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By A. E. Kehew

Earth resistivity surveys using the Wenner electrode configuration were made in unmined areas and reclaimed spoils at three surface lignite mines in western North Dakota. The study sites were the Center, Indian Head, and Falkirk Mines. Automatic interpretation of the curves was accomplished with the method of Zohdy and Bisdorf (1975). Overburden materials become more homogeneous with respect to resistivity during the mining and reclamation process. The spoils curves show localized hetero-geneities probably related to discontinuous moisture content variations in the spoils. Consistent resistivity differences in spoils occur between mines with over-burdens of different mineralogic compositions. Groundwater chemical composition in terms of total-dissolved-solids (TDS) is inversely correlated (r=-0.61) with apparent resistivity at the 80-foot spacing from a survey centered at a piezometer screened near the base of the spoils. Better inverse correlation is probably pre-vented by high variability in TDS within the spoils groundwater. A useful predictive relationship may be the plot of mean apparent resistivity at the 80-foot spacing for ar. entire mine against mean TDS for all wells in spoils at that mine. Data from more mines are needed to test the hypothesis.

Jan 1, 1982

By E. L. Rawlins

The development of commercial natural-gas reserves in the Michigan stray sandstone horizon of central Michigan during the past few years has resulted in expansion of the natural-gas industry in that State. The location of the natural-gas reserves of Michigan in the general vicinity of domestic and industrial markets is of economic importance, and in supplying these markets with natural gas a reasonable knowledge of, the extent and availability of the reserves is needed in formulating regulations for drilling gas wells and producing natural gas in analyzing the feasibility of projects to construct natural-gas transmission lines, in promoting and developing markets for the domestic and industrial consumption of natural gas, and in solving many engineering and economic problems common to the natural-gas industry. The development of the natural-gas industry in Michigan has been related closely to the development of oil production. The potential oil production of Michigan is comparable with that in most of the eastern oil-producing States. The development of oil production probably will continue, especially in the central Michigan Basin area; and as wells are drilled to deep horizons in the search for oil, more knowledge will be obtained of the gas reserves in formations above the oil-bearing horizons.

Jan 1, 1936

By Paul C. McWilliams

This Bureau of Mines report analyzes data on the physical properties of quartzite rock from the Crescent mine, Coeur d?Alene mining district, Kellogg, Idaho, to demonstrate the use of multivariate techniques. After regression, factor, component, cluster, and discriminant analyses are discussed, these techniques are applied to the Crescent mine data. Three appendixes contain some of the required mathematical and statistical detail plus heuristic examples of three multivariate techniques --component, cluster, and discriminant analysis.

Jan 1, 1978

By R. V. Ramani, A. S. C. Owili-eger

This report was prepared by The Pennsylvania State University under USBM Contract No. G0111808. The contract was initiated under the Coal Mine Health and Safety Program. It was administered under the technical direction of DMSE, with Mr. G. R. Schottler acting as the technical project officer. Mr. J. A. Herickes was the contract administrator for the Bureau of Mines. This report is a summary of the work recently completed as part of this contract during the period June, 1971 to December, 1973. This report was submitted by the authors on March 31, 1974. Part of the research reported here was originally done on a grant from the Department of Environmental Resources, Commonwealth of Pennsylvania and reported in Special Research Report No. SR-95 (February 25, 1973) of the Coal Research Board, The Pennsylvania State University.

Jan 1, 1974

By L. R. Burdick, J. F. Barkley

"The agglomerating index of coal is an index based upon the nature of the coke residue left when the standard volatile-matter determination of the well-known proximate analysis is made. In this determination a small amount of coal is heated in a container to about 950° C. (1,742° F.), at which temperature the volatile matter is driven off, leaving a coke formation. The coke residues for various coals are quite different in physical structure: and, for some time past, work has been done on studies of the nature of these residues in connection with the coking of coal. In 1934 Gilmore, Connell, and Nicolls proposed use of the agglomerating index for indicating the dividing line between noncaking coals and those having weakly caking properties. 4/ Its use was adopted in the standard classification of coals by rank as a requisite physical property index to differentiate semianthracite from low-volatile bituminous coal and also high-volatile ""C"" bituminous from subbituminous ""A"" coal, as shown in table 1, the standard coal classification adopted by the American Society for Testing Materials and the American Standards Association. 5./In studying the agglomerating properties of coals based on the coke residue the Bureau of Mines has adopted the notation given in table 2. Coals that in the volatile-matter determination give a coke residue either in the form of an agglomerate button that will support a 500-gram weight without pulverizing or a button that shows swelling or cell structure are considered to be agglomerating."

