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By R. Simon, L. Yarborough

This paper presents a correlation for predicting the critical pressures of gas-solvent-reservoir oil systems of the type encountered in gas and solvent injection processes. Experimental data from 14 systems were used to develop the correlation which expresses critical pressure as a function of composition, C7+ mol weight, and C7+ characterization factor. Critical pressures predicted by the correlation for the 14 gas-solvent-reservoir oil systems have an average deviation of 2.8 per cent of the experimental values. The correlation war used to study a wide variety of other hydrocarbon mixtures reported in the literature whose critical conditions are in the range of interest in oil recovery work (100 to 280F and 2,000 to 6,000 psia). Critical pressures predicted by the correlation had an average deviation, expressed as per cent of experimental value, of 5 per cent for 20 miscellaneous mixtures from the literature, and 6.4 per cent for I7 methane-butane-decane mixtures reported by Sage and Lucey. INTRODUCTION Predicting critical points of hydrocarbon mixtures is an important part of phase behavior calculations. If the critical point can be predicted for a specific mixture, the separation between the bubble-point and dew-point regions will be defined, and physical properties of the mixture can be calculated by using the principle of corresponding states. Numerous correlations for predicting critical points of hydrocarbon mixtures have been published. Six of these correlationsl-8 were for light hydrocarbons, and two correlations7,8 ere for high boiling-point petroleum distillates. Organick9 And Eilerts" presented correlations which combined the published data from both light and heavy mixtures, and these correlations became the only available methods for predicting critical pressures for wide boiling range mixtures. In the course of the authors' work on secondary recovery by gas and solvent injection, experimental data were obtained for 14 mixtures of dry gas, ethane-propane-butane solvents, and various reservoir oils. The critical pressures and critical temperatures of these gas-solvent-reservoir oil systems were in the range of 1,900 to 4,800 psia and 180 to 265F. The critical pressures predicted for the 14 mixtures by the correlations of Organick and Eilerts had an average deviation from the measured values of about 13 per cent. The authors felt that it was necessary to develop a better correlation for engineering calculations and the resultant correlation, which is presented on Figs. 1 and 2, predicts the critical pressures of the 14 mixtures with an average deviation of 2.8 per cent. The validity of the correlation was tested by applying the correlation to other hydrocarbon mixtures reported in the literature. This subject is discussed later in the paper. The authors feel that there is also a need for an improved critical temperature correlation for gas-solvent-reservoir oil systems. However, developing a critical temperature correlation is a significant study in itself and is not included in this paper. EXPERIMENTAL DATA The compositions and critical points obtained by the authors for 14 gas-solvent-reservoir oil mixtures are shown on Table 1. The methane concentrations in these mixtures varied from 20 to 63 mol per cent. The intermediate hydrocarbon group, consisting of ethane, propane, and butane, varied from 20 to 64 mol per cent, and the concentration of the C,, fraction from 10 to 20 mol per cent. The physical properties of the C,, fraction covered the range from light, paraffinic, nonasphaltic (Mixtures 5, 6, 7, 8, 9 and 10) to heavy, aromatic, and asphaltic (Mixtures 13 and 14).

By Falconer A. J

Two magnetic parameters are proposed as a basis for the assessment of ironsands beneficiation. The parameters are deter- mined for raw sand prior to dredging and for magnetic separator head feed over a production period of five months. The relationships between these parameters and the performance of the magnetic separators are examined to establish the value of magnetic assessment compared with the traditional soluble iron assay method. The results illustrate that the first parameter, true magnetic fraction (TMF), has a value superior to that of soluble iron when relating raw sand grade calculated by tri- angulation to magnet performance. In terms of the relationship between magnet head feed grade and magnet performance, TMF and soluble iron perform equally as assessment parameters. For the ironsands mined during the five month period, the second magnetic assessment parameter, composite fraction (CR), is shown to merely reflect TMF and offers no additional information for assess- Ment. Conclusions are that true magnetic fraction has many advantages over soluble iron in terms of time and cost of determination and that it is a meaningful and reliable parameter upon which to base all calculations relating to the mining and beneficiation of ironsands.

