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By S J. Neethling and, S J. R Simons

In this paper the effect of humic substances (natural surfactants), electrolytes and solid particles on bubble coalescence, and as a consequence on froth stability, have been investigated. In this study two bubbles of equal size were formed and forced to collide using a novel experimental apparatus. The interactions were recorded by a high-speed camera, the images of which helped to determine the coalescence frequency and the coalescence time, as well as the mechanisms of the interactions. Two types of humic substances were used, along with three different electrolytes. Humic substances appeared to have a considerable effect on bubble coalescence, while the effect of electrolytes was minimal. Moderate and high hydrophobic glass spheres were used between two bubbles. Very hydrophobic spheres promoted fast bubble coalescence, while moderate hydrophobic spheres had no effect. Data of coalescence frequency and time is presented, as well as images of the coalescence events. The coalescence frequency was used to validate a parameter, Pf, known as the film failure frequency, used in a simulation model to predict foam height in a gas-sparged vessel. Predictions determined using Pf were then validated by experimentation.

Jan 1, 2005

By S Brochot, M-V Durance

In many cases, current metallurgical accounting practice does not consider the errors associated with the measurements used in obtaining the metal balance. Considering all measurement errors, including errors associated at each step of the process - from sampling and analytical errors to measurement errors in circuit instrumentation, can improve the accuracy of the final metal balance - assisting in the improvement of process performance, optimisation and control.The consequences of the inclusion of measurement errors on metal balance for different circuit configurations and typical metallurgical accounting practice (two product and three product formulae) will be discussed in this paper.Examples of the tools, methodology of implementation, and periodical metal balance tasks are presented to illustrate the advantage of this approach in meeting the different requirements of each department.CITATION:Brochot, S and Durance, M-V, 2012. A new approach to metallurgical accounting, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 217-224 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By D Tuazon, M Powell, M Ziemski, G D. Corder

Although mining companies have made broad corporate-level commitments to adopt sustainability, there continue to be problems when attempts are made to adopt higher-level sustainability aspirations and translate them into appropriate targets and methods at the more-specific operational level. The integration of sustainability principles into minerals processing operational decision-making processes has unique challenges that are not addressed adequately by current tools and methodologies, yet impacts from operational decisions can have longer-term effects realised at closure and rehabilitation.This paper describes a proposed methodology to achieve the integration of sustainability at the operational level through a systematic and rigorous process of identifying and qualifying sustainability issues and opportunities in an operation. The methodology, starting from a sustainability point of view rather than an operational one, guides the identification of process issues and opportunities by examining the operation, unit-by-unit, similar to a Hazard and Operability (HAZOP) process. Each issue or opportunity is qualified according to its measurability, scopes of impact and consequences so that it may be understood fully and the correct engineering problems are formed. Through improved decision-making to account for broader sustainability factors, operations can better address environmental and social expectations and pressures (both corporate and community, as well as immediate and in the longer-term), whilst still delivering on operational and business goals.The methodology has been tested with two case studies at minerals processing operations. At one site, the methodology identified a dust issue which had considerable business risks (loss of valuable product) compared to conventional engineering analysis processes. The other site also benefited from using the methodology as an opportunity to improve the operation of the milling and flotation circuits was identified. The opportunity not only showed a potential to improve operational efficiency, but also potential improvements in water and energy efficiency and a resulting increased resilience against water and energy supply risks. It was important to utilise the holistic approach of the methodology in the identification of opportunities at this site; the goals of the operation showed a strong coupling between water and energy issues which would be difficult to overcome using the operationÆs current organisational model, which deals with such issues separately of each other.CITATION:Tuazon, D, Corder, G D, Powell, M and Ziemski, M, 2012. A practical and rigorous approach for integrating sustainability principles into decision-making processes at minerals processing operations, in Proceedings Life-of-Mine 2012 , pp 233-242 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By J Tickner, Y Van Haarlem, G Roach, D Abernethy, M Smith, J OÆDwyer