Nov 1, 1938

By R. B. Prater

The Bureau of Mines conducted research to separate the F from byproduct Zn concentrates obtained from fluorspar (CaF2) production, as part of the Bureau's effort to devise efficient, environmentally acceptable technology for recovering Zn from resources considered undesirable by Zn producers. Sulfuric acid (H2SO4) was found to be effective in F removal, while ammonium carbonate [(NH4)2C031 was not. The most important variables for reducing the necessary residence time were found to be temperature and agitation. Optimum leaching conditions were 75° C and 500 r/min for 2 h at 40 pct solids with 0.2 g acid per gram of concentrate, which resulted in a 98.3-pct F extraction. Zinc losses during F removal were in the range of 2 to 3.3 pct. Other elements such as Fe, Cd, Ca, and Cu were also partially dissolved. About 93 pct of the F was removed from the leach solution by neutralization and precipitation with calcium hydroxide [Ca(OH)2]. Additional treatment might be necessary to limit the buildup of soluble elements in the recycled leach solution.

Jan 1, 1985

By James J. Olson

Previous Bureau of Mines studies of vibrations from quarry blasts have shown that the square root of the charge-weight may be used to group particle velocity data from various charge sizes, and that empirical propagation equations may be used to estimate vibration amplitudes. Particle accelerations of the sandstone roof of the White Pine Copper mine, Michigan, were measured to determine whether similar propagation equations may be developed for underground mine blasts. Vibration data from White Pine blasts were best grouped by scaling with the square root of the charge weight. Cube root scaling did not effectively group the data. The empirical propagation equation AW1/2 = 50,000 (R/W1/2)-2.21 where A is peak-to-peak acceleration in g's, W is the zero-delay charge-weight in pounds, and R is the distance from the blast in feet, may be used to estimate maximum vibration amplitudes from production sized blasts. Vibration differences among headings and types of explosive charge (AN-FO and dynamite), while statistically significant, were not a major factor in the estimation of maximum vibration amplitudes with an empirical propagation equation. Vibration differences between types of explosive charge were larger than the differences among headings, indicating that some reduction of vibration amplitude might be gained by using AN-FO rather than dynamite. Acceleration records from both White Pine's AN-FO and dynamite production blasts show that high intensity vibrations from the delayed portions of the blast (each delay interval = 25 milliseconds) were separate events, and that the zero-delay portion of the blast produced the maximum vibration amplitudes. If the pull of the underground blast round can be maintained, a reduction of the zero-delay charge-weight may effectively reduce the maximum vibration amplitude of the blast.

Jan 1, 1970

By Steven W. Schmauch

In 1985, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied 27,930 acres of the 52,000 acre East Fork High Rock Canyon Wilderness Study Area, CA-020-914/NV-020-006A, in order to evaluate the mineral resources. The study area is located in Humboldt and Washoe Counties, NV, about 45 miles east of Cedarville, CA. Bureau of Mines personnel reviewed pertinent literature and county mining records and examined prospects or mineralized areas. There are no organized mining districts and no historical or active claims in the study area; one small pit lies in the southwest corner of the study area. Based on published literature, sample results and field observations, there are no recognized mineral, geothermal, or fossil fuel resources. Epithermal mineralization indicators are not present or exposed. Sand and gravel deposits in the study area are not likely to be developed as other deposits are closer to market areas.

Jan 1, 1986

By Thomas E. Green

A solvent extraction procedure using 8-hydroxyquinoline and chloroform was investigated by the Bureau of Mines as a preconcentration technique for the determination of aluminum, calcium, cobalt, copper, iron, lead, magnesium, manganese, nickel, and zinc in large samples of high purity tungsten. X-ray spectrographic and atomic absorption methods were used to determine the trace metals after preconcentration. The presence of 10 grams of tungsten had a pronounced effect on the distribution of 8-hydroxyquinoline between the aqueous and chloroform phases. This change in the 8-hydroxyquinoline distribution in turn had an adverse effect on the extraction of the trace metals. Extraction efficiencies can also be adversely affected by an increase in the quantity of extractable metals present, as shown by radiotracer tests using 65Zn. Excess 8-hydroxyquinoline in the extracts did not interfere with the determination -of the serious interference in the combined ion exchange paper--X-ray spectrographic method. Although preconcentration by 8-hydroxyquinoline extraction was found to be partially successful, other preconcentrationn methods based on ion exchange and dithizone extraction were found to be superior.