Jan 1, 1980

By Robert C. Bacon

The first commercial installation of the Dashaveyor has recently been completed at the White Pine Mine in Northern Michigan. After four years of development work, including prototype testing, and pilot plant operation, this new and unique system is being tested under operational conditions. Many of you may be familiar with the concept through numerous articles which have appeared in the technical press. But this discussion of the system will be simplified and less time consuming with the presentation of a portion of a film showing the Dashaveyor in actual operation. After the movie, I will show some slides which will supplement and clarify it and hopefully lay the basis for questions you will undoubtedly wish to ask.

Jan 1, 1968

By L. Louis

High resolution X-ray computed tomography imaging (with voxel size 48 µm) was conducted on various sandstone samples with different initial degrees of heterogeneity. All samples were imaged intact, and some after having developed localized compaction features in conventional triaxial experiments at high confining pressure, i.e. in the shear enhanced compaction domain (Wong et al., 1997). Our analysis of heterogeneity from X-ray CT data is based on the use of the coefficient of variation d =s /µ (s being the standard deviation and µ the average value). The coefficient of variation was shown by Otani et al. (2005) to be a convenient indicator of material heterogeneity in CT images of experimentally deformed sand piles. The authors reported differences in d before and after their experiments, and interpreted these differences as the effect of grain crushing resulting in more even material distribution within the voxels, hence in lower d values. The same concept was used by Louis et al. (2006) to image contrasts in d values throughout a volume of rock that had developed compaction bands in triaxial laboratory testing, knowing that the bands that had formed could be identified by visual inspection but not on the X-ray CT images. This study resulted in a radically enhanced image of the discrete compacted zones within the CT-scan series, whereby more deformed areas showed relatively low values of coefficient of variation due to grain crushing and pore collapse, as compared to nominally undeformed areas.

May 1, 2009

By Jochen Petersen, David G. Dixon

"Although heap leaching may be perceived as a somewhat low-tech route for the extraction of low-grade minerals, the underlying physical, chemical and biological processes are in fact extremely complex. There has been increased interest in heap leaching of sulphide minerals in recent years with the advent of controlled bio-heap leaching, and the need to mine more marginal ore deposits.A detailed investigation into the dynamics of heap leach processes has provided much insight into the underlying complexities, and has led to the development of a sophisticated modelling tool, HeapSim. Some of the sub-processes that are modelled include mineral kinetics, particle size effects, bacterial growth, oxidation and adsorption, gas adsorption, pore diffusion, bulk advection, gas balance and heat conservation. The interplay of these various sub-processes is illustrated in the paper.Two case studies are presented which illustrate specific features of the model for different applications and how these have helped to identify key areas of concern. The first is focussed on chalcocite heap bioleaching, which shows that by nature of the reaction the process is strongly dependent on the initial supply of acid to the mineral site. In heaps this acid supply can be severely limited by the rate of diffusion from channels of flowing solution into stagnant zones of the heap, whereas in narrow-bore laboratory columns this effect is not observed."

Jan 1, 2003

By Tom Dettweiler, Robina Sharpe, Wright. Michael

The International Seabed Authority and a number of countries have or are in the process of developing environmental impact assessment guidelines and legislation for seafloor mineral development. The formal decision to grant a project an environmental permit is based on an environmental and social impact assessment (ESIA), culminating in an environmental impact statement (EIS). The EIS needs to be supported by sufficient data upon which an assessment of impacts can be made and mitigation measures developed. Given the remote locations of many seafloor prospects, collection of sufficient environmental data to inform an EIS is often a difficult, expensive and lengthy process.

