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By Richard Mainiero, James H. Rowland III

For many years there have been small scale tests available for evaluating the toxic fumes production by capsensitive explosives (DOT Class 1. l), but these could not be used with blasting agents due to the large charge sizes and heavy confinement required for proper detonation. Considering the extensive use of blasting agents in construction and mining, there is a need to determine the quantities of toxic ti,tmes generated by blasting agents. At the International Society of Explosive Engineers Twenty Third Annual Conference on Explosives and Blasting Technique in 1997, the authors reported on a facility for detonating large (4.54 kg), confined blasting agent charges in a controlled volume that had been constructed at the National Institute for Occupational Safety and Health’s Pittsburgh Research Lab’s Experimental Mine. Since 1997, this facility has been used to collect data on toxic fumes produced by the detonation of various ammonium nitrate/fuel oil (ANFO) mixtures and several cap-sensitive explosives. ANFO composition ranging from 1 to 10 percent (pet) tieI oil have been studied. As expected from previous studies, with an increase in fuel oil content the carbon monoxide production increases, while nitric oxide and nitrogen dioxide production decrease. The detonation velocity varies from 3,000 to 4,000 m/set for the 1 to 10 pet range of fuel oil content, suggesting that ANFO mixes with improper fuel oil content may appear to detonate properly, while their fume production differs significantly from optimum. The study also considers such factors as degree of confinement, water contamination, and aluminum content on blasting agent fume production. Results indicate that water contamination of the ANFO has little effect on carbon monoxide production, but causes significant increase in nitric oxide and nitrogen dioxide production. Decreasing confinement from Schedule 80 steel pipe to 0.4~mm thick sheet metal also has little effect on carbon monoxide production, but significantly increases nitric oxide and nitrogen dioxide production. Adding 5 and 10 pet aluminum to the ANFO had no clear effect on carbon monoxide, nitric oxide, or nitrogen dioxide production.

Jan 1, 2000

By Don Houston

Vertical crater retreat mining (VCR) requires initiation methods that minimize debris in the borehole. The use of detonating cord and shock tube detonators eliminates debris that could interfere with subsequent loading operations and avoids the cost of using drilling equipment to clear the debris. The explosive must not be sensitive to the strength of detonating cord used, otherwise timing will be affected. “Slicing and Dicing” of product before “Air mailing” down boreholes may facilitate loading, especially in wet holes, and can result in product surrounding the detonating cord. Cord sensitivity testing confirmed that having the detonating cord surrounded by product significantly increases the likelihood of an energetic reaction. Careful formulation and testing, based on a thorough knowledge of the application and the role of ingredients in affecting performance, ensures reliable initiation and avoids cord sensitivity. The use of certain metallic nitrate salts, even in relatively small amounts, was found to significantly increase the cord sensitivity of watergel formulations. Evidence of increasing cord sensitivity includes increasing amounts of damage to product and packaging, to ejection of product from the test pipe, then cracking of the pipe, followed by deflagration then detonation of the product. Predictably, the likelihood of an energetic reaction increases with product temperature, cord strength, and borehole diameter, while it is inversely related to product density.

Jan 1, 2002

By M-C. Lee, Shomaker, R. Turcotte, B. Short

This research program was undertaken to better understand the factors causing abnormal NOx fumes generation from blasting operations in surface coal mining. More specifically, unusual quantities of nitrogen dioxide and nitric oxide have been observed at several surface coal mines in the Powder River Basin, Wyoming. All these mining operations have several points in common: (i) Blasting is performed using gravity loaded emulsions or emulsion/ANFO blends (ii) Unusual NOx (Oxides of Nitrogen) emissions are observed mostly when blasting is conducted in the overburden as opposed to the coal seam itself (iii) The overburden consists of very weakly consolidated ground strata, providing relatively weak confinement conditions for the explosives, and (iv) Significant ground water is observed.

Jan 1, 2002

By Donald Hurd, James Rowland, Richard Mainiero

In previous conferences the authors have reported on toxic fumes generated by the detonation of ANFO. The research reported here extends the earlier work to include an emulsion blasting agent and ANFO/emulsion blends. Explosive mixtures were shot in 4-inch Schedule 80 steel pipe (outer diameter 4.50 in (11.43 cm), inner diameter 3.83 in (9.72 cm)) in a chamber in the experimental mine at the Pittsburgh Research Laboratory (PRL). Following each shot, the fumes in the chamber were analyzed using on-line instrumentation.

Jan 1, 2001

By David Lilly, Robert Ethier, David Bremer

The Lafarge Ravena Cement Plant in Ravena, New York demonstrated continuous and extraordinary improvement in productivity during the past several years. The factors driving continuous improvement at the Lafarge Ravena Plant include: 1) Management techniques including regular scheduled and effective Blasting Optimization Team meetings. 2) A real time blasting database to guide blasting product and procedure decisions. Key decisions involved all levels of quarry and blasting supplier personnel and a close working relationship between production and blasting areas of expertise was demonstrated. 3) Blast optimization and optimization of quarry operating parameters such as blast location relative to crusher location, hours worked, etc.