The development of novel technologies capable of real-time, high-accuracy, automated analysis of gold, other precious metals and mineralogy, both in ore samples and directly on process streams is reported.X-ray fluorescence (XRF) analysis is widely used for process stream monitoring of base metals. However, detection limits are generally a few parts-per-million (ppm) or larger, precluding the use of this method for monitoring precious metals. Complex interferences with other elements also limit accuracy. An XRF slurry analyser that uses advanced data-analysis techniques to resolve overlapping fluorescence lines, achieving detection limits in the parts-per-billion (ppb) range has been developed. This allows feed, concentrate and tailings streams in precious metal applications to be monitored in real-time. An extended trial of our technology in a platinum group element concentrator and laboratory tests on gold process slurries in the 0.1 - 2.0 ppm concentration range is discussed.Analysis of process stream mineralogy can provide useful information to supplement conventional elemental data. An on-stream X-ray diffraction analysis technique that provide real-time mineral and elemental measurement of process slurry streams has been developed. Both X-ray techniques can be combined into a single on-stream analyser to provide simultaneous elemental and mineralogical information. The successful trial of a combined XRDF (X-ray diffraction and fluorescence) slurry analyser is also reported.It is widely recognised that rapid, accurate analysis of grade is an essential prerequisite for optimising the efficiency of exploration, mining and processing of metals ores. The low grades of precious metals ores, such as gold and the platinum group elements, have led to fire assay becoming the predominant analysis technique. Significant drawbacks of fire assay include long turn-around times, limited absolute accuracy, high costs and requirement for skilled operating staff. For rapid measurement of gold samples, a technique that allows the gold content of large samples to be determined absolutely with high accuracy in less than two minutes using activation with high-energy X-rays has been developed. The method is non-destructive, has detection limits in the low ppb range, is capable of measuring slurries, ground or crushed solids with minimal preparation and can be made fully automatic. Initial results from laboratory trials are presented.CITATION:Roach, G, Abernethy, D, OÆDwyer, J, Smith, M, Tickner, J and Van Haarlem, Y, 2013. Advanced instrumentation for analysis of exploration, mining and process materials, in Proceedings World Gold 2013 , pp 277-282 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By L C. P J Fonteneau, B Godel, E R. Ramanaidou

The Hamersley Province in Western Australia hosts large iron ore deposits. Each deposit displays various iron ore types that were defined on their metallurgical properties, especially in terms of porosity and mineralogy. Conventional porosity and mineralogy information on iron ore types are provided on 2D thin sections using automated image analysis with scanning electron microscopy (SEM)-based techniques combined with chemical analyses. However these techniques cannot accurately quantify the 3D porosity. High-resolution X-ray computed tomography (HRXCT) is a non-destructive technique providing a 3D image of the sample with a resolution close to 0.5 - 0.7 ¦m for samples size of up to few centimetres in length. 3D image analysis using customised algorithms now provide accurate quantitative porosity and mineralogy of iron ore types.CITATION:Fonteneau, L C P J, Godel, B and Ramanaidou, E R, 2013. Application of high-resolution x-ray computed tomography to iron ore characterisation, in Proceedings Iron Ore 2013 , pp 243-250 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By J Joy, A Bye, G V. Kizil