Jan 1, 1968

By G. Schuman

Variations in pyrite reactivity are known to exist within samples collected from different areas. Using samples collected from acid and non-acid sites, the relationship between the factors affecting pyrite oxidation and observed variations in pyrite reactivity was studied. Heavy liquid separations were used to extract the pyrite from nine pulverized rock, coal, and coal refuse samples. Simulated weathering tests were used to determine the degree of reactivity of the extracted pyritic material. Representative portions of each pyritic sample were analyzed for whole rock composition (including pyritic sulfur and neutralization potential), for elemental composition, and by x-ray diffractometry. The samples were also examined with reflected light microscopy to ascertain pyrite morphology distributions. Tests for the presence of iron-oxidizing bacteria were all negative indicating the leaching tests were conducted under abiotic conditions. The results of the simulated weathering tests permitted the partitioning of the samples into two groups based on positive or negative neutralization potential (NP) values. Determinations were then made to evaluate the degree to which a variety of factors, including temperature, partial pressure of oxygen and water, and crystallography affected pyrite reactivity. Multiple regression analyses showed no statistically significant relationship between degree of reactivity and elemental composition. However, for samples with negative NPs, a simple regression analysis showed a strong linear relationship to exist between the reactivity of the pyrite and the proportion of "unstable" pyrite (framboidal + mossy pitted) found in each extracted pyrite sample. Samples of pyrite with positive NPs, although producing acidity, did so in at least one order of magnitude less than the NP deficient samples, indicating the important role that NP plays in controlling pyrite reactivity. A simple linear regression between cumulative sulfate production and NP for the three samples with positive NPs had a correlation coefficient of 0.99. For the nine samples grouped together, a linear regression model between cumulative sulfate production and NP (both negative and positive) was established between log of sulfate and NP.

Jan 1, 1991

By Lewis M. McNay

The Bureau of Mines located and examined 292 burning coal refuse banks throughout the Nation's coal-producing regions in 1968. These coal waste fires, extending over 3,200 acres, produce poisonous, acrid gases and particulate matter that pose a threat to health and safety in the surrounding areas, damage vegetation, and cause the deterioration of nearby structures and buildings. Methods of extinguishing coal refuse fires are discussed, and an approach to eliminating future occurrences of these fires is presented.

Jan 1, 1971

By Ralph B. Adair

The Bureau of Mines conducted laboratory and continuous pilot plant flotation tests to determine the feasibility of recovering commercial-grade mica from an Alabama graphitic-mica schist. Preconcentration of the ground ore on a Humphrey's spiral was employed to reject the heavy minerals and part of the quartz in a product virtually free of mica. The acid-cationic mica flotation process recovered over 89 percent of the mica in a product containing 98.7 percent mica. Grinding of the mica concentrate in a fluid energy mill produced a product with a bulk density of 12 lb per cubic foot.

Jan 1, 1969

By G. C. Branner

The bauxite diagram presented as figure 1 was developed to clarify, by graphic means, the theoretical chemical constituents of gibbsite-kaolinite-type bauxite for all possible proportions of these two minerals from pure gibbsite to pure kaolinite. The tables in the report reflect the same date. The diagram provides (1) a graphic representation of the relations of constituents with respect to a ill possible percentages of alumina and silica, (2) a basis for verifying the accuracy of analyses of gibbsite-kaolinite bauxite, and (3) a basis for estimating the type and proportion of alumina hydrate and/or silicate minerals that may be present in gibbsite-kaolinite-type bauxite. The diagram, with accompanying interpretations and use formulas, will be useful to those connected with the mining and processing of bauxite.

Jan 1, 1955

By R. K. Koch

The vapor pressures of liquid columbium and liquid hafnium were deter-mined by the Langmuir free evaporation method as a part of the Bureau of Mines program on the study of transition metals. An electron-beam furnace with a water-cooled copper crucible was used for melting. Temperature was measured with a two-color ratio pyrometer. Least-squares analyses of the vapor pres-sure data gave the following equations: [Logp (atm) = 5 .429 -31,310 T] for liquid columbium in the range 2,740° - 3,140° K, and [Log p (atm) = 5,690 28 T] for liquid zirconium in the range 2,500° -2,810° K. Third-law evaluations of each data set gave mean heats of sublimation (298.15° K) of 175.1±3.2 kcal/mole and 148.3±1.2 kcal/mole for columbium and hafnium, respectively. Second-law standard heats of sublimation determined from sigma plots and from sigma-prime plots agreed fairly well with the third-law values. The sigma-prime plots gave standard entropies of sublimation of 30.96±0.84 eu and 33.S6±0.44 eu for columbium and hafnium, respectively.