Jan 1, 2007

By David Cheung, S. Paul Singh

"The characteristics of a blasted muck pile can have a significant effect on the productivity and economyof loading and hauling operations. Poorly fragmented and tight muck piles, caused by insufficientdisplacement of the broken rock, lead to higher digging and hauling costs. Therefore muck pile must be tailored to suit the loading and hauling equipment. In order to achieve this objective, it is imperative to understand the relevant muck pile characteristics and factors governing them. In general, muck pile characteristics are governed by the blast design parameters, rock mass geology, explosive characteristics and post-blasting requirements."

Jan 1, 2017

By John S. Manka

Of the various methods used to reduce the density of emulsion explosives prior to detonation; ammonium nitrate prill addition, glass micro-balloon addition and chemical gassing, chemical gassing is the method most often selected by emulsion explosive end users. Chemically gassing emulsions costs less than adding micro-balloons and chemically gassed emulsions have better water resistance than emulsions that add ammonium nitrate prills to reduce the bulk density. Unfortunately, the chemical gassing of emulsion explosives can be intricate and is often more art than a science. To gain a better understanding of chemical gassing, we investigated the factors that may affect the chemical gassing of emulsion explosives. Variables investigated as having an effect on gassing were the pH of the oxidizer phase, the amount and type of nitrogen in the emulsifier, the composition of the oxidizer phase, the use of pH buffers in the oxidizer phase, and how the gassing reagents are added to the emulsion.

Jan 1, 2004

By Robert Hopler

In issuing this pamphlet on stump and boulder blasting for the use of farmers, we wish to call attention to the fact that Du Pont High Explosives have been used with universal satisfaction for many years under diverse conditions, and have never failed to give satisfaction in mining, quarrying, roadmaking, blasting stumps and boulders, or for any other work where regard to economy and safety in use is the object.

Jan 1, 2008

By Natalie Zeleznik, Brian Hawkins, David Bradley, Rachel Gooding, Patrick Wilson

"The United States (U.S.) Department of Homeland Security (DHS) Directorate of Science and Technology (S&T), utilizes a probabilistic risk assessment (PRA) approach to explore the risks (anduncertainty) from chemical, biological, radiological and nuclear (CBRN) threat agents to the Homeland.This end-to-end risk methodology considers a broad range of hazards incorporating emergingtechnologies, available countermeasures and input from the Intelligence and Law Enforcementcommunities (IC/LE) to evaluate the acute risk to human health due to an attack on the U.S. homeland. The PRA generated output provides a mechanism to examine risk mitigation strategies, critical vulnerabilities, critical data and knowledge gaps and relative risk rankings of materials, targets, classes of compounds and scenarios."

Jan 1, 2017

By Kenneth Eltschlager

Blasting represents the highest risk of any surface coal mining activity that could result in injury and/or property damage off the permit area. In addition, blasting related issues e.g. flyrock, vibrations, air blast, etc., are responsible for a large percentage of citizen complaints. Thorough and consistent regulation of individuals certified to conduct blasting by the Office of Surface Mining Reclamation and Enforcement in Federal Program states and on Indian Lands under Federal jurisdiction is vital, as it serves to: facilitate coal production to meet the nation’s energy needs; protect people and property on and adjacent to Federal mining permits; form a basis for states to grant reciprocity certificates to Federal blasters; and be a positive example to primacy states. OSM issues Federal blaster certificates for blasting on Federal surface coal mine permits. The certification program includes experience, training and testing components similar to many of the states. But where a state program may focus on the specific blasting applications within its boundary, the OSM certificate requires a very diverse test to cover all potential blasting applications and products across the nation. Therefore, the Federal certificate is a good surface mining credential for blasters anywhere in the United States.

Jan 1, 2010

By Tom C. Palangio

Commercially available online particle size analyzers (OPSA) are in their third decade of development (Palangio, T.C., 1985), (Franklin, J. A., Maerz, N.H., 1987), (Maerz, N.H., Franklin, J.A., and Coursen, D.L., 1987). The installed base of operating analyzer numbers is in the hundreds. This paper takes a look at five critically important relationships that users have discovered through the use of OPSA systems. The two key attributes of these systems are: 1) consistency and, 2) historical context compared with traditional practices.

Jan 1, 2016

By Shad M. Sargand, Manseok Chang, Glenn A. Hazen

Customarily, peak particle velocity of surface wave vibrations has been the recommended criterion for the prediction of blast damage to structures. Currently blast spectrum and natural frequencies of a structure have been also recognized as important for predicting damage potential. While others have considered the importance of structural frequencies, they have not analyzed the structural response spectrum when establishing damage criteria.