This paper demonstrates an application of a recently developed Risk-Cost-Benefit (RCB) Framework to environmental risk management in the mining industry. The environmental application of the RCB Framework as part of an ACARP project (Kizil, Bye and Joy, 2012) involved a thorough selection process with site visits and in-depth discussions with the case study siteÆs environmental management team. Under their guidance, the highest risk of environmental impact at the case study site was identified as æroad subsidenceÆ at the time when the project work was undertaken. This paper presents the unique application of the RCB Framework to examine the risk of mining-induced subsidence and its impact on one of AustraliaÆs busiest highways, with a traffic volume of 38 000 vehicles per day (NSW RTA AADT, 2008). The RCB Framework was employed to assess the optimum group of controls for road subsidence risk management to ensure highway availability while mining occurs. Whilst this paper focuses on road subsidence, the methodology employed can be directly applied to other environmental concerns including preparation for mine closure, rehabilitation planning and waste management. The RCB Framework incorporates mathematical modules which were developed to enable complex yet tightly integrated RCB calculations. The process integrates the risk-control effectiveness assessment to determine that the selected safety initiative is financially beneficial to the mine site and company. This concept has been applied to a number of high-risk mining areas targeting safety, productivity and environmental issues. This paper introduces the five-staged RCB Framework, incorporating the RCB tools RCBGEN (Risk-Cost-Benefit Generator) and RCEMETHOD (Risk-Control-Effectiveness Method), and demonstrates its practical application to the risk management of a road subsidence case study. The case study looks at potential pavement damages, in particular, the occurrence of pavement stepping on the surface of the highway as a result of vertical subsidence. This type of road damage was previously experienced at another major inter-city route while underground mining occurred in the region where the case study site is located. The RCB Framework has been successfully applied to the analysis of the road subsidence case study and determined the risk reduction and financial benefits of implementing a range of risk-controls. User-friendly RCB Charts to provide an aid for decision-making were produced. The value of using the RCB charts to achieve balance between risk, cost and productivity in the decision-making process for risk management has been explained. The case study determined that pavement slots and fibre-optic cable monitoring were relatively low-cost and effective controls applied in the mining industry for the first time at a global level.This paper supports the industryÆs ongoing efforts to manage risk to ALARP (as low as reasonably practicable) and achieve æzero harmÆ by providing a new Framework to more effectively establish the adequacy of controls.CITATION:Kizil, G V, Bye, A and Joy, J, 2012. Application of risk-cost-benefit analysis to highway subsidence due to mining, in Proceedings Life-of-Mine 2012 , pp 197-206 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By M I. Pownceby, S Bhargava, F Charalambous, S McMaster, R Ram, J Tardio

"A key component of any geometallurgical investigation involves being able to predict element or mineral recoveries from simplified input data such as bulk chemistry and/or mineralogy. This relies on the metallurgist having access to accurate information regarding the chemistry of the ore and gangue minerals as well as the likely impact on processing/extraction caused by the impurities (present either as gangue or as substitutional impurities). In this study the chemical properties of two commercially important uranium minerals, brannerite (U4+Ti2O6), and uraninite (U4+O2), were characterised using X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). Significant levels of impurities were present in both samples with the uranium minerals deviating significantly from their ideal chemical formulae. Differences in chemistry were due to: cationic substitution decay of the uranium isotopes into radiogenic lead and other daughter products mixed uranium oxidation states post-depositional alteration.As well, the brannerite sample showed evidence of significant radiation-induced metamictisation. Leach tests to measure the ease of extraction of uranium from both samples were conducted over a wide range of conditions (temperature, acid concentration and oxidant concentration). For uraninite, the lower U dissolution rates observed in the natural sample compared to a synthetic UO2 sample were directly attributed to the presence of impurities. For brannerite, significant metamictisation of the natural sample led to enhanced U extraction rates compared to a heat treated fully crystalline sample. This study highlights the importance of detailed mineralogical characterisation studies in any uranium process mineralogy investigation as the compositional, textural and microstructural aspects of the main uranium phases present will likely play an important role in any process to extract uranium.CITATION:Ram, R, Charalambous, F, McMaster, S, Pownceby, M I, Tardio, J and Bhargava, S, 2013. Chemical and microstructural characterisation studies on naturally occurring uranium minerals - implications for processing, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013, pp 325-334 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 29, 2013