Sep 1, 2014

By R. H. Thielemann

THE conventional short-time tensile test provides a reliable means of predicting the sustained load-carrying capacity of steels only when the temperature is such that continuous plastic flow does not occur. At elevated temperatures, stresses considerably less than the short-time rupture value may produce continuous flow, with fracture occurring only after long periods of time. The amount of flow or creep accompany-ing failure varies for different steels, and depends, to a large extent, on the temperature and the duration of the test. Service records of cracking stills, steam superheaters and high-temperature boilers have shown that brittle fractures sometimes occur with little or no warning. In installa-tions of this type, localized stresses are often encountered, and steels must be capable of withstanding a certain amount of deformation without fracture. The sustained-load rupture test determines the expected life and corresponding ductility of steels at various stresses and tempera-tures. It also yields additional information regarding the effect of micro-structure and metallurgical stability on the high-temperature properties.

Jan 1, 1939

By M. S. Safarzadeh, V. Agarwal

"The solvent extraction of cerium(III) and samarium(III) from mixed solutions of all rare earth elements (REEs) except promethium using PC88A (2-ethyl hexyl phosphonic acid mono-2-ethyl hexyl ester), an acidic extractant, was investigated. The effects of aqueous equilibrium pH, various acids (sulfuric acid (H2 SO4 ), hydrochloric acid (HCl) and nitric acid (HNO3 )), initial metal ion concentration and extractant concentration on the solvent extraction of Ce(III) and Sm(III) were systematically studied. From the experimental results, HNO3 and HCl were found to be the preferred aqueous media for the solvent extraction of both Sm(III) and Ce(III). The most promising experimental conditions of pH, PC88A concentration and metal ion concentration were identified for the extraction of Ce(III) and Sm(III). Separation results showed that H2 SO4 at pH 2 provided the best separation between Sm(III) and Ce(III). IntroductionIn recent years, demand for rare earth elements (REEs) has increased significantly because of their many commercial applications. REEs have especially important high-tech applications owing to their unique physical and chemical properties, and they are used in a wide range of areas such as catalysts, ceramics, magnets, lasers, glass, neutron absorption and alloys. As REEs have very similar physicochemical properties, their separation and purification from each other is challenging and gaining significant interest. Samarium (Sm) and cerium (Ce) are found in different REE minerals, including bastnäsite ((Ce,La,Nd(CO3)F), xenotime (YPO4) and monazite ((Ce,La,Nd,Th)PO4) at major production sites in the United States and China, as listed in Table 1 (Bleiwas and Gambogi, 2013). The most common acidic organophosphorous extractants used for REEs extraction and separation are DEHPA (di-(2-ethylhexyl)phosphoric acid), PC88A (2-ethyl hexyl phosphonic acid mono-2-ethyl hexyl ester), Cyanex 272 (bis-2,4,4-trimethylpentyl phosphinic acid) and Cyanex 301 (bis(2,4,4-trimethylpentyl)dithiophosphinic acid) (Sarangi, Reddy and Das, 1999; Surampally et al., 2012; Tian, Jia and Liao, 2013). Out of these extractants, PC88A is known for providing higher separation factors (Acharya, Mishra and Misra, 2015). El-Hefny et al. (2010) investigated the kinetics of the solvent extraction of Sm from chloride media using sodium salt of Cyanex 272 and reported the extracted species to be Sm(OH)A2•2HA. Lee et al. (2005) investigated the solvent extraction of Sm(III) with PC88A and saponified PC88A from chloride solutions and found the stoichiometry of the extraction reactions to be 1.5 with PC88A and 3 with saponified PC88A."