Jan 1, 1992

By Minoru Kawamora, Koichi Kurokawa, Kenji Hashimoto

We developed concentrated remote control blasting system to blasting simultaneously at a large number of sites in a mine of large scale. This system is consisted of three parts, the first part is a control station with high voltage power source units, the second part is a relay terminal with relaying and branching units, and the third part is a blasting machine with charging and discharging units. The control station is connected with the blasting machine by mean of control bus wire. The blasting machine adopts MBS(electromagnetic induction blasting system) for the reason of safety and good handling.

Jan 1, 1990

By Kurt Oakes, Paul Worsey, Braden Lusk, Tony Brasier, Scott Crabtree, Randy Wheeler

Theoretical description of destructive wave interference and the use of sacrifi cial holes is included and is supported by data collected at Springfi eld Underground. Finally, the process by which the reduction in vibration was achieved in practice is described. Results are discussed for several production blasts taking place over a one year period.

Jan 1, 2008

By Douglas Bartley, Brian Wingfield, Robert McClure

Recent studies and limited tests indicate favorable results utilizing high accuracy electronic detonator technology over conventional non-electric pyrotechnic systems. This study discusses the application of this technology using the Daveytronic programmable system in an on-going production basis. The study quantifies the performance as it relates to fragmentation, excavation, vibration and productivity in an eastern U.S. aggregate mining operation.

Jan 1, 2001

By Douglas Bartley, Brian Wingfield, Robert McClure

Recent studies and limited tests indicate favorable results utilizing high accuracy electronic detonator technology over conventional non-electric pyrotechnic systems. This study discusses the application of this technology using the Daveytronic programmable system in an on-going production basis. The study quantifies the performance as it relates to fragmentation, excavation, vibration and productivity in an eastern U.S. aggregate mining operation. In order to insure accurate data, tight field controls were adhered to during the drilling and blasting process as they related to blast design, bench preparation, pattern layout, drilling and blasthole loading. Following the blast the excavation and crushing procedures were studied to quantify any down stream advantages due to improvements in fragmentation. This study will help provide the industry with information as to the advantages of high accuracy electronic blasting systems over conventional pyrotechnic systems and show the results of an operation utilizing electronic detonator technology through their production season.

Jan 1, 2000

By M J. Ball, R Watt

ICI has developed a new electrical shotfiring system which has markedly improved safety features and operational advantages over existing initiating systems. The development of the 'Magnadet' Electric Detonator and the related product 'Magna' Primer were described in a paper presented at the 1981 S.E.E. Annual Conference. Since then the system has been adopted in many different applications and conditions around the world. The present paper describes these applications, the experience gained and the more recent developments which have taken place.

Jan 1, 1982

By V R. Sastry, D P. Singh, N R. Thote

Rock parameters which are uncontrollable impose restrictions on the procurement of desirable fragmentation. Blast design parameters which are controllable prove to be important tool in blasting operations. An attempt was made by the authors to investigate parameters which causes big oversize boulders in overburden blasting. A case study of coal mine is discussed in this paper.

Jan 1, 1995

By Yang Ruilin

Bulk gassing technology is a growing trend in the commercial explosive industry. The gassed bulk products produced differ from microballooned bulk products or cartridged products. It is easy to know the loaded or in-hole density for microballooned bulk products or cartridged products, whereas it is not as straight forward to know the m-hole density for gassed bulk emulsions. The loaded density is one of the key parameters affecting explosive performance and therefore it is important to have a field technique to monitor the in-hole properties of gassed bulk products in order to accurately predict the blast performance and to ensure efficient use of the products.

Jan 1, 1999

By Richard J. Mainiero, Michael J. Sapko, Marcia L. Harris

Since 1988, there have been thirteen documented incidents in the United States and Canada in which carbon monoxide (CO) is suspected to have migrated through near surface strata into structures or other enclosed spaces as a result of nearby trench blasting or surface mine blasting. From these incidents, there are thirty suspected or medically verified CO poisonings and one fatality associated with these incidents. To better understand the variables contributing to this hazard, the National Institute for Occupational Safety and Health (NIOSH) carried out a small- scale field study to identify key factors that may contribute to the migration of CO through the ground. NIOSH conducted single- hole heavily confined experimental test shots to measure the radial pressure pulse as it propagated through surrounding monitoring holes to determine if a relationship existed between the pressure pulse and resulting CO measurements afterwards. NIOSH also monitored blasts at an airport construction site. Following the detonations, the concentrations of CO, nitric oxide (NO), and nitrogen dioxide (NO2) were monitored for several days in the surrounding satellite holes. The peak CO measurements relative to distances from the shots were compared. Pressure histories and peak particle velocities (PPV) were measured at monitoring boreholes. It was found that the differential pressures recorded within the boreholes give some indication as to the likelihood of CO appearing, whereas the PPV measurements do not seem to be as good an indicator for potential CO migration. In this limited study, changes in barometric pressure had very little influence on removing the trapped detonation products, whereas applying a vacuum to the monitoring holes was effective in reducing the entrapped CO concentration.

Jan 1, 2005