By Medhurst TP, Trueman R, Hutchinson IN

A breaker line support (BLS) monitoring system, BLSmon, has been designed and constructed by the CSIRO and installed and commissioned at Laleham No.] Colliery, Queensland. This system was designed to record hydraulic leg pressure and canopy position measurements and relay these, in real time, to the surface. The system has shown itself to be capable of operating on the BLSs without any adverse affect on production. Analysis of the results of the monitoring exercise has shown that rate of change of leg pressures on the BLSs could be used as an aid in the prediction of adverse mining conditions. Under favourable mining conditions the supports were observed to initially unload from the set pressure, this unloading reduced with time and by the end of a typical lift cycle had either ceased or reversed slightly. This behaviour was considered to be due to one of four possible causes, these being; the compaction of floor debris, and/or compaction of the floor, and/or crushing of the roof and /or support creep. The actual cause can only be determined through detailed monitoring of both roof and support convergence. However observational data would suggest that compaction of debris and softened floor material beneath the supports was the most likely cause. The few positive loading rates recorded under these conditions were of short duration and occurred towards the end of individual lifts. Where mining conditions were unfavourable the negative rates of change of pressure, unloading of the support, were reduced throughout a lift, in both duration and magnitude, when compared with favourable mining conditions. Over the same period the positive rates of change were observed to be greater. The rate of change of loading and convergence can be utilised to identify the onset of instability in the lift area. However, before this facility can be utilised by the mine for the reliable prediction of instability more monitored data and sophisticated processing techniques are required.

Jan 1, 1992

By W. J. LANGRON

This paper describes the results of VLF-EM test surveys, using the Ronka EM-16 equipment, over a selection of environments in Australia and Papua.Using comparisons with known geology, drilling information and other geophysical work it is shown that the maximum depth of penetration of the method is about 100 ft but is considerably less than this in most areas.The author believes the method could aid in geological mapping and provide a useful adjunct to aeromagnetic surveying in some areas.

Jan 1, 1972

By S Hapugoda, J R. Manuel, M J. Peterson, A Poliakov, E Donskoi

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Aug 12, 2013

By J D. Illescas, S N. Arnold, D R. Shaw

Ion exchange (IX) as a primary production technique has been applied commercially since the 1950s; its application in the uranium industry continues to be widespread and is utilised to a lesser degree in the gold industry. The majority of ion exchange applications, outside of gold and uranium, have primarily been for secondary metal recovery and impurity removal. Newer developments in the application of ion exchange, as well as changes in regulatory requirements, are bringing about the wider use of ion exchange as a primary production technique not only for high value metals such as uranium, platinum group metals (PGM), refractory metals and rare earths, but also looking at base metals such as nickel and copper. The ability to build lower-cost, safer, less polluting processing plants with smaller footprints is driving a greater interest in IX, with the main competitors remaining solvent extraction and carbon-in-pulp/leach. This paper discusses a number of areas where IX has been applied and its advantages compared with other techniques.CITATION:Shaw, D R, Arnold, S N and Illescas, J D, 2012. Ion exchange in hydrometallurgy - Secondary metal removal or primary production technique?, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 17-22 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By J S. J van Deventer

"Conventional wisdom is that gold not assayable is not recoverable or does not exist. There has been no formal study on the possibility that gold assays using advanced spectroscopy such as mass spectrometry and neutron activation could grossly underestimate the gold recoverable by proprietary extraction techniques. Such gold is not considered here to be æinvisibleÆ to detection but rather æabnormalÆ or ædistortedÆ at atomic level. Large-scale extraction of gold from æabnormalÆ ores has not been demonstrated, hence this emerging field still lacks credibility and acceptance. For fear of harming their reputation, few academic researchers or companies are expected to venture into this field until it is well proven. This paper aims to create awareness amongst metallurgists of the potential of æabnormalÆ gold ores by reviewing unconventional observations, the pseudoscience mainly available in non-peer reviewed web sites, and hypotheses for the recovery of ænon-assayableÆ gold, including: the occurrence of high levels of nano-sized gold in clays detectable by high-precision analytical instruments, which represents æinvisibleÆ gold accounts of ambient transmutation of elements, mainly using thermal methods orbitally rearranged monoatomic elements (ORMEs), which are virtually undetectable by conventional means, and their conversion to normal metals the possibility of a æhigh spinÆ state of transition metals the formation of microclusters altering the chemical behaviour of gold and the possibility of clustering with other elements. It is suggested here that gold in ores displays a range of clustering, from ænormalÆ gold amenable to conventional extraction to the ORME state. The concepts of æintermolecular waterÆ in forming complex salts locking up precious metals, electro-dissolution in strong acids, and electrowinning at both the anode and cathode are discussed as a means of treating æabnormalÆ gold ores. It is also possible that the gas phase extraction of gold chlorides under controlled temperature and pressure conditions, as well as transferred-arc plasma fuming of gold through carbothermic reduction of sulfides, could be used as a basis for extraction of gold from æabnormalÆ ores.CITATION:van Deventer, J S J, 2013. Is there gold that we do not recognise?, in Proceedings World Gold 2013, pp 27-34 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 26, 2013