Jan 1, 2017

By P. A. Beck, W. D. Manly

In a recent note Sully and Head1 showed that the Cr-Fe sigma phase is isomorplious with the Cr-Co gamma phase, and that the lattice constants are also nearly identical. In a preliminary investigation of the ternary Cr-Co-Fe system at 800°C at this laboratory the above findings were confirmed, and it was found by microscopic techniques, using various etching reagents, that the two binary phases form an urinterrupted series of solid solutions with each other. These solid solutions occupy a straight narrow band which cuts across the 800°C isothermal section of the ternary system, connecting the two binary phases. A detailed investigation of the Cr-Co-Ni ternary system at 1200°C disclosed that here, too, the Cr-Co gamma phase extends deep into the ternary system in the form of a long narrow lip. The fact that this sigma type lattice is sustained even when well over half of the Co atoms in it are replaced by Ni atoms, with relatively little change in the Cr content, clearly indicates that Ni itself has a certain tendency to form the sigma phase with chromium. This tendency is hidden in the binary Cr-Ni alloys, where the sigma phase is not known to occur, but it becomes operative in the presence of a suficient amount of Co. The interpretation of these facts in terms of electron concentrations is rendered difficult by the uncertainty of our present knowledge of the valency electron structure of the transition elements in their alloys. However, Sully and Heal's results and the present work suggest that intermetallic phases with signla type lattice may occur more frequently in these little investigated alloys than heretofore suspected. In particular, it is expected that a similar phase may exist in the V-Co and perhaps in the V-Ni system, in analogy to the known sigma type phase in the V-Fe system, and that all these sigma type phases may form extensive solid solutions with one another.

Jan 1, 1950

By J. Macassi M.

La plata es uno de los recursos metálicos más importantes de Centromin, cuya complejidad de sus características requiere de un proceso de caracterización, identificación y conocimiento del comportamiento de los minerales que lo contienen, frente a los procesos existentes y a las nuevas posibilidades técnicas propuestas. En ese sentido, el texto plantea una alternativa hidrometalúrgica de solución para la recuperación de plata contenida en menas de hierro del tipo óxido sulfato, considerándola como una etapa de pretratamiento con una solución básica de hidróxido de sodio, de forma que esta tecnología permite beneficiar menas de naturaleza refractaria que contienen significativas cantidades de metales preciosos a un costo más económico.

Aug 26, 1988

By G. St. J. Perrott

ONE of the important hazards in coal mining is the danger of ignition of explosive mixtures of methane and air or coal dust and air, or both, by the explosives used in blasting the coal. It has long been recognized that certain explosives are more dangerous than others in this respect. In America and abroad, government testing stations have been established for officially passing on the suitability of explosives for use in coal mines. In this country the Federal government is given no power to enforce the use of the approved explosives but merely publishes from time to time, through the Bureau of Mines, those explosives which have passed the tests necessary to place them on the list for use in coal mines. In spite of this lack of police power, the increase in the use of permissible explosives since the promulgation of the first list in 1909 has been rapid. In 1912, only 8 per cent. of the explosives used in coal mines were permissible; in 1925, this figure had increased to 25 per cent. While the past record of permissible explosives has been most gratifying, it is very desirable that we pave the way for further improvement in explosives and blasting methods by learning more about the mechanism of ignition of gas and coal dust by explosives. To this end a considerable amount of investigative work already has been carried out and a large amount yet remains to be done. It is the purpose of this paper to discuss briefly the effect of the characteristics of explosives and method of loading in the borehole on the liability of a blown-out shot to ignite explosive mixtures of gas or dust. For an account of the methods by which an explosive is tested for permissibility for use in coal mines, the reader is referred to Schedule 17-A of the U. S. Bureau of Mines.

