, John P. Shubilla

The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory, has undertaken a study to determine how well self-contained self-rescuers (SCSRs), deployed in accordance with Federal regulations (30 CFR 75.1714), hold up in the underground environment with regard to both physical damage and aging. This report presents findings regarding laboratory-tested SCSRs in the sixth phase of testing from mid-1996 to early 1998. The SCSRs were tested on human subjects and on a breathing and metabolic simulator. These results indicate that most of the apparatus, if they pass their inspection criteria, perform satisfactorily. However, the deployed CSE SR-100s exhibited significantly higher inhaled CO2 levels than new units, as in the previous phase. This will cause higher ventilation rates in most users, which will, in turn, result in higher breathing pressures, possibly causing users to prematurely remove the apparatus. CSE Corp. has developed a noise test that can identify apparatus suffering from chemical-bed degradation causing the early CO2 breakthrough. This test was added to the inspection criteria for the SR-100. In addition, several of the MSA Portal-Packs that passed their inspection criteria were found to have KO2 dust in their mouthpieces. Further investigations by NIOSH and the Mine Safety and Health Administration confirmed these findings, which resulted in the decertification of the apparatus and their removal from service.

Jan 1, 2000

By Antti Roine

Sulfidic zinc concentrates are usually roasted in a fluidized bed furnace into sulfur-free oxide form. Metallic zinc is produced from this oxidic calcine using hydrometallurgical leaching, solution purification and electrowinning stages. The roasting step is necessary because zinc oxides are easier to dissolve using traditional leaching methods than zinc sulfides. The Kokkola Zinc smelter uses various types of zinc concentrates and secondary materials as feed mixture. This makes it difficult to find optimum process parameters for the roaster when the composition and particle size distribution of the feed mixture varies even on a daily basis. Certain conditions may even cause difficult accretion problems or increase the amount of calcine in the process off-gas line excessively. A thermochemical heat and material balance model was developed for process advisor, in order to estimate the effects of different process parameters (temperature, process air coefficient, concentrate feed, oxygen enrichment, water feed, etc.) on the heat balance, roasting temperature and calcine composition. This model was constructed using the heat balance module of HSC Chemistry 4.0 software. The prevailing chemical compounds in the concentrate and calcine were verified using mineralogical analyses and equilibrium calculations. The roasting process seems to operate near chemical equilibrium conditions, if the behavior of the main components is considered. This paper describes briefly the basic principles of the calculation model and outlines the results with several diagrams and discussion. The calculated results were in reasonable agreement with the recent process air oxygen enrichment and water feed test campaigns carried out at Kokkola in 1999.

Jan 1, 2000

By T A. Helms, P Gottlieb, S E, R Bateman

In response to the ever-increasing challenges facing the modern gold mining industry and the need for improved gold recoveries within all processing streams, CSIRO has upgraded its latest automated mineralogical analysis system, QemSCAN (formerly QEM*SEM), with special purpose hardware that speeds up the location and measurement of precious metal-bearing phases. By rapidly scanning the surface of polished blocks, and accepting only fields that contain the minerals of interest, QemSCAN is able to find, map, and quantify target minerals in extreme detail. Phase identification and quantification is achieved by placing a grid of points over the target particle and collecting X-ray information at each analysis point. The resulting mineral maps provide the metallurgist with a complete textural description of all gold-bearing phases within the product measured, together with quantification of the gold phases in terms of their modal abundance, particle size, mineral associations, relative contributions to gold deportment and liberation characteristics. Examples are presented which illustrate how QemSCAN is able to find and quantify gold-bearing phases within low-grade ores from the Super Pit, Kalgoorlie. This work is the result of a collaborative project between Kalgoorlie Consolidated Gold Mines (KCGM), CSIRO Minerals, and the University of Queensland, and is on-going.

Jan 1, 2000

By Kim A. Lapakko, David A. Antonson, Jon R. Wagner

This study examined the potential of mixing rotary kiln fines (RK fines), a waste product generated when limestone is converted to lime (CaO), with acid producing mine waste to provide 1) short-term mitigation by neutralizing acid produced by iron sulfide oxidation and 2) long-term mitigation by facilitating the passivation of iron sulfide mineral surfaces. Five loadings of RK fines were mixed with 75 g of Duluth Complex rock to produce neutralization potential (NP) added: acid potential (AP) quotients of 0,0.11,0.22,0.66 and 1.1. The mixtures were subjected to wet-dry cycling laboratory testing for 585 weeks. The rock alone produced acidic drainage, with pH decreasing below 4 after about 20 weeks of reaction and ultimately reaching the approximate range of 3.3 to 3.5; sulfate release did not decrease over time. The RK fines elevated pH and inhibited sulfate release for time periods which increased with the mass of RK fines present. The pH of drainage from the 0.11 quotient (NP added1AP) loading decreased below 6.0 after 75 weeks of dissolution and decreased to 3.6 after 117 weeks, at which time the reactor was terminated. The duplicate 0.22 quotient loadings of RK fines decreased below 6.0 after 95 and 170 weeks. The former was terminated after 117 weeks, and the latter reached a minimum pH of 2.8 after 512 weeks. Drainage pH from the 0.66 quotient decreased below 6 after 581 weeks. For the drainages which acidified, the cumulative calcium release prior to pH decreasing below 6.0 was 92 to 103 percent of that initially present as calcium carbonateloxide in the RK fines. The pH of drainage from the 1.1 quotient typically remained above 8.0 throughout the period of record. Sulfate concentrations in the drainages decreased while the neutralizing fraction of the RK fines was present, but increased after this fraction was depleted.

Jan 1, 2000

By J. Nielen van der Merwe

The effects of horizontal stress in coal mine roofs in South Africa did not receive the attention it deserved for several years, but now there is a danger that it may be over emphasized. A number of phenomena that are ascribed to elevated levels of horizontal stress, are shown to he explained by fundamental considerations. The stress concentration caused by the creation of an opening in rock and the beam effects in a stratified roof are briefly reviewed It is shown that guttering can be present without high horizontal stress, depending on the nature of the roof material. Three examples from practice are presented where horizontal stress was initially erroneously believed to be responsible for roof collapses A comprehensive program of roof displacement monitoring in South Africa yielded results that are compatible with gravity loading on roof beams without the assistance of horizontal stress. It is also shown that one of the diagrams that are used to explain guttering as a result of horizontal stress is misleading The over emphasis on horizontal stress may obscure the real causes of roof instability, resulting in ineffective remedial action to be taken by mine operators.

Jan 1, 2000