Factors that Affect the Chemical Gassing of Emulsion Explosives

Of the various methods used to reduce the density of emulsion explosives prior to detonation; ammonium nitrate prill addition, glass micro-balloon addition and chemical gassing, chemical gassing is the method most often selected by emulsion explosive end users. Chemically gassing emulsions costs less than adding micro-balloons and chemically gassed emulsions have better water resistance than emulsions that add ammonium nitrate prills to reduce the bulk density. Unfortunately, the chemical gassing of emulsion explosives can be intricate and is often more art than a science. To gain a better understanding of chemical gassing, we investigated the factors that may affect the chemical gassing of emulsion explosives. Variables investigated as having an effect on gassing were the pH of the oxidizer phase, the amount and type of nitrogen in the emulsifier, the composition of the oxidizer phase, the use of pH buffers in the oxidizer phase, and how the gassing reagents are added to the emulsion.