Jan 10, 1926

By Jeffrey Loeb

Recent trends in blasting engineering and its related fields, at the level of professional academia, have tended to exclude detailed discussion and examination of the formative experiences of the engineering student. In particular, the extra-curricular aspects of the undergraduate program in engineering—focused, in this case, on the summer job—will be shown to contain a wealth of heretofore underappreciated knowledge in the field. In Surveying the Damage: Post Traumatic Stress and Pre-Blast Surveys, I intend to outline and examine some of the more unusual experiences afforded me by my work as a preblast surveyor in the summer of 2007. In this capacity, I was required to make a visual note of existing conditions of surrounding residential and commercial structures within 100 m (328 ft) of two separate blasting sites in central-east Ontario. In the interest of both convenience and specificity, I have attempted to organize the paper as a crossdiscipline survey of the field according to the conference’s list of suggested topics. In the paper’s first section, I will discuss the topic of Environmental Improvement and Remediation by using a case study in which not one, but two dead cats were found during the course of a routine pre-blast survey. The second section will undertake a discussion of on-site blaster gossip as an entry point into a wider discussion of Workplace Communications Management. In the paper’s final section, I will detail an early morning encounter with a 300 lb, stark-naked trailer park inhabitant as a cross-sectional analysis of the topics of Drilling in Hostile Environments, Vibration and Seismology (Sizemology?), Ethics in Blasting, Crisis Management, Risk Assessment and Public Relations. It is my hope that this paper will begin to open up a critical space for discussion of the formative experiences of engineering students during the undergraduate university program in terms of their far-reaching effects on later performance within the industry.

Jan 1, 2009

By Luis Martín Tejeda

El presente texto señala cómo los parámetros geotécnicos de resistencia y deformabilidad pueden generar mayor confiabilidad en un estudio técnico. En este sentido, la literatura geotécnica indica que los resultados obtenidos a través de métodos numéricos son sensibles a la variación de estos parámetros y que algunas propuestas de cálculo son más satisfactorias. Para ello, se utilizó el criterio de falla de Hoek & Brown en términos de Mohr–Coulomb, donde se presenta un ejemplo aplicativo para mineria superficial, en el cual el factor de seguridad y la probabilidad de ruptura del macizo rocoso son calculados mediante métodos geoestadísticos aplicados a la ingeniería de rocas (FOSM - First Order Second Method y puntos de estimación de Rosenblueth).

Sep 19, 2006

By M. J. Sanzotti, C. J. Bise

This paper examines the potential for controlling longwall-induced subsidence by pneumatically backstowing waste rock into the void created by mining. The paper also examines scheduling the process as a unit operation of the mining activity. Based on a review of background literature and interviews with representatives of various mining companies, public-interest groups and state and federal regulatory agencies, a hypothetical case-study evaluation of pneumatic stowing at a southwestern Pennsylvania mine was conducted. The study indicated that current stowing technology cannot keep pace with the production potential of longwall systems in the United States. Further, at the mine used in this case study, concomitant stowing would reduce subsidence by only 50% of what would normally be incurred during full longwall caving, and the longwall coal-production rate would decrease from 3,630 t (4,000 st) per shift in the nonstowing case to 1,360 t (1,500 st) in the stowing case. A preliminary cost analysis reveals that pneumatic stowing would add from $5.79 to $11.57 per t ($5.25 to $10.50 per st) to the operating cost of producing coal at the case-study site.

Jan 1, 1997

By Stephen G. Tough, Ted M. Noskiewicz

INTRODUCTION For many years, in Europe and in North America, pre-formed metallic and concrete segmental linings in tunnels have been used extensively as temporary and permanent ground support systems. In the United Kingdom the use of cast iron as a means of ground support in mining shafts dates from the first decade of the 19th century. Although at that time wood tubbing was extensively employed, cast iron was used in shafts at Wallsend and Percy Main collieries in the North East of England. The original form of cast iron tubbing consisted of cylinders which were lowered bodily into the pit and were built from the bottom up, but subsequently they were subdivided into segments which involved the making of vertical as well as horizontal joints. Principally, the practice of providing immediate pre-formed support developed because of the incompetent state of the surrounding ground and, although this still remains the over-riding consideration nowadays, several other factors are examined before finally deciding what type of lining to use. Other branches of sub-terranean technology such as tunnel thrusting or immersed tubes (both of which involve pre-formed linings) can provide alternative solutions to problems hitherto thought better solved by bored tunnelling methods. However, this paper will confine itself to those linings developed for the more traditional tunnelling methods. Usually the shape of segmentally lined tunnels is circular because this profile is the most suitable for bad ground and many tunnelling machines. This does not always lead to the most economic use of space within the tunnel and horseshoe or elliptical linings are sometimes used in suitable ground. The number of segments