By S Vink, A Wolhuter

Increasingly the community and government regulators are calling for æzero dischargeÆ mines. Some mining companies are beginning to explore ways in which they can transition to zero discharge. When striving to attain zero discharge, mines must consider multiple variables in addition to water quantity. These include climate regime, water quality and regional water budgets. This paper explores the drivers behind the concept of zero discharge mines and will use examples to illustrate the feasibility of attaining this goal.CITATION:Wolhuter, A and Vink, S, 2013. Is zero discharge a viable or useful concept in mine water management?, in Proceedings Water in Mining 2013 , pp 329-334 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By B Dodd

This paper details how the Australian Securities and Investments Commission (ASIC), as a disclosure and conduct regulator, approaches regulation of continuous disclosure, capital raising and control transactions in the mining and resources sector, and the reasons for the approach. In examining this topic the paper considers the Joint Ore Reserves Committee (JORC) Code (JORC, 2004), the VALMIN Code (VALMIN Committee, 2005), the relevant ASX Listing Rules and the relevant provisions of the Corporations Act 2001 (Corporations Act). This paper discusses ASICÆs approach to expert reports and disclosure with reference to Regulatory Guides 111 Content of expert reports and 170 Prospective financial information.CITATION:Dodd, B, 2012. Issues in capital raisings and disclosure, in Proceedings International Mine Management 2012, pp 3-14 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 20, 2012

By G Lane, M Bueno

In a recent publication (Bueno and Lane, 2011) the authors presented the analysis of a consolidated dataset composed by 137 autogenous/semi-autogenous grinding (AG/SAG) mill pilot trials. By comparing the measured data against theoretical specific energy consumption, the analysis indicated which circuit configurations were more or less energy efficient. However, the analysis has also indicated that the energy efficiency of each of the types of circuits vary significantly.There are numerous factors that contribute to the variations of energy efficiency of AG/SAG mill-based circuits, such as feed size distribution, recycle ratios and ore characteristics. In view of this, the present work accesses these factors individually and discusses what may lead a particular circuit configuration to be more or less efficient in terms of energy and costs.CITATION:Bueno, M and Lane, G, 2012. Key drivers of energy and cost efficiency in autogenous/semi-autogenous grinding circuits, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 113-118 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By P Holtham, R Dunne, D Stoll

Flash flotation is a process designed to remove coarse, liberated, fast floating minerals from hydrocyclone underflow. Irrespective of liberation, coarse particles would normally remain in a grinding circuit until they are reground fine enough to report to the hydrocyclone overflow. Additionally, minerals of high density also report to hydrocyclone underflow despite being fine in size and/or liberated because hydrocyclones separate on the characteristics of both particle size and density. Dense particles continually reporting to the hydrocyclone underflow can lead to over-grinding and the production of ultra fine particles. These particles exhibit slow flotation kinetics and thus are difficult to float in conventional flotation circuits. Therefore, removing coarse, liberated particles from the hydrocylcone underflow by flash flotation has the potential to improve recovery and can improve dewatering unit operations and reduce grinding costs.The impact on the overall performance of the flotation circuit by removing coarse, fast floating minerals prior to conventional flotation is not well understood. Ultimately, predicting the overall recovery improvement provides the justification for the installation of a flash flotation cell within the milling circuit. This paper will describe attempts to estimate flash flotation recovery improvements to the overall circuit using kinetic data from simplified batch cell flotation tests combined with limn-based modelling techniques.CITATION:Stoll, D, Dunne, R and Holtham, P, 2012. Modelling the impact of flash flotation from batch cell flotation tests using limn, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 179-184 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