Jan 1, 1968

By R. L. Blake

The crystal structure of hematite, a-Fe203, has been refined as part of a continuing study of the behavior of phases in the Fe-O system during reduction and oxidation. Three-dimensional diffraction intensities were collected on two spherical single crystals of hematite with a semiautomated Buerger single-crystal diffractometer. The first crystal refined was a natural Elba hematite with minor impurities. The other, a synthetic crystal, was refined at the request of Mossbauer spectroscopy investigators concerned with impurities in the natural crystal. The structure has been refined with a least-squares program and the final structure for the natural crystal irradiated with CuKa-radiation gave a discrepancy factor (R) of 3.65 percent using 49 unrejected reflections of the 51 measured. For the synthetic crystal, using MoKa-radiation, the discrepancy factor converged to 2.8 percent using 95 unrejected reflections and was 3.3 percent for all 109 reflections. The structure model of Pauling and Hendricks has been confirmed with essentially no change in the iron coordinates and approximately a 5-percent change in the oxygen coordinates. Selected interatomic distances and angles were calculated as were anisotropic temperature factors.

Jan 1, 1970

By W. L. Falke

Procedures in which manganese compounds are reduced and the metal is volatilized and selectively condensed, a hitherto neglected area, were investigated. More than 95 percent of the manganese was recovered from high-melting-point ores whether vacuum volatilization or atmospheric pressure volatilization was used, but neither process is economically attractive under present price-cost conditions.

Jan 1, 1966

By J. B. Gayle

Numerous investigators have studied the addition of inert4 substances to coking blends. Generally, the results have yielded trends applicable only to the particular coals and inerts studied. Recently, somewhat more general results were obtained for cokes produced from blends containing added inerts, using the sole-heated oven. The present investigation represents an extension of this work to include a wider range of inerts and to determine the applicability of the various conclusions to cokes produced with the Tuscaloosa oven. The results indicated that an increase in dry-coal charge density of 1 pound per cubic foot (p.c.f.) caused a corresponding change in the hardness (1/4-inch tumbler index) of Tuscaloosa oven cokes of 0.9 percentage points. This value compares favorably with the value of 0.7 determined previously for the sole-heated oven and Bureau of Mines-American Gas Association (BM-AGA) retort.

Jan 1, 1961

By H. W. St. Clair

This study of the rate of evaporation of zinc was undertaken as a part, of a general investigation on refining mixtures of metals resulting from melting reclaimed scrap. One of the methods by which the more volatile metals, such as zinc, magnesium, and cadmium, may be separated is by distillation. Distillation may be carried out at lower temperatures if it is done in an evacuated enclosure. The immediate purpose of the present investigation was to determine accurately the effect of temperature, pressure, and other factors on the rate of evaporation of zinc.

Jan 1, 1950

By D. Harrington

Fine ventilation was discussed. much more 15 to 20 years ago than it is now, yet today there are tendencies in connection with ,-line ventilation (in fact, numerous ventilation systems have been installed in recent years) indicating that the lessons learned by bitter experience in the past either have been forgotten or lave not been brought to the attention of the present generation. Possibly, the mining min of today considers that conditions have changed so much that experiences of the past cannot be repeated today. At any rate, it seems desirable to restate some of the principles of mine ventilation that were understood more or less in the past and to call attention to some danger in connection with present-day trends or practices.

Jan 1, 1939

By Richard J. Mainiero, Harry C. Verakis

The Bureau of Mines has conducted research to determine whether the total elapsed delay time for blasting bituminous coal in underground mines could be safely expanded beyond the present 500-ms limitation without igniting a methane or methane-coal dust atmosphere. The results indicated that the increase of total delay from 500 to 1,000 ms had no detectable effect on safety relative to incendivity as long as permissible practices were observed in all other aspects. Research was also conducted to evaluate the safety of 18-in hole spacing for delay blasting in coal relative to misfires. For a variety of permissible explosives, misfires were observed for about 50 pct of the holes at 18-in spacing. Based on this observation, the Bureau has recommended that the new regulations prohibit hole spacings of less than 24 inches in underground coal mines. Misfires were also observed for 24-in spacing, but the number of misfires and test shots was too small to sup- port any firm conclusions.