Jan 1, 1974

By John J. Moore

This paper discusses the application of a video technique to construct stability diagrams for the combustion synthesis of ceramic-metal composites. Several model exothermic combustion synthesis reactions have been used to investigate the effect of the reaction parameters, eg. stoichiometry, green density, etc, on the stability of the propagating combustion reaction front and subsequent product morphology. The effect of varying the reactants and their stoichiometry to provide a range of reactant and product species ie. solids, liquids and gases, in the synthesis of both dense and expanded (foamed) ceramic and ceramic-metal composites was also investigated with respect to their corresponding combustion front stabilities.

Jan 1, 1993

In a coal mine there are many substances capable of ignition under certain circumstances, which can be placed in the following groups: ordinary combustible solids, dusts, liquids and vapours, gases, metals and plastics. There are many factors influencing ignition, including temperature, minimum ignition energy, particle size, explosion pressure level, rate of pressure rise, specific energy content and also explosive limit. Not all are applicable in every case. Frictional ignition of methane is an accident statistic of increasing concern and is considered in some detail. Practical measures that can be taken to reduce the incidence of frictional ignitions are considered, and also possible ways of ignition suppression.

Jan 1, 1981

By Peter Halbach

Cobalt-rich ferromanganese crusts are one type of the two oxidic metallic mineral resources in the deep ocean that incorporate metals supplied and transported from both land (aerosols, continental run-off) and sea sources (oxygen-minimum zone, hydrothermal alteration of the oceanic crust). The substances directly precipitate from cold seawater under more or less oxic conditions and form thin layers (2 up to 25 cm thick) on hard substrate rocks like volcanic hyaloclastites, weathered basaltic rocks and/or carbonate-fluorapatite; in the crusts many metals therefore exist in the highest state of oxidation. Deposits of the Co-rich ferromanganese crusts are found throughout the global oceans on the flanks, terraces and summits of seamounts and submerged volcanic mountain ranges and platforms, where the ocean currents have kept the seafloor more or less free of sediment for millions of years. The process of hydrogenetic precipitation is basically an inorganic colloidal-chemical and surface-chemical mechanism. Elements in seawater may occur as dissolved hydrated ions or as inorganic as well as organic complexes which in general have either a positive or a negative surface charge depending on the pH of the respective aqueous environment. Those complexes may form hydrated colloids that interact with each other and with other dissolved hydrous metal ions. Hydrated cations such as Co, Ni, Zn, Sn are, for example, attracted by the negatively charged surfaces of colloidal hydrous Mn-oxide particles, whereas hydrated anions (e.g. oxyanions) and elements forming larger complexes with low-charge densities (e.g. U, As, Th, Hf, REE) are attracted by the slightly positively charged hydrous Fe oxihydroxide particles.

Jan 1, 2008

By S. S. Todd

[The purpose of this investigation was to obtain, heat-of-formation values a four Common titanates and, to conjunction with other requisite data, to derive free-energy-of-formation values In tem peratures in the range of 1,600°-1,800° K. T ht four titanites are tricalcium ?ditanite !['a¬spheremr?raritanar( rint-tir.rniurn rill( 1 This rc rr,rt sul,rlc?nu?nIs :r },r; vinu~ hul,lrc.irse,n3i n wlti h eht-rmnnIN-ti i n c {ar.a ai?rc? pu -,csseeri (or, 11 in(c-rnxiLIic co mrc+unrls conraininL~ rir:,niurrl. 'f Lac? !1~:)mc? c?xpcrirnc'ntnl n-ut rhod w,i. rna~loycul. lic?.ats of for rn:ltion of rlre comi?c,unr4~ it 29S.N. ut re mca,urc?,l by tioItl[ion e':iIorrr)utrv, using a ctrneaR }ryrlrc,fllanric-hY rir~chlorie- ,aci l mixttrrt .is rhr c-zle~rinrrrric- fluid and rc.actic~n rtu,liura}.]

Jan 1, 1956