Increasing demands on quality of metallurgical grade alumina and for lower production costs led to the development of a new fluid bed calcining process. The process, jointly developed in Germany by Vereinigte Aluminium Werke A. G. and Lurgi Gesellschaften m.b.H., takes advantage of modern chemical engineering methods such as counter-current flow of combustion air and solids, direct heat-exchange between combustion air and fine solids, and near stoichiometric combustion of oil in a fluid bed. Using a two-stage Venturi-type suspension preheater for heat-recovery from combustion flue-gases, the circulating fluid bed technique with internal oil combustion at 220°F for the calcining step and a five-stage fluidized bed cooler for heat-recovery from calcines, the process gives an outstanding heat-efficiency. In a first industrial plant for 560 sh. tons/day of alumina heat consumption figures of less than 1·400 B.T.U./lb Al203 g were achieved.

Jan 1, 1972

By R Kerrich

Early-Archaean (3.26 Ga) volcanogenic massive sulphide (VMS) deposits located within the low strain and sub-prehnite-pumpellyite metamorphic-grade Strelley greenstone belt, East Pilbara, Western Australia, contain exceptionally well preserved sulphide textures which are directly analogous to those of sulphide chimneys formed by black smokers at present day submarine hydrothermal vents. The VMS deposits are associated with seafloor alteration zones in and below silica-carbonate laminites, at the top of tholeiitic to calc-alkaline intermediate and felsic rocks. VMS mineralisation comprises stratabound Zn-rich sulphide lenses with significant Cu and barite, and variable Pb and Ag, above Cu-rich stringer zones, all of which are similar to Phanerozoic polymetallic or Kuroko VMS deposits. Sulphide-sulphate mineralisation implicates hydrothermal discharge into sulphate-bearing ocean waters, ruling out a globally anoxic Archaean hydrosphere. The volcanic rocks and co-magmatic sub-volcanic intrusion hosting the VMS deposits are characterised by the conjunction of LILE>LREE>HREE, and Phanerozoic La/Yb with negative normalised anomalies of Nb, P and Ti, consistent with derivation via subduction zone hydrous metasomatism fusing the mantle lithosphere.

Jan 1, 1995

Gallium occurs at above background levels in most samples collected from 11 of the major geothermal areas in the Taupo Volcanic Zone. Concentrations of Ga in the 48 samples ranged from 8 to 144 mg kg-1 and varies widely from place to place within each geothermal area. Gallium is contained within the alumino-silicate structure of clay in the mud, having substituted mainly for Al. Suggested deposition mechanisms for Ga also involve co-precipitation with Sb, As, and SiO2 colloids. Digestion trials, carried out to determine extraction conditions for possible commercial exploitation, showed that heating the mud to 500 - 600¦C for 1 hour followed by acid/alkali treatment gave complete recoveries.

Jan 1, 1995

The Hall-Heroult process is likely to be the dominant method of aluminium production for the remainder of the century. The characteristics of the operation of a modern smelter are described and attention drawn to their disabilities which are due chiefly to the small production capacity of individual cells.The principal components of the Hall-Heroult cell- the electrolyte, the anode and the cathodes are discussed in order to identify the problems of scale-up. The factors influencing current efficiency and energy consumption are analysed and lead to the conclusion that the greatest potential for energy saving lies in reducing the anode to cathode distance (ACD).The most promising direction for major change is in the application of a new titanium diboride-carbon composite for coating of the surface of the cathode carbon. It improves the wetting of the carbon by aluminium and should permit the use of sloping cathodes and anodes. The deep metal pad would thereby be eliminated and, in the absence of magnetic perturbations, the ACD could be substantially decreased.

Jan 1